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RESEARCH PAPER · Journal of the American Chemical Society · 2016

A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response

Lin Li, Ying Wang, Bing‐Hua Lei, Shujuan Han, Zhihua Yang, Kenneth Reinhard Poeppelmeier, Shilie Pan

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A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation ResponseOriginalAMgPO 4 ·6H 2 O (A = Rb, Cs): strong SHG responses originated from orderly PO 4 groups59KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge109Deep-Ultraviolet Transparent Cs 2 LiPO 4 Exhibits an Unprecedented Second Harmonic Generation162Syntheses and Characterizations of Three Bismuth(III)‐Containing Mixed‐Metal Phosphates:Ba 2 Bi 2 M II (PO 4 ) 4 (M= Mn, Ni, Cu)2Strong Nonlinear-Optical Response in the Pyrophosphate CsLiCdP2O7 with a Short Cutoff Edge69LiRb 2 PO 4 : a new deep-ultraviolet nonlinear optical phosphate with a large SHG response95LiRb 2 LaB 2 O 6 : a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge15A new phase-matchable nonlinear optical silicate: Rb 2 ZnSi 3 O 826Application of the dimensional reduction formalism to Pb 9−x Ba x [Li 2 (P 2 O 7 ) 2 (P 4 O 13 ) 2 ] (x = 0, 2, 6, 7): a series of phosphates with two types of isolated polyphosphate groups13Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity44BaCu 2 M IV Q 4 (M IV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations55Enhancing optical anisotropy of crystals by optimizing bonding electron distribution in anionic groups237Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response23Solvent-controlled syntheses of mixed-alkali-metal borates exhibiting UV nonlinear optical properties23Structure comparison and optical properties of Na 7 Mg 4.5 (P 2 O 7 ) 4 : a sodium magnesium phosphate with isolated P 2 O 7 units16Syntheses, structures and properties of metal phosphates Pb 2 Mg(PO 4 ) 2 , Pb 4 Zn 8 (PO 4 ) 8 and α-BaZn 2 (PO 4 ) 28Theoretical investigation on the balance between large band gap and strong SHG response in BMO 4 (M = P and As) crystals22Top-Seeded Solution Crystal Growth and Linear and Nonlinear Optical Properties of Ba 4 B 11 O 20 F42M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications240A3Sr2P7O21 (A = Rb, Cs): Two Polyphosphates Based on Different Types of P–O Chains and Ring Structures36Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold51(H 3 O)Ca 2 Zn 3.5 (PO 4 ) 4 and Ba 2 Cd 3 (PO 4 ) 2 (HPO 4 ) 2 : Syntheses, crystal structures and characterizations of two mixed metal phosphates12Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion64Growth, Properties, and Theoretical Analysis of M2LiVO4 (M = Rb, Cs) Crystals: Two Potential Mid-Infrared Nonlinear Optical Materials36Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials5Second-harmonic generation in noncentrosymmetric phosphates47Deep-Ultraviolet Nonlinear-Optical Material K3Sr3Li2Al4B6O20F: Addressing the Structural Instability Problem in KBe2BO3F2105Linear-to-λ-Shape P–O–P Bond Transmutation in Polyphosphates with Infinite (PO3)∞ Chain15Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se137CsB 4 O 6 F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units185CsB4O6F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units895Neutron diffraction reveals the existence of confined water in triangular and hexagonal channels of modified YPO4 at elevated temperatures7New Compressed Chalcopyrite-like Li2BaMIVQ4 (MIV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials246Synthesis, Structure, and Properties of Nonlinear Optical Crystal Na2SiF622Li1.52Na4.48Cd8(PO4)2(P2O7)4: A new mixed-anion diphosphate containing four types of dimensions groups9K2[B3O3(OH)5]: A new deep-UV nonlinear optical crystal with isolated [B3O3(OH)5]2- anionic groups31Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials268Two different types of channels exhibiting distinct proton transport behavior in an open-framework aluminophosphate3From a Metastable Layer to a Stable Ring: A Kinetic Study for Transformation Reactions of Li2Mo3TeO12 to Polyoxometalates12A beryllium-free deep-UV nonlinear optical material CsNaMgP 2 O 7 with honeycomb-like topological layers53Cs 3 VO(O 2 ) 2 CO 3 : an exceptionally thermostable carbonatoperoxovanadate with an extremely large second-harmonic generation response129Four new quaternary chalcogenides A 2 Ba 7 Sn 4 Q 16 (A = Li, Na; Q = S, Se): syntheses, crystal structures determination, nonlinear optical performances investigation26K 2 TeP 2 O 8 : a new telluro-phosphate with a pentagonal Te–P–O layer structure26Li 8 NaRb 3 (SO 4 ) 6 ·2H 2 O as a new sulfate deep-ultraviolet nonlinear optical material93Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials192Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials714A Joint Strategy To Evaluate the Microscopic Origin of the Second-Harmonic-Generation Response in Nonpolar ABCO3F Compounds32Non-Centrosymmetric RbNaMgP 2 O 7 with Unprecedented Thermo-Induced Enhancement of Second Harmonic Generation240Syntheses, Crystal Structures and Luminescent Properties of Two New Heterometallic Phosphates: Sn 2 Ge(PO 4 ) 2 (OH) 2 and Sn 2 Mn(PO 4 ) 27Synthesis, crystal structure and characterizations of a new diphosphate Rb2CaP2O719The Large Second‐Harmonic Generation of LiCs2PO4 is caused by the Metal‐Cation‐Centered Groups107The Large Second‐Harmonic Generation of LiCs2PO4 is caused by the Metal‐Cation‐Centered Groups23M2B10O14F6 (M = Ca, Sr): Two Noncentrosymmetric Alkaline Earth Fluorooxoborates as Promising Next-Generation Deep-Ultraviolet Nonlinear Optical Materials357Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals256Crystal structures and theoretical studies of polyphosphate LiZnP3O9 for nonlinear optical applications19The relationship between covalent bonds and the optical response in a nonpolar family ATeMoO 6 (A=Mg, Zn, Cd): A Berry-phase investigation14Computer-Assisted Design of a Superior Be 2 BO 3 F Deep-Ultraviolet Nonlinear-Optical Material41Synthesis, structure and electronic structure calculation of a new perovskite-type phosphate fluoride K2BaPO4F10Rational Design of the First Lead/Tin Fluorooxoborates MB2O3F2 (M = Pb, Sn), Containing Flexible Two-Dimensional [B6O12F6]∞ Single Layers with Widely Divergent Second Harmonic Generation Effects212From Sr2Nb2O7to CaxSr2–xNb2O7: An Effective Enhancement of Nonlinear Optical Activity by a Simple Way of Cation Substituting11MIMIIP3O9 (MI = Rb, MII = Cd, Mg, Ca; MI = Cs, MII = Pb, Sr; MI = K, MII = Mg): Cation Substitution Application in Cyclophosphate Family and Nonlinear Optical Properties35Non-centrosymmetric BaNaP3O9 with a short deep-ultraviolet cutoff edge14Expanding Frontiers of Ultraviolet Nonlinear Optical Materials with Fluorophosphates266Two noncentrosymmetric polyphosphates featuring infinite one-dimensional (PO3)∞ chain, LiMP2O6 (M = Rb, Cs): Synthesis, structure and optical properties8Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials102Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24Module-Guided Design Scheme for Deep-Ultraviolet Nonlinear Optical Materials197ALiZnP2O7 (A = Rb, Cs): Two Mixed Alkali Zinc Pyrophosphates Featuring a [Li2Zn2P4O20]14– Anionic Skeleton36Two new mixed metal borates with the large birefringence in borates system confirmed by a disordered crystal optical calculation method6Synthesis, Structure, and Properties of the Non-Centrosymmeteric Compound LiNaRbB5O8(OH)23A Langbeinite-Type Yttrium Phosphate LiCs2Y2(PO4)336Physical Properties of a Promising Nonlinear Optical Crystal K3Ba3Li2Al4B6O20F15Ba2NaClP2O7: Unprecedented Phase Matchability Induced by Symmetry Breaking and Its Unique Fresnoite-Type Structure246Monofluorophosphates: A New Source of Deep-Ultraviolet Nonlinear Optical Materials258The linear and nonlinear optical response of CsGeX3 (X=Cl, Br, and I): The finite field and first-principles investigation26Experimental characterization and first principles calculations of linear and nonlinear optical properties of two orthophosphates A 3 Al 2 (PO 4 ) 3 (A = Rb, K)37A 2 Bi 2 (SO 4 ) 2 Cl 4 (A = NH 4 , K, Rb): achieving a subtle balance of the large second harmonic generation effect and sufficient birefringence in sulfate nonlinear optical materials99A new ultraviolet transparent hydra-cyanurate K 2 (C 3 N 3 O 3 H) with strong optical anisotropy from delocalized π-bonds56Adjustable optical nonlinearity in d 10 cations containing chalcogenides via dp hybridization interaction13An alkali metal phosphate RbPbBi 2 (PO 4 ) 3 with three kinds of disorder: the effect of isolated soft cation units on the crystal structure7Centrosymmetric K 2 SO 4 ·(SbF 3 ) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3 ) 2 resulting from cooperative effects of lone pair and cation size63Exploration of the deep-ultraviolet nonlinear optical materials in the derivatives of KBe2BO3F27Growth and theoretical study on the deep-ultraviolet transparent β-CsBa 2 (PO 3 ) 5 nonlinear optical crystal10Hybridization-activated new deep ultraviolet transparent nonlinear optical material Ba 11 [Al(PO 4 ) 4 ](P 2 O 7 )(PO 4 ) 3 with balanced overall performance and parsimony-forbidden structure23K 2 SrP 4 O 12 : a deep-UV transparent cyclophosphate as a nonlinear optical crystal79LiGeBO 4 : a nonlinear optical material with a balance between deep-ultraviolet cut-off edge and large SHG response induced by hand-in-hand tetrahedra21Modulation of perovskite-related frameworks induced by alkaline earth metals in phosphate fluorides A 2 MPO 4 F (A = K, Rb; M = Ba, Ca)8Non-concentration quenching, good thermal stability and high quantum efficiency of K 5 Y(P 2 O 7 ) 2 :Eu 3+ /Tb 3+ phosphors with a novel two-dimensional layer structure79RbSbSO 4 Cl 2 : an excellent sulfate nonlinear optical material generated due to the synergistic effect of three asymmetric chromophores79Structural insights into three phosphates with distinct polyanionic configurations20Three new phosphates, Cs8Pb4(P2O7)4, CsLi7(P2O7)2 and LiCa(PO3)3: structural comparison, characterization and theoretical calculation23Two new tin( iv )-containing phosphate fluorides with two types of Sn( iv )–P–O–F frameworks and short cutoff edges0A New Cadmium‐Based Pb2Cd3(PO4)2(P2O7) with Two Types of Isolated P–O Groups18Lone‐Pair Enhanced Birefringence in an Alkaline‐Earth Metal Tin(II) Phosphate BaSn 2 (PO 4 ) 2131KLi(HC 3 N 3 O 3 )·2H 2 O: Solvent-drop Grinding Method toward the Hydro-isocyanurate Nonlinear Optical Crystal314Bismuth vanadate single crystal particles modified with tungsten for efficient photoeletrochemical water oxidation15Two Non-π-Conjugated Deep-UV Nonlinear Optical Sulfates269Investigating Cationic Distribution, Defect Structure and Phosphor Characteristics of Na 2 Sm 2 Ca 6 (PO 4 ) 6 F 27Refractive Index Modulates Second-Harmonic Responses in RE 8 O(CO 3 ) 3 (OH) 15 X (RE = Y, Lu; X = Cl, Br): Rare-Earth Halide Carbonates as Ultraviolet Nonlinear Optical Materials37The first barium lead oxychloride Ba27Pb8O8Cl54 with new isolated [Pb4O4] clusters3Rational Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Fluorinated Orthophosphate: BaZn(PO4)F16RbB 11 O 16 (OH) 2 : First Hydroxyl Rubidium Borate with the B‐O 2D Layer Featuring Large Birefringence in the Rb‐B‐O‐H System5Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses67Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)·H2O and Non-Centrosymmetric K2B5O8(OH)·2H2O8Cs2Zn5(PO4)4 and Cs3La(PO4)2: Two Cs‐Containing Phosphates with Three‐Dimensional Frameworks14Uniform Alignment of Non-π-Conjugated Species Enhances Deep Ultraviolet Optical Nonlinearity370LiGaP 2 O 7 : A Potential UV Nonlinear-Optical Crystal14Selective Propylene Production via Propane Oxychlorination on Metal Phosphate Catalysts23Highly Polarizable Hg2+ Induced a Strong Second Harmonic Generation Signal and Large Birefringence in LiHgPO4268Untangling electronic, optical and bonding properties of hexagonal bismuth borate SrBi2B2O7 crystal for ultraviolet opto-electronic applications: An ab initio study8Further Example of Diphosphates: Synthesis and Characterization of K2Li2P2O72Synthesis, characterization and theoretical calculation of a noncentrosymmetric compound, Cs0.92B0.92Si5.08O122Centrosymmetric Rb2Mg3(SO4)4 and non-centrosymmetric Cs2Mg3(SO4)4 with a phase-matching nonlinear optical response35Syntheses, crystal structures, and characterizations of three new pyrophosphates CsNaZnP2O7, RbNaZnP2O7, and RbLiMgP2O710A solid-state chemist’s eye for the development of materials science in China5[NH4]12[(MoO2)2O(HPO4)2]4[PO4]Cl·0.5H2O: A mixed phosphomolybdate with nonlinear optical properties4LiCsPbP2O7: A new alkali metal lead pyrophosphate featuring two dimensional [LiP2O7]∞ layer2KMg(H 2 O)PO 4 : A Deep-Ultraviolet Transparent Nonlinear Optical Material Derived from KTiOPO 484Synthesis, characterization, and properties of two new phosphate crystals MZnAl(PO4)2 (M = Na, K) with 3D framework tunnel structures14β-Ba(PO3)2 with DUV cut-off edge and large birefringence5Crystal property and spectroscopic investigation on electro-optic and physico-chemical properties of NLO crystal; 3-(3,4-Dihydroxyphenyl)-L-Alanine3A new iodate-phosphate Pb 2 (IO 3 )(PO 4 ) achieving great improvement in birefringence activated by (IO 3 ) − groups54Emergent Deep‐Ultraviolet Nonlinear Optical Candidates327Neue Kandidaten für die nichtlineare Optik im Tief‐UV‐Bereich43Syntheses, characterization, and theoretical calculation of Rb2Mg3(P2O7)2 polymorphs with deep-ultraviolet cutoff edges18(NH 4 ) 3 [B(OH) 3 ] 2 (COOH) 3 : a graphite-like UV nonlinear optical material with a large birefringence via structural optimization31BaWO 2 F 4 : a mixed anion X-ray scintillator with excellent photoluminescence quantum efficiency19Experimental and theoretical studies of the ternary thiophosphate PbPS 3 featuring ethane-like [P 2 S 6 ] 4− units15From centrosymmetric to noncentrosymmetric: intriguing structure evolution in d 10 -transition metal iodate fluorides36M 4 LiBe 4 P 7 O 24 and M 4 Li(Li 3 P)P 7 O 24 (M = Cs, Rb): deep-ultraviolet nonlinear-optical phosphates with a tetrahedra-substituted paracelsian-like framework9Na 3 Sc 2 (PO 4 ) 2 F 3 : rational design and synthesis of an alkali rare-earth phosphate fluoride as an ultraviolet nonlinear optical crystal with an enlarged birefringence49PbSrSiO 4 : a new ultraviolet nonlinear optical material with a strong second harmonic generation response and moderate birefringence37Polar polymorphism: α- and β-KCsWP 2 O 9 nonlinear optical materials with a strong second harmonic generation response25Syntheses, structures and characterization of non-centrosymmetric Rb 2 Zn 3 (P 2 O 7 ) 2 and centrosymmetric Cs 2 M 3 (P 2 O 7 ) 2 (M = Zn and Mg)26Te 3 O 3 (PO 4 ) 2 : a phosphate crystal with large birefringence activated by the highly distorted [TeO 5 ] group and antiparallel [PO 4 ] pseudo-layer33The functionality of tetrahedral units in fluoroxoiodates: fluorine-modulating effects in iodates with lone pair electrons3Three diphosphates, α-Li 2 Na 2 P 2 O 7 , Li 8 Pb 3 Ba(P 2 O 7 ) 4 and Li 7 Rb(P 2 O 7 ) 2 : influences of co-substitution on the crystal structure9Three non-centrosymmetric bismuth phosphates, Li 2 ABi(PO 4 ) 2 (A = K, Rb, and Cs): effects of cations on the crystal structure and SHG response24Two new ammonium/alkali-rare earth metal difluorophosphates ALa(PO 2 F 2 ) 4 (A = NH 4 and K) with moderate birefringence and short cutoff edges26Ultraviolet nonlinear optical crystal: (NH4)ZnPO47Key Factors Controlling the Large Second Harmonic Generation in Nonlinear Optical Materials38Effects of P2O7 clusters arrangement on second harmonic generation responses of pyrophosphates14A reversible, benzothiazole-based “Turn-on” fluorescence sensor for selective detection of Zn2+ ions in vitro9Influence of Cation on the Anion Frameworks and Properties of Four Lead Phosphates, A2PbBi2(PO4)2(P2O7) (A = Rb, Cs) and A2PbP2O7 (A = K, Rb)15Synthesis, Crystal Structure, and Characterization of a Noncentrosymmetric Sulfate Cs2Ca2(SO4)320The first rare-earth lead phosphates Pb3AP3O12 (A=Sc, Gd) with remarkable SHG enhancement8Noncentrosymmetric Orthophosphate YM3(PO4)3 (M = Sr, Ba) Crystals: Single Crystal Growth, Structure, and Properties34Designing Silicates as Deep‐UV Nonlinear Optical (NLO) Materials using Edge‐Sharing Tetrahedra148Designing Silicates as Deep‐UV Nonlinear Optical (NLO) Materials using Edge‐Sharing Tetrahedra43Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials164

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  1. AMgPO 4 ·6H 2 O (A = Rb, Cs): strong SHG responses originated from orderly PO 4 groups

    Journal of Materials Chemistry C · 2016-01-01

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  2. KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge

    Journal of Materials Chemistry C · 2016-01-01

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  3. Deep-Ultraviolet Transparent Cs 2 LiPO 4 Exhibits an Unprecedented Second Harmonic Generation

    Chemistry of Materials · 2016-09-13

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  4. Syntheses and Characterizations of Three Bismuth(III)‐Containing Mixed‐Metal Phosphates:Ba 2 Bi 2 M II (PO 4 ) 4 (M= Mn, Ni, Cu)

    ChemistrySelect · 2016-10-01

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  5. Strong Nonlinear-Optical Response in the Pyrophosphate CsLiCdP2O7 with a Short Cutoff Edge

    Inorganic Chemistry · 2016-10-31

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  6. LiRb 2 PO 4 : a new deep-ultraviolet nonlinear optical phosphate with a large SHG response

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  7. LiRb 2 LaB 2 O 6 : a new rare-earth borate with a MOF-5-like topological structure and a short UV cut-off edge

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  8. A new phase-matchable nonlinear optical silicate: Rb 2 ZnSi 3 O 8

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  9. Application of the dimensional reduction formalism to Pb 9−x Ba x [Li 2 (P 2 O 7 ) 2 (P 4 O 13 ) 2 ] (x = 0, 2, 6, 7): a series of phosphates with two types of isolated polyphosphate groups

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  10. Ba 6 Li 2 CdSn 4 S 16 : lithium substitution simultaneously enhances band gap and SHG intensity

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  11. BaCu 2 M IV Q 4 (M IV = Si, Ge, and Sn; Q = S, Se): synthesis, crystal structures, optical performances and theoretical calculations

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  12. Enhancing optical anisotropy of crystals by optimizing bonding electron distribution in anionic groups

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  13. Low-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response

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  14. Solvent-controlled syntheses of mixed-alkali-metal borates exhibiting UV nonlinear optical properties

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  15. Structure comparison and optical properties of Na 7 Mg 4.5 (P 2 O 7 ) 4 : a sodium magnesium phosphate with isolated P 2 O 7 units

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  16. Syntheses, structures and properties of metal phosphates Pb 2 Mg(PO 4 ) 2 , Pb 4 Zn 8 (PO 4 ) 8 and α-BaZn 2 (PO 4 ) 2

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  17. Theoretical investigation on the balance between large band gap and strong SHG response in BMO 4 (M = P and As) crystals

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  18. Top-Seeded Solution Crystal Growth and Linear and Nonlinear Optical Properties of Ba 4 B 11 O 20 F

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  19. M4Mg4(P2O7)3 (M = K, Rb): Structural Engineering of Pyrophosphates for Nonlinear Optical Applications

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  20. A3Sr2P7O21 (A = Rb, Cs): Two Polyphosphates Based on Different Types of P–O Chains and Ring Structures

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  21. Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold

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  22. (H 3 O)Ca 2 Zn 3.5 (PO 4 ) 4 and Ba 2 Cd 3 (PO 4 ) 2 (HPO 4 ) 2 : Syntheses, crystal structures and characterizations of two mixed metal phosphates

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  23. Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion

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  24. Growth, Properties, and Theoretical Analysis of M2LiVO4 (M = Rb, Cs) Crystals: Two Potential Mid-Infrared Nonlinear Optical Materials

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  25. Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials

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  26. Second-harmonic generation in noncentrosymmetric phosphates

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  27. Deep-Ultraviolet Nonlinear-Optical Material K3Sr3Li2Al4B6O20F: Addressing the Structural Instability Problem in KBe2BO3F2

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  28. Linear-to-λ-Shape P–O–P Bond Transmutation in Polyphosphates with Infinite (PO3)∞ Chain

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  29. Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se13

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  30. CsB 4 O 6 F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units

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  31. CsB4O6F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units

    Angewandte Chemie International Edition · 2017-09-12

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  32. Neutron diffraction reveals the existence of confined water in triangular and hexagonal channels of modified YPO4 at elevated temperatures

    Physical Review Materials · 2017-09-15

    S. K. Mishra, R. S. Ningthoujam, R. Mittal, R. K. Vatsa, Mohamed Zbiri, K. Shitaljit Sharma, B. P. Singh, P. U. Sastry, T. Hansen, H. Schober, Samrath Lal Chaplot

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  33. New Compressed Chalcopyrite-like Li2BaMIVQ4 (MIV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials

    Journal of the American Chemical Society · 2017-09-25

    Kui Wu, Bingbing Zhang, Zhihua Yang, Shilie Pan

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  34. Synthesis, Structure, and Properties of Nonlinear Optical Crystal Na2SiF6

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  35. Li1.52Na4.48Cd8(PO4)2(P2O7)4: A new mixed-anion diphosphate containing four types of dimensions groups

    Inorganic Chemistry Communications · 2017-11-07

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  36. K2[B3O3(OH)5]: A new deep-UV nonlinear optical crystal with isolated [B3O3(OH)5]2- anionic groups

    Journal of Alloys and Compounds · 2017-11-16

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  37. Chemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials

    Journal of the American Chemical Society · 2017-11-22

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  38. Two different types of channels exhibiting distinct proton transport behavior in an open-framework aluminophosphate

    Journal of Solid State Chemistry · 2017-12-05

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  39. From a Metastable Layer to a Stable Ring: A Kinetic Study for Transformation Reactions of Li2Mo3TeO12 to Polyoxometalates

    Chemistry - A European Journal · 2017-12-07

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  40. A beryllium-free deep-UV nonlinear optical material CsNaMgP 2 O 7 with honeycomb-like topological layers

    Journal of Materials Chemistry C · 2018-01-01

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  41. Cs 3 VO(O 2 ) 2 CO 3 : an exceptionally thermostable carbonatoperoxovanadate with an extremely large second-harmonic generation response

    Chemical Science · 2018-01-01

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  42. Four new quaternary chalcogenides A 2 Ba 7 Sn 4 Q 16 (A = Li, Na; Q = S, Se): syntheses, crystal structures determination, nonlinear optical performances investigation

    New Journal of Chemistry · 2018-01-01

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  43. K 2 TeP 2 O 8 : a new telluro-phosphate with a pentagonal Te–P–O layer structure

    Dalton Transactions · 2018-01-01

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  44. Li 8 NaRb 3 (SO 4 ) 6 ·2H 2 O as a new sulfate deep-ultraviolet nonlinear optical material

    Journal of Materials Chemistry C · 2018-01-01

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  45. Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials

    Angewandte Chemie · 2018-01-10

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  46. Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2018-01-10

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  47. A Joint Strategy To Evaluate the Microscopic Origin of the Second-Harmonic-Generation Response in Nonpolar ABCO3F Compounds

    Inorganic Chemistry · 2018-01-17

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  48. Non-Centrosymmetric RbNaMgP 2 O 7 with Unprecedented Thermo-Induced Enhancement of Second Harmonic Generation

    Journal of the American Chemical Society · 2018-01-18

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  49. Syntheses, Crystal Structures and Luminescent Properties of Two New Heterometallic Phosphates: Sn 2 Ge(PO 4 ) 2 (OH) 2 and Sn 2 Mn(PO 4 ) 2

    ChemistrySelect · 2018-01-25

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  50. Synthesis, crystal structure and characterizations of a new diphosphate Rb2CaP2O7

    Journal of Alloys and Compounds · 2018-02-13

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