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RESEARCH PAPER · Journal of Solid State Chemistry · 2012

Crystal structures and second-order NLO properties of borogermanates

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Crystal structures and second-order NLO properties of borogermanatesOriginalChemInform Abstract: Crystal Structures and Second‐Order NLO Properties of Borogermanates0An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }19Molecular Germanium Selenophosphate Salts: Phase-Change Properties and Strong Second Harmonic Generation85Facile Assembly of an Unusual Lead Borate with Different Cluster Building Units via a Hydrothermal Process38SrGe2B2O8 and Sr3Ge2B6O16: Novel Strontium Borogermanates with Three-Dimensional and Layered Anionic Architectures50KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups36PbCd 2 B 6 O 12 and EuZnB 5 O 10 : syntheses, crystal structures and characterizations of two new mixed metal borates43Space formations and nonlinear properties of noncentrosymmetric germanates9NaB3O5·0.5H2O and NH4NaB6O10: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units41Synthesis and Characterization of the New Strontium Borogermanate Sr3–x/2B2–xGe4+xO14 (x = 0.32)16Hydrothermal Growth of Lanthanide Borosilicates: A Useful Approach to New Acentric Crystals Including a Derivative of Cappelenite16Synthesis of CaY2−x Ln x Ge3O10 (Ln = Eu or Tb) phosphors via the EDTA complexing process0Linear optical and thermo-physical properties of polar K3B6O10Cl crystal21A Series of Aluminoborates Templated or Supported by Zinc–Amine Complexes51Gel combustion synthesis of La x Gd14–x B6Ge2O34 (x = 3 and 4) codoped with Yb3+–Er3+ and Yb3+–Tm3+ active ions5Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials340Synthesis of IR phosphors based on germanatoborate Gd14Ge2B6O346Structure modulations in nonlinear optical (NLO) materials Cs2TB4O9(T= Ge, Si)14Effect of the [Ba 2 BO 3 F] ∞ Layer on the Band Gap: Synthesis, Characterization, and Theoretical Studies of BaZn 2 B 2 O 6 · n Ba 2 BO 3 F ( n = 0, 1, 2)21Synthesis and structural characterization of Ca12Ge17B8O583Influence of Synthetic Conditions on Chemistry and Structural Properties of Alkaline Earth Uranyl Borates23Na7[Ga2B13O24(OH)4]: A Luminescent Sodium Gallium Borate Containing Two Different Types of Oxoboron Framework Building Blocks4ACaBO 3 (A = Cs, Rb): two new cubic borates with isolated BO 3 groups24CsBxGe6–xO12 (x = 1): A Zeolite Sodalite-Type Borogermanate with a High Ge/B Ratio by Partial Boron Substitution21An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units56Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate34Divergent Structural Chemistry of Uranyl Borates Obtained from Solid State and Hydrothermal Conditions19A novel mixed-metal borate with large [B12O18(OH)6]6- motif: Synthesis, structure and property5Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations12Synthesis and Study of the First Zeolitic Uranium Borate22Thermal Expansion and Luminescent Properties of Triorthogermanates CaLa2-xEu x Ge3O10 (x = 0.0–0.6)4Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics495Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics67Two Lanthanide Borate Chlorides LnB4O6(OH)2Cl (Ln = La, Ce) with Wide Ultraviolet Transmission Windows and Large Second-Harmonic Generation Responses25Ca 2 GeB 2 O 7 and Ca 1.78 Cd 0.22 GeB 2 O 7 : two acentric borogermanates with a melilite-like structure and short ultraviolet cutoff edge14Li 2 Na 2 [B 12 O 19 (OH) 2 ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units8Luminescence properties in relation to controllable morphologies of Ba 3 [Ge 2 B 7 O 16 (OH) 2 ](OH)(H 2 O):Eu 3+ and its thermal conversion product Ba 3 Ge 2 B 6 O 16 :Eu 3+6Structural, electronic, and optical studies of BaRE 2 Ge 3 O 10 (RE = Y, Sc, Gd–Lu) germanates with a special focus on the [Ge 3 O 10 ] 8− geometry15Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra73Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra18Mg3Pt(BO3)2O2: The first platinum borate from the flux technique13Hydrothermal synthesis of anisotropic SrGe 4 O 9 :Yb 3+ /Er 3+ nanorods and optimized upconversion luminescence for optical temperature sensing2Hydrothermal Synthesis of Anisotropic Srge4o9:Yb3+/Er3+ Nanorods and Optimized Upconvertion Luminescence for Fir Temperature Sensing0Na 3 B 6 O 10 (HCOO): an ultraviolet nonlinear optical sodium borate-formate33NaBa3[M2B7O16(OH)2]F2 (M = Ge, Si): Two Synthetic F Analogues of Garrelsite with [B7O16(OH)2]13– Polyanions and Deep-Ultraviolet Cutoff Edges8Spectral-Luminescent Properties of Oxogermanate-Borates La3Gd11 – x – yYbxEryGe2B6O34 Prepared by Coprecipitation5Topologically prone or cation compression restricted phase transition: An example of feldspar-related SrGe2B2O82Cs[B 3 O 3 F 2 (OH) 2 ]: discovery of a hydroxyfluorooxoborate guided by selective organic–inorganic transformation13Two Acentric Aluminoborates Incorporated d10 Cations: Syntheses, Structures, and Nonlinear Optical Properties24Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra21Thermal Expansion of Oxoborogermanate Sm14(GeO4)2(BO3)6O81Synthesis, structural analysis and investigation of photoluminescence properties of mixed metal cation borates12β‐Ga4GeO8 Stability Under Extreme Conditions (up to 600 °C and 30 GPa)0Synthesis and high pressure stability of novel GaGeO3OH compound - Analog of phase egg AlSiO3OH3Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions9Synthesis, scintillation properties, and the influence of trap states on luminescence of gadolinium-lanthanum-europium germanate borates Gd13-xLaxEuGe2B6O340Enhanced Ion-Exchange Properties of a Complex Microporous Uranyl Borophosphate0New system mixed metal borates NaBaR(BO3)2 (R = La3+, Ce3+, Nd3+, Sm3+, Er3+). Synthesis, structural characterization and photoluminescence properties0Novel mixed metal borate (NaCaR(BO3)2) compounds: Synthesis, structure, and light-emitting properties0

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  1. ChemInform Abstract: Crystal Structures and Second‐Order NLO Properties of Borogermanates

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  2. An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }

    Dalton Transactions · 2012-11-15

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  3. Molecular Germanium Selenophosphate Salts: Phase-Change Properties and Strong Second Harmonic Generation

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  4. Facile Assembly of an Unusual Lead Borate with Different Cluster Building Units via a Hydrothermal Process

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  5. SrGe2B2O8 and Sr3Ge2B6O16: Novel Strontium Borogermanates with Three-Dimensional and Layered Anionic Architectures

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  6. KSbB2O6 and BaSb2B4O12: Novel Boroantimonates with 3D Anionic Architectures Composed of 1D Chains of SbO6 Octahedra and B2O5 Groups

    Inorganic Chemistry · 2014-03-25

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  7. PbCd 2 B 6 O 12 and EuZnB 5 O 10 : syntheses, crystal structures and characterizations of two new mixed metal borates

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  8. Space formations and nonlinear properties of noncentrosymmetric germanates

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  9. NaB3O5·0.5H2O and NH4NaB6O10: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units

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  10. Synthesis and Characterization of the New Strontium Borogermanate Sr3–x/2B2–xGe4+xO14 (x = 0.32)

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    Benedikt Petermüller, Lucas L. Petschnig, Klaus Wurst, Günter Heymann, Hubert Huppertz

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  11. Hydrothermal Growth of Lanthanide Borosilicates: A Useful Approach to New Acentric Crystals Including a Derivative of Cappelenite

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  12. Synthesis of CaY2−x Ln x Ge3O10 (Ln = Eu or Tb) phosphors via the EDTA complexing process

    Journal of Sol-Gel Science and Technology · 2015-02-05

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  13. Linear optical and thermo-physical properties of polar K3B6O10Cl crystal

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  14. A Series of Aluminoborates Templated or Supported by Zinc–Amine Complexes

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  15. Gel combustion synthesis of La x Gd14–x B6Ge2O34 (x = 3 and 4) codoped with Yb3+–Er3+ and Yb3+–Tm3+ active ions

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  16. Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

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  17. Synthesis of IR phosphors based on germanatoborate Gd14Ge2B6O34

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  18. Structure modulations in nonlinear optical (NLO) materials Cs2TB4O9(T= Ge, Si)

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  19. Effect of the [Ba 2 BO 3 F] ∞ Layer on the Band Gap: Synthesis, Characterization, and Theoretical Studies of BaZn 2 B 2 O 6 · n Ba 2 BO 3 F ( n = 0, 1, 2)

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  20. Synthesis and structural characterization of Ca12Ge17B8O58

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  21. Influence of Synthetic Conditions on Chemistry and Structural Properties of Alkaline Earth Uranyl Borates

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  22. Na7[Ga2B13O24(OH)4]: A Luminescent Sodium Gallium Borate Containing Two Different Types of Oxoboron Framework Building Blocks

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  23. ACaBO 3 (A = Cs, Rb): two new cubic borates with isolated BO 3 groups

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  24. CsBxGe6–xO12 (x = 1): A Zeolite Sodalite-Type Borogermanate with a High Ge/B Ratio by Partial Boron Substitution

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  25. An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units

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  28. A novel mixed-metal borate with large [B12O18(OH)6]6- motif: Synthesis, structure and property

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  29. Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations

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  31. Thermal Expansion and Luminescent Properties of Triorthogermanates CaLa2-xEu x Ge3O10 (x = 0.0–0.6)

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  32. Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics

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  33. Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics

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  34. Two Lanthanide Borate Chlorides LnB4O6(OH)2Cl (Ln = La, Ce) with Wide Ultraviolet Transmission Windows and Large Second-Harmonic Generation Responses

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  35. Ca 2 GeB 2 O 7 and Ca 1.78 Cd 0.22 GeB 2 O 7 : two acentric borogermanates with a melilite-like structure and short ultraviolet cutoff edge

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  36. Li 2 Na 2 [B 12 O 19 (OH) 2 ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units

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  37. Luminescence properties in relation to controllable morphologies of Ba 3 [Ge 2 B 7 O 16 (OH) 2 ](OH)(H 2 O):Eu 3+ and its thermal conversion product Ba 3 Ge 2 B 6 O 16 :Eu 3+

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  38. Structural, electronic, and optical studies of BaRE 2 Ge 3 O 10 (RE = Y, Sc, Gd–Lu) germanates with a special focus on the [Ge 3 O 10 ] 8− geometry

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  39. Cs2Bi2O(Ge2O7) (CBGO): A Larger SHG Effect Induced by Synergistic Polarizations of BiO5 Polyhedra and GeO4 Tetrahedra

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  41. Mg3Pt(BO3)2O2: The first platinum borate from the flux technique

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  46. Spectral-Luminescent Properties of Oxogermanate-Borates La3Gd11 – x – yYbxEryGe2B6O34 Prepared by Coprecipitation

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  47. Topologically prone or cation compression restricted phase transition: An example of feldspar-related SrGe2B2O8

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  48. Cs[B 3 O 3 F 2 (OH) 2 ]: discovery of a hydroxyfluorooxoborate guided by selective organic–inorganic transformation

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  50. Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra

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