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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2022

Na 3 B 6 O 10 (HCOO): an ultraviolet nonlinear optical sodium borate-formate

Yinan Zhang, Qing-Fen Li, Bing-Ben Chen, You‐Zhao Lan, Jian‐Wen Cheng, Guo‐Yu Yang

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Na 3 B 6 O 10 (HCOO): an ultraviolet nonlinear optical sodium borate-formateOriginalTwo porous-layered borates built by B 7 O 13 (OH) clusters and AlO 4 /GaO 4 tetrahedra7ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps22Mg assists in modulating the dimensionalities of the anionic frameworks of borates1Structure and optical property evolution in PbM(PO 4 )X (M = Zn, Sn; X = halogen): SHG effect and birefringence21Two Acentric Aluminoborates Incorporated d10 Cations: Syntheses, Structures, and Nonlinear Optical Properties24Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System15Recent progress in ultraviolet and deep-ultraviolet nonlinear optical aluminoborates17Mixed polyanionic manganese(II) phosphate-oxalate compound as anode material for Li-ion batteries7Na4[B6O9 (OH)3](H2O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B6O9 (OH)3]3–}∞ Chains5Mixed Alkali Metal and Alkaline Earth Metal Scandium Borate Birefringence Material with Layered Structure and Short Ultraviolet Cutoff Edge17Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra21Li2RbSO4Cl with a Short Ultraviolet Absorption Edge and an Acentric Structure through Assembling Heteroleptic [LiO3Cl] Tetrahedra2Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge12A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I9From Layered Borate to Porous-Layered Aluminoborate7Hydroxyl-Driven Enhanced Birefringence in Borophosphates3Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks18Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives8Halide-driven polarity tuning and optimized SHG-bandgap balance in (C 4 H 11 N 2 )ZnX 3 (X = Cl, Br, I)34Sr2[B5O8(OH)]2 ⋅ [B(OH)3] ⋅ H2O: A Strontium Borate That Shows Deep‐Ultraviolet‐Transparent Nonlinear Optical Properties17Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups15M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion10Two polyoxovanadoborates with over 100 nuclei assembled from a {V14Co12B72} cluster13Insight into stable, concentrated radicals from sulfur-functionalized alkyne-rich crystalline frameworks and application in solar-to-vapor conversion5Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework8Lithium Borate-Squarate: An Organic–Inorganic Groups-Mixed Nonlinear Optical Crystal with Large Birefringence4Breaking the Natural Tendency of Deep‐UV Polyborate Anion Clusters to Inducing Strong Optical Anisotropy13Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions9Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties3Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency1Construction of {BCo 9 }-Based Polyoxometalates with Banana- and Peanut-Shaped Structures: Catalytic Activity in Knoevenagel Condensation Reactions1Assembly of Functional Units for Constructing an Ultraviolet-Transparent Nonlinear Optical Mixed Alkaline Metal Borate-Formate1

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  1. Two porous-layered borates built by B 7 O 13 (OH) clusters and AlO 4 /GaO 4 tetrahedra

    CrystEngComm · 2022-01-01

    Yazhuo Dong, Chong‐An Chen, Juan Chen, Jian‐Wen Cheng, Jinhua Li, Guo‐Yu Yang

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  2. ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps

    Inorganic Chemistry · 2022-10-26

    Jin Chen, Ke‐Zhao Du

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  3. Mg assists in modulating the dimensionalities of the anionic frameworks of borates

    Dalton Transactions · 2023-01-01

    Qianzhen Zhang, Feixiang Wang, Xifa Long, Yun Mo Yang

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  4. Structure and optical property evolution in PbM(PO 4 )X (M = Zn, Sn; X = halogen): SHG effect and birefringence

    Inorganic Chemistry Frontiers · 2023-01-01

    Xiaobao Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  5. Two Acentric Aluminoborates Incorporated d10 Cations: Syntheses, Structures, and Nonlinear Optical Properties

    Inorganic Chemistry · 2023-01-06

    Xuyan Li, Jinhua Li, Jian‐Wen Cheng, Guo‐Yu Yang

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  6. Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System

    Inorganic Chemistry · 2023-01-18

    Feixiang Wang, Mengfan Wu, Zhihua Yang, Xifa Long, Yun Mo Yang, Shilie Pan

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  7. Recent progress in ultraviolet and deep-ultraviolet nonlinear optical aluminoborates

    Chinese Journal of Structural Chemistry · 2023-02-17

    Qingfen Li, Weifeng Chen, You‐Zhao Lan, Jian‐Wen Cheng

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  8. Mixed polyanionic manganese(II) phosphate-oxalate compound as anode material for Li-ion batteries

    Journal of Solid State Chemistry · 2023-06-07

    Sitong Lu, Yanyan Li, Guo‐Dong Zou, Kangzhe Cao, Fan Yang

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  9. Na4[B6O9 (OH)3](H2O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B6O9 (OH)3]3–}∞ Chains

    Inorganic Chemistry · 2023-06-12

    Ru‐Ling Tang, Lei Huai, Wenlong Liu

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  10. Mixed Alkali Metal and Alkaline Earth Metal Scandium Borate Birefringence Material with Layered Structure and Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-06-15

    Wenhao Liu, Pifu Gong, Weiqi Huang, Mengran Sun, Sangen Zhao, Zheshuai Lin, Jiyong Yao

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  11. Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra

    Molecules · 2023-06-28

    Jinɡjinɡ Li, Weifeng Chen, You‐Zhao Lan, Jian‐Wen Cheng

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  12. Li2RbSO4Cl with a Short Ultraviolet Absorption Edge and an Acentric Structure through Assembling Heteroleptic [LiO3Cl] Tetrahedra

    Inorganic Chemistry · 2023-08-08

    Huanhuan Cheng, Fuming Li, Juanjuan Lu, Xueling Hou

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  13. Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-09-04

    Qianzhen Zhang, Ran An, Abudukadi Tudi, Zhihua Yang, Xifa Long, Yun Mo Yang

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  14. A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I

    Solid State Sciences · 2023-10-04

    Sergey N. Volkov, Dmitri O. Charkin, Vadim E. Kireev, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Nikita Sergeyevich Tsvetov, Yulia A. Vaitieva, Sergey M. Aksenov, Р. С. Бубнова

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  15. From Layered Borate to Porous-Layered Aluminoborate

    Crystal Growth & Design · 2023-10-04

    Xuyan Li, Chong‐An Chen, Guo‐Yu Yang

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  16. Hydroxyl-Driven Enhanced Birefringence in Borophosphates

    Inorganic Chemistry · 2023-11-22

    Yang Xia, Wen-Bin Zhang, Xueting Pan, Xueling Hou, Shujuan Han

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  17. Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks

    Inorganic Chemistry Frontiers · 2024-01-01

    Miao‐Bin Xu, Jin Chen, Huai‐Yu Wu, Jiajia Li, Ning Yu, Mo-Fan Zhuo, Fei‐Fei Mao, Ke‐Zhao Du

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  18. Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives

    Dalton Transactions · 2024-01-01

    Jingyi Lu, Yangfeifei Ou, Congcong Jin, Jian‐Wen Cheng

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  19. Halide-driven polarity tuning and optimized SHG-bandgap balance in (C 4 H 11 N 2 )ZnX 3 (X = Cl, Br, I)

    Inorganic Chemistry Frontiers · 2024-01-01

    Jin Chen, Huai-Yu Wu, Miao‐Bin Xu, Mingchang Wang, Qianqian Chen, Bingxuan Li, Chun‐Li Hu, Ke‐Zhao Du

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  20. Sr2[B5O8(OH)]2 ⋅ [B(OH)3] ⋅ H2O: A Strontium Borate That Shows Deep‐Ultraviolet‐Transparent Nonlinear Optical Properties

    Chemistry - A European Journal · 2024-03-18

    Weifeng Chen, J. Lu, Jingjing Li, You‐Zhao Lan, Jian‐Wen Cheng, Guo‐Yu Yang

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  21. Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups

    Inorganic Chemistry · 2024-04-23

    Wencong Li, Junbo Wang, Lili Liu, Chunmei Huang, Yanyan Ding, Mengmeng Zhu, Jindan Tian, Hai-Xin Qi, Yaoqing Chu, Jiayue Xu

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  22. M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion

    Inorganic Chemistry · 2024-05-09

    Weifeng Chen, Mei-Jun Zou, Jinɡjinɡ Li, Yinan Zhang, You‐Zhao Lan, Jian‐Wen Cheng, Guo‐Yu Yang

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  23. Two polyoxovanadoborates with over 100 nuclei assembled from a {V14Co12B72} cluster

    Science China Chemistry · 2024-05-31

    Shuangxue Wu, Yujiao Dong, Yang Yang, Chao Qin, Chunyi Sun, Wei Guan, Xinlong Wang, Zhong‐Min Su

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  24. Insight into stable, concentrated radicals from sulfur-functionalized alkyne-rich crystalline frameworks and application in solar-to-vapor conversion

    Chinese Journal of Structural Chemistry · 2024-06-26

    Jian‐Rong Li, Jieying Hu, Lai‐Hon Chung, Jilong Zhou, Parijat Borah, Zhiqing Lin, Yuan‐Hui Zhong, Hua‐Qun Zhou, Xianghua Yang, Zhengtao Xu, Jun Hui He

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  25. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  26. Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework

    Inorganic Chemistry · 2024-12-31

    Juan Chen, Dan Qin, Guo‐Yu Yang

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  27. Lithium Borate-Squarate: An Organic–Inorganic Groups-Mixed Nonlinear Optical Crystal with Large Birefringence

    Inorganic Chemistry · 2025-02-18

    Zhiyong Xue, Xin Wen, Yuchen Yan, Jindong Chen, Zhanggui Hu, Jiyang Wang, Ning Ye, Guang Peng

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  28. Breaking the Natural Tendency of Deep‐UV Polyborate Anion Clusters to Inducing Strong Optical Anisotropy

    Small · 2025-04-24

    Ziqi Chen, Changyou Liu, Zhi Li, Juanjuan Lu, Junjie Li, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  29. Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions

    Chinese Journal of Structural Chemistry · 2025-09-01

    Yangfeifei Ou, Xiaoliang Zhou, You‐Zhao Lan, Jian‐Wen Cheng

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  30. Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties

    The Journal of Physical Chemistry Letters · 2025-12-26

    Zi-Xuan Zhao, Wei Chen, Hui‐Yan Zhao, Mengjiao Xu, Chao He, Qi Wei, Guo-Ming Wang

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  31. Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency

    Inorganic Chemistry · 2026-02-05

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu, Yongmin Guo

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  32. Construction of {BCo 9 }-Based Polyoxometalates with Banana- and Peanut-Shaped Structures: Catalytic Activity in Knoevenagel Condensation Reactions

    Inorganic Chemistry · 2026-02-23

    Cheng-Ri Wang, Hai-Lou Li, Zheng Wang, Yu Wang, Jin-Ni Zhao, Juan Chen, Meng‐Ze Jia, Guo‐Yu Yang

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  33. Assembly of Functional Units for Constructing an Ultraviolet-Transparent Nonlinear Optical Mixed Alkaline Metal Borate-Formate

    Inorganic Chemistry · 2026-05-22

    Mei-Jun Zou, Dong-Ling Liu, Xiao-Liang Zhou, Yi-Nan Zhang, You‐Zhao Lan, Jian‐Wen Cheng

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