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RESEARCH PAPER · Chemistry of Materials · 2020

Infrared Nonlinear Optical Polymorphs α- and β-SrCu 2 SnS 4 Exhibiting Large Second Harmonic Generation Responses with Requisite Phase-Matching Behavior

Ya Feng Yang, Kui Wu, Bingbing Zhang, Xiaowen Wu, Ming‐Hsien Lee

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Infrared Nonlinear Optical Polymorphs α- and β-SrCu 2 SnS 4 Exhibiting Large Second Harmonic Generation Responses with Requisite Phase-Matching BehaviorOriginalDefect suppression in multinary chalcogenide photovoltaic materials derived from kesterite: progress and outlook58Experimental and theoretical studies of the ternary thiophosphate PbPS 3 featuring ethane-like [P 2 S 6 ] 4− units15Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra11(Na0.60Ba0.70)Ga2Se4: An Infrared Nonlinear Optical Crystal Designed using AgGaSe2 as the Template38Volume Modulation of Nonlinear Optical Properties by Cation Substitution8KInSi1.32Sn0.68Se6: An Infrared Nonlinear Optical Material Containing Three Types of Tetrahedral Units19HgCuPS4: An Exceptional Infrared Nonlinear Optical Material with Defect Diamond-like Structure145A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials130LiGaF2(IO3)2: A mixed-metal gallium iodate-fluoride with large birefringence and wide band gap39α-CdP2: Large SHG Effect Originating from the Synergism of Parallel ∞1[P–] Polyanion Chains and Distorted CdP4 Tetrahedra21Investigation of the second-order nonlinear optical property of Sr6Sb6S173Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95A 3 Mn 2 Sb 3 S 8 (A = K and Rb): a new type of multifunctional infrared nonlinear optical material based on unique three-dimensional open frameworks53A review on the recently developed promising infrared nonlinear optical materials103Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials47New Polymorphism for Ba3Zn2(BO3)3F with Two Polymorphs Exhibiting Anomalous Phase Transition2A Series of Pentanary Salt-Inclusion Chalcogenoborates Containing a B12Q12 (Q = S, Se) Cluster Exhibiting a Kleinman-Forbidden Frequency-Doubling Effect25α-Ca2CdP2 and β-Ca2CdP2: Two Polymorphic Phosphide-Based Infrared Nonlinear Crystals with Distorted NLO-Active Tetrahedral Motifs Realizing Large Second Harmonic Generation Effects and Suitable Band Gaps30Structural and physical properties of 99 complex bulk chalcogenides crystals using first-principles calculations34A review of the structural diversity of [P x S y ] n − motifs and their potential application prospects in metal thiophosphates21Structural, Optical, and Electronic Properties of Two Quaternary Chalcogenide Semiconductors: Ag2SrSiS4 and Ag2SrGeS420Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials184Halogen-Ion-Induced Structural Phase Transition Giving a Polymorph of HgBr2 with Balanced Nonlinear Optical Properties8KAg3Ga8S14: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold※3Quaternary Noncentrosymmetric Rare-Earth Sulfides Ba4RE2Cd3S10 (RE = Sm, Gd, or Tb): A Joint Experimental and Theoretical Investigation17Synthesis, characterization, and electronic structure of SrBi2S43A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications114AIB3IIC3IIIQ8VI: A New Family for the Design of Infrared Nonlinear Optical Materials by Coupling Octahedra and Tetrahedra Units152Effect of strain on the band structure and optical properties of Na2Bi2(SeO3)3F21Na 2 Ba[Na 2 Sn 2 S 7 ]: Structural Tolerance Factor‐Guided NLO Performance Improvement50Na2Ba[Na2Sn2S7]: Structural Tolerance Factor‐Guided NLO Performance Improvement0Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance64BaCu2SiS4: A New Member of the AIIBI2MIVQ4 Chalcogenide Family with a Chiral Crystal Structure6Polymorphism and White Light Emission of 1‐Bromo‐3,5,7‐triphenyladamantane Compared with 1,3,5,7‐Tetraphenyladamantane2Structure‐Prediction‐Oriented Synthesis of Thiophosphates as Promising Infrared Nonlinear Optical Materials24Structure‐Prediction‐Oriented Synthesis of Thiophosphates as Promising Infrared Nonlinear Optical Materials1Large Mid-Infrared Second-Harmonic Generation in Eu(II)-Based Quaternary Chalcogenides19Mechanochemical synthesis of rock salt-type Na 2 CaSnS 4 as a sodium-ion conductor0Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12Br10Modulating Nonlinear Optical Performances in α/β-SnGa2GeS6 Polymorphs via Atomic Coordination Engineering1AsSe-free Si–Te–Ge chalcogenide glass OTS selectors designed by interpretable machine learning0SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice0AgEuPS4: Unlocking the Centrosymmetric Shackle of Rare-Earth Thiophosphates via Microscopic Distortion Cascading for Enhanced Second-Harmonic Generation Response0

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  1. Defect suppression in multinary chalcogenide photovoltaic materials derived from kesterite: progress and outlook

    Journal of Materials Chemistry A · 2020-01-01

    Qingwen Tian, Shengzhong Frank Liu

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  2. Experimental and theoretical studies of the ternary thiophosphate PbPS 3 featuring ethane-like [P 2 S 6 ] 4− units

    Dalton Transactions · 2020-01-01

    Peng Wang, Maierhaba Abudoureheman, Zhaohui Chen

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  3. Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra

    Dalton Transactions · 2020-01-01

    Jun Sun, Miriding Mutailipu, Shichao Cheng, Zhihua Yang, Shilie Pan

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  4. (Na0.60Ba0.70)Ga2Se4: An Infrared Nonlinear Optical Crystal Designed using AgGaSe2 as the Template

    Inorganic Chemistry · 2020-03-03

    Yanan Li, Huaiguo Xue, Sheng‐Ping Guo

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  5. Volume Modulation of Nonlinear Optical Properties by Cation Substitution

    The Journal of Physical Chemistry C · 2020-04-15

    Jingmei Min, Hao Li, Jun Zhang

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  6. KInSi1.32Sn0.68Se6: An Infrared Nonlinear Optical Material Containing Three Types of Tetrahedral Units

    Inorganic Chemistry · 2020-04-21

    Xiaohui Li, Yiting Chen, Huaiguo Xue, Sheng‐Ping Guo

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  7. HgCuPS4: An Exceptional Infrared Nonlinear Optical Material with Defect Diamond-like Structure

    Chemistry of Materials · 2020-04-24

    Mengyue Li, Zuju Ma, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  8. A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs

    Coordination Chemistry Reviews · 2020-05-25

    Kui Wu, Ya Feng Yang, Lihua Gao

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  9. Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2020-06-29

    Weikang Wang, Dajiang Mei, Fei Liang, Jun Zhao, Yuandong Wu, Zheshuai Lin

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  10. LiGaF2(IO3)2: A mixed-metal gallium iodate-fluoride with large birefringence and wide band gap

    Science China Materials · 2020-07-22

    Jin Chen, Chun‐Li Hu, Jiang‐Gao Mao

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  11. α-CdP2: Large SHG Effect Originating from the Synergism of Parallel ∞1[P–] Polyanion Chains and Distorted CdP4 Tetrahedra

    Chemistry of Materials · 2020-11-25

    Jindong Chen, Chensheng Lin, Feng Xu, Shunda Yang, Yingshuang Sun, Xin Lei Zhao, Xiaotian Jiang, Bingxuan Li, Tao Yan, Ning Ye

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  12. Investigation of the second-order nonlinear optical property of Sr6Sb6S17

    Journal of Solid State Chemistry · 2020-12-19

    Qian-Ting Xu, Wen‐Dong Yao, Xiaohui Li, Sheng‐Ping Guo

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  13. Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials

    Crystal Growth & Design · 2020-12-22

    Mei Yan, Huaiguo Xue, Sheng‐Ping Guo

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  14. A 3 Mn 2 Sb 3 S 8 (A = K and Rb): a new type of multifunctional infrared nonlinear optical material based on unique three-dimensional open frameworks

    Inorganic Chemistry Frontiers · 2021-01-01

    Yu Xiao, Man-Man Chen, Yaying Shen, Pengfei Liu, Hua Lin, Yi Liu

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  15. A review on the recently developed promising infrared nonlinear optical materials

    Dalton Transactions · 2021-01-01

    Ailijiang Abudurusuli, Junjie Li, Shilie Pan

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  16. Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials

    Journal of Materials Chemistry C · 2021-01-01

    Chang Liu, Shenghua Zhou, Yu Xiao, Chao Zhang, Hua Lin, Yi Liu

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  17. New Polymorphism for Ba3Zn2(BO3)3F with Two Polymorphs Exhibiting Anomalous Phase Transition

    European Journal of Inorganic Chemistry · 2021-01-24

    Yanna Chen, Wenyao Zhang, Donghai An, Maierhaba Abudoureheman, Zhaohui Chen, Hongyu Mi

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  18. A Series of Pentanary Salt-Inclusion Chalcogenoborates Containing a B12Q12 (Q = S, Se) Cluster Exhibiting a Kleinman-Forbidden Frequency-Doubling Effect

    Inorganic Chemistry · 2021-02-09

    Shanshan Han, Wen‐Dong Yao, Su‐Xin Yu, Yueling Sun, Anhua Gong, Sheng‐Ping Guo

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  19. α-Ca2CdP2 and β-Ca2CdP2: Two Polymorphic Phosphide-Based Infrared Nonlinear Crystals with Distorted NLO-Active Tetrahedral Motifs Realizing Large Second Harmonic Generation Effects and Suitable Band Gaps

    Inorganic Chemistry · 2021-05-03

    Yingshuang Sun, Chensheng Lin, Jindong Chen, Feng Xu, Shunda Yang, Bingxuan Li, Guangsai Yang, Min Luo, Ning Ye

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  20. Structural and physical properties of 99 complex bulk chalcogenides crystals using first-principles calculations

    Scientific Reports · 2021-05-10

    Sahib Hasan, Khagendra Baral, Neng Li, W. Y. Ching

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  21. A review of the structural diversity of [P x S y ] n − motifs and their potential application prospects in metal thiophosphates

    Journal of Physics D Applied Physics · 2021-07-16

    Ya Yang, Miao Song, Xiaowen Wu, Kui Wu

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  22. Structural, Optical, and Electronic Properties of Two Quaternary Chalcogenide Semiconductors: Ag2SrSiS4 and Ag2SrGeS4

    Inorganic Chemistry · 2021-07-28

    Garrett C. McKeown Wessler, Tianlin Wang, Jon‐Paul Sun, Yuheng Liao, Martin C. Fischer, Volker Blüm, David B. Mitzi

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  23. Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2021-08-26

    Hong Chen, Wenbo Wei, Hua Lin, Xintao Wu

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  24. Halogen-Ion-Induced Structural Phase Transition Giving a Polymorph of HgBr2 with Balanced Nonlinear Optical Properties

    Inorganic Chemistry · 2021-12-02

    Qi Wu, Can Yang, Jie Ma, Xian Liu, Yanjun Li

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  25. KAg3Ga8S14: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold※

    化学学报 · 2022-01-01

    Jin-Xu Zhao, Mingshu Zhang, Wen‐Fa Chen, Xiao‐Ming Jiang, Binwen Liu, Guo‐Cong Guo

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  26. Quaternary Noncentrosymmetric Rare-Earth Sulfides Ba4RE2Cd3S10 (RE = Sm, Gd, or Tb): A Joint Experimental and Theoretical Investigation

    Inorganic Chemistry · 2022-01-11

    Qing-Gang Yue, Shenghua Zhou, Bingxuan Li, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  27. Synthesis, characterization, and electronic structure of SrBi2S4

    Journal of Solid State Chemistry · 2022-05-17

    Subhendu Jana, Gopabandhu Panigrahi, Bikash Tripathy, Sairam K. Malladi, Muthukumaran Sundaramoorthy, S. Arumugam, Manish K. Niranjan, Jai Prakash

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  28. A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications

    Coordination Chemistry Reviews · 2022-07-19

    Hong Chen, Mao‐Yin Ran, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  29. AIB3IIC3IIIQ8VI: A New Family for the Design of Infrared Nonlinear Optical Materials by Coupling Octahedra and Tetrahedra Units

    Journal of the American Chemical Society · 2022-11-18

    Ling Luo, Linan Wang, Jianbang Chen, Jiazheng Zhou, Zhihua Yang, Shilie Pan, Junjie Li

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  30. Effect of strain on the band structure and optical properties of Na2Bi2(SeO3)3F2

    Computational Materials Science · 2022-12-21

    Zhen Hong Fan, Zhixin Sun, Guangyong Jin, Chao Xin

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  31. Na 2 Ba[Na 2 Sn 2 S 7 ]: Structural Tolerance Factor‐Guided NLO Performance Improvement

    Angewandte Chemie International Edition · 2022-12-21

    Rui‐An Li, Qianqian Liu, Xin Liu, Youquan Liu, Xingxing Jiang, Zheshuai Lin, Fei Jia, Lin Xiong, Ling Chen, Li‐Ming Wu

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  32. Na2Ba[Na2Sn2S7]: Structural Tolerance Factor‐Guided NLO Performance Improvement

    Angewandte Chemie · 2022-12-21

    Rui‐An Li, Qianqian Liu, Xin Liu, Youquan Liu, Xingxing Jiang, Zheshuai Lin, Fei Jia, Lin Xiong, Ling Chen, Li‐Ming Wu

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  33. Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance

    Small · 2023-02-12

    Mao‐Yin Ran, Shenghua Zhou, Wenbo Wei, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  34. BaCu2SiS4: A New Member of the AIIBI2MIVQ4 Chalcogenide Family with a Chiral Crystal Structure

    Zeitschrift für anorganische und allgemeine Chemie · 2023-09-08

    Arka Sarkar, Gayatri Viswanathan, Kui Wu, Gordon J. Miller, Kirill A. Kovnir

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  35. Polymorphism and White Light Emission of 1‐Bromo‐3,5,7‐triphenyladamantane Compared with 1,3,5,7‐Tetraphenyladamantane

    European Journal of Organic Chemistry · 2024-03-24

    Saravanan Gowrisankar, Andrey A. Fokin, Jonathan Becker, Neeshma Mathew, Jörn Schmedt auf der Günne, Peter Richard Schreiner

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  36. Structure‐Prediction‐Oriented Synthesis of Thiophosphates as Promising Infrared Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2024-06-03

    Yi Bo Huang, Dongdong Chu, Yong an Zhang, Congwei Xie, Guangmao Li, Shilie Pan

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  37. Structure‐Prediction‐Oriented Synthesis of Thiophosphates as Promising Infrared Nonlinear Optical Materials

    Angewandte Chemie · 2024-06-03

    Yi Bo Huang, Dongdong Chu, Yong an Zhang, Congwei Xie, Guangmao Li, Shilie Pan

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  38. Large Mid-Infrared Second-Harmonic Generation in Eu(II)-Based Quaternary Chalcogenides

    Chemistry of Materials · 2024-09-19

    Subhendu Jana, Eric A. Gabilondo, Machima Mongkhonratanachai, Yujie Zhang, P. Shiv Halasyamani, Paul A. Maggard

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  39. Mechanochemical synthesis of rock salt-type Na 2 CaSnS 4 as a sodium-ion conductor

    RSC Mechanochemistry · 2024-12-03

    Hamdi Ben Yahia, Atsushi Sakuda, Akitoshi Hayashi

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  40. Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12Br

    Inorganic Chemistry · 2025-03-24

    Baozhu Zhu, Lei Geng, Shoubao Zhang, Shuo Han, Chang‐Yu Meng, You‐Zhao Lan, Qi Wu

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  41. Modulating Nonlinear Optical Performances in α/β-SnGa2GeS6 Polymorphs via Atomic Coordination Engineering

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    Jingjing Xu, Yan Xiao, Dazhi Lu, Bingbing Zhang, Kui Wu, Haohai Yu, Huaijin Zhang

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  42. AsSe-free Si–Te–Ge chalcogenide glass OTS selectors designed by interpretable machine learning

    Matéria (Rio de Janeiro) · 2026-01-01

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  43. SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice

    Inorganic Chemistry · 2026-01-21

    Chenyao Zhao, Yanhong Wang, Yun Lv, SeungGyum Jung, Hyun‐Joo Koo, Myung‐Hwan Whangbo, Hongcheng Lu

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  44. AgEuPS4: Unlocking the Centrosymmetric Shackle of Rare-Earth Thiophosphates via Microscopic Distortion Cascading for Enhanced Second-Harmonic Generation Response

    Chemistry of Materials · 2026-08-13

    Ao Guo, Si Yang, Yang Chi, Yu‐Xuan Zhang, Tianwei He, Mao‐Yin Ran, Sheng‐Ping Guo

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