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RESEARCH PAPER · Inorganic Chemistry · 2019

HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate System

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HBa2.5(IO3)6(I2O5) and HBa(IO3)(I4O11): Explorations of Second-Order Nonlinear Optical Materials in the Alkali-Earth Polyiodate SystemOriginal(H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer19Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity19LiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution68REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62A new iodate-phosphate Pb 2 (IO 3 )(PO 4 ) achieving great improvement in birefringence activated by (IO 3 ) − groups53Bi 4 O(I 3 O 10 )(IO 3 ) 3 (SeO 4 ): trimeric condensation of IO 4 3− monomers into the I 3 O 10 5− polymeric anion observed in a three-component mixed-anion NLO material20K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions46Ba(IO3)F: An Alkaline-Earth-Metal Iodate Fluoride Crystal with Large Band Gap and Birefringence24From Ag2Zr(IO3)6 to LaZr(IO3)5F2: A Case of Constructing Wide‐band‐gap Birefringent Materials through Chemical Cosubstitution11The first actinide polyiodate: a complex multifunctional compound with promising X-ray luminescence properties and proton conductivity17Two bismuth iodate sulfates with enhanced optical anisotropy17Titanium Iodates with a Second-Harmonic-Generation Response8High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies324[ o ‐C 5 H 4 NHOH] 2 [I 7 O 18 (OH)]⋅3 H 2 O: An Organic–Inorganic Hybrid SHG Material Featuring an [I 7 O 18 (OH)] Branched Polyiodate Chain86[o‐C5H4NHOH]2[I7O18(OH)]⋅3 H2O: An Organic–Inorganic Hybrid SHG Material Featuring an [I7O18(OH)] Branched Polyiodate Chain21Hydrothermal Synthesis of New Iodates Ln2(IO3)3(IO4) (Ln = La, Nd, Pr) Containing the Tetraoxoiodate(V) Anion: Creation of Luminescence Properties by Doping with Eu, Dy, and Tb5The Role of Acidity in the Synthesis of Novel Uranyl Selenate and Selenite Compounds and Their Structures2A new I 3 O 9 3− group constructed from IO 3 − and IO 5 5− anion units in Cs 3 [Ga 2 O(I 3 O 9 )(IO 3 ) 4 (HIO 3 )]4M4O(IO3)3(I3O7F3)BF4 (M = Pb, Sr): Promising Nonlinear Optical Materials Featuring the Unprecedented Windmill-Shaped [I3O7F3]2– Polyfluoroiodate Anion12K6(IO6H4)(HI2O6)(HIO3)2(IO3)4·2H2O: A Case of Iodate with Coexisting [I5+O3] and [I7+O6] Units6Ba 4 Ag 5 (IO 3 ) 6 (I 3 O 8 ) 3 (I 4 O 11 ) 2 : a nonlinear optical crystal containing two types of polyiodate anions16BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups2Cd 2 (IO 3 )(PO 4 ) and Cd 1.62 Mg 0.38 (IO 3 )(PO 4 ): metal iodate-phosphates with large SHG responses and wide band gaps28Centrosymmetric Rb[Te 2 O 4 (OH) 5 ] and noncentrosymmetric K 2 [Te 3 O 8 (OH) 4 ]: metal tellurates with corner and edge-sharing (Te 4 O 18 ) 12− anion groups8Pressure-induced phase transition and increase of oxygen-iodine coordination in magnesium iodate16General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates15NH4IO2F2 and (NH4)3(IO2F2)3·H2O: A Series of Ammonium-Containing Fluoroiodates with Wide Band Gaps12Two New Rb3Sc(IO3)6 Polytypes in Proposed Nonlinear Optical Family A3M(IO3)6 (A = K, Rb; M = Sc, In): Topology–Symmetry Analysis, Order–Disorder and Structure–Properties Relation9C(NH2)3Rb(I3O8)(IO3)(I2O6H2): An unprecedented organic–inorganic hybrid polyiodate with two different polyiodate groups13[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology20New layered nonlinear optical iodate Cs 3 Ta(IO 3 ) 8 : topology-symmetry analysis and structure prediction6Noncentrosymmetric γ-Cs2I4O11 Obtained from IO4 Polyhedral Rearrangements in the Centrosymmetric β-Phase16A review on the advancements in the characterization of the high-pressure properties of iodates44Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions20(NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence22A survey of stereoactive oxysalts for linear and nonlinear optical applications40Synthesis and Structure of a New Iodate Cs5[Sc2(IO3)9](IO3)2 with a Complex Framework Based on the Condensation of [Sc(IO3)6] Building Blocks4NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure3NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure0[(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect60Novel cesium cerium( iv ) iodate Cs 2 Ce(IO 3 ) 6 : hydrothermal synthesis, crystal structures and thermal stability2Diversity of [M(IO3)6] Building Blocks in Iodate Families and the New Trigonal Polymorph of Cs2HIn(IO3)64Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)60Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates13Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching19Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching0Negative linear compressibility and phonon softening in Mg ( IO 3 ) 2 under pressure1Hydrogen-Bond-Directed Assembly of Polyanionic Cluster [Mo 2 O 5 (IO 3 ) 4 ] 2– for Nonlinear Optical Crystal Design0

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  1. (H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer

    Chemical Communications · 2019-01-01

    Fei‐Fei Mao, Chun‐Li Hu, Jin Chen, Ru‐Ling Tang, Bao-Lin Wu, Jiang‐Gao Mao

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  2. Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity

    Dalton Transactions · 2019-01-01

    Yanjun Li, Dan Zhang, Lili Liu, Weiguo Zhang, Jiang Zhang, Ye Cong, Xuanke Li, P. Shiv Halasyamani

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  3. LiMg(IO 3 ) 3 : an excellent SHG material designed by single-site aliovalent substitution

    Chemical Science · 2019-01-01

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Xiaohan Zhang, Bing‐Ping Yang, Jiang‐Gao Mao

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  4. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie International Edition · 2019-06-18

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiao‐Han Zhang, Jiang‐Gao Mao

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  5. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie · 2019-06-18

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiaohan Zhang, Jiang‐Gao Mao

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  6. A new iodate-phosphate Pb 2 (IO 3 )(PO 4 ) achieving great improvement in birefringence activated by (IO 3 ) − groups

    Chemical Communications · 2019-12-04

    Xiaohan Zhang, Bing‐Ping Yang, Jin Chen, Chun‐Li Hu, Zhi Gang Fang, Zujian Wang, Jiang‐Gao Mao

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  7. Bi 4 O(I 3 O 10 )(IO 3 ) 3 (SeO 4 ): trimeric condensation of IO 4 3− monomers into the I 3 O 10 5− polymeric anion observed in a three-component mixed-anion NLO material

    Dalton Transactions · 2020-01-01

    Fei‐Fei Mao, Jinyu Hu, Bingxuan Li, Hua Wu

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  8. K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions

    Chemistry of Materials · 2020-04-02

    Tushagu Abudouwufu, Min Zhang, Shichao Cheng, Hao Zeng, Zhihua Yang, Shilie Pan

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  9. Ba(IO3)F: An Alkaline-Earth-Metal Iodate Fluoride Crystal with Large Band Gap and Birefringence

    Inorganic Chemistry · 2020-05-13

    Huixin Fan, Guang Peng, Chensheng Lin, Kaichuang Chen, Shunda Yang, Ning Ye

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  10. From Ag2Zr(IO3)6 to LaZr(IO3)5F2: A Case of Constructing Wide‐band‐gap Birefringent Materials through Chemical Cosubstitution

    Chemistry - An Asian Journal · 2020-09-25

    Fei‐Fei Mao, Jiadi Liu, Jinyu Hu, Hua Wu

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  11. The first actinide polyiodate: a complex multifunctional compound with promising X-ray luminescence properties and proton conductivity

    Chemical Communications · 2020-12-17

    Gabriel L. Murphy, Yaxing Wang, Philip Kegler, Yumin Wang, Shuao Wang, Evgeny V. Alekseev

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  12. Two bismuth iodate sulfates with enhanced optical anisotropy

    Dalton Transactions · 2021-01-01

    Yilin Li, Chun‐Li Hu, Jin Chen, Jiang‐Gao Mao

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  13. Titanium Iodates with a Second-Harmonic-Generation Response

    Inorganic Chemistry · 2021-03-29

    Yuan‐Bin Fang, Ruibiao Fu, Hong‐Xin Tang, Qirui Shui, Zuju Ma, Xintao Wu

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  14. High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies

    Accounts of Chemical Research · 2021-05-27

    Jin Chen, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  15. [ o ‐C 5 H 4 NHOH] 2 [I 7 O 18 (OH)]⋅3 H 2 O: An Organic–Inorganic Hybrid SHG Material Featuring an [I 7 O 18 (OH)] Branched Polyiodate Chain

    Angewandte Chemie International Edition · 2021-05-31

    Qian‐Qian Chen, Chun‐Li Hu, Jin Chen, Yilin Li, Bingxuan Li, Jiang‐Gao Mao

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  16. [o‐C5H4NHOH]2[I7O18(OH)]⋅3 H2O: An Organic–Inorganic Hybrid SHG Material Featuring an [I7O18(OH)] Branched Polyiodate Chain

    Angewandte Chemie · 2021-06-01

    Qian‐Qian Chen, Chun‐Li Hu, Jin Chen, Yilin Li, Bingxuan Li, Jiang‐Gao Mao

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  17. Hydrothermal Synthesis of New Iodates Ln2(IO3)3(IO4) (Ln = La, Nd, Pr) Containing the Tetraoxoiodate(V) Anion: Creation of Luminescence Properties by Doping with Eu, Dy, and Tb

    Crystal Growth & Design · 2021-07-15

    Ceren Kütahyalı Aslani, Vladislav V. Klepov, Mahmoud A. A. Aslani, Hans‐Conrad zur Loye

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  18. The Role of Acidity in the Synthesis of Novel Uranyl Selenate and Selenite Compounds and Their Structures

    Crystals · 2021-08-16

    Gabriel L. Murphy, Philip Kegler, Eike M. Langer, Evgeny V. Alekseev

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  19. A new I 3 O 9 3− group constructed from IO 3 − and IO 5 5− anion units in Cs 3 [Ga 2 O(I 3 O 9 )(IO 3 ) 4 (HIO 3 )]

    CrystEngComm · 2021-11-11

    Dandan Wang, Xiaoqing Jiang, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  20. M4O(IO3)3(I3O7F3)BF4 (M = Pb, Sr): Promising Nonlinear Optical Materials Featuring the Unprecedented Windmill-Shaped [I3O7F3]2– Polyfluoroiodate Anion

    Crystal Growth & Design · 2021-11-18

    Yiyi Xu, Yuqiao Zhou, Chensheng Lin, Bingxuan Li, Xia Hao, Ning Ye, Min Luo

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  21. K6(IO6H4)(HI2O6)(HIO3)2(IO3)4·2H2O: A Case of Iodate with Coexisting [I5+O3] and [I7+O6] Units

    Inorganic Chemistry · 2021-12-17

    Jun Sun, Tushagu Abudouwufu, Congcong Jin, Zhiyong Guo, Min Zhang

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  22. Ba 4 Ag 5 (IO 3 ) 6 (I 3 O 8 ) 3 (I 4 O 11 ) 2 : a nonlinear optical crystal containing two types of polyiodate anions

    Inorganic Chemistry Frontiers · 2022-01-01

    Jin Chen, Qianqian Chen, Fei‐Fei Mao, Zhen Liu, Bingxuan Li, Xiaohui Wu, Ke‐Zhao Du

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  23. BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups

    New Journal of Chemistry · 2022-01-01

    Wenjuan Ma, Jianlong Huang, Bin Dai, Feng Yu

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  24. Cd 2 (IO 3 )(PO 4 ) and Cd 1.62 Mg 0.38 (IO 3 )(PO 4 ): metal iodate-phosphates with large SHG responses and wide band gaps

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    Qianqian Chen, Chun‐Li Hu, Li-Jia Yao, Jin Chen, Ming‐Yang Cao, Bingxuan Li, Jiang‐Gao Mao

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  25. Centrosymmetric Rb[Te 2 O 4 (OH) 5 ] and noncentrosymmetric K 2 [Te 3 O 8 (OH) 4 ]: metal tellurates with corner and edge-sharing (Te 4 O 18 ) 12− anion groups

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    Dandan Wang, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  26. Pressure-induced phase transition and increase of oxygen-iodine coordination in magnesium iodate

    Physical review. B./Physical review. B · 2022-02-17

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  27. General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates

    Physical Review Materials · 2022-04-28

    Akun Liang, Robin Turnbull, Plácida Rodríguez-Hernández, Alfonso Muñoz, M. Jasmin, Lan-Ting Shi, Daniel Errandonea

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  28. NH4IO2F2 and (NH4)3(IO2F2)3·H2O: A Series of Ammonium-Containing Fluoroiodates with Wide Band Gaps

    Inorganic Chemistry · 2022-07-21

    Jianlong Huang, Fengjiao Guo, Zhiyong Guo, Jianbang Chen, Bin Dai, Feng Yu

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  29. Two New Rb3Sc(IO3)6 Polytypes in Proposed Nonlinear Optical Family A3M(IO3)6 (A = K, Rb; M = Sc, In): Topology–Symmetry Analysis, Order–Disorder and Structure–Properties Relation

    Symmetry · 2022-08-16

    Olga Reutova, Elena L. Belokoneva, Anatoly S. Volkov, Olga V. Dimitrova, Sergey Yu. Stefanovich

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  30. C(NH2)3Rb(I3O8)(IO3)(I2O6H2): An unprecedented organic–inorganic hybrid polyiodate with two different polyiodate groups

    Journal of Solid State Chemistry · 2022-08-28

    Dong Yan, Yao Ma, Ru‐Ling Tang, Liang Hu, Fei‐Fei Mao, Jie Zheng, Xiu‐Du Zhang, Shu‐Fang Li

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  31. [M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology

    Inorganic Chemistry Frontiers · 2023-01-01

    Qianqian Chen, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

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  32. New layered nonlinear optical iodate Cs 3 Ta(IO 3 ) 8 : topology-symmetry analysis and structure prediction

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  33. Noncentrosymmetric γ-Cs2I4O11 Obtained from IO4 Polyhedral Rearrangements in the Centrosymmetric β-Phase

    Inorganic Chemistry · 2023-01-30

    Mingli Liang, Matthew R. Lacroix, Ce Tao, Michael J. Waters, James M. Rondinelli, P. Shiv Halasyamani

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  34. A review on the advancements in the characterization of the high-pressure properties of iodates

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  35. Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions

    ACS Materials Letters · 2023-05-08

    Jiale Chen, Pengcheng Yang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  36. (NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence

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  37. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  38. Synthesis and Structure of a New Iodate Cs5[Sc2(IO3)9](IO3)2 with a Complex Framework Based on the Condensation of [Sc(IO3)6] Building Blocks

    Symmetry · 2023-09-17

    Olga Reutova, Elena L. Belokoneva, Anatoly S. Volkov, Olga V. Dimitrova

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  39. NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure

    Russian Journal of Inorganic Chemistry · 2023-11-01

    Oksana P. Grigorieva, Sergey Yu. Stefanovich, Dmitri O. Charkin, В. А. Долгих, Konstantin A. Lysenko

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  40. NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure

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  41. [(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect

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  42. Novel cesium cerium( iv ) iodate Cs 2 Ce(IO 3 ) 6 : hydrothermal synthesis, crystal structures and thermal stability

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  43. Diversity of [M(IO3)6] Building Blocks in Iodate Families and the New Trigonal Polymorph of Cs2HIn(IO3)6

    Crystallography Reports · 2024-08-01

    Olga Reutova, Elena L. Belokoneva, Anatoly S. Volkov, Olga V. Dimitrova

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  44. Diversity of fundamental building blocks [M(IO3)6] in iodate families and new trigonal polymorph of Cs2HIn(IO3)6

    Кристаллография · 2024-09-25

    Olga Reutova, Elena L. Belokoneva, Anatoly S. Volkov, Olga V. Dimitrova

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  45. Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates

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  46. Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching

    Angewandte Chemie International Edition · 2025-03-31

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  47. Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching

    Angewandte Chemie · 2025-03-31

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  48. Negative linear compressibility and phonon softening in Mg ( IO 3 ) 2 under pressure

    Physical review. B./Physical review. B · 2025-12-16

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  49. Hydrogen-Bond-Directed Assembly of Polyanionic Cluster [Mo 2 O 5 (IO 3 ) 4 ] 2– for Nonlinear Optical Crystal Design

    Inorganic Chemistry · 2026-07-07

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