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RESEARCH PAPER · Journal of Materials Chemistry C · 2016

AMgPO 4 ·6H 2 O (A = Rb, Cs): strong SHG responses originated from orderly PO 4 groups

Yuqiao Zhou, Liling Cao, Chensheng Lin, Min Luo, Tao Yan, Ning Ye, Wendan Cheng

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AMgPO 4 ·6H 2 O (A = Rb, Cs): strong SHG responses originated from orderly PO 4 groupsOriginalKPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge109Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response23A3Sr2P7O21 (A = Rb, Cs): Two Polyphosphates Based on Different Types of P–O Chains and Ring Structures36Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals257Synthesis, structure and electronic structure calculation of a new perovskite-type phosphate fluoride K2BaPO4F9MIMIIP3O9 (MI = Rb, MII = Cd, Mg, Ca; MI = Cs, MII = Pb, Sr; MI = K, MII = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties35A 2 Bi 2 (SO 4 ) 2 Cl 4 (A = NH 4 , K, Rb): achieving a subtle balance of the large second harmonic generation effect and sufficient birefringence in sulfate nonlinear optical materials98Centrosymmetric K 2 SO 4 ·(SbF 3 ) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3 ) 2 resulting from cooperative effects of lone pair and cation size63Modulation of perovskite-related frameworks induced by alkaline earth metals in phosphate fluorides A 2 MPO 4 F (A = K, Rb; M = Ba, Ca)8Syntheses, structures, anomalous phase transition and optical properties of two new polymorphic α- and β-LiMoPO 611KLi(HC 3 N 3 O 3 )·2H 2 O: Solvent-drop Grinding Method toward the Hydro-isocyanurate Nonlinear Optical Crystal314KMg(H 2 O)PO 4 : A Deep-Ultraviolet Transparent Nonlinear Optical Material Derived from KTiOPO 483Synthesis, characterization, and properties of two new phosphate crystals MZnAl(PO4)2 (M = Na, K) with 3D framework tunnel structures14Na 3 Sc 2 (PO 4 ) 2 F 3 : rational design and synthesis of an alkali rare-earth phosphate fluoride as an ultraviolet nonlinear optical crystal with an enlarged birefringence49Syntheses, structures and characterization of non-centrosymmetric Rb 2 Zn 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 M 3 (P 2 O 7 ) 2 (M = Zn and Mg)26Effect of Mo/P Ratios on Dimensions: Syntheses, Structures, and Properties of Three New Molybdophosphates10Synthesis, crystal structures and optical properties of open-framework gallium phosphates: NaGa3F4(PO4)2(H2O)2 and AGa2P2O7(OH)3(H2O) (A = K, Rb)1A powder method for the high-efficacy evaluation of electro-optic crystals28Infrared and Raman spectra of magnesium ammonium phosphate hexahydrate (struvite) and its isomorphous analogues. X. Vibrational spectra of magnesium rubidium arsenate hexahydrate and magnesium thallium arsenate hexahydrate3K 3 B 4 PO 10 and K 2 MB 4 PO 10 (M = Rb/Cs): rare mixed-coordinated borophosphates with large birefringence33Na 1.5 Rb 0.5 PO 3 F·H 2 O: synthesis, properties, and stepwise reconstruction of the hydrogen bond network13Ba3Sb2(PO4)4 and Cd3Sb2(PO4)4(H2O)2: Two New Antimonous Phosphates with Distinct [Sb(PO4)2] Structure Types and Enhanced Birefringence37A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups106Growth and characterization of lithium chloride doped KDP crystals: a DFT and experimental approach25Halonitrides Zn 2 NX (X=Cl,Br): Novel Mid-Infrared Nonlinear Optical Materials30[C(NH2)3]3PO4·2H2O: A new metal-free ultraviolet nonlinear optical phosphate with large birefringence and second-harmonic generation response70AZn(PO3)3 (A = K, Rb): Deep-Ultraviolet Nonlinear Optical Phosphates Derived from Synergy of a Unique [ZnO6] Octahedron and a [PO3]∞ Chain25Struvite-type AMgPO4·6H2O (A = NH4, K): Two Natural Deep-Ultraviolet Transparent Nonlinear Optical Crystals13Linear and Nonlinear Optical Properties of Centrosymmetric Sb 4 O 5 SO 4 and Noncentrosymmetric Sb 4 O 4 (SO 4 )(OH) 2 Induced by Lone Pair Stereoactivity55Tin(II)-Induced Large Birefringence Enhancement in Metal Phosphates22H{[Na(H2O)3]6F}(PO4)2 ⋅ 2(H2O): A New Polycation‐Type Phosphate with Deep Ultraviolet Transparency0NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence19A 6 Mo 2 P 4 O 19 (A = Rb, Cs) and Rb 2 MoP 2 O 9 : new molybdophosphates with distinct polyanionic configurations5Hybrid organic–inorganic triguanidine arsenate dihydrate for ultraviolet nonlinear optical application15Halogen regulation triggers structural transformation from centrosymmetric to noncentrosymmetric switches in tin phosphate halides Sn 2 PO 4 X (X = F, Cl)47Lone Pair-Driven Enhancement of Birefringence in Polar Alkali Metal Antimony Phosphates46First-Principles Calculations of the Structural, Electronic, Optical, and Mechanical Properties of 21 Pyrophosphate Crystals10LiKCuP2O7: Cation substitution application with mixed-alkaline copper-containing pyrophosphate and magnetic properties2Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 323Structure and optical property evolution in PbM(PO 4 )X (M = Zn, Sn; X = halogen): SHG effect and birefringence21Sb4O3(TeO3)2(HSO4)(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity30Tunable, efficient, ultrafast broadband nonlinear optical properties of TiO2–loaded complex phosphate glasses15Form-controlled synthesis of a polymorphic nonlinear optical crystal CsMgPO 4 ·6H 2 O3Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer16Novel antimony phosphates with enlarged birefringence induced by lone pair cations4Structural characterisation and optical properties of new alkaline earth phosphate CaMg(P 4 O 12 ) and alkaline alumophosphate Cs 3 Al 4 (PO 4 ) 51Syntheses, structures and characterization of noncentrosymmetric MZnPO 4 (M = K, NH 4 )4RbY(SO4)2·4H2O: A new ultraviolet birefringent crystal3Enhanced Birefringence in Phosphates via “Two Steps in One”: d0 Transition Metal Regulation and Fluorination Synergistic Strategy7Sb2O2SeO3 and Sb2O(SeO3)2: Two-Layered Antimony(III) Selenites with Enhanced Birefringence10Synthesis, structure and characterizations of the first alkali-metal/alkaline-earth-metal oxalatophosphate Na4Mg3(HPO4)4(C2O4)·2H2O3Mutual polymorphic transformation of CsMgPO 4 ·6H 2 O induced by solution pH2A 3 Sc(PO 4 ) 2 (A = Li, Na): rare earth cations effectively regulate phosphate structures for enhanced birefringence4Na3RE(PO4)2 with a Glaserite-Like Structure: The Effect of Cation on Structural Evolution2Ba 3 (MoO 2 F 3 )PO 4 F 2 : Rational Design and Synthesis of an Alkaline-Earth Phosphate Fluoride as a Birefringent Crystal1Magnesium Methylphosphonate Ultraviolet Nonlinear Optical Crystal With Ultrawide Bandgap and Strong Second‐Harmonic Generation Response0Dimensionality Engineering of Fluorozirconium Phosphates for Deep-UV-Transparent Crystals with Enhanced Second-Harmonic Generation and Birefringence10Sustainable Recovery of Dibutyl Terephthalate from Aromatic Polyester Waste via Solvothermal Alcoholysis0Ultrafast nonlinear optical properties of erbium−doped fluorophosphate glasses in the near−infrared spectral region0

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  1. KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge

    Journal of Materials Chemistry C · 2016-01-01

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  2. Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response

    Dalton Transactions · 2017-01-01

    Chao Wu, Longhua Li, Gang Yang, Jun‐Ling Song, Bing Yan, Mark Graeme Humphrey, Long Zhang, Jianda Shao, Chi Zhang

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  3. A3Sr2P7O21 (A = Rb, Cs): Two Polyphosphates Based on Different Types of P–O Chains and Ring Structures

    Inorganic Chemistry · 2017-03-15

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  4. Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

    Coordination Chemistry Reviews · 2018-03-15

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  5. Synthesis, structure and electronic structure calculation of a new perovskite-type phosphate fluoride K2BaPO4F

    Inorganic Chemistry Communications · 2018-05-19

    Mei-Si Zhang, Li‐Xian Chang, Li Wang, Mehriban Hojahmat, Maierhaba Abudoureheman

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  6. MIMIIP3O9 (MI = Rb, MII = Cd, Mg, Ca; MI = Cs, MII = Pb, Sr; MI = K, MII = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties

    Inorganic Chemistry · 2018-05-30

    Maierhaba Abudoureheman, Xiaobo Pan, Shujuan Han, Yilimiranmu Rouzhahong, Zhihua Yang, Hongping Wu, Shilie Pan

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  7. A 2 Bi 2 (SO 4 ) 2 Cl 4 (A = NH 4 , K, Rb): achieving a subtle balance of the large second harmonic generation effect and sufficient birefringence in sulfate nonlinear optical materials

    Journal of Materials Chemistry C · 2019-01-01

    Kaichuang Chen, Yi Jin Yang, Guang Peng, Shunda Yang, Tao Yan, Huixin Fan, Zheshuai Lin, Ning Ye

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  8. Centrosymmetric K 2 SO 4 ·(SbF 3 ) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3 ) 2 resulting from cooperative effects of lone pair and cation size

    Inorganic Chemistry Frontiers · 2019-01-01

    Qian Wang, Lei Wang, Xiaoyu Zhao, Ling Huang, Daojiang Gao, Jian Bi, Xin Wang, Guohong Zou

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  9. Modulation of perovskite-related frameworks induced by alkaline earth metals in phosphate fluorides A 2 MPO 4 F (A = K, Rb; M = Ba, Ca)

    New Journal of Chemistry · 2019-01-01

    Kun Chai, Shichao Cheng, Hongyi Li, Bin Dai

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  10. Syntheses, structures, anomalous phase transition and optical properties of two new polymorphic α- and β-LiMoPO 6

    Dalton Transactions · 2019-01-01

    Haonan Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Yicheng Wu

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  11. KLi(HC 3 N 3 O 3 )·2H 2 O: Solvent-drop Grinding Method toward the Hydro-isocyanurate Nonlinear Optical Crystal

    Journal of the American Chemical Society · 2019-02-12

    Donghong Lin, Min Luo, Chensheng Lin, Feng Xu, Ning Ye

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  12. KMg(H 2 O)PO 4 : A Deep-Ultraviolet Transparent Nonlinear Optical Material Derived from KTiOPO 4

    Chemistry of Materials · 2019-11-01

    Zhiyong Bai, Chun‐Li Hu, Lehui Liu, Lizhen Zhang, Yisheng Huang, Feifei Yuan, Zhoubin Lin

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  13. Synthesis, characterization, and properties of two new phosphate crystals MZnAl(PO4)2 (M = Na, K) with 3D framework tunnel structures

    Journal of Alloys and Compounds · 2019-11-25

    Hao Wang, Lei Geng, Yunjian Wang, Hong‐Yan Lu, Chang‐Yu Meng

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  14. Na 3 Sc 2 (PO 4 ) 2 F 3 : rational design and synthesis of an alkali rare-earth phosphate fluoride as an ultraviolet nonlinear optical crystal with an enlarged birefringence

    Journal of Materials Chemistry C · 2020-01-01

    Feng Xu, Guang Peng, Chensheng Lin, Dan Zhao, Bingxuan Li, Ge Zhang, Shunda Yang, Ning Ye

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  15. Syntheses, structures and characterization of non-centrosymmetric Rb 2 Zn 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 M 3 (P 2 O 7 ) 2 (M = Zn and Mg)

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  16. Effect of Mo/P Ratios on Dimensions: Syntheses, Structures, and Properties of Three New Molybdophosphates

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  17. Synthesis, crystal structures and optical properties of open-framework gallium phosphates: NaGa3F4(PO4)2(H2O)2 and AGa2P2O7(OH)3(H2O) (A = K, Rb)

    Journal of Solid State Chemistry · 2020-04-28

    Tianyou Wang, Chao Wu, Lin Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  18. A powder method for the high-efficacy evaluation of electro-optic crystals

    National Science Review · 2020-05-16

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  19. Infrared and Raman spectra of magnesium ammonium phosphate hexahydrate (struvite) and its isomorphous analogues. X. Vibrational spectra of magnesium rubidium arsenate hexahydrate and magnesium thallium arsenate hexahydrate

    Macedonian Journal of Chemistry and Chemical Engineering · 2020-12-11

    Viktor Stefov, Violeta G. Koleva, Metodija Ž. Najdoski, A. Cahil, Zuldjevat Abdija

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  20. K 3 B 4 PO 10 and K 2 MB 4 PO 10 (M = Rb/Cs): rare mixed-coordinated borophosphates with large birefringence

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  21. Na 1.5 Rb 0.5 PO 3 F·H 2 O: synthesis, properties, and stepwise reconstruction of the hydrogen bond network

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  22. Ba3Sb2(PO4)4 and Cd3Sb2(PO4)4(H2O)2: Two New Antimonous Phosphates with Distinct [Sb(PO4)2] Structure Types and Enhanced Birefringence

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  23. A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups

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  24. Growth and characterization of lithium chloride doped KDP crystals: a DFT and experimental approach

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  25. Halonitrides Zn 2 NX (X=Cl,Br): Novel Mid-Infrared Nonlinear Optical Materials

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  26. [C(NH2)3]3PO4·2H2O: A new metal-free ultraviolet nonlinear optical phosphate with large birefringence and second-harmonic generation response

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  27. AZn(PO3)3 (A = K, Rb): Deep-Ultraviolet Nonlinear Optical Phosphates Derived from Synergy of a Unique [ZnO6] Octahedron and a [PO3]∞ Chain

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  28. Struvite-type AMgPO4·6H2O (A = NH4, K): Two Natural Deep-Ultraviolet Transparent Nonlinear Optical Crystals

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  29. Linear and Nonlinear Optical Properties of Centrosymmetric Sb 4 O 5 SO 4 and Noncentrosymmetric Sb 4 O 4 (SO 4 )(OH) 2 Induced by Lone Pair Stereoactivity

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  30. Tin(II)-Induced Large Birefringence Enhancement in Metal Phosphates

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  31. H{[Na(H2O)3]6F}(PO4)2 ⋅ 2(H2O): A New Polycation‐Type Phosphate with Deep Ultraviolet Transparency

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  32. NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence

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  33. A 6 Mo 2 P 4 O 19 (A = Rb, Cs) and Rb 2 MoP 2 O 9 : new molybdophosphates with distinct polyanionic configurations

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  34. Hybrid organic–inorganic triguanidine arsenate dihydrate for ultraviolet nonlinear optical application

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  35. Halogen regulation triggers structural transformation from centrosymmetric to noncentrosymmetric switches in tin phosphate halides Sn 2 PO 4 X (X = F, Cl)

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  36. Lone Pair-Driven Enhancement of Birefringence in Polar Alkali Metal Antimony Phosphates

    Chemistry of Materials · 2022-04-29

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  37. First-Principles Calculations of the Structural, Electronic, Optical, and Mechanical Properties of 21 Pyrophosphate Crystals

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  38. LiKCuP2O7: Cation substitution application with mixed-alkaline copper-containing pyrophosphate and magnetic properties

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  39. Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3

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  40. Structure and optical property evolution in PbM(PO 4 )X (M = Zn, Sn; X = halogen): SHG effect and birefringence

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  41. Sb4O3(TeO3)2(HSO4)(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity

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  42. Tunable, efficient, ultrafast broadband nonlinear optical properties of TiO2–loaded complex phosphate glasses

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  43. Form-controlled synthesis of a polymorphic nonlinear optical crystal CsMgPO 4 ·6H 2 O

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  44. Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer

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  45. Novel antimony phosphates with enlarged birefringence induced by lone pair cations

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  46. Structural characterisation and optical properties of new alkaline earth phosphate CaMg(P 4 O 12 ) and alkaline alumophosphate Cs 3 Al 4 (PO 4 ) 5

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  47. Syntheses, structures and characterization of noncentrosymmetric MZnPO 4 (M = K, NH 4 )

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  48. RbY(SO4)2·4H2O: A new ultraviolet birefringent crystal

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  49. Enhanced Birefringence in Phosphates via “Two Steps in One”: d0 Transition Metal Regulation and Fluorination Synergistic Strategy

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  50. Sb2O2SeO3 and Sb2O(SeO3)2: Two-Layered Antimony(III) Selenites with Enhanced Birefringence

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