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RESEARCH PAPER · Dalton Transactions · 2016

Three new phosphates with isolated P 2 O 7 units: noncentrosymmetric Cs 2 Ba 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 BaP 2 O 7 and LiCsBaP 2 O 7

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Three new phosphates with isolated P 2 O 7 units: noncentrosymmetric Cs 2 Ba 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 BaP 2 O 7 and LiCsBaP 2 O 7OriginalAMgPO 4 ·6H 2 O (A = Rb, Cs): strong SHG responses originated from orderly PO 4 groups59Experimental and theoretical studies on the linear and nonlinear optical properties of lead phosphate crystals LiPbPO 474K 8 Nb 7 P 7 O 39 : a new type of complicated incommensurately modulated structure and photoluminescence properties of Eu 3+ -doped solid solutions15KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge109A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response384Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)17Strong Nonlinear-Optical Response in the Pyrophosphate CsLiCdP2O7 with a Short Cutoff Edge69LiRb 2 PO 4 : a new deep-ultraviolet nonlinear optical phosphate with a large SHG response95Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response23Structure comparison and optical properties of Na 7 Mg 4.5 (P 2 O 7 ) 4 : a sodium magnesium phosphate with isolated P 2 O 7 units16Syntheses, structures and properties of metal phosphates Pb 2 Mg(PO 4 ) 2 , Pb 4 Zn 8 (PO 4 ) 8 and α-BaZn 2 (PO 4 ) 28M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications238(H 3 O)Ca 2 Zn 3.5 (PO 4 ) 4 and Ba 2 Cd 3 (PO 4 ) 2 (HPO 4 ) 2 : Syntheses, crystal structures and characterizations of two mixed metal phosphates12Linear-to-λ-Shape P–O–P Bond Transmutation in Polyphosphates with Infinite (PO3)∞ Chain15Li1.52Na4.48Cd8(PO4)2(P2O7)4: A new mixed-anion diphosphate containing four types of dimensions groups9Insights of BO 3 –PO 4 replacement for the design and synthesis of a new borate–phosphate with unique 1∞[Zn 4 BO 11 ] chains and two new phosphates16K 2 TeP 2 O 8 : a new telluro-phosphate with a pentagonal Te–P–O layer structure26Non-Centrosymmetric RbNaMgP 2 O 7 with Unprecedented Thermo-Induced Enhancement of Second Harmonic Generation239Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals257Crystal structures and theoretical studies of polyphosphate LiZnP3O9 for nonlinear optical applications18Enhanced photoluminescence properties and energy transfer in a new Tb3+ and Ce3+ co-doped KBa2(PO3)5 green-emitting phosphor4ALiZnP2O7 (A = Rb, Cs): Two Mixed Alkali Zinc Pyrophosphates Featuring a [Li2Zn2P4O20]14– Anionic Skeleton34Czochralski Growth and Characterization of a Novel Nonlinear Optical Crystal Te2P2O923Experimental characterization and first principles calculations of linear and nonlinear optical properties of two orthophosphates A 3 Al 2 (PO 4 ) 3 (A = Rb, K)36A new diphosphate Ba 2 LiGa(P 2 O 7 ) 2 : synthesis, crystal structure and Eu 3+ -activated fluorescence performance14Fluoroborophosphates: a family of potential deep ultraviolet NLO materials43K 2 SrP 4 O 12 : a deep-UV transparent cyclophosphate as a nonlinear optical crystal79Modulation of perovskite-related frameworks induced by alkaline earth metals in phosphate fluorides A 2 MPO 4 F (A = K, Rb; M = Ba, Ca)8Structural insights into three phosphates with distinct polyanionic configurations20Three new phosphates, Cs8Pb4(P2O7)4, CsLi7(P2O7)2 and LiCa(PO3)3: structural comparison, characterization and theoretical calculation23Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges0Lone‐Pair Enhanced Birefringence in an Alkaline‐Earth Metal Tin(II) Phosphate BaSn 2 (PO 4 ) 2130CsLiMgP2O7: A congruently melting pyrophosphate with a [LiMgP4O18] 6-membered ring fundamental building block5Investigating Cationic Distribution, Defect Structure and Phosphor Characteristics of Na 2 Sm 2 Ca 6 (PO 4 ) 6 F 27RbB 11 O 16 (OH) 2 : First Hydroxyl Rubidium Borate with the B‐O 2D Layer Featuring Large Birefringence in the Rb‐B‐O‐H System5LiGaP 2 O 7 : A Potential UV Nonlinear-Optical Crystal14Synthesis, structure and characterization of a new triphosphate: CsMg2P3O102Syntheses, crystal structures, and characterizations of three new pyrophosphates CsNaZnP2O7, RbNaZnP2O7, and RbLiMgP2O710A new rare-earth phosphate compound Cs4PbTb2(PO3)12: Crystal structure and multicolor emitting properties introduced by Eu3+ doping5Three diphosphates, α-Li 2 Na 2 P 2 O 7 , Li 8 Pb 3 Ba(P 2 O 7 ) 4 and Li 7 Rb(P 2 O 7 ) 2 : influences of co-substitution on the crystal structure9Three non-centrosymmetric bismuth phosphates, Li 2 ABi(PO 4 ) 2 (A = K, Rb, and Cs): effects of cations on the crystal structure and SHG response23Highly Efficient Green‐to‐Yellowish‐Orange Emitting Eu2+‐Doped Pyrophosphate Phosphors with Superior Thermal Quenching Resistance for w‐LEDs99Ultraviolet nonlinear optical crystal: (NH4)ZnPO47Effects of P2O7 clusters arrangement on second harmonic generation responses of pyrophosphates14The first rare-earth lead phosphates Pb3AP3O12 (A=Sc, Gd) with remarkable SHG enhancement8Noncentrosymmetric Orthophosphate YM3(PO4)3 (M = Sr, Ba) Crystals: Single Crystal Growth, Structure, and Properties34Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials137Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials29Computationally assisted multistage design and prediction driving the discovery of deep-ultraviolet nonlinear optical materials41A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups106A new series of rare-earth borate-phosphate family CsNa2Ln2(BO3)(PO4)2 (Ln = Ho, Er, Tm, Yb): Tunnel structure, upconversion luminescence and optical thermometry properties28AZn(PO3)3 (A = K, Rb): Deep-Ultraviolet Nonlinear Optical Phosphates Derived from Synergy of a Unique [ZnO6] Octahedron and a [PO3]∞ Chain25An Overview on Recent Trends in Deep‐Ultraviolet (DUV) and Ultraviolet (UV) Nonlinear Optical Crystals25Studies on structural, Optical and electrical properties of K2Ba3(P2O7)213Recent Development of Non-π-Conjugated Deep Ultraviolet Nonlinear Optical Materials106Structural and spectral investigation of a near-UV-converted LiSrP3O9:Dy3+ phosphor for white light-emitting diodes16Lone Pair-Driven Enhancement of Birefringence in Polar Alkali Metal Antimony Phosphates46Co-substitution design: a new glaserite-type rare-earth phosphate K 2 RbSc(PO 4 ) 2 with high structural tolerance6Syntheses, characterization and theoretical calculation of the first alkali magnesium pyrophosphate fluorides with a short cutoff edge4Towards efficient blue Eu2+ activated pyrophosphate phosphor for warm white LED applications13K2Sr4(PO3)10: A Polyphosphate with Deep-UV Cutoff Edge and Enlarged Birefringence6The effect of co-substitution of heterovalent ions Ga 3+ and Sb 5+ on nonlinear optical properties of phosphate crystals0Crystal structures and photoluminescence properties of undoped and Fe3+ doped Li2Ba3(P2O7)2 pyrophosphate nanopowders9Deep‐Ultraviolet Transparent Nonlinear Optical Phosphates: A New Alternative to Conventional Borates9Four noncentrosymmetric molybdophosphates discovered by a chemical substitution strategy4Multi-site occupied Cs2Ba3(P2O7)2:Eu2+ phosphor with blue-green dual emission for full-spectrum lighting2Mn-, Co-, Cu-, and Cd-substituted Ti 2 (PO 4 ) 3 nanoparticles: optical, magnetic, and photocatalytic properties3Dimensionality Engineering of Fluorozirconium Phosphates for Deep-UV-Transparent Crystals with Enhanced Second-Harmonic Generation and Birefringence10

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  1. AMgPO 4 ·6H 2 O (A = Rb, Cs): strong SHG responses originated from orderly PO 4 groups

    Journal of Materials Chemistry C · 2016-01-01

    Yuqiao Zhou, Liling Cao, Chensheng Lin, Min Luo, Tao Yan, Ning Ye, Wendan Cheng

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  2. Experimental and theoretical studies on the linear and nonlinear optical properties of lead phosphate crystals LiPbPO 4

    Physical Chemistry Chemical Physics · 2016-01-01

    Guopeng Han, Qiong Liu, Ying Wang, Xin Su, Zhihua Yang, Shilie Pan

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  3. K 8 Nb 7 P 7 O 39 : a new type of complicated incommensurately modulated structure and photoluminescence properties of Eu 3+ -doped solid solutions

    Journal of Materials Chemistry C · 2016-01-01

    Dan Zhao, Junyan Cui, Hongxian Han, Can Li

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  4. KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge

    Journal of Materials Chemistry C · 2016-01-01

    Maierhaba Abudoureheman, Shujuan Han, Bing‐Hua Lei, Zhihua Yang, Xifa Long, Shilie Pan

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  5. A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response

    Journal of the American Chemical Society · 2016-07-12

    Lin Li, Ying Wang, Bing‐Hua Lei, Shujuan Han, Zhihua Yang, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  6. Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)

    Journal of Alloys and Compounds · 2016-08-20

    Maierhaba Abudoureheman, Shujuan Han, Xiaoyu Dong, Bing‐Hua Lei, Ying Wang, Zhihua Yang, Xifa Long, Shilie Pan

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  7. Strong Nonlinear-Optical Response in the Pyrophosphate CsLiCdP2O7 with a Short Cutoff Edge

    Inorganic Chemistry · 2016-10-31

    Yaoguo Shen, Sangen Zhao, Bingqing Zhao, Chengmin Ji, Lina Li, Zhihua Sun, Maochun Hong, Junhua Luo

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  8. LiRb 2 PO 4 : a new deep-ultraviolet nonlinear optical phosphate with a large SHG response

    Journal of Materials Chemistry C · 2016-11-21

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  9. Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response

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    Chao Wu, Longhua Li, Gang Yang, Jun‐Ling Song, Bing Yan, Mark Graeme Humphrey, Long Zhang, Jianda Shao, Chi Zhang

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  10. Structure comparison and optical properties of Na 7 Mg 4.5 (P 2 O 7 ) 4 : a sodium magnesium phosphate with isolated P 2 O 7 units

    New Journal of Chemistry · 2017-01-01

    Ruru Ma, Yun Mo Yang, Shilie Pan, Yanzhou Sun, Zhihua Yang

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  11. Syntheses, structures and properties of metal phosphates Pb 2 Mg(PO 4 ) 2 , Pb 4 Zn 8 (PO 4 ) 8 and α-BaZn 2 (PO 4 ) 2

    Dalton Transactions · 2017-01-01

    Xiaobo Pan, Ming Wen, Guijie He, Hongyi Li, Dianzeng Jia

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  12. M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications

    Chemistry of Materials · 2017-01-30

    Hongwei Yu, Joshua Young, Hongping Wu, Weiguo Zhang, James M. Rondinelli, P. Shiv Halasyamani

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  13. (H 3 O)Ca 2 Zn 3.5 (PO 4 ) 4 and Ba 2 Cd 3 (PO 4 ) 2 (HPO 4 ) 2 : Syntheses, crystal structures and characterizations of two mixed metal phosphates

    Journal of Solid State Chemistry · 2017-04-08

    Tong-Ying Chang, Chun‐Li Hu, Dong Yan, Jiang‐Gao Mao

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  14. Linear-to-λ-Shape P–O–P Bond Transmutation in Polyphosphates with Infinite (PO3)∞ Chain

    Inorganic Chemistry · 2017-08-15

    Ying Wang, Lin Li, Shujuan Han, Bing‐Hua Lei, Maierhaba Abudoureheman, Zhihua Yang, Shilie Pan

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  15. Li1.52Na4.48Cd8(PO4)2(P2O7)4: A new mixed-anion diphosphate containing four types of dimensions groups

    Inorganic Chemistry Communications · 2017-11-07

    Yuan Fang, Zhaohui Chen, Yunjing Shi, Wenyao Zhang, Xiaoyu Dong

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  16. Insights of BO 3 –PO 4 replacement for the design and synthesis of a new borate–phosphate with unique 1∞[Zn 4 BO 11 ] chains and two new phosphates

    Inorganic Chemistry Frontiers · 2017-11-27

    Fengjiao Guo, Cong Hu, Ying Wang, Jian Wei Han, Zhihua Yang, Shilie Pan

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  17. K 2 TeP 2 O 8 : a new telluro-phosphate with a pentagonal Te–P–O layer structure

    Dalton Transactions · 2018-01-01

    Ming Wen, Cong Hu, Zhihua Yang, Xiaohong Wu, Shilie Pan

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  18. Non-Centrosymmetric RbNaMgP 2 O 7 with Unprecedented Thermo-Induced Enhancement of Second Harmonic Generation

    Journal of the American Chemical Society · 2018-01-18

    Sangen Zhao, Xiaoyan Yang, Yi Jin Yang, Xiaojun Kuang, Fengqi Lu, Pai Shan, Zhihua Sun, Zheshuai Lin, Maochun Hong, Junhua Luo

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  19. Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

    Coordination Chemistry Reviews · 2018-03-15

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  20. Crystal structures and theoretical studies of polyphosphate LiZnP3O9 for nonlinear optical applications

    Journal of Solid State Chemistry · 2018-03-29

    Zhiqing Xie, Xin Su, Hanqin Ding, Hongyi Li

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  21. Enhanced photoluminescence properties and energy transfer in a new Tb3+ and Ce3+ co-doped KBa2(PO3)5 green-emitting phosphor

    Optik · 2018-04-16

    Cong-Kui Nie, Lei Zhang, Ji Zhao, Meng-Yu Duan, Yun-Chang Fan, Dan Zhao

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  22. ALiZnP2O7 (A = Rb, Cs): Two Mixed Alkali Zinc Pyrophosphates Featuring a [Li2Zn2P4O20]14– Anionic Skeleton

    Inorganic Chemistry · 2018-08-20

    Zhaohui Chen, Yuan Fang, Wenyao Zhang, Wenqiang Chen, Xuefang Lu, Qun Jing, Ming‐Hsien Lee

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  23. Czochralski Growth and Characterization of a Novel Nonlinear Optical Crystal Te2P2O9

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  24. Experimental characterization and first principles calculations of linear and nonlinear optical properties of two orthophosphates A 3 Al 2 (PO 4 ) 3 (A = Rb, K)

    Inorganic Chemistry Frontiers · 2018-12-20

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  25. A new diphosphate Ba 2 LiGa(P 2 O 7 ) 2 : synthesis, crystal structure and Eu 3+ -activated fluorescence performance

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  26. Fluoroborophosphates: a family of potential deep ultraviolet NLO materials

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  27. K 2 SrP 4 O 12 : a deep-UV transparent cyclophosphate as a nonlinear optical crystal

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  28. Modulation of perovskite-related frameworks induced by alkaline earth metals in phosphate fluorides A 2 MPO 4 F (A = K, Rb; M = Ba, Ca)

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  29. Structural insights into three phosphates with distinct polyanionic configurations

    Dalton Transactions · 2019-01-01

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  30. Three new phosphates, Cs8Pb4(P2O7)4, CsLi7(P2O7)2 and LiCa(PO3)3: structural comparison, characterization and theoretical calculation

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  31. Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges

    New Journal of Chemistry · 2019-01-01

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  32. Lone‐Pair Enhanced Birefringence in an Alkaline‐Earth Metal Tin(II) Phosphate BaSn 2 (PO 4 ) 2

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  33. CsLiMgP2O7: A congruently melting pyrophosphate with a [LiMgP4O18] 6-membered ring fundamental building block

    Solid State Sciences · 2019-03-04

    Yunfei Li, Fei Liang, Huimin Song, Wang Liu, Zheshuai Lin, Guochun Zhang, Yicheng Wu

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  34. Investigating Cationic Distribution, Defect Structure and Phosphor Characteristics of Na 2 Sm 2 Ca 6 (PO 4 ) 6 F 2

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  35. RbB 11 O 16 (OH) 2 : First Hydroxyl Rubidium Borate with the B‐O 2D Layer Featuring Large Birefringence in the Rb‐B‐O‐H System

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  36. LiGaP 2 O 7 : A Potential UV Nonlinear-Optical Crystal

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  37. Synthesis, structure and characterization of a new triphosphate: CsMg2P3O10

    Solid State Sciences · 2019-06-14

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  38. Syntheses, crystal structures, and characterizations of three new pyrophosphates CsNaZnP2O7, RbNaZnP2O7, and RbLiMgP2O7

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  39. A new rare-earth phosphate compound Cs4PbTb2(PO3)12: Crystal structure and multicolor emitting properties introduced by Eu3+ doping

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  40. Three diphosphates, α-Li 2 Na 2 P 2 O 7 , Li 8 Pb 3 Ba(P 2 O 7 ) 4 and Li 7 Rb(P 2 O 7 ) 2 : influences of co-substitution on the crystal structure

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  41. Three non-centrosymmetric bismuth phosphates, Li 2 ABi(PO 4 ) 2 (A = K, Rb, and Cs): effects of cations on the crystal structure and SHG response

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  42. Highly Efficient Green‐to‐Yellowish‐Orange Emitting Eu2+‐Doped Pyrophosphate Phosphors with Superior Thermal Quenching Resistance for w‐LEDs

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  43. Ultraviolet nonlinear optical crystal: (NH4)ZnPO4

    Inorganic Chemistry Communications · 2020-01-21

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  44. Effects of P2O7 clusters arrangement on second harmonic generation responses of pyrophosphates

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  45. The first rare-earth lead phosphates Pb3AP3O12 (A=Sc, Gd) with remarkable SHG enhancement

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  46. Noncentrosymmetric Orthophosphate YM3(PO4)3 (M = Sr, Ba) Crystals: Single Crystal Growth, Structure, and Properties

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  47. Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials

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  48. Two Pyrophosphates with Large Birefringences and Second‐Harmonic Responses as Ultraviolet Nonlinear Optical Materials

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  49. Computationally assisted multistage design and prediction driving the discovery of deep-ultraviolet nonlinear optical materials

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  50. A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups

    Coordination Chemistry Reviews · 2021-01-19

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