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RESEARCH PAPER · Inorganic Chemistry · 2021

Triclinic Layered A2ZnSi3S8 (A = Rb and Cs) with Large Optical Anisotropy and Systematic Research on the Inherent Structure–Performance Relationship in the A2MIIBMIV3Q8 Family

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Triclinic Layered A2ZnSi3S8 (A = Rb and Cs) with Large Optical Anisotropy and Systematic Research on the Inherent Structure–Performance Relationship in the A2MIIBMIV3Q8 FamilyOriginalRb2MGe3S8 (M=Zn, Cd): Non-Centrosymmetry Transformation Led by Structure Change of [MGe3S8]2- Unit※4d6versus d10, Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K2TGe3Ch8 (T = Fe, Cd; Ch = S, Se)18[Sr 4 Cl 2 ][Si 3 S 9 ]: Ultrawide-bandgap salt-inclusion thiosilicate nonlinear optical material with unprecedented tri-polymerized [Si 3 S 9 ] clusters21Na3SiS3F: A Wide Bandgap Fluorothiosilicate with Unique [SiS3F] Unit and High Laser‐Induced Damage Threshold39Alkali halide flux synthesis, crystal structure, and photoelectric response of quaternary thiosilicates K 3 Ga 3 Si 7 S 20 and K 2 ZnSi 3 S 81Crystal Growth of Quaternary AkRE 2 Si 2 S 8 (Ak = Ca and Sr; RE = La–Tb) Thiosilicates Using Flux-Assisted Boron Chalcogen Mixture Method: Exploring X-ray Scintillation, Luminescence, and Magnetic Properties11K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties6Alkali metal/mercury dual-metal sulfides as infrared nonlinear optical materials with high laser-induced damage thresholds5Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides11Research progress and future prospect of chalcogenides with large optical anisotropy46Isothermal sections Tl2Se–CdSe–DIVSe2 (DIV – Si, Ge), quasi-binary systems Tl2DIVSe3–CdSe, Tl2CdGeSe4–GeSe2 and the crystal structure, electronic and optical properties of novel quaternary selenides Tl2CdDIV3Se80

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  1. Rb2MGe3S8 (M=Zn, Cd): Non-Centrosymmetry Transformation Led by Structure Change of [MGe3S8]2- Unit※

    化学学报 · 2022-01-01

    Xiandan Chai, Wen‐Fa Chen, Qiu-Nan Yan, Binwen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  2. d6versus d10, Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K2TGe3Ch8 (T = Fe, Cd; Ch = S, Se)

    Inorganic Chemistry · 2022-12-27

    Bingheng Ji, Fei Wang, Kui Wu, Bingbing Zhang, Jian Wang

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  3. [Sr 4 Cl 2 ][Si 3 S 9 ]: Ultrawide-bandgap salt-inclusion thiosilicate nonlinear optical material with unprecedented tri-polymerized [Si 3 S 9 ] clusters

    Journal of Materials Chemistry C · 2023-01-01

    Chenyao Zhao, Kui Wu, Yan Xiao, Bingbing Zhang, Haohai Yu, Huaijin Zhang

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  4. Na3SiS3F: A Wide Bandgap Fluorothiosilicate with Unique [SiS3F] Unit and High Laser‐Induced Damage Threshold

    Advanced Optical Materials · 2023-05-17

    Jiazheng Zhou, Linan Wang, Yu Chu, Hongshan Wang, Shilie Pan, Junjie Li

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  5. Alkali halide flux synthesis, crystal structure, and photoelectric response of quaternary thiosilicates K 3 Ga 3 Si 7 S 20 and K 2 ZnSi 3 S 8

    CrystEngComm · 2024-01-01

    Jia-Ting Liu, Abdusalam Ablez, Qianqian Hu, Jun-Hao Tang, Chuan Lv, Lu Yang, Mei‐Ling Feng, Xiao‐Ying Huang

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  6. Crystal Growth of Quaternary AkRE 2 Si 2 S 8 (Ak = Ca and Sr; RE = La–Tb) Thiosilicates Using Flux-Assisted Boron Chalcogen Mixture Method: Exploring X-ray Scintillation, Luminescence, and Magnetic Properties

    Inorganic Chemistry · 2024-06-29

    Gopabandhu Panigrahi, Anna A. Berseneva, Gregory W. Morrison, Adam A. King, Robin L. Conner, Luiz Gustavo Jacobsohn, Hans‐Conrad zur Loye

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  7. K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties

    Inorganic Chemistry · 2024-08-26

    Guili Wang, Pifu Gong, Jiyong Yao

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  8. Alkali metal/mercury dual-metal sulfides as infrared nonlinear optical materials with high laser-induced damage thresholds

    Dalton Transactions · 2025-01-01

    Guili Wang, Bohui Xu, Chunxiao Li, Pifu Gong, Zheshuai Lin, Jiyong Yao

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  9. Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides

    Inorganic Chemistry Frontiers · 2025-01-01

    Ping Feng, Shenghua Zhou, Mao‐Yin Ran, Bingxuan Li, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

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  10. Research progress and future prospect of chalcogenides with large optical anisotropy

    Coordination Chemistry Reviews · 2025-06-20

    Zhen-Cheng Wu, Sheng‐Ping Guo

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  11. Isothermal sections Tl2Se–CdSe–DIVSe2 (DIV – Si, Ge), quasi-binary systems Tl2DIVSe3–CdSe, Tl2CdGeSe4–GeSe2 and the crystal structure, electronic and optical properties of novel quaternary selenides Tl2CdDIV3Se8

    Journal of Alloys and Compounds · 2026-07-22

    Л.В. Піскач, Andrii Selezen, Lubomir D. Gulay, Yuri M. Kogut, Dmytro Ivanyuk, Galyna Myronchuk, Stepan V. Syrotyuk, Yu. V. Klysko, Svitlana Bolshanina, Oleksiy Synelnychenko, Oleg Khyzhun

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