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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2018

Experimental characterization and first principles calculations of linear and nonlinear optical properties of two orthophosphates A 3 Al 2 (PO 4 ) 3 (A = Rb, K)

Ming Wen, Hongping Wu, Shichao Cheng, Jun Sun, Zhihua Yang, Xiaohong Wu, Shilie Pan

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Experimental characterization and first principles calculations of linear and nonlinear optical properties of two orthophosphates A 3 Al 2 (PO 4 ) 3 (A = Rb, K)OriginalAn alkali metal phosphate RbPbBi 2 (PO 4 ) 3 with three kinds of disorder: the effect of isolated soft cation units on the crystal structure7Ba 3 Ca 4 (BO 3 ) 3 (SiO 4 )Cl: a new non-centrosymmetric complex alkaline-earth metal borosilicate chloride with a deep-ultraviolet cut-off edge19Hybridization-activated new deep ultraviolet transparent nonlinear optical material Ba 11 [Al(PO 4 ) 4 ](P 2 O 7 )(PO 4 ) 3 with balanced overall performance and parsimony-forbidden structure23Modulation of perovskite-related frameworks induced by alkaline earth metals in phosphate fluorides A 2 MPO 4 F (A = K, Rb; M = Ba, Ca)8Further Example of Diphosphates: Synthesis and Characterization of K2Li2P2O72Ionothermal Synthesis of Metal Chalcogenides M2Ag3Sb3S7 (M = Rb, Cs) Displaying Nonlinear Optical Activity in the Infrared Region33Highly porous aluminophosphates with unique three dimensional open framework structures from mild hydrothermal syntheses16K 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups14Three non-centrosymmetric bismuth phosphates, Li 2 ABi(PO 4 ) 2 (A = K, Rb, and Cs): effects of cations on the crystal structure and SHG response23Na3AMg7(PO4)6 (A = K, Rb and Cs): Structures, properties and theoretical studies of alkali metal magnesium orthophosphates14K8Cd21Pb7(P2O7)16 and KCd2P3O10: Two new phosphates featuring special structure configurations2A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups106Struvite-type AMgPO4·6H2O (A = NH4, K): Two Natural Deep-Ultraviolet Transparent Nonlinear Optical Crystals13Insights into varying dimension structures for deep-UV optical crystals NaBa2Al(P2O7)2 and NaBaAl(PO4)2 constructed separately from unique [Al(P2O7)2] chains and [Al(PO4)2] layers6Synthesis and characterization of a novel alkali mixed magnesium-aluminum phosphate with a layered structure–KMgAl(PO4)23Ca-cluster-constructed deep-ultraviolet nonlinear-optical crystal Na2Ca17Al2(PO4)14 with strong NLO response11Cd 2 (IO 3 )(PO 4 ) and Cd 1.62 Mg 0.38 (IO 3 )(PO 4 ): metal iodate-phosphates with large SHG responses and wide band gaps28Li 3 [Al(PO 4 ) 2 (H 2 O) 1.5 ] and Na[AlP 2 O 7 ]: from 2D layered polar to 3D centrosymmetric framework structures8Lone Pair-Driven Enhancement of Birefringence in Polar Alkali Metal Antimony Phosphates46Synthesis, crystal structure, and characterization of two bismuth phosphates Rb2CaBi2P4O15 and Rb3SrBiP4O143A series of novel phosphites/phosphates with deep-ultraviolet cut-off edges from 0D polar to 3D non-polar architectures13Ce 3 F 4 (SO 4 ) 4 : cationic framework assembly for designing polar nonlinear optical material through fluorination degree modulation23Nonlinear optical properties of gold nanoparticles containing borate glasses at spectral region of surface plasmon resonance10Nanosecond nonlinear optical and gamma radiation shielding behavior of Eu2O3 doped lanthanum containing heavy metal borate glasses: a comparative investigation8Tunable, efficient, ultrafast broadband nonlinear optical properties of TiO2–loaded complex phosphate glasses15Nonlinear refractive index enhancement of Nd3+ ions loaded borate glasses in the near–infrared region by silver nanoparticles8Enhanced resonant nonlinear optical traits and optical limiting performance of metal nanoparticles containing borate glasses in nanosecond pulse regime10Syntheses and characterization of noncentrosymmetric layered phosphates, Sr3Nb2P2O13 and Sr3Ta2P2O130Enhanced nonlinear optical absorption and optical limiting performance of nanoparticles embedded lanthanum alkali borate glasses bearing holmium ions at off–resonant spectral excitation5Two noncentrosymmetric alkali metal phosphates MZnPO4 (M = Rb, Cs) with honeycomb-like structures8Novel antimony phosphates with enlarged birefringence induced by lone pair cations4Syntheses, structures and characterization of noncentrosymmetric MZnPO 4 (M = K, NH 4 )4Li3[AlP2O7F(OH)](H2O)0.5 and A[Al2(PO4)2F(H2O)](A = K, Rb): Counter Cation Templates Derived Three Polar Alkaline Metal Fluoroaluminophosphates6Four noncentrosymmetric molybdophosphates discovered by a chemical substitution strategy4Polar [ NH ( CH2SO3 )2]2− Dimers Enable the First Promising Iminodimethanesulfonate with Nonlinear Optical Properties and Wide UV Transparency19Design, Synthesis, and Improvement of Nonlinear Optical Properties from Aluminophosphite to Aluminophosphate1

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  1. An alkali metal phosphate RbPbBi 2 (PO 4 ) 3 with three kinds of disorder: the effect of isolated soft cation units on the crystal structure

    Inorganic Chemistry Frontiers · 2019-01-01

    Ming Wen, Hongping Wu, Zhihua Yang, Xiaohong Wu, Shilie Pan

    Read original paper ↗ ·

  2. Ba 3 Ca 4 (BO 3 ) 3 (SiO 4 )Cl: a new non-centrosymmetric complex alkaline-earth metal borosilicate chloride with a deep-ultraviolet cut-off edge

    Inorganic Chemistry Frontiers · 2019-01-01

    Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Sujuan Yu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  3. Hybridization-activated new deep ultraviolet transparent nonlinear optical material Ba 11 [Al(PO 4 ) 4 ](P 2 O 7 )(PO 4 ) 3 with balanced overall performance and parsimony-forbidden structure

    Journal of Materials Chemistry C · 2019-01-01

    Zhi Gang Fang, Bing‐Ping Yang, Chun‐Li Hu, Jiang‐Gao Mao

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  4. Modulation of perovskite-related frameworks induced by alkaline earth metals in phosphate fluorides A 2 MPO 4 F (A = K, Rb; M = Ba, Ca)

    New Journal of Chemistry · 2019-01-01

    Kun Chai, Shichao Cheng, Hongyi Li, Bin Dai

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  5. Further Example of Diphosphates: Synthesis and Characterization of K2Li2P2O7

    Zeitschrift für anorganische und allgemeine Chemie · 2019-07-10

    Lingyun Dong, Xusheng Ge, Pengfei Zhang, Qian Li, Sufang Sun, Shigang Shen

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  6. Ionothermal Synthesis of Metal Chalcogenides M2Ag3Sb3S7 (M = Rb, Cs) Displaying Nonlinear Optical Activity in the Infrared Region

    Inorganic Chemistry · 2019-09-25

    Gang Yang, Long-Hua Li, Chao Wu, Mark Graeme Humphrey, Chi Zhang

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  7. Highly porous aluminophosphates with unique three dimensional open framework structures from mild hydrothermal syntheses

    CrystEngComm · 2020-01-01

    Yucheng Hao, Yang Pan, Yuan Hua Lin, Linbo He, Guangjie Ge, Yu Ruan, Haida Zhou, Yang Xue, Kisan Koirala

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  8. K 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups

    Dalton Transactions · 2020-01-01

    Wenyao Zhang, Wenqi Jin, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  9. Three non-centrosymmetric bismuth phosphates, Li 2 ABi(PO 4 ) 2 (A = K, Rb, and Cs): effects of cations on the crystal structure and SHG response

    Inorganic Chemistry Frontiers · 2020-01-01

    Ming Wen, Cong Hu, Hongping Wu, Zhihua Yang, Hao Yu, Shilie Pan

    Read original paper ↗ ·

  10. Na3AMg7(PO4)6 (A = K, Rb and Cs): Structures, properties and theoretical studies of alkali metal magnesium orthophosphates

    Journal of Molecular Structure · 2020-09-28

    Jiahao Jiao, Wenqi Jin, Min Zhang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  11. K8Cd21Pb7(P2O7)16 and KCd2P3O10: Two new phosphates featuring special structure configurations

    Journal of Solid State Chemistry · 2020-12-05

    Na Li, Lu Qi, Lu Li, Zhongqi Jiang, Jihong Fu, Ming‐Hsien Lee, Zhaohui Chen

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  12. A comprehensive survey on nonlinear optical phosphates: Role of multicoordinate groups

    Coordination Chemistry Reviews · 2021-01-19

    Junhui Dang, Dajiang Mei, Yuandong Wu, Zheshuai Lin

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  13. Struvite-type AMgPO4·6H2O (A = NH4, K): Two Natural Deep-Ultraviolet Transparent Nonlinear Optical Crystals

    Inorganic Chemistry · 2021-05-24

    Feifei Yuan, Lei Hu, Zhiyong Bai, Lehui Liu, Yisheng Huang, Lizhen Zhang, Dongshan Wei, Zhoubin Lin

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  14. Insights into varying dimension structures for deep-UV optical crystals NaBa2Al(P2O7)2 and NaBaAl(PO4)2 constructed separately from unique [Al(P2O7)2] chains and [Al(PO4)2] layers

    Journal of Solid State Chemistry · 2021-06-15

    Fang Wang, Xiao-Ni Yao, Yao Guo, Yang Liguo, Yi-Gang Chen, Xian‐Ming Zhang

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  15. Synthesis and characterization of a novel alkali mixed magnesium-aluminum phosphate with a layered structure–KMgAl(PO4)2

    Journal of Molecular Structure · 2021-09-20

    Inès Mokni, Abdessalem Badri, Sami Slimi, Karim Omri, Pavel A. Loiko, Rosa Maria Solé, Magdalena Aguiló, Francesc Dı́az, Xavier Mateos, Mongi Ben Amara

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  16. Ca-cluster-constructed deep-ultraviolet nonlinear-optical crystal Na2Ca17Al2(PO4)14 with strong NLO response

    Journal of Alloys and Compounds · 2021-11-30

    Yi-Gang Chen, Xiaoxiu Yu, Yao Guo, Yuanbin Xue, Xiaohui Hao, Xiao-Ni Yao, Xian‐Ming Zhang

    Read original paper ↗ ·

  17. Cd 2 (IO 3 )(PO 4 ) and Cd 1.62 Mg 0.38 (IO 3 )(PO 4 ): metal iodate-phosphates with large SHG responses and wide band gaps

    Chemical Communications · 2022-01-01

    Qianqian Chen, Chun‐Li Hu, Li-Jia Yao, Jin Chen, Ming‐Yang Cao, Bingxuan Li, Jiang‐Gao Mao

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  18. Li 3 [Al(PO 4 ) 2 (H 2 O) 1.5 ] and Na[AlP 2 O 7 ]: from 2D layered polar to 3D centrosymmetric framework structures

    CrystEngComm · 2022-01-01

    Xinlei Li, Yang Zhang, Yang Pan, Yucheng Hao, Yuan Hua Lin, Haijian Li, Minghua Li, Changzeng Fan, Evgeny V. Alekseev

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  19. Lone Pair-Driven Enhancement of Birefringence in Polar Alkali Metal Antimony Phosphates

    Chemistry of Materials · 2022-04-29

    Chenhui Hu, Xintong Cai, Mengfan Wu, Zhihua Yang, Jian Wei Han, Shilie Pan

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  20. Synthesis, crystal structure, and characterization of two bismuth phosphates Rb2CaBi2P4O15 and Rb3SrBiP4O14

    Journal of Solid State Chemistry · 2022-08-05

    Hao Wu, Yaoguo Shen

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  21. A series of novel phosphites/phosphates with deep-ultraviolet cut-off edges from 0D polar to 3D non-polar architectures

    CrystEngComm · 2023-01-01

    Yucheng Hao, Yang Zhang, Yuying Zhang, Zixiang Fu, Chunyang Heng, Junjie Li, Jiatian You, Kunhong Hu, Yuan Hua Lin, Haijian Li

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  22. Ce 3 F 4 (SO 4 ) 4 : cationic framework assembly for designing polar nonlinear optical material through fluorination degree modulation

    Inorganic Chemistry Frontiers · 2023-01-01

    Tianhui Wu, Xingxing Jiang, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  23. Nonlinear optical properties of gold nanoparticles containing borate glasses at spectral region of surface plasmon resonance

    Materials Today Communications · 2023-04-20

    K. Gurushantha, B.N. Swetha, Sangeeta B. Kolavekar, A.G. Pramod, Aljawhara H. Almuqrin, M.I. Sayyed, Gangareddy Jagannath, K. Keshavamurthy

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  24. Nanosecond nonlinear optical and gamma radiation shielding behavior of Eu2O3 doped lanthanum containing heavy metal borate glasses: a comparative investigation

    Journal of Materials Science · 2023-04-25

    K. Gurushantha, G. Jagannath, Sangeeta B. Kolavekar, A.G. Pramod, Aljawhara H. Almuqrin, M.I. Sayyed, K. Keshavamurthy, P. Ramesh

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  25. Tunable, efficient, ultrafast broadband nonlinear optical properties of TiO2–loaded complex phosphate glasses

    Materials Research Bulletin · 2023-06-20

    Gangareddy Jagannath, Hamad Syed, Saswata Chakraborty, Prince Sen, Manasi Ghosh, Krishna Kishor Dey, Kankan Bhattacharyya, K. Annapurna, Venugopal Rao Soma, Amarnath Reddy Allu

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  26. Nonlinear refractive index enhancement of Nd3+ ions loaded borate glasses in the near–infrared region by silver nanoparticles

    Optical Materials · 2023-06-26

    N. Chowdareddy, Ashok R. Lamani, A.G. Pramod, Vadiraj B. Tangod, Aljawhara H. Almuqrin, M.I. Sayyed, Halepoojar Siddalingappa Jayanna, Gangareddy Jagannath, S. Venugopal Rao, K. Keshavamurthy

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  27. Enhanced resonant nonlinear optical traits and optical limiting performance of metal nanoparticles containing borate glasses in nanosecond pulse regime

    Inorganic Chemistry Communications · 2023-06-28

    Abeer S. Altowyan, Gangareddy Jagannath, K. Keshavamurthy, M.I. Sayyed

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  28. Syntheses and characterization of noncentrosymmetric layered phosphates, Sr3Nb2P2O13 and Sr3Ta2P2O13

    Journal of Solid State Chemistry · 2023-09-27

    Rintu Robert, Kanamaluru Vidyasagar

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  29. Enhanced nonlinear optical absorption and optical limiting performance of nanoparticles embedded lanthanum alkali borate glasses bearing holmium ions at off–resonant spectral excitation

    Optical Materials · 2023-10-09

    B.N. Swetha, K. Keshavamurthy, A.L. Latha, A.G. Pramod, Gangareddy Jagannath, Dalal Abdullah Aloraini, Aljawhara H. Almuqrin, M.I. Sayyed, T.N. Ashoka, S. Venugopal Rao, M.K. Kokila

    Read original paper ↗ ·

  30. Two noncentrosymmetric alkali metal phosphates MZnPO4 (M = Rb, Cs) with honeycomb-like structures

    Optical Materials · 2023-11-28

    Qun Jing, Menglin Zhu, Lu Li, Xu Ji, Haiming Duan, Henglei Chen, Ming‐Hsien Lee

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  31. Novel antimony phosphates with enlarged birefringence induced by lone pair cations

    Dalton Transactions · 2024-01-01

    Mei Hu, Jialong Wang, Nuerbiye Tuerhong, Zhiyuan Zhang, Qun Jing, Zhaohui Chen, Yonglei Yang, Ming‐Hsien Lee

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  32. Syntheses, structures and characterization of noncentrosymmetric MZnPO 4 (M = K, NH 4 )

    Dalton Transactions · 2024-01-01

    Jiawei Zhao, Wei Wei, Meihui Chen, Yanna Chen, Donghai An

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  33. Li3[AlP2O7F(OH)](H2O)0.5 and A[Al2(PO4)2F(H2O)](A = K, Rb): Counter Cation Templates Derived Three Polar Alkaline Metal Fluoroaluminophosphates

    Inorganic Chemistry · 2024-12-17

    Yucheng Hao, Changlin Chen, Cheng Hou, S. Liu, Peng Zheng, Yuan Ching Lin, Haijian Li, Xi Zhao, Kisan Koirala, Hongdian Lu, Chonghai Deng, Kunhong Hu

    Read original paper ↗ ·

  34. Four noncentrosymmetric molybdophosphates discovered by a chemical substitution strategy

    Dalton Transactions · 2025-01-01

    Zhixia Gao, Ke Li, Hong Du, Tuohetijiang Baiheti

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  35. Polar [ NH ( CH2SO3 )2]2− Dimers Enable the First Promising Iminodimethanesulfonate with Nonlinear Optical Properties and Wide UV Transparency

    Chinese Journal of Chemistry · 2025-03-25

    Yipeng Song, Yuexin Zhang, Yanqiang Li, Zhiyong Bai, Weiqi Huang, Kunpeng Wang, Sangen Zhao, Junhua Luo

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  36. Design, Synthesis, and Improvement of Nonlinear Optical Properties from Aluminophosphite to Aluminophosphate

    Inorganic Chemistry · 2025-06-27

    Yucheng Hao, Changlin Chen, Cheng Hou, Xi Zhao, Yuan Hua Lin, Rongfang Zhang, Hongdian Lu, Kunhong Hu, Wei Cheng, Mingli Liang

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