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RESEARCH PAPER · Inorganic Chemistry · 2017

An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units

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An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building UnitsOriginalLow-temperature-flux syntheses of ultraviolet-transparent borophosphates Na 4 MB 2 P 3 O 13 (M = Rb, Cs) exhibiting a second-harmonic generation response23Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate34Ion-induced structural and optical performance evolution in LBO-like crystals: experimental and theoretical investigation13NH 4 B 11 O 16 (OH) 2 : a new ammonium borate with wavy-shaped polycyclic 2∞[B 11 O 16 (OH) 2 ] layers27Linking 1D Transition-Metal Coordination Polymers and Different Inorganic Boron Oxides To Construct a Series of 3D Inorganic–Organic Hybrid Borates42Synthesis, Structure and Characterization of Two Borates Templated by Organic Super Base5Synthesis, structure characterization, photoluminescence properties and TD–DFT calculations for two new borates3Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals257From LiB3O5 to NaRbB6O9F2: Fluorine‐Directed Evolution of Structural Chemistry33An inorganic-organic hybrid solid with B5O7(OH)3 clusters bridged and decorated by zinc–amine complexes1Synthesis, Structure, and Properties of the Non-Centrosymmeteric Compound LiNaRbB5O8(OH)23Three Alumino/Galloborate Frameworks Templated by Organic Amines: Syntheses, Structures, and Nonlinear Optical Properties23K 2 [B 4 O 5 (OH) 4 ]·H 2 O and K 2 [B 4 O 5 (OH) 4 ]: two new hydrated potassium borates with isolated [B 4 O 5 (OH) 4 ] 2− units and different structural frameworks8Li 2 Na 2 [B 12 O 19 (OH) 2 ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units8Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions98Transformation of the B–O Units from Corner-Sharing to Edge-Sharing Linkages in BaMBO4 (M = Ga, Al)33Al8(BO3)4(B2O5)F8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups12Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra11Trinuclear Cd 3 O 14 hexaborate and two nickel borates based on molten salt synthesis and precursor synthesis: structure, characterization, and properties10Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution50Borates: A Rich Source for Optical Materials1089Sn2B5O9Br as an Outstanding Bifunctional Material with Strong Second‐Harmonic Generation Effect and Large Birefringence84M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric Structures20Structural Chemistry of Metal‐Oxo Clusters1Structural Chemistry of Metal‐Oxo Clusters1Two Chiral Metal Complex Templated Aluminoborates Constructed from Three Types of Oxoboron Clusters17Li3La2(BO3)3 and Li1.75Na1.25La2(BO3)3: A Great Enhancement in Birefringence Induced by Optimal Arrangement of π-Conjugated [BO3] Units28K2Na3[{B6O10(OH)}{B3O4(OH)3}] ⋅ H2O: A Layered Borate Built by Mixed Oxoboron Clusters with Nonlinear‐Optical Property20LiB9O15·H2dap·H2O: A Cotemplated Acentric Layer-Pillared Borate Built by Mixed Oxoboron Clusters12Спектроскопическое исследование структурных и магнитных свойств TbCr-=SUB=-3-=/SUB=-(BO-=SUB=-3-=/SUB=-)-=SUB=-4-=/SUB=-0Sr 3 B 14 O 24 : a new borate with a [B 14 O 30 ] fundamental building block and an unwonted 2D double layer11Na 3 B 6 O 10 (HCOO): an ultraviolet nonlinear optical sodium borate-formate33Two porous-layered borates built by B 7 O 13 (OH) clusters and AlO 4 /GaO 4 tetrahedra7Two Indium Iodate–Nitrates with Large Birefringence Induced by Hybrid Anionic Functional Groups and Their Favorable Arrangements22Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate36Double‐Modification Oriented Design of a Deep‐UV Birefringent Crystal Functionalized by [B12O16F4(OH)4] Clusters9Double‐Modification Oriented Design of a Deep‐UV Birefringent Crystal Functionalized by [B12O16F4(OH)4] Clusters139Highly Efficient Uranium Capture via Crystalline Water Coordination Coupling with Cation Exchange and Surface Redox Reaction Mechanisms within an Open-Framework Vanadoborate10C(NH2)3Rb(I3O8)(IO3)(I2O6H2): An unprecedented organic–inorganic hybrid polyiodate with two different polyiodate groups13Noncentrosymmetric versus Centrosymmetric: Halogen Induced Variable Coordination Modes of Sn2+ and Structural Transition in Sn3B3O7X (X = Cl and Br)17Two Acentric Aluminoborates Incorporated d10 Cations: Syntheses, Structures, and Nonlinear Optical Properties24Structural Regulation and Oxygen Reduction Reaction Activity of [Co(bpy)2BO2(OH)] and [Cu(bpy)(OH)]2– Complex Templated Borates11Na4[B6O9 (OH)3](H2O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B6O9 (OH)3]3–}∞ Chains5Mixed Alkali Metal and Alkaline Earth Metal Scandium Borate Birefringence Material with Layered Structure and Short Ultraviolet Cutoff Edge17Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra21Spectroscopic Investigation of Structural and Magnetic Properties of TbCr3(BO3)43Co (II) -doped hybrid Zn (II) tetraborate complexes, [Zn x Co (1− x ) (1,3-dap)B 4 O 7 ] (1,3-dap = 1,3-diaminopropane): BET analysis and N 2 /H 2 O/D 2 O adsorption studies0Syntheses, structures and properties of two new members of the pentaborate family: NaKB 5 O 8 (OH)·H 2 O and KB 5 O 8 ·2H 2 O3Sr2[B5O8(OH)]2 ⋅ [B(OH)3] ⋅ H2O: A Strontium Borate That Shows Deep‐Ultraviolet‐Transparent Nonlinear Optical Properties17Rb 1.87 Cs 1.13 B 8 O 13 (NO 3 ): a new acentric borate-nitrate with two types of three-dimensional interpenetrating lattices1Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework8In Situ Synthesized Cobalt Nanocrystal via Bipyridine Ligand Cobaltic Borate Annealing Method for High‐performance Zinc‐air Battery5Li6[{BO3}{B15O21(OH)6}]: An Acentric Layered Borate Constructed from Unprecedented Oxoboron Cluster Building Units6Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions9Two {B 6 }-Based Borates: From 1D Chain to 3D Framework1Two Acentric Borates with 2-/3-D Frameworks: Syntheses, Structures, and Nonlinear Optical Properties0

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  2. Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate

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  3. Ion-induced structural and optical performance evolution in LBO-like crystals: experimental and theoretical investigation

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  4. NH 4 B 11 O 16 (OH) 2 : a new ammonium borate with wavy-shaped polycyclic 2∞[B 11 O 16 (OH) 2 ] layers

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  5. Linking 1D Transition-Metal Coordination Polymers and Different Inorganic Boron Oxides To Construct a Series of 3D Inorganic–Organic Hybrid Borates

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  7. Synthesis, structure characterization, photoluminescence properties and TD–DFT calculations for two new borates

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  8. Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals

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  9. From LiB3O5 to NaRbB6O9F2: Fluorine‐Directed Evolution of Structural Chemistry

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  10. An inorganic-organic hybrid solid with B5O7(OH)3 clusters bridged and decorated by zinc–amine complexes

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  11. Synthesis, Structure, and Properties of the Non-Centrosymmeteric Compound LiNaRbB5O8(OH)2

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  12. Three Alumino/Galloborate Frameworks Templated by Organic Amines: Syntheses, Structures, and Nonlinear Optical Properties

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  13. K 2 [B 4 O 5 (OH) 4 ]·H 2 O and K 2 [B 4 O 5 (OH) 4 ]: two new hydrated potassium borates with isolated [B 4 O 5 (OH) 4 ] 2− units and different structural frameworks

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  14. Li 2 Na 2 [B 12 O 19 (OH) 2 ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units

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  15. Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions

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  16. Transformation of the B–O Units from Corner-Sharing to Edge-Sharing Linkages in BaMBO4 (M = Ga, Al)

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  17. Al8(BO3)4(B2O5)F8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups

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  18. Rb 3 BaTeB 7 O 15 : a novel [B 7 O 16 ] fundamental building block in a new telluroborate with [TeO 3 ] polyhedra

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  19. Trinuclear Cd 3 O 14 hexaborate and two nickel borates based on molten salt synthesis and precursor synthesis: structure, characterization, and properties

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  20. Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution

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  21. Borates: A Rich Source for Optical Materials

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  22. Sn2B5O9Br as an Outstanding Bifunctional Material with Strong Second‐Harmonic Generation Effect and Large Birefringence

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  23. M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric Structures

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  30. Спектроскопическое исследование структурных и магнитных свойств TbCr-=SUB=-3-=/SUB=-(BO-=SUB=-3-=/SUB=-)-=SUB=-4-=/SUB=-

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  31. Sr 3 B 14 O 24 : a new borate with a [B 14 O 30 ] fundamental building block and an unwonted 2D double layer

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  35. Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate

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  40. Noncentrosymmetric versus Centrosymmetric: Halogen Induced Variable Coordination Modes of Sn2+ and Structural Transition in Sn3B3O7X (X = Cl and Br)

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  42. Structural Regulation and Oxygen Reduction Reaction Activity of [Co(bpy)2BO2(OH)] and [Cu(bpy)(OH)]2– Complex Templated Borates

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  43. Na4[B6O9 (OH)3](H2O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B6O9 (OH)3]3–}∞ Chains

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  46. Spectroscopic Investigation of Structural and Magnetic Properties of TbCr3(BO3)4

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  47. Co (II) -doped hybrid Zn (II) tetraborate complexes, [Zn x Co (1− x ) (1,3-dap)B 4 O 7 ] (1,3-dap = 1,3-diaminopropane): BET analysis and N 2 /H 2 O/D 2 O adsorption studies

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