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RESEARCH PAPER · Inorganic Chemistry · 2021

Tin(II)-Induced Large Birefringence Enhancement in Metal Phosphates

Mengya Ji, Chun‐Li Hu, Zhi Gang Fang, Yan Chen, Jiang‐Gao Mao

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Tin(II)-Induced Large Birefringence Enhancement in Metal PhosphatesOriginal[C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy40Nain(C2o4)(Hpo4)(H2o)5: An Ultraviolet Transparent Nonlinear Optical Oxalate-Phosphate with Large Birefringence0Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: Two Phosphite Halides with 3D Structural Networks and Enlarged Birefringence18Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence130Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials53Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials5The induced polarization enhanced birefringence in AlPS4 family: A first-principles investigation6Stereochemically Active Tin(II)‐Induced Enhancement of Birefringence in SnIISnIV(PO4)2 and SrSn(PO4)PO2(OH)23(NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence22Designing a Hybrid Perovskite with Enlarged Birefringence and Bandgap for Modulation of Light Polarization32Vanadate Crystals with an Enhanced Birefringence and a Broadened Transparency Spectrum through Controlled [VO3]∞ Chain Arrangements and Alkali Metal Cation Introduction4Rational Design of the Alkali Metal Sn‐Based Mixed Halides with Large Birefringence and Wide Transparent Range44Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks18From (NH 4 ) 3 [Zr(PO 4 ) 2 F] to (NH 4 ) 3 [Sn 2 (PO 4 ) 2 ]Cl: the rational design of a tin-based short-wave ultraviolet phosphate with large optical anisotropy14RbSb(SO 4 )(H 2 PO 2 )F: a short-wave UV antimony( iii ) oxysalt with mixed-anions demonstrating enhanced birefringence11From Ba2Bi2Zn(PO4)4 to Ba2Bi2Cu(PO4)4: Rational design of an ultraviolet phosphate with enhanced birefringence2Functional assembly and modification of nonlinear optical fundamental motifs in phosphates27A 3 Sc(PO 4 ) 2 (A = Li, Na): rare earth cations effectively regulate phosphate structures for enhanced birefringence4All-three-in-one: Pb2(H2PO4)2(C2O4) significantly enhanced birefringence in phosphate materials4(NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance1A Strategy for Enhancing the Optical Anisotropy of Phosphates via Tetrahedral Unit Modification0

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  1. [C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy

    Inorganic Chemistry Frontiers · 2022-01-01

    Xuehua Dong, Zhizhuan Zhang, Ling Huang, Guohong Zou

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  2. Nain(C2o4)(Hpo4)(H2o)5: An Ultraviolet Transparent Nonlinear Optical Oxalate-Phosphate with Large Birefringence

    SSRN Electronic Journal · 2022-01-01

    Xuqi Zhang, Yanyan Xue, Lei Yang, Chao Wu, Zhipeng Huang, Jun Xu, Mark Graeme Humphrey, Chi Zhang

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  3. Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: Two Phosphite Halides with 3D Structural Networks and Enlarged Birefringence

    Inorganic Chemistry · 2023-01-09

    Gang-Xiang Liu, Ru‐Ling Tang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  4. Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie International Edition · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  5. Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  6. Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials

    Angewandte Chemie International Edition · 2023-03-29

    Guangmao Li, Zhihua Yang, Xueling Hou, Shilie Pan

    Read original paper ↗ ·

  7. Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials

    Angewandte Chemie · 2023-03-29

    Guangmao Li, Zhihua Yang, Xueling Hou, Shilie Pan

    Read original paper ↗ ·

  8. The induced polarization enhanced birefringence in AlPS4 family: A first-principles investigation

    Chemical Physics Letters · 2023-04-05

    Ruixin Zhang, Xiuhua Cui, Haiming Duan, Qun Jing, Zhaohui Chen, Ming‐Hsien Lee, Haibin Cao

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  9. Stereochemically Active Tin(II)‐Induced Enhancement of Birefringence in SnIISnIV(PO4)2 and SrSn(PO4)PO2(OH)2

    Chemistry - A European Journal · 2023-05-03

    Lihan Deng, Ruonan Zhang, Jie Zhang, Wenlong Xie, Chunyan Bai, Zhihua Yang, Xueling Hou, Shujuan Han, Shilie Pan

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  10. (NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence

    Small · 2023-07-25

    Nan Ma, Jin Chen, Bingxuan Li, Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·

  11. Designing a Hybrid Perovskite with Enlarged Birefringence and Bandgap for Modulation of Light Polarization

    Small · 2023-10-20

    Weiqi Huang, Xianyu Song, Yanqiang Li, Zhou Yang, Qian-Ting Xu, Yipeng Song, Han Wang, Minjuan Li, Sangen Zhao, Junhua Luo

    Read original paper ↗ ·

  12. Vanadate Crystals with an Enhanced Birefringence and a Broadened Transparency Spectrum through Controlled [VO3]∞ Chain Arrangements and Alkali Metal Cation Introduction

    Inorganic Chemistry · 2023-11-24

    Jinlei Cheng, Die Xu, Juanjuan Lu, Feng Zhang, Xueling Hou

    Read original paper ↗ ·

  13. Rational Design of the Alkali Metal Sn‐Based Mixed Halides with Large Birefringence and Wide Transparent Range

    Small · 2023-12-15

    Jun-Bo Wang, Mengmeng Zhu, Yaoqing Chu, Jindan Tian, Lili Liu, Bingbing Zhang, P. Shiv Halasyamani

    Read original paper ↗ ·

  14. Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks

    Inorganic Chemistry Frontiers · 2024-01-01

    Miao‐Bin Xu, Jin Chen, Huai‐Yu Wu, Jiajia Li, Ning Yu, Mo-Fan Zhuo, Fei‐Fei Mao, Ke‐Zhao Du

    Read original paper ↗ ·

  15. From (NH 4 ) 3 [Zr(PO 4 ) 2 F] to (NH 4 ) 3 [Sn 2 (PO 4 ) 2 ]Cl: the rational design of a tin-based short-wave ultraviolet phosphate with large optical anisotropy

    Inorganic Chemistry Frontiers · 2024-01-01

    Zhi Gang Fang, Wenhua Ma, Qiuyu Chen, Xin-Ting Zhu, Xin-Mei Zeng, P. L. Li, Q-W Zhou, Tingting Song, Meihong Duan

    Read original paper ↗ ·

  16. RbSb(SO 4 )(H 2 PO 2 )F: a short-wave UV antimony( iii ) oxysalt with mixed-anions demonstrating enhanced birefringence

    Journal of Materials Chemistry C · 2024-01-01

    Jinwen Tan, Han Luo, Shiyi Wang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  17. From Ba2Bi2Zn(PO4)4 to Ba2Bi2Cu(PO4)4: Rational design of an ultraviolet phosphate with enhanced birefringence

    Journal of Alloys and Compounds · 2024-11-26

    Yin-Jie Peng, Yanbo Li, Jun Li, Chao-Qian Li, Baichuan Wang, Zhi Gang Fang, Meihong Duan

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  18. Functional assembly and modification of nonlinear optical fundamental motifs in phosphates

    Coordination Chemistry Reviews · 2024-11-27

    Fan Liu, Pifu Gong, Zheshuai Lin, Lei Kang

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  19. A 3 Sc(PO 4 ) 2 (A = Li, Na): rare earth cations effectively regulate phosphate structures for enhanced birefringence

    Dalton Transactions · 2025-01-01

    Hongheng Chen, Xudong Leng, Mei Hu, Yibo Han, Haiming Duan, Qun Jing, Zhaohui Chen, Ming‐Hsien Lee

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  20. All-three-in-one: Pb2(H2PO4)2(C2O4) significantly enhanced birefringence in phosphate materials

    Science China Chemistry · 2025-05-28

    Qingpeng Shao, Qingran Ding, Yanqiu Zhang, Weiqi Huang, Zihao Yu, Yipeng Song, Chengmin Ji, Ziyi Wang, Sangen Zhao, Junhua Luo

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  21. (NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance

    Journal of Molecular Structure · 2025-06-07

    Chen-Yuan Ma, Qiang Tu, Yu-Ming Pan, Pei De Han, Meihong Duan, Zhi Gang Fang

    Read original paper ↗ ·

  22. A Strategy for Enhancing the Optical Anisotropy of Phosphates via Tetrahedral Unit Modification

    Crystal Growth & Design · 2026-06-26

    Bao Jiang, Hongheng Chen, Lei Wu, Xueyin Fu, Maierhaba Abudoureheman, Yi Huang, Ailijiang Abudurusuli, Qun Jing, Xue Yu, Zhaohui Chen

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