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RESEARCH PAPER · Inorganic Chemistry · 2018

Two Lanthanide Borate Chlorides LnB4O6(OH)2Cl (Ln = La, Ce) with Wide Ultraviolet Transmission Windows and Large Second-Harmonic Generation Responses

Fengjiao Guo, Jian Wei Han, Jianian Cheng, Zhihua Yang, Miriding Mutailipu, Shilie Pan

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Two Lanthanide Borate Chlorides LnB4O6(OH)2Cl (Ln = La, Ce) with Wide Ultraviolet Transmission Windows and Large Second-Harmonic Generation ResponsesOriginalUniform colloidal spheres for RE 3 BO 6 (RE = Eu‐Yb, Y) and excitation‐dependent luminescence of Y 3 BO 6 :Eu 3+ red phosphor9[O 2 Pb 3 ] 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains6Designing Sulfide Borate as a Novel Type of Second-Order Nonlinear-Optical Material91Synthesis, structure, and characterization of RbNdGe2O6 as a novel visible-light-driven catalyst for photodegradation methylene blue5La1-Eu B4O6(OH)2Cl (0 ≤ x ≤ 0.54): Strong 4f-4f excitations due to the noncentrosymmetric and oxychloride coordination of Eu3+3K5Mg2La3(BO3)6: An Efficient, Deep-Ultraviolet Nonlinear Optical Material70Recent advances in nonlinear optical rare earth structures63Complex coordinated functional groups: A great genes for nonlinear optical materials64Ba2B13O19(OH)5·5H2O: A promising nonlinear optical material with a unique 2[B13O19(OH)5]∞ two-dimensional layer9Na 3 YB 8 O 15 : a new rare-earth borate with an infinite one-dimensional [B 8 O 15 ] ∞ chain and a short ultraviolet cutoff edge8Deep Ultraviolet-Transparent Materials with Strong Second-Harmonic Response50Cs2B4O5(OH)4: A new hydrated borate with a short UV cutoff edge2KREP2Se6 (RE = Sm, Gd, Tb): The First Rare‐Earth Selenophosphates with Remarkable Nonlinear Optical Activities Realized by Synergistic Effect of RE‐ and P‐Based Motifs39Na2BaB12O18F4: A Mixed Alkali/Alkaline-Earth Metal Fluorooxoborate with Two Unprecedented Interpenetrating Three-Dimensional B–O/F Anionic Networks and a Short Ultraviolet Cutoff Edge9Chromium iodate: the structure and origin of optical second harmonic generation1Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships13CsLa(SO 4 ) 2 : A Lanthanum Sulfate Crystal for Nonlinear Optical Applications10NH4B5O7(OH)2 and CsRbB10O14(OH)4·H2O: Two Hydroxyborates Feature Significant Optical Anisotropy and Contain 1∞[B5O7(OH)2] Chains1Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials3Ternary Anion‐Engineered Rare Earth Crystals for Broadband UV Transparency and Enhanced Second‐Harmonic Generation1Topology-symmetry analysis and structure prediction in nonlinear optical AB4O6F (A = Na, K, Rb, Cs, NH4) and AAlB3O6F (A = K, Rb, Cs) polytypes1A Polar Cerium Iodate Ce 2 (IO 3 ) 6 (H 2 O) with a Strong Second-Harmonic Generation Response in Trivalent Ce-Based Materials1K 3 Yb 2 (BO 3 ) 3 and Rb 3 Yb 2 (BO 3 ) 3 : Two Rare-Earth Borate Ultraviolet Nonlinear Optical Crystals1Fluorine‐Driven Chemical Scissor Effect in Scandium Borates: Structural Evolution with Retained Optically Active Motifs0

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  1. Uniform colloidal spheres for RE 3 BO 6 (RE = Eu‐Yb, Y) and excitation‐dependent luminescence of Y 3 BO 6 :Eu 3+ red phosphor

    Journal of the American Ceramic Society · 2019-06-27

    Qi Zhu, Zhenshu Fan, Shuo Wang, Junqing Xiahou, Ji‐Guang Li

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  2. [O 2 Pb 3 ] 2 (BO 3 )I: a new lead borate iodide with 1∞[O 2 Pb 3 ] double chains

    Dalton Transactions · 2020-01-01

    Kuan Li, Alimujiang Yalikun, Zhi Su

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  3. Designing Sulfide Borate as a Novel Type of Second-Order Nonlinear-Optical Material

    Inorganic Chemistry · 2020-01-07

    Yang Chi, Huaiguo Xue, Sheng‐Ping Guo

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  4. Synthesis, structure, and characterization of RbNdGe2O6 as a novel visible-light-driven catalyst for photodegradation methylene blue

    Journal of Solid State Chemistry · 2020-02-08

    Jian‐Han Zhang, Xian-Dong Hao, Xin Wang, Zhizhong Su, Ju-Xiang Luo, Hongyan Wu, Fuxing Lin

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  5. La1-Eu B4O6(OH)2Cl (0 ≤ x ≤ 0.54): Strong 4f-4f excitations due to the noncentrosymmetric and oxychloride coordination of Eu3+

    Journal of Solid State Chemistry · 2020-10-06

    Yan Gao, Ruirui Yang, Pengfei Jiang, Wenliang Gao, Rihong Cong, Tao Yang

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  6. K5Mg2La3(BO3)6: An Efficient, Deep-Ultraviolet Nonlinear Optical Material

    Chemistry of Materials · 2021-05-21

    Runqing Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  7. Recent advances in nonlinear optical rare earth structures

    Journal of Rare Earths · 2021-07-15

    Jun Zhao, Dajiang Mei, Weikang Wang, Yuandong Wu, Dongfeng Xue

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  8. Complex coordinated functional groups: A great genes for nonlinear optical materials

    Chinese Chemical Letters · 2021-12-03

    Weikang Wang, Dajiang Mei, Shaoguo Wen, Jian Wang, Yuandong Wu

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  9. Ba2B13O19(OH)5·5H2O: A promising nonlinear optical material with a unique 2[B13O19(OH)5]∞ two-dimensional layer

    Journal of Alloys and Compounds · 2021-12-09

    Kaitong Liu, Jian Wei Han, Fuming Li, Congcong Jin, Zhihua Yang, Miriding Mutailipu, Shilie Pan

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  10. Na 3 YB 8 O 15 : a new rare-earth borate with an infinite one-dimensional [B 8 O 15 ] ∞ chain and a short ultraviolet cutoff edge

    Dalton Transactions · 2022-01-01

    Jianlong Huang, Chengfa Wu, Jianbang Chen, Zhiyong Guo, Wenjuan Ma, Feng Yu, Bin Dai

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  11. Deep Ultraviolet-Transparent Materials with Strong Second-Harmonic Response

    Chemistry of Materials · 2022-08-22

    Binqian Yuan, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  12. Cs2B4O5(OH)4: A new hydrated borate with a short UV cutoff edge

    Inorganica Chimica Acta · 2022-10-19

    Aixin Zhu, Jianbang Chen, Yanhui Zhang, Zhi Guo Su

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  13. KREP2Se6 (RE = Sm, Gd, Tb): The First Rare‐Earth Selenophosphates with Remarkable Nonlinear Optical Activities Realized by Synergistic Effect of RE‐ and P‐Based Motifs

    Small · 2022-12-11

    Zi‐Xia Chen, Chen‐Yi Zhao, Xiaohui Li, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  14. Na2BaB12O18F4: A Mixed Alkali/Alkaline-Earth Metal Fluorooxoborate with Two Unprecedented Interpenetrating Three-Dimensional B–O/F Anionic Networks and a Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-03-16

    Tuohetijiang Baiheti, Abudukadi Tudi, Minqiang Gai, Xuping Wang, Shujuan Han

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  15. Chromium iodate: the structure and origin of optical second harmonic generation

    Dalton Transactions · 2024-01-01

    Yang Chi, Mei-Ling Xin

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  16. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  17. Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships

    Coordination Chemistry Reviews · 2025-04-06

    Junben Huang, Chenglong Zhang, Siying Chen, Ailijiang Abudurusuli

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  18. CsLa(SO 4 ) 2 : A Lanthanum Sulfate Crystal for Nonlinear Optical Applications

    Inorganic Chemistry · 2025-05-23

    Lehui Liu, Feifei Yuan, Yisheng Huang, Lizhen Zhang, Zhoubin Lin

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  19. NH4B5O7(OH)2 and CsRbB10O14(OH)4·H2O: Two Hydroxyborates Feature Significant Optical Anisotropy and Contain 1∞[B5O7(OH)2] Chains

    Inorganic Chemistry · 2025-07-17

    Xueli Du, Haoran Wang, Haoran Liu, Qingyu Liu, Wenhu Wang, Jiahao Jiao, Yuchen Yan, Xueyan Wu, Min Zhang

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  20. Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials

    Chinese Chemical Letters · 2025-11-01

    Xuan Li, Tianhui Wu, Meiqi Liu, Yang Zhao, Jiahang Liu, Miao Zhang, Weiwei Cao, Jianmin Gu, Desong Wang

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  21. Ternary Anion‐Engineered Rare Earth Crystals for Broadband UV Transparency and Enhanced Second‐Harmonic Generation

    Chinese Journal of Chemistry · 2026-03-12

    Xiaohui Zhang, Ye Tao, Qianshuang Lu, J. N. Tan, Chenglong Xu, Yingjie Li, Yi Chen, Jianke Pan, F. H. Su, Tingchao He, Haifeng Dong, Heng Wang, Zhi Chen, Xiujun Yu, Xiaopeng Li

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  22. Topology-symmetry analysis and structure prediction in nonlinear optical AB4O6F (A = Na, K, Rb, Cs, NH4) and AAlB3O6F (A = K, Rb, Cs) polytypes

    Chinese Journal of Structural Chemistry · 2026-03-12

    Olga Reutova, Wenqi Jin, Congwei Xie, Junjie Li, Zhihua Yang, Xueling Hou, Shilie Pan

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  23. A Polar Cerium Iodate Ce 2 (IO 3 ) 6 (H 2 O) with a Strong Second-Harmonic Generation Response in Trivalent Ce-Based Materials

    Inorganic Chemistry · 2026-03-17

    Jiahang Liu, Miao Zhang, Shizheng Li, Ziyang Wang, Yang Zhao, NianRui Qu, Weiwei Cao, Jianmin Gu, Tianhui Wu

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  24. K 3 Yb 2 (BO 3 ) 3 and Rb 3 Yb 2 (BO 3 ) 3 : Two Rare-Earth Borate Ultraviolet Nonlinear Optical Crystals

    Inorganic Chemistry · 2026-07-02

    Jingjing Xu, Huili Zhang, Xuemei Shi, Xin Wen, Jingyao Lu, Jindong Chen, Chensheng Lin, Ning Ye, Guang Peng

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  25. Fluorine‐Driven Chemical Scissor Effect in Scandium Borates: Structural Evolution with Retained Optically Active Motifs

    Chinese Journal of Chemistry · 2026-08-03

    Linsen Wang, Qianzhen Zhang, Ran An, Zhihua Yang, Yun Yang, Xueyan Wu

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