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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2020

Syntheses, structures and characterization of non-centrosymmetric Rb 2 Zn 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 M 3 (P 2 O 7 ) 2 (M = Zn and Mg)

Zhongfu Song, Hongwei Yu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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Syntheses, structures and characterization of non-centrosymmetric Rb 2 Zn 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 M 3 (P 2 O 7 ) 2 (M = Zn and Mg)OriginalFrom centrosymmetric to noncentrosymmetric: effect of the cation on the crystal structures and birefringence values of (NH 4 ) n−2 AE(PO 2 F 2 ) n (AE = Mg, Sr and Ba; n = 2, 3 and 4)9In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 219Ultraviolet nonlinear optical crystals A 3 SrBi(P 2 O 7 ) 2 (A = K, Rb) with large second harmonic generation responses15Synthesis, characterization and optical properties of three novel lanthanide sulfates10Triangulation in the Li2ZnP2O7–Na2ZnP2O7–K2ZnP2O7 System7A deep ultraviolet transparent birefringent monofluorophosphate: Cd2.5(NH4)2(PO3F)3Cl ⋅ 2H2O4Structure and optical property evolution in PbM(PO 4 )X (M = Zn, Sn; X = halogen): SHG effect and birefringence21A broad emission band of phosphor Cs2Zn3(P2O7)2:Mn2+ induced by multi-sites of Mn2+12Isomeric Cd(NH4)2(PO3F)2·2H2O: Solution concentration-driven elimination of antiparallel dipole-dipole interaction generating an SHG β phase12Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response7Structural and Magnetic Investigations of the Novel Pyrophosphate Na7Ni3Fe(P2O7)47Synthesis and Structure of New Potassium and Cesium Zinc Diphosphates0Isolated Coordination Polyhedron Confinement in ABP2O7:Mn2+ (A = Ba/Sr; B = Mg/Zn)5Synthesis and Structure of New Potassium and Cesium Zinc Diphosphates2Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances12From ZnF2 to ZnF2(H2O)4: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge19Two Acentric Zn-Based l -Tartrates with Moderate Second Harmonic Generation Responses and Large Birefringence6Crystal structures and photoluminescence properties of undoped and Fe3+ doped Li2Ba3(P2O7)2 pyrophosphate nanopowders9Structural, vibrational and optical characterisations of Li 2 Ba 3 (P 2 O 7 ) 2 :Cr 3+ by solid-state reaction method3Flux Method Growth and Structural Analysis of Two Tetravalent Uranium Orthophosphate Single Crystals, Cs2UIV(PO4)2 and Isostructural Cs2(UIV0.75CeIV0.25)(PO4)24K0.9Rb2.1B8PO16: Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Crystal with Balanced Performance Derived from π-Conjugated and Non-π-Conjugated Groups11Crystallization features of solid solutions of hydrated diphosphates in the system ZnSO4–CoSO4–K4P2O7–H2O0Deep‐Ultraviolet Transparent Nonlinear Optical Phosphates: A New Alternative to Conventional Borates9Four noncentrosymmetric molybdophosphates discovered by a chemical substitution strategy4Incorporation of uranium to the langbeinite family in Cs2UⅣLn(PO4)3 actinide waste forms3Dimensionality Engineering of Fluorozirconium Phosphates for Deep-UV-Transparent Crystals with Enhanced Second-Harmonic Generation and Birefringence10

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  1. From centrosymmetric to noncentrosymmetric: effect of the cation on the crystal structures and birefringence values of (NH 4 ) n−2 AE(PO 2 F 2 ) n (AE = Mg, Sr and Ba; n = 2, 3 and 4)

    Dalton Transactions · 2021-01-01

    Wenyao Zhang, Wenqi Jin, Meng Cheng, Ruonan Zhang, Zhihua Yang, Shilie Pan

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  2. In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 2

    Inorganic Chemistry Frontiers · 2021-01-01

    Chao Wu, Xingxing Jiang, Lin Lin, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  3. Ultraviolet nonlinear optical crystals A 3 SrBi(P 2 O 7 ) 2 (A = K, Rb) with large second harmonic generation responses

    Inorganic Chemistry Frontiers · 2021-01-01

    Shiwei Liu, Bingbing Zhang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  4. Synthesis, characterization and optical properties of three novel lanthanide sulfates

    Journal of Solid State Chemistry · 2021-07-30

    Hui Yang, Cuixia Xu, Li Zhu, Min Li, Guoliang Liu

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  5. Triangulation in the Li2ZnP2O7–Na2ZnP2O7–K2ZnP2O7 System

    Russian Journal of Inorganic Chemistry · 2022-02-01

    М. А. Петрова, O. Yu. Sinel’shchikova

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  6. A deep ultraviolet transparent birefringent monofluorophosphate: Cd2.5(NH4)2(PO3F)3Cl ⋅ 2H2O

    Zeitschrift für anorganische und allgemeine Chemie · 2022-04-01

    Xinrui Yang, Xin Liu, Ling Chen, Li‐Ming Wu

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  7. Structure and optical property evolution in PbM(PO 4 )X (M = Zn, Sn; X = halogen): SHG effect and birefringence

    Inorganic Chemistry Frontiers · 2023-01-01

    Xiaobao Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  8. A broad emission band of phosphor Cs2Zn3(P2O7)2:Mn2+ induced by multi-sites of Mn2+

    Inorganic Chemistry Communications · 2023-01-30

    Shuang-Yin Zhu, Dan Zhao, Wen Liu

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  9. Isomeric Cd(NH4)2(PO3F)2·2H2O: Solution concentration-driven elimination of antiparallel dipole-dipole interaction generating an SHG β phase

    Materials Today Physics · 2023-01-31

    Xinrui Yang, Xin Liu, Xue‐Bin Deng, Ling Chen, Li‐Ming Wu

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  10. Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response

    Chinese Journal of Structural Chemistry · 2023-02-13

    Boxuan Zhang, Zhaohui Chen

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  11. Structural and Magnetic Investigations of the Novel Pyrophosphate Na7Ni3Fe(P2O7)4

    Magnetochemistry · 2023-06-24

    Sirine El Arni, Mohammed Hadouchi, Abderrazzak Assani, Mohamed Saadi, M. El Marssi, Abdelilah Lahmar, Lahcen El Ammari

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  12. Synthesis and Structure of New Potassium and Cesium Zinc Diphosphates

    Физика и химия стекла · 2023-11-01

    D. I. Tsygankova, O. Yu. Sinel’shchikova, В. Л. Уголков

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  13. Isolated Coordination Polyhedron Confinement in ABP2O7:Mn2+ (A = Ba/Sr; B = Mg/Zn)

    Inorganic Chemistry · 2023-11-02

    Li Song, Zhenzhen Zhang, Jilin Zhang, Jiayu Wu, Zhongxian Qiu, M.G. Brik, Shixun Lian

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  14. Synthesis and Structure of New Potassium and Cesium Zinc Diphosphates

    Glass Physics and Chemistry · 2023-12-01

    D. I. Tsygankova, O. Yu. Sinel’shchikova, В. Л. Уголков

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  15. Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances

    Inorganic Chemistry Frontiers · 2024-01-01

    Beibei Zhang, Wen‐Ye Gao, Wei Lin Xu, L. Ma, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

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  16. From ZnF2 to ZnF2(H2O)4: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2024-01-17

    Yue‐Qi Wei, Wei Xu, Lei Huai, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  17. Two Acentric Zn-Based l -Tartrates with Moderate Second Harmonic Generation Responses and Large Birefringence

    Inorganic Chemistry · 2024-03-14

    Ting Yu, Jiahao Wan, Jingye Yang, Xiaokang Luo, Man Xie, Lehui Liu, Hongming Liu

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  18. Crystal structures and photoluminescence properties of undoped and Fe3+ doped Li2Ba3(P2O7)2 pyrophosphate nanopowders

    Nano-Structures & Nano-Objects · 2024-05-01

    N. Ch. Anjaneyulu, Ch. Aswini, K. Josephus Alex Libnah, R.V.S.S.N. Ravikumar

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  19. Structural, vibrational and optical characterisations of Li 2 Ba 3 (P 2 O 7 ) 2 :Cr 3+ by solid-state reaction method

    Materials Research Innovations · 2024-05-09

    N. Ch. Anjaneyulu, Y.V.K. Suresh, G. Vasu, G. Venkata Ramana, R.V.S.S.N. Ravikumar

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  20. Flux Method Growth and Structural Analysis of Two Tetravalent Uranium Orthophosphate Single Crystals, Cs2UIV(PO4)2 and Isostructural Cs2(UIV0.75CeIV0.25)(PO4)2

    Inorganic Chemistry · 2024-09-05

    Yu Wang, Xiaochen Zhang, Lanxin Li, Tao Bo, Lei Zhang

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  21. K0.9Rb2.1B8PO16: Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Crystal with Balanced Performance Derived from π-Conjugated and Non-π-Conjugated Groups

    Inorganic Chemistry · 2024-09-22

    Wenyu He, Xianchao Zhu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  22. Crystallization features of solid solutions of hydrated diphosphates in the system ZnSO4–CoSO4–K4P2O7–H2O

    Functional materials · 2024-09-28

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  23. Deep‐Ultraviolet Transparent Nonlinear Optical Phosphates: A New Alternative to Conventional Borates

    Chemistry - A European Journal · 2024-11-20

    Hua‐Jun Zhao, Jia-Xiang Zhang, Hua Lin

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  24. Four noncentrosymmetric molybdophosphates discovered by a chemical substitution strategy

    Dalton Transactions · 2025-01-01

    Zhixia Gao, Ke Li, Hong Du, Tuohetijiang Baiheti

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  25. Incorporation of uranium to the langbeinite family in Cs2UⅣLn(PO4)3 actinide waste forms

    Communications Chemistry · 2025-11-27

    Yu Wang, Lanxin Li, Tao Bo, Zhenyu Han, Yongliang Tang, Wenwen Lin, Meng Zhang, Jie Qiu, Lei Zhang

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  26. Dimensionality Engineering of Fluorozirconium Phosphates for Deep-UV-Transparent Crystals with Enhanced Second-Harmonic Generation and Birefringence

    Journal of the American Chemical Society · 2026-03-26

    Yuexin Zhang, Yipeng Song, Zhiyong Bai, Zhou Yuan, Wei Huang, Ji Qi, Xinwei Zhou, Sangen Zhao, Ling Chen, Kang Min Ok, Junhua Luo

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