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RESEARCH PAPER · Dalton Transactions · 2017

Experimental and theoretical studies on the NLO properties of two quaternary non-centrosymmetric chalcogenides: BaAg 2 GeS 4 and BaAg 2 SnS 4

Hong Chen, Pei-Fei Liu, Bingxuan Li, Hua Lin, Li‐Ming Wu, Xin‐Tao Wu

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Experimental and theoretical studies on the NLO properties of two quaternary non-centrosymmetric chalcogenides: BaAg 2 GeS 4 and BaAg 2 SnS 4OriginalEffect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)63Synthesis and characterization of multifunctional homochiral 1-D aminoacetic acid potassium metal organic framework7Ternary Mixed-Metal Cd4GeS6: Remarkable Nonlinear-Optical Properties Based on a Tetrahedral-Stacking Framework41Cu2EuMQ4 (M = Si, Ge; Q = S, Se): Syntheses, structure study and physical properties determination26A 2 SrM IV S 4 (A = Li, Na; M IV = Ge, Sn) concurrently exhibiting wide bandgaps and good nonlinear optical responses as new potential infrared nonlinear optical materials78Centric-to-acentric structure transformation induced by a stereochemically active lone pair: a new insight for design of IR nonlinear optical materials90Rational design of a new chalcogenide with good infrared nonlinear optical performance: SrZnSnS 452Super-broadband hybrid mid-infrared laser systems3Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey48Verification of an integral figure of merit for mid-IR nonlinear crystals13Solvothermal syntheses, characterizations and semiconducting properties of four quaternary thioargentates Ba2AgInS4, Ba3Ag2Sn2S8, BaAg2MS4 (M = Sn, Ge)21Solvothermal Syntheses and Characterizations of Four Quaternary Copper Sulfides BaCu3MS4 (M = In, Ga) and BaCu2MS4 (M = Sn, Ge)27A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystals48Rational design of infrared nonlinear optical chalcogenides by chemical substitution287A review of the AI2B II C IV DVI4 family as infrared nonlinear optical materials: the effect of each site on the structure and optical properties59Ab Initio Calculations of Structural, Mechanic, Electronic and Optical Properties of Ag2BaSn(Se, S)4 in Kesterite Structure1Coordinated regulation on critical physiochemical performances activated from mixed tetrahedral anionic ligands in new series of Sr 6 A 4 M 4 S 16 (A = Ag, Cu; M = Ge, Sn) nonlinear optical materials28Infrared Nonlinear Optical Polymorphs α- and β-SrCu 2 SnS 4 Exhibiting Large Second Harmonic Generation Responses with Requisite Phase-Matching Behavior44One-Dimensional Double Chains in Sodium-Based Quaternary Chalcogenides Displaying Intriguing Red Emission and Large Optical Anisotropy17An assessment of the structural, electronic, optical and thermoelectric properties of the BaAg2GeS4 compound11Mild solvothermal syntheses and characterizations of two layered sulfides Ba2Cu2Cd2S5 and Ba3Cu4Hg4S915Cd4SiQ6 (Q = S, Se): Ternary Infrared Nonlinear Optical Materials with Mixed Functional Building Motifs21Mild solvothermal syntheses and characterizations of four quaternary layered sulfides AAgCdS2 (A = K, Rb, Cs) and Cs2Cu2Cd2S413NLO response as a function of structural water presence: A comparative experimental (UV-vis) and DFT (structural, NPA, MEP) study on Cs2Ni(SeO4)2•4H2O and Cs2Ni(SeO4)220Effect of Pb Substitution in Sr2-xPbxGeSe4 on Crystal Structures and Nonlinear Optical Properties Predicted by DFT Calculations17Synthesis, crystal structure, and electronic structure of Li2PbSiS4: a quaternary thiosilicate with a compressed chalcopyrite-like structure4Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials47New nonlinear optical-active AAgGa 6 S 10 (A = K, Rb, Cs) featuring {[AgGa 6 S 10 ] − } ∞ framework and high laser damage threshold42Temperature controlling valance changes of crystalline thioarsenates and thioantimonates21Inorganic Chalcogenides: From Zero‐Dimensional Clusters to Three‐Dimensional Frameworks5Synthesis, Spectroscopic, Conceptual DFT Characterization and Molecular Docking Studies of Two Versatile di-Bromobenzaldehyde Derived Compounds3Synthesis, spectroscopic characterization and in-silico bio-activity studies of (E)-4,6-dibromo-2-[(2-bromo-4-methylphenylimino)methyl]-3-methoxyphenol2Structural, Optical, and Electronic Properties of Two Quaternary Chalcogenide Semiconductors: Ag2SrSiS4 and Ag2SrGeS420Triclinic Layered A2ZnSi3S8 (A = Rb and Cs) with Large Optical Anisotropy and Systematic Research on the Inherent Structure–Performance Relationship in the A2MIIBMIV3Q8 Family11Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials184AAg 2 PS 4 (A = K, Na/K): the first-type of noncentrosymmetric alkali metal Ag-based thiophosphates exhibiting excellent second-order nonlinear optical performances21AAg 3 Ga 8 Se 14 (A = Rb, Cs): second-harmonic generation responses realized through the parallel arrangement of AgSe 4 and GaSe 4 tetrahedrons5DFT study of alkali and alkaline earth metal-doped benzocryptand with remarkable NLO properties67Five coordinated Mn in Ba 4 Mn 2 Si 2 Te 9 : synthesis, crystal structure, physical properties, and electronic structure10KAg3Ga8S14: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold※3Ba6(CuxZy)Sn4S16 (Z = Mg, Mn, Zn, Cd, In, Bi, Sn): High Chemical Flexibility Resulting in Good Nonlinear-Optical Properties12BaSi7P10 and SrSi7P10: Two Infrared Nonlinear Optical Phosphides with T2 Supertetrahedra Exhibiting Strong Second‐Harmonic Generation Effects22Temperature effect on potassium nitrate-tricine nanoparticles synthesis to enhance third order optical nonlinearity2A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications115Structural study, Oxytetracycline electrochemical sensing property and molecular docking analysis of a novel synthesized non-centrosymmetric hybrid compound, (C9H11N2O5)2(NO3)23(Na0.74Ag1.26)BaSnS4: A New AgGaS2‐Type Nonlinear Optical Sulfide with a Wide Band Gap and High Laser Induced Damage Threshold14Ag-based chalcogenides and derivatives as promising infrared nonlinear optical materials90Na 2 Ba[Na 2 Sn 2 S 7 ]: Structural Tolerance Factor‐Guided NLO Performance Improvement50Na2Ba[Na2Sn2S7]: Structural Tolerance Factor‐Guided NLO Performance Improvement0Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization133BaCu2SiS4: A New Member of the AIIBI2MIVQ4 Chalcogenide Family with a Chiral Crystal Structure6Nonlinear optical response of facially polarized all cis-1,3,5-trifluorocyclohexane doped with transition metals and calcium2Flexible Anionic Groups‐Activated Structure Dissymmetry for Strong Nonlinearity in Ln 2 Ae 3 M IV 3 S 12 Family16Temperature-dependent interatomic force constants and phonon coherent resonance contribution in quaternary non-centrosymmetric chalcogenides BaAg2SnSe49Multi-step cation substitution facilitating the exploration of potential infrared nonlinear optical materials6Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70Infrared nonlinear optical materials with multiple strongly ionic cations5Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Ag 2 GeS 3 : A Diamond‐Like Chalcogenide as an IR Nonlinear Optical Material with Outstanding Second‐Harmonic Generation Response28Exploring the influence of fused heterocyclic donor moieties on optical nonlinearity of styrylthiophene based chromophores: A DFT study4Large Mid-Infrared Second-Harmonic Generation in Eu(II)-Based Quaternary Chalcogenides19The electronic, optical and transport properties of BaAgMF (M = Se, Te) quaternary chalcogenides: a systematic first-principles study3Five Transition Metal-Mixed Germanium Chalcogenide Materials: Solvothermal Syntheses, Crystal Structures, Photoelectric Response Properties, and Ion-Exchange Properties3Non-centrosymmetric Y3FeGaSe7 and Y3Mn0·5SiSe7 with extremely low thermal conductivities2Mild solvothermal syntheses, crystal structures, characterizations and properties of four ternary alkaline earth metal sulfides1Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties6[La3Br][GeS4]2: Cationic-Moiety-Guided Strategy Enables Record Birefringence and Broad Optical Window0

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  1. Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)

    Inorganic Chemistry · 2018-03-06

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  2. Synthesis and characterization of multifunctional homochiral 1-D aminoacetic acid potassium metal organic framework

    Journal of Organometallic Chemistry · 2018-04-26

    Vadivel Sasikala, Anna Lakshmi Muppidathi, Kalyana Sundar Jeyaperumal, Anbarasu Selvaraj

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  3. Ternary Mixed-Metal Cd4GeS6: Remarkable Nonlinear-Optical Properties Based on a Tetrahedral-Stacking Framework

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  4. Cu2EuMQ4 (M = Si, Ge; Q = S, Se): Syntheses, structure study and physical properties determination

    Journal of Solid State Chemistry · 2018-09-25

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  5. A 2 SrM IV S 4 (A = Li, Na; M IV = Ge, Sn) concurrently exhibiting wide bandgaps and good nonlinear optical responses as new potential infrared nonlinear optical materials

    Chemical Science · 2019-01-01

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  6. Centric-to-acentric structure transformation induced by a stereochemically active lone pair: a new insight for design of IR nonlinear optical materials

    Journal of Materials Chemistry C · 2019-01-01

    Hua Lin, Yanyan Li, Mengyue Li, Zuju Ma, Li‐Ming Wu, Xintao Wu, Qi‐Long Zhu

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  7. Rational design of a new chalcogenide with good infrared nonlinear optical performance: SrZnSnS 4

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    Yiling Zhang, Dajiang Mei, Yi Jin Yang, Wangzhu Cao, Yuandong Wu, Jie Lü, Zheshuai Lin

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  8. Super-broadband hybrid mid-infrared laser systems

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    А. А. Ионин, I. O. Kinyaevskiy, Dmitrii V. Sinitsyn, Yu. M. Klimachëv, А. А. Котков, A. Yu. Kozlov, Adilya M. Sagitova, Leonid V. Seleznev

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  9. Balanced Second-Order Nonlinear Optical Properties of Adducts CHI3·(S8)3 and AsI3·(S8)3: A Systematic Survey

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    Zhen‐Tao Lu, Zongdong Sun, Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

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  10. Verification of an integral figure of merit for mid-IR nonlinear crystals

    Applied Optics · 2019-03-22

    А. А. Ионин, I. O. Kinyaevskiy, Adilya M. Sagitova, Yu. М. Andreev

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  11. Solvothermal syntheses, characterizations and semiconducting properties of four quaternary thioargentates Ba2AgInS4, Ba3Ag2Sn2S8, BaAg2MS4 (M = Sn, Ge)

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    Yan Liu, Yanhua Li, Jie Zhao, Ren‐Chun Zhang, Min Ji, Zhong‐Lu You, Yong‐Lin An

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  12. Solvothermal Syntheses and Characterizations of Four Quaternary Copper Sulfides BaCu3MS4 (M = In, Ga) and BaCu2MS4 (M = Sn, Ge)

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  13. A new family of quaternary thiosilicates SrA 2 SiS 4 (A = Li, Na, Cu) as promising infrared nonlinear optical crystals

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  14. Rational design of infrared nonlinear optical chalcogenides by chemical substitution

    Coordination Chemistry Reviews · 2019-12-21

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  15. A review of the AI2B II C IV DVI4 family as infrared nonlinear optical materials: the effect of each site on the structure and optical properties

    Chemical Communications · 2020-01-01

    Guangmao Li, Zhihua Yang, Junjie Li, Shilie Pan

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  16. Ab Initio Calculations of Structural, Mechanic, Electronic and Optical Properties of Ag2BaSn(Se, S)4 in Kesterite Structure

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    Rabia Rahmani, Bouhalouane Amrani, Kouider Driss-Khodja, Hayat Sediki

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  17. Coordinated regulation on critical physiochemical performances activated from mixed tetrahedral anionic ligands in new series of Sr 6 A 4 M 4 S 16 (A = Ag, Cu; M = Ge, Sn) nonlinear optical materials

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    Ya Feng Yang, Miao Song, Jie Zhang, Lihua Gao, Xiaowen Wu, Kui Wu

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  18. Infrared Nonlinear Optical Polymorphs α- and β-SrCu 2 SnS 4 Exhibiting Large Second Harmonic Generation Responses with Requisite Phase-Matching Behavior

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    Ya Feng Yang, Kui Wu, Bingbing Zhang, Xiaowen Wu, Ming‐Hsien Lee

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  19. One-Dimensional Double Chains in Sodium-Based Quaternary Chalcogenides Displaying Intriguing Red Emission and Large Optical Anisotropy

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  20. An assessment of the structural, electronic, optical and thermoelectric properties of the BaAg2GeS4 compound

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  21. Mild solvothermal syntheses and characterizations of two layered sulfides Ba2Cu2Cd2S5 and Ba3Cu4Hg4S9

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  22. Cd4SiQ6 (Q = S, Se): Ternary Infrared Nonlinear Optical Materials with Mixed Functional Building Motifs

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  23. Mild solvothermal syntheses and characterizations of four quaternary layered sulfides AAgCdS2 (A = K, Rb, Cs) and Cs2Cu2Cd2S4

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  24. NLO response as a function of structural water presence: A comparative experimental (UV-vis) and DFT (structural, NPA, MEP) study on Cs2Ni(SeO4)2•4H2O and Cs2Ni(SeO4)2

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  25. Effect of Pb Substitution in Sr2-xPbxGeSe4 on Crystal Structures and Nonlinear Optical Properties Predicted by DFT Calculations

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  26. Synthesis, crystal structure, and electronic structure of Li2PbSiS4: a quaternary thiosilicate with a compressed chalcopyrite-like structure

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  27. Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials

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  28. New nonlinear optical-active AAgGa 6 S 10 (A = K, Rb, Cs) featuring {[AgGa 6 S 10 ] − } ∞ framework and high laser damage threshold

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  29. Temperature controlling valance changes of crystalline thioarsenates and thioantimonates

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  30. Inorganic Chalcogenides: From Zero‐Dimensional Clusters to Three‐Dimensional Frameworks

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  31. Synthesis, Spectroscopic, Conceptual DFT Characterization and Molecular Docking Studies of Two Versatile di-Bromobenzaldehyde Derived Compounds

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  32. Synthesis, spectroscopic characterization and in-silico bio-activity studies of (E)-4,6-dibromo-2-[(2-bromo-4-methylphenylimino)methyl]-3-methoxyphenol

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  33. Structural, Optical, and Electronic Properties of Two Quaternary Chalcogenide Semiconductors: Ag2SrSiS4 and Ag2SrGeS4

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  34. Triclinic Layered A2ZnSi3S8 (A = Rb and Cs) with Large Optical Anisotropy and Systematic Research on the Inherent Structure–Performance Relationship in the A2MIIBMIV3Q8 Family

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  35. Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials

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  36. AAg 2 PS 4 (A = K, Na/K): the first-type of noncentrosymmetric alkali metal Ag-based thiophosphates exhibiting excellent second-order nonlinear optical performances

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  37. AAg 3 Ga 8 Se 14 (A = Rb, Cs): second-harmonic generation responses realized through the parallel arrangement of AgSe 4 and GaSe 4 tetrahedrons

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  38. DFT study of alkali and alkaline earth metal-doped benzocryptand with remarkable NLO properties

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  39. Five coordinated Mn in Ba 4 Mn 2 Si 2 Te 9 : synthesis, crystal structure, physical properties, and electronic structure

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  40. KAg3Ga8S14: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold※

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  41. Ba6(CuxZy)Sn4S16 (Z = Mg, Mn, Zn, Cd, In, Bi, Sn): High Chemical Flexibility Resulting in Good Nonlinear-Optical Properties

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  42. BaSi7P10 and SrSi7P10: Two Infrared Nonlinear Optical Phosphides with T2 Supertetrahedra Exhibiting Strong Second‐Harmonic Generation Effects

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  43. Temperature effect on potassium nitrate-tricine nanoparticles synthesis to enhance third order optical nonlinearity

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  44. A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications

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  45. Structural study, Oxytetracycline electrochemical sensing property and molecular docking analysis of a novel synthesized non-centrosymmetric hybrid compound, (C9H11N2O5)2(NO3)2

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  46. (Na0.74Ag1.26)BaSnS4: A New AgGaS2‐Type Nonlinear Optical Sulfide with a Wide Band Gap and High Laser Induced Damage Threshold

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  47. Ag-based chalcogenides and derivatives as promising infrared nonlinear optical materials

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  48. Na 2 Ba[Na 2 Sn 2 S 7 ]: Structural Tolerance Factor‐Guided NLO Performance Improvement

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  49. Na2Ba[Na2Sn2S7]: Structural Tolerance Factor‐Guided NLO Performance Improvement

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  50. Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization

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