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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2022

Halogen regulation triggers structural transformation from centrosymmetric to noncentrosymmetric switches in tin phosphate halides Sn 2 PO 4 X (X = F, Cl)

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Halogen regulation triggers structural transformation from centrosymmetric to noncentrosymmetric switches in tin phosphate halides Sn 2 PO 4 X (X = F, Cl)OriginalKSb(BeF 3 )F 3 : a totally fluorine strategy for achieving wide bandgap and large birefringence23Surface-halogen-introduced 2D NiCo bimetallic MOFs via a modulation method for elevated electrochemical glucose sensing48Symmetry Analysis of the Complex Polytypism of Layered Rare-Earth Tellurites and Related Selenites: The Case of Introducing Transition Metals6ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps22Noncentrosymmetric versus Centrosymmetric: Halogen Induced Variable Coordination Modes of Sn2+ and Structural Transition in Sn3B3O7X (X = Cl and Br)17Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)16Anisotropic structure building unit involving diverse chemical bonds: a new opportunity for high-performance second-order NLO materials181Structure and optical property evolution in PbM(PO 4 )X (M = Zn, Sn; X = halogen): SHG effect and birefringence21Visualizing the alignment of lone pair electrons in La 3 AsS 5 Br 2 and La 5 As 2 S 9 Cl 3 to form an acentric or centrosymmetric structure10Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: Two Phosphite Halides with 3D Structural Networks and Enlarged Birefringence18Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence130Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6Four UV Transparent Linear and Nonlinear Optical Materials Explored from Pure Selenite Compounds22Improvement on Magnetocaloric Effect through Structural Evolution in Gadolinium Borate Halides Ba2Gd(BO3)2X (X = F, Cl)9Positive and Negative Contribution from Lead–Oxygen Groups and Halogen Atoms to Birefringence: A First Principles Investigation4CsSn2(HPO3)2I: The first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework24Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks18Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence10From (NH 4 ) 3 [Zr(PO 4 ) 2 F] to (NH 4 ) 3 [Sn 2 (PO 4 ) 2 ]Cl: the rational design of a tin-based short-wave ultraviolet phosphate with large optical anisotropy14Greatly enhanced optical anisotropy in thiophosphates inspired by rational coupling of tetrahedra and ethane-like [P 2 S 6 ] 4− groups7Halogen regulation of multifunctional hybrid materials with photoluminescence and dielectric response20Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer16Li 3 Na 7 B 4 P 6 O 26 : a new ultraviolet transparent congruently melting non-linear optical crystal3Na 4 Sn 4 (C 2 O 4 ) 3 F 6 and NaSnC 2 O 4 F·H 2 O: two tin( ii ) fluoride oxalates display large birefringence11From ZnF2 to ZnF2(H2O)4: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge19The electronic structures and optical properties induced by spin-orbit-coupling in LiPbPO4 compound6Structural Regulations of Layered Borates: From Centric Layers to Chiral Porous Layers3Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56Optimization of Functional Building Blocks Generates a Substantial Improvement in Birefringence from Sn2OSO4 to Sn3O2(OH)(HSO4)6Na(C2H10N2)2[Zn3(PO4)2(H0.5PO4)]2: A Short-Wave Ultraviolet Open-Framework Zincophosphate Exhibiting Substantial Optical Dispersion Ability4From Ba2Bi2Zn(PO4)4 to Ba2Bi2Cu(PO4)4: Rational design of an ultraviolet phosphate with enhanced birefringence2Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials1501D Bi ribbon/[PO 4 ] synergy-driven bismuth phosphates for ultraviolet nonlinear optical crystals with large SHG and birefringence0A new ultraviolet-transparent molybdate featuring a layered structure and moderate birefringence0SnHPO4: A Layered Tin(II) Phosphate with Enhanced Birefringence51Na2MP3O9 (M = K, Rb): Two Potential Zero-Order Waveplate Materials with DUV Cutoff Edges2LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride10Halide Ion-Directed Symmetry Control in π-Conjugated Molecular Crystals6A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy5The different response in band structures and optical properties induced by spin-orbit coupling in Ba3X2(PO4)4 (X = Sb and Bi): A first-principles investigation0Assembly of Highly Polarizable “Linkers” with Heteroleptic Groups for Inducing Large Optical Anisotropy in Ba2SnIIGe3O8S and Ba3SnIIGe3O2S82Facile stoichiometric interfacial engineering of tin phosphate/reduced graphene oxide composites: An efficient electrocatalyst for epinephrine in biological samples3Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals5Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps2Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps1Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides0Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides0

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  1. KSb(BeF 3 )F 3 : a totally fluorine strategy for achieving wide bandgap and large birefringence

    Journal of Materials Chemistry C · 2022-01-01

    Xuehua Dong, Ying Long, Ling Huang, Liling Cao, Daojiang Gao, Jian Bi, Guohong Zou

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  2. Surface-halogen-introduced 2D NiCo bimetallic MOFs via a modulation method for elevated electrochemical glucose sensing

    Inorganic Chemistry Frontiers · 2022-01-01

    Panpan Li, Yang Bai, Guangxun Zhang, Xiaotian Guo, Xiangren Meng, Huan Pang

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  3. Symmetry Analysis of the Complex Polytypism of Layered Rare-Earth Tellurites and Related Selenites: The Case of Introducing Transition Metals

    Symmetry · 2022-10-07

    Dmitri O. Charkin, В. А. Долгих, Timofey A. Omelchenko, Yulia A. Vaitieva, Sergey N. Volkov, Dina V. Deyneko, Sergey M. Aksenov

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  4. ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps

    Inorganic Chemistry · 2022-10-26

    Jin Chen, Ke‐Zhao Du

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  5. Noncentrosymmetric versus Centrosymmetric: Halogen Induced Variable Coordination Modes of Sn2+ and Structural Transition in Sn3B3O7X (X = Cl and Br)

    Inorganic Chemistry · 2022-12-30

    Jingyu Guo, Abudukadi Tudi, Xiaoquan Lu, Shujuan Han

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  6. Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)

    Inorganic Chemistry Frontiers · 2023-01-01

    Jinmiao Jiao, Conggang Li, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

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  7. Anisotropic structure building unit involving diverse chemical bonds: a new opportunity for high-performance second-order NLO materials

    Chemical Society Reviews · 2023-01-01

    Xin Liu, Yi‐Chang Yang, Mengyue Li, Ling Chen, Li‐Ming Wu

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  8. Structure and optical property evolution in PbM(PO 4 )X (M = Zn, Sn; X = halogen): SHG effect and birefringence

    Inorganic Chemistry Frontiers · 2023-01-01

    Xiaobao Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  9. Visualizing the alignment of lone pair electrons in La 3 AsS 5 Br 2 and La 5 As 2 S 9 Cl 3 to form an acentric or centrosymmetric structure

    CrystEngComm · 2023-01-01

    Gary Cicirello, Andrew Swindle, Jian Wang

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  10. Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: Two Phosphite Halides with 3D Structural Networks and Enlarged Birefringence

    Inorganic Chemistry · 2023-01-09

    Gang-Xiang Liu, Ru‐Ling Tang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  11. Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie International Edition · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  12. Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  13. Four UV Transparent Linear and Nonlinear Optical Materials Explored from Pure Selenite Compounds

    Advanced Optical Materials · 2023-09-01

    Pengfei Li, Ya-Ping Gong, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

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  14. Improvement on Magnetocaloric Effect through Structural Evolution in Gadolinium Borate Halides Ba2Gd(BO3)2X (X = F, Cl)

    Inorganic Chemistry · 2023-09-14

    Yuwei Chen, Pifu Gong, Ruixin Guo, Feidi Fan, Jun Shen, Guochun Zhang, Heng Tu

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  15. Positive and Negative Contribution from Lead–Oxygen Groups and Halogen Atoms to Birefringence: A First Principles Investigation

    Nanomaterials · 2023-11-28

    Can Deng, Jialong Wang, Mei Hu, Xiuhua Cui, Haiming Duan, Peng Li, Ming‐Hsien Lee

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  16. CsSn2(HPO3)2I: The first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework

    Scripta Materialia · 2023-12-14

    Liang Ma, Wei Xu, Liyuanyue Xu, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  17. Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks

    Inorganic Chemistry Frontiers · 2024-01-01

    Miao‐Bin Xu, Jin Chen, Huai‐Yu Wu, Jiajia Li, Ning Yu, Mo-Fan Zhuo, Fei‐Fei Mao, Ke‐Zhao Du

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  18. Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence

    Inorganic Chemistry Frontiers · 2024-01-01

    Chenhui Hu, Dongdong Chu, Xueling Hou, Feng Zhang, Jian Wei Han

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  19. From (NH 4 ) 3 [Zr(PO 4 ) 2 F] to (NH 4 ) 3 [Sn 2 (PO 4 ) 2 ]Cl: the rational design of a tin-based short-wave ultraviolet phosphate with large optical anisotropy

    Inorganic Chemistry Frontiers · 2024-01-01

    Zhi Gang Fang, Wenhua Ma, Qiuyu Chen, Xin-Ting Zhu, Xin-Mei Zeng, P. L. Li, Q-W Zhou, Tingting Song, Meihong Duan

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  20. Greatly enhanced optical anisotropy in thiophosphates inspired by rational coupling of tetrahedra and ethane-like [P 2 S 6 ] 4− groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Ning Zhao, Dazhi Lu, Jingjing Xu, Kui Wu, Haohai Yu, Huaijin Zhang

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  21. Halogen regulation of multifunctional hybrid materials with photoluminescence and dielectric response

    Inorganic Chemistry Frontiers · 2024-01-01

    Jiu-Yang Liu, Ming Zhu, Feng-Wen Zhang, Hao‐Fei Ni, Zhi-Long Li, Bo Zhuang, Kun Ying Ding, Da‐Wei Fu, Hai‐Feng Lu, Meng‐Meng Lun

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  22. Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer

    Inorganic Chemistry Frontiers · 2024-01-01

    Qiao Xia, Xingxing Jiang, Qi Lu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Kazuyuki Tatsumi, Chi Zhang

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  23. Li 3 Na 7 B 4 P 6 O 26 : a new ultraviolet transparent congruently melting non-linear optical crystal

    Dalton Transactions · 2024-01-01

    Sujuan Yu, Jiangtao Fan, Zhanggui Hu, Yicheng Wu

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  24. Na 4 Sn 4 (C 2 O 4 ) 3 F 6 and NaSnC 2 O 4 F·H 2 O: two tin( ii ) fluoride oxalates display large birefringence

    Dalton Transactions · 2024-01-01

    Liying Ren, Zeqiao Yin, Shiyi Wang, Zhengyan Lin, Liling Cao, Xuehua Dong, Ling Huang, Yuqiao Zhou, Daojiang Gao, Guohong Zou

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  25. From ZnF2 to ZnF2(H2O)4: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge

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  26. The electronic structures and optical properties induced by spin-orbit-coupling in LiPbPO4 compound

    Journal of Physics D Applied Physics · 2024-05-07

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  27. Structural Regulations of Layered Borates: From Centric Layers to Chiral Porous Layers

    Precision Chemistry · 2024-05-19

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  28. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  29. Optimization of Functional Building Blocks Generates a Substantial Improvement in Birefringence from Sn2OSO4 to Sn3O2(OH)(HSO4)

    Inorganic Chemistry · 2024-07-31

    Yuqi Chen, Han Luo, Zeqiao Yin, Xuehua Dong, Daojiang Gao, Yuqiao Zhou, Ling Huang, Liling Cao, Guohong Zou

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  30. Na(C2H10N2)2[Zn3(PO4)2(H0.5PO4)]2: A Short-Wave Ultraviolet Open-Framework Zincophosphate Exhibiting Substantial Optical Dispersion Ability

    Inorganic Chemistry · 2024-09-25

    Zhi Gang Fang, Chao-Qian Li, Bing‐Ping Yang, Meihong Duan

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  31. From Ba2Bi2Zn(PO4)4 to Ba2Bi2Cu(PO4)4: Rational design of an ultraviolet phosphate with enhanced birefringence

    Journal of Alloys and Compounds · 2024-11-26

    Yin-Jie Peng, Yanbo Li, Jun Li, Chao-Qian Li, Baichuan Wang, Zhi Gang Fang, Meihong Duan

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  32. Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials

    Accounts of Chemical Research · 2024-12-12

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  33. 1D Bi ribbon/[PO 4 ] synergy-driven bismuth phosphates for ultraviolet nonlinear optical crystals with large SHG and birefringence

    Inorganic Chemistry Frontiers · 2025-01-01

    Lei Wu, Xudong Leng, Bao Jiang, Xueyin Fu, Yi Huang, Xue Yu, Qun Jing, Zhaohui Chen

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  34. A new ultraviolet-transparent molybdate featuring a layered structure and moderate birefringence

    New Journal of Chemistry · 2025-01-01

    Shiyu Du, Paipai Zhang, Haozhen Liu, Donghai An, Yanna Chen

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  35. SnHPO4: A Layered Tin(II) Phosphate with Enhanced Birefringence

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  36. Na2MP3O9 (M = K, Rb): Two Potential Zero-Order Waveplate Materials with DUV Cutoff Edges

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  37. LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride

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  38. Halide Ion-Directed Symmetry Control in π-Conjugated Molecular Crystals

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  39. A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy

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  40. The different response in band structures and optical properties induced by spin-orbit coupling in Ba3X2(PO4)4 (X = Sb and Bi): A first-principles investigation

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  41. Assembly of Highly Polarizable “Linkers” with Heteroleptic Groups for Inducing Large Optical Anisotropy in Ba2SnIIGe3O8S and Ba3SnIIGe3O2S8

    Inorganic Chemistry · 2025-09-30

    Jiaxue Wang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  42. Facile stoichiometric interfacial engineering of tin phosphate/reduced graphene oxide composites: An efficient electrocatalyst for epinephrine in biological samples

    Materials Science and Engineering B · 2025-10-09

    Aravindan Santhan, Kuo‐Yuan Hwa, Cheng-Han Wang

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  43. Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals

    Chemical Science · 2025-11-18

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  44. Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps

    Angewandte Chemie International Edition · 2026-04-23

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  45. Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps

    Angewandte Chemie · 2026-04-23

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  46. Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides

    Angewandte Chemie International Edition · 2026-09-03

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  47. Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides

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