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RESEARCH PAPER · Chemical Communications · 2023

Cs[B 3 O 3 F 2 (OH) 2 ]: discovery of a hydroxyfluorooxoborate guided by selective organic–inorganic transformation

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Cs[B 3 O 3 F 2 (OH) 2 ]: discovery of a hydroxyfluorooxoborate guided by selective organic–inorganic transformationOriginalHydroxyfluorooxoborate (NH 4 )[C(NH 2 ) 3 ][B 3 O 3 F 4 (OH)] for exploring the effects of cation substitution on structure and optical properties26K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence18Target-Oriented Synthesis of Borate Derivatives Featuring Isolated [B3O3] Six-Membered Rings as Structural Features20Heterologous Isomorphic Substitution Induces Optical Property Enhancement for Deep-UV Crystals: a Case in Rb[B3O3F2(OH)2]10Discovery of a new bimetallic borate with strong optical anisotropy activated by π-conjugated [B 2 O 5 ] units3Two Hydroxyfluorooxoborates Achieving Deep‐Ultraviolet Cutoff Edges and Moderate Birefringence by Assembling Multi‐Anionic Groups6(C3N2H5)B3O3F2(OH)2: Realizing Large Birefringence via a Synergistic Effect between Anion F/OH‐Ratio Optimization and Cation Activation25From β-KB3O4F2 to α-KB3O4F2: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy4CN 4 H 7 B 3 O 3 F 2 (OH) 2 : short-wave UV hydroxyfluorooxyborate crystals with large birefringence2Triple Integration of π‐Conjugated Building Blocks: Unprecedented Assembly for Large Optical Anisotropy11孤对电子效应羟基硼酸盐非线性光学研究进展(特邀)0Parallel arrangement of functional building blocks: toward performance synergy in oxalate borate ultraviolet nonlinear optical crystals0Fluorination‐Driven Molecular Polarization Engineering in Hydroxyfluorooxoborates for Generating Strong Short‐Wavelength Nonlinear Optical Responses0

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  1. Hydroxyfluorooxoborate (NH 4 )[C(NH 2 ) 3 ][B 3 O 3 F 4 (OH)] for exploring the effects of cation substitution on structure and optical properties

    Chemical Communications · 2023-01-01

    Ziqi Chen, Fuming Li, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  2. K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence

    Dalton Transactions · 2023-01-01

    Luyong Zhang, Shi‐Bin Wang, Fangfang Zhang, Zhihua Yang, Xueling Hou

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  3. Target-Oriented Synthesis of Borate Derivatives Featuring Isolated [B3O3] Six-Membered Rings as Structural Features

    Inorganic Chemistry · 2023-05-31

    Meng Cheng, Congcong Jin, Wenqi Jin, Xueling Hou

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  4. Heterologous Isomorphic Substitution Induces Optical Property Enhancement for Deep-UV Crystals: a Case in Rb[B3O3F2(OH)2]

    Inorganic Chemistry · 2023-08-29

    Ziqi Chen, Fuming Li, Yanli Liu, Cui Chen, Miriding Mutailipu

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  5. Discovery of a new bimetallic borate with strong optical anisotropy activated by π-conjugated [B 2 O 5 ] units

    Dalton Transactions · 2024-01-01

    Meihui Chen, Wei Wei, Jiawei Zhao, Donghai An, Yanna Chen

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  6. Two Hydroxyfluorooxoborates Achieving Deep‐Ultraviolet Cutoff Edges and Moderate Birefringence by Assembling Multi‐Anionic Groups

    Chemistry - A European Journal · 2024-04-15

    Huanhuan Cheng, Xiaojing Li, Shilie Pan, Shilie Pan, Zhihua Yang

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  7. (C3N2H5)B3O3F2(OH)2: Realizing Large Birefringence via a Synergistic Effect between Anion F/OH‐Ratio Optimization and Cation Activation

    Small Structures · 2024-07-28

    Chenhui Hu, Chunjie Shen, Huan Zhou, Jian Wei Han, Zhihua Yang, Kenneth Reinhard Poeppelmeier, Feng Zhang, Shilie Pan

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  8. From β-KB3O4F2 to α-KB3O4F2: Phase Transition-Directed Great Changes in Structure and Optical Anisotropy

    Inorganic Chemistry · 2024-11-06

    Ruyi Niu, Qing‐Yu Liu, Minqiang Gai, Zhihua Yang, Shujuan Han, Shilie Pan

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  9. CN 4 H 7 B 3 O 3 F 2 (OH) 2 : short-wave UV hydroxyfluorooxyborate crystals with large birefringence

    Chemical Communications · 2025-01-01

    Chunjie Shen, Huan Zhou, Chenhui Hu, Zhihua Yang, Feng Zhang, Shilie Pan

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  10. Triple Integration of π‐Conjugated Building Blocks: Unprecedented Assembly for Large Optical Anisotropy

    Small · 2025-10-07

    Ruyi Niu, Xiaona Li, Zhihua Yang, Juanjuan Lu, Xueling Hou, Shujuan Han, Shilie Pan, Miriding Mutailipu

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  11. 孤对电子效应羟基硼酸盐非线性光学研究进展(特邀)

    Chinese Journal of Lasers · 2026-01-01

    刘开通 Liu Kaitong, 饶远 Rao Yuan, 熊龙耀 Xiong Longyao, 张志忠 Zhang Zhizhong

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  12. Parallel arrangement of functional building blocks: toward performance synergy in oxalate borate ultraviolet nonlinear optical crystals

    Science China Chemistry · 2026-07-13

    Juhui Cui, Minqiang Gai, Ke Li, Z L Yang, Xueling Hou, Shilie Pan, Miriding Mutailipu

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  13. Fluorination‐Driven Molecular Polarization Engineering in Hydroxyfluorooxoborates for Generating Strong Short‐Wavelength Nonlinear Optical Responses

    Advanced Functional Materials · 2026-10-09

    Hongkang Su, Juhui Cui, chenxu li, Xiaona Li, Minqiang Gai, Zhihua Yang, Shilie Pan, Min Zhang

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