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RESEARCH PAPER · Crystal Growth & Design · 2006

Crystal Engineering with the Uranyl Cation II. Mixed Aliphatic Carboxylate/Aromatic Pyridyl Coordination Polymers: Synthesis, Crystal Structures, and Sensitized Luminescence

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Crystal Engineering with the Uranyl Cation II. Mixed Aliphatic Carboxylate/Aromatic Pyridyl Coordination Polymers: Synthesis, Crystal Structures, and Sensitized LuminescenceOriginalHomo- and heterometallic coordination polymers from the f elements413Structural diversity and properties of M(ii) 4-carboxyl phenoxyacetate complexes with 0D-, 1D-, 2D- and 3D M-cpoa framework60Uranyl citrate dimers as guests in a copper–bipyridine framework: a novel heterometallic inorganic–organic hybrid compound35Uranyl Ion Complexation by Citric and Citramalic Acids in the Presence of Diamines61Different aliphatic dicarboxylates affected assemble of new coordination polymers constructed from flexible–rigid mixed ligands39One- and Two-Dimensional Silver and Zinc Uranyl Phosphates Containing Bipyridyl Ligands32Structural Diversity and Potential Applications of Metal–Organic Coordination Polymers0Novel two-dimensional uranyl–organic assemblages in the citrate and d (–)-citramalate families46Affinity of the Highly Preorganized Ligand PDA (1,10-Phenanthroline-2,9-dicarboxylic acid) for Large Metal Ions of Higher Charge. A Crystallographic and Thermodynamic Study of PDA Complexes of Thorium(IV) and the Uranyl(VI) ion111Species Distribution and Coordination of Uranyl Chloro Complexes in Acetonitrile49Pyrazinetetracarboxylic Acid as an Assembler Ligand in Uranyl−Organic Frameworks74Preparation, Structures, and Photocatalytic Properties of Three New Uranyl−Organic Assembly Compounds218One- and two-dimensional divalent copper coordination polymers based on kinked organodiimine and long flexible aliphatic dicarboxylate ligands5Thorium(IV) Coordination Polymers in the Pyridine and Pyrazinedicarboxylic Acid Systems56Structural Variation within Homometallic Uranium(VI) Carboxyphosphonates: In Situ Ligand Synthesis, Directed Assembly, Metal−Ligand Coordination and Hydrogen Bonding82Uranyl Ion Complexes with Cucurbit[n]urils (n = 6, 7, and 8): A New Family of Uranyl-Organic Frameworks127Two novel uranyl–organic frameworks with cyclohexane-1,3-dicarboxylate ligands40Syntheses, structures, characterizations and charge-density matching of novel amino-templated uranyl selenates45Generation of Three-Dimensional Networks through Aliphatic Chain Disorder in a Divalent Metal Dicarboxylate/Organodiimine Coordination Polymer System22A novel uranyl complex UO2(tci)(C3H5N2) · H2O: Synthesis, crystal structure and characterization19Influence of metal ions, coligands and reaction conditions on the structural versatility and properties of 5-pyrimidyl-tetrazolate containing complexes51The uranyl tetrachloride anion as a tecton in the assembly of U(VI) hybrid materials63Divalent metal succinate/perchlorate coordination polymers incorporating a kinked hydrogen-bonding capable diimine: Chains, layers and a (5,6)-connected binodal network featuring alternating rectangular and hexagonal grids9Metal azelate coordination polymers containing a kinked dipyridyl tether: CdSO4 topology and “ligand vacancy” primitive cubic three-dimensional networks5Copper benzenedicarboxylate coordination polymers incorporating a long-spanning neutral co-ligand: Effect of anion inclusion and carboxylate pendant-arm length on topology and magnetism50Design and construction of two new polymers featuring macrocyclic subunits based on a rigid clamp-like ligand15Homometallic Uranium(VI) Phosphonoacetates Containing Interlayer Dipyridines69Synthesis, crystal structure and photoelectric property of two novel coordinated complexes constructed by 4,4′-bipyridine and sebacic acid12Structure and physical properties of substituted malonate divalent metal coordination polymers with dipyridylamine co-ligands: acentric chain, herringbone layer, and novel binodal network topologies21Synthesis and luminescent properties of the first series of lanthanide complexes based on sebacate and 2,5-pyridinedicarboxylate11Homometallic UO22+ diphosphonates assembled under ambient and hydrothermal conditions29Synthesis and Characterization of 1‐, 2‐, and 3‐Dimensional Bimetallic UO22+/Zn2+ Phosphonoacetates66Lanthanide(III) Coordination Polymers with Longer-Spanning Flexible Ligand: Synthesis, Crystal Structure and Luminescence Property8Supramolecular chemistry with uranyl tetrahalide ([UO2X4]2−) anions44Construction of Three‐Dimensional Uranyl–Organic Frameworks with Benzenetricarboxylate Ligands77Synthesis, structure and fluorescence properties of a uranyl-2,5-pyridinedicarboxylic acid coordination polymer: The missing member of the UO22+-2,n-pyridinedicarboxylic series34Combination of covalent and hydrogen bonding in the formation of 3D uranyl-carboxylate networks28Synthesis, crystal structure and photoelectric property of two new coordination polymers constructed by longer-spanning suberic acid and 4,4′-bipyridine ligands8Syntheses, structures and luminescence of a series of Cd(II)-containing coordination polymers constructed from a long flexible bis-triazole ligand17Uranyl(VI)–Acetylacetonate Coordination Compounds with Various N-Heterocyclic Ligands16Tetrameric entity resulting from two distinct dinuclear uranyl-centered motifs bridged through μ2-OH and pyridazine-3,6-dicarboxylate26An uranyl citrate coordination polymer with a 3D open-framework involving uranyl cation-cation interactions57Combining coordination and supramolecular chemistry for the formation of uranyl-organic hybrid materials38Revisiting the Uranyl-phthalate System: Isolation and Crystal Structures of Two Types of Uranyl−Organic Frameworks (UOF)78Uranyl Ion Complexation by Aliphatic Dicarboxylic Acids in the Presence of Cucurbiturils as Additional Ligands or Structure-Directing Agents124Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds412Occurence of an Octanuclear Motif of Uranyl Isophthalate with Cation–Cation Interactions through Edge-Sharing Connection Mode94Crystal Engineering with the Uranyl Cation III. Mixed Aliphatic Dicarboxylate/Aromatic Dipyridyl Coordination Polymers: Synthesis, Structures, and Speciation74Crystallogeny and photobehavior of supramolecular aggregates based on Nd(III)-binicotinate sheets: Toward the effect of 4,4′-bipyridine0Effect of Carboxylate Coligands with Different Rigidity on Supramolecular Architectures Based on One Rigid Didentate Linear Ligand86Uranyl–Pyromellitate Coordination Polymers: Toward Three-Dimensional Open Frameworks with Large Channel Systems83Uranyl Ion Complexes with Ammoniobenzoates as Assemblers for Cucurbit[6]uril Molecules56Uranyl and/or Rare-Earth Mellitates in Extended Organic–Inorganic Networks: A Unique Case of Heterometallic Cation–Cation Interaction with UVI═O–LnIII Bonding (Ln = Ce, Nd)1173-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials76Nitrogen-rich Compounds of the Actinoids: Dioxouranium(VI) 5,5′-Azobis[tetrazolide] Pentahydrate and Its Unusually Small Uranyl Angle13Binuclear biologically active Co(II) complexes with octazamacrocycle and aliphatic dicarboxylates7Complexes of unsymmetric bis-hydrazide ligands: crystal structures and properties6Nanomaterials and nanotechnologies in nuclear energy chemistry46Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures418Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers82Copper uranyl phosphate and arsenate incorporating an organic ligand with a pillared layer structure: [Cu(4,4′-bpy)(UO2)0.5(HPO4)(H2PO4)]·H2O and [Cu(4,4′-bpy)(UO2)0.5(HAsO4)(H2AsO4)]·1.5H2O15Synthesis, structure and photocatalytic property of a novel 3D (3,8)-connected metal–organic framework based on a flexible triphosphonate and a pentanuclear Cu(II) unit21Syntheses, structures, and fluorescent properties of two uranium coordination polymers with carboxylic acids15Series of Mixed Uranyl–Lanthanide (Ce, Nd) Organic Coordination Polymers with Aromatic Polycarboxylates Linkers92Clusters of Actinides with Oxide, Peroxide, or Hydroxide Bridges344Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products372Bisactinyl halogenated complexes: relativistic density functional theory calculation and experimental synthesis9Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate71Structural Observations of Heterometallic Uranyl Copper(II) Carboxylates and Their Solid‐State Topotactic Transformation upon Dehydration63Synthesis, Structural Characterization, and Dehydration Analysis of Uranyl Zinc Mellitate, (UO2)Zn(H2O)4(H2mel)·2H2O31Five sra Topological Ln(III)-MOFs Based on Novel Metal-Carboxylate/Cl Chain: Structure, Near-Infrared Luminescence and Magnetic Properties100Construction of four coordination polymers with helical character based on a flexible bis(triazole) derivative and dicarboxylate coligands82,2′‐Bipyridine and 1,10‐Phenanthroline as Coligands or Structure‐Directing Agents in Uranyl–Organic Assemblies with Polycarboxylic Acids56The crystal chemistry of uranium carboxylates394Crystal structures and characterization of two divalent metal selenates templated by dabco, (C6H14N2)[MII(H2O)6](SeO4)2 (MII: NiII, ZnII)11Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties29Synthesis, crystal structure, photoluminescence property and photoelectronic behavior of two uranyl-organic frameworks constructed from 1, 2, 4, 5-benzenetetracarboxylic acid as ligand34MOFs of Uranium and the Actinides95Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules60Postsynthetic Rearrangement/Metalation as a Route to Bimetallic Uranyl Coordination Polymers: Syntheses, Structures, and Luminescence70Synthesis and characterization of 1-D uranyl thiodigycolate coordination polymers10Synthesis, crystal structure and spectroscopic studies of some organic/inorganic hybrid materials containing isostructural monomeric uranyl complexes bridged by bipyridyl typed ligands16Increasing Complexity in the Uranyl Ion–Kemp’s Triacid System: From One- and Two-Dimensional Polymers to Uranyl–Copper(II) Dodeca- and Hexadecanuclear Species47Photocatalytic Application of 4f–5f Inorganic–Organic Frameworks: Influence of Lanthanide Contraction on the Structure and Functional Properties of a Series of Uranyl–Lanthanide Complexes34Uranyl Ion Complexes with trans‐3‐(3‐Pyridyl)acrylic Acid Including a Uranyl–Copper(II) Heterometallic Framework21Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers46Eu-MOFs with 2-(4-Carboxyphenyl)imidazo[4,5- f ]-1,10-phenanthroline and Ditopic Carboxylates as Coligands: Synthesis, Structure, High Thermostability, and Luminescence Properties67UO 2 2+ -amino hybrid materials: structural variation and photocatalysis properties29A family of uranyl-aromatic dicarboxylate (pht-, ipa-, tpa-) framework hybrid materials: photoluminescence, surface photovoltage and dye adsorption31Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Two novel uranyl complexes of a semi-rigid aromatic tetracarboxylic acid supported by an organic base as an auxiliary ligand or a templating agent: an experimental and theoretical exploration16Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties68Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers53Tetranuclear Uranyl Polyrotaxanes: Preferred Selectivity toward Uranyl Tetramer for Stabilizing a Flexible Polyrotaxane Chain Exhibiting Weakened Supramolecular Inclusion28Structural Variations in the Uranyl/4,4′-Biphenyldicarboxylate System. Rare Examples of 2D → 3D Polycatenated Uranyl–Organic Networks78Complexes of uranyl glutarate with urea and dimethylurea: Synthesis and structure5Multifunctional Uranyl Hybrid Materials: Structural Diversities as a Function of pH, Luminescence with Potential Nitrobenzene Sensing, and Photoelectric Behavior as p-type Semiconductors56Silver Ion-Mediated Heterometallic Three-Fold Interpenetrating Uranyl–Organic Framework52A New Form of Triple-Stranded Helicate Found in Uranyl Complexes of Aliphatic α,ω-Dicarboxylates34A Family of Uranyl Coordination Polymers Containing O-Donor Dicarboxylates and Trispyridyltriazine Guests36The templated synthesis of a unique type of tetra-nuclear uranyl-mediated two-fold interpenetrating uranyl–organic framework36Anchoring flexible uranyl dicarboxylate chains through stacking interactions of ancillary ligands on chiral U( vi ) centres37Counter-ion control of structure in uranyl ion complexes with 2,5-thiophenedicarboxylate39From Helicates to Borromean Links: Chain Length Effect in Uranyl Ion Complexes of Aliphatic α,ω-Dicarboxylates21Nano-diamond particles functionalized with single/double-arm amide–thiourea ligands for adsorption of metal ions49Uranyl Ion Complexes with Long-Chain Aliphatic α,ω-Dicarboxylates and 3d-Block Metal Counterions34Counterion-Induced Variations in the Dimensionality and Topology of Uranyl Pimelate Complexes41Synthesis, structure, luminescence and photocatalytic properties of an uranyl-2,5-pyridinedicarboxylate coordination polymer32Entangled Uranyl Organic Frameworks with (10,3)-b Topology and Polythreading Network: Structure, Luminescence, and Computational Investigation43Uranyl oxamate hydrates: hydrothermal synthesis, crystal structure, photophysical properties, and selective crystallization0Exploring Crystal Engineering for Porous Uranyl–Organic Frameworks: Insight into Hydrolysis and In Situ Reaction, Structural Variation‐Dependent Physical Properties6Crystal structures of new uranyl glutarate coordination polymers (NH4)2[(UO2)2(glt)3]·nH2O (n= 3 or 6) and R[UO2(glt)(Hglt)]·H2O (R = Na, K, Rb or Cs)10Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework31Structural elucidation and physicochemical properties of mononuclear Uranyl(VI) complexes incorporating dianionic units22Dicyanoaurate-based heterobimetallic uranyl coordination polymers26Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species93The crystalline α,ω-dicarboxylate metal complex with the longest aliphatic chain to date: uranyl 1,15-pentadecanedioate10Potassium and magnesium succinatouranilates – Synthesis and crystal structure12AgI and PbII as Additional Assembling Cations in Uranyl Coordination Polymers and Frameworks44Experimental and Theoretical Approaches to Three Uranyl Coordination Polymers Constructed by Phthalic Acid and N,N′-Donor Bridging Ligands: Crystal Structures, Luminescence, and Photocatalytic Degradation of Tetracycline Hydrochloride56Utilizing bifurcated halogen-bonding interactions with the uranyl oxo group in the assembly of a UO2–3-bromo-5-iodobenzoic acid coordination polymer17Exploring New Assembly Modes of Uranyl Terephthalate: Templated Syntheses and Structural Regulation of a Series of Rare 2D → 3D Polycatenated Frameworks39Crystal structure and luminescent properties of novel coordination polymers constructed with bifurandicarboxylic acid3Influence of Pyrazine/Piperazine Based Guest Molecules in the Crystal Structures of Uranyl Thiophene Dicarboxylate Coordination Polymers: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye47Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters16Structural Consequences of 1,4-Cyclohexanedicarboxylate Cis/Trans Isomerism in Uranyl Ion Complexes: From Molecular Species to 2D and 3D Entangled Nets67Mg, Ca and Ba glutaratouranylates – Synthesis and structure9Understanding the origins of O yl –U–O yl bending in the uranyl (UO 2 2+ ) ion56Actinide-based MOFs: a middle ground in solution and solid-state structural motifs110Simultaneous elimination of cationic uranium( vi ) and anionic rhenium( vii ) by graphene oxide–poly(ethyleneimine) macrostructures: a batch, XPS, EXAFS, and DFT combined study118Ordered Entanglement in Actinide-Organic Coordination Polymers40Large-Pore Layered Networks, Polycatenated Frameworks, and Three-Dimensional Frameworks of Uranyl Tri(biphenyl)amine/Tri(phenyl)amine Tricarboxylate: Solvent-/Ligand-Dependent Dual Regulation23Structure-Directing Effects of Counterions in Uranyl Ion Complexes with Long-Chain Aliphatic α,ω-Dicarboxylates: 1D to Polycatenated 3D Species31Fabrication of blue organic light-emitting diodes from novel uranium complexes: synthesis, characterization, and electroluminescence studies of uranium anthracene-9-carboxylate complexes9A UO2-based salt target for rapid isolation of fission products2Bipyridine-Directed Syntheses of Uranyl Compounds Containing Semirigid Dicarboxylate Linkers: Diversity and Consistency in Uranyl Speciation28The effect of organic cations on the structure of uranyl glutarate complexes1Synthesis, Characterization, and X-ray Structure of Tetraaminoguanidinium Diuranyl Tetraoxalate Monohydrate (HAgun)4[(UO2)2(C2O4)4]·H2O0Synthèses, caractérisations et cristallochimie de polyoxométallates incorporant des actinides et des lanthanides comme simulants d’actinides0Noncomplexed Cucurbituril-Mediated Structural Evolution of Layered Uranyl Terephthalate Compounds13Occurrence of polyoxouranium motifs in uranyl organic networks constructed by using silicon-centered carboxylate linkers: structures, spectroscopy and computation11Synthesis and Structure of New Glutarate-Containing U(VI), Np(V), and Pu(VI) Compounds3Controlling Cation‐Cation Interactions in Uranyl Coordination Dimers by Varying the Length of the Dicarboxylate Linker4Auxiliary Ligand-Dependent Adaptive Regulation of Uranyl Coordination in Mixed-Ligand Uranyl Compounds of Flexible Biphenyltetracarboxylic Acid16Introducing Bluish-Green Light-Emitting Diodes (OLEDs) and Tuning Their Color Intensity by Uranium Complexes: Synthesis, Characterization, and Photoluminescence Studies of 8‑Hydroxyquinoline Complexes of Uranium8Síntesis de redes metal-orgánicas heteroestructurales con ligandos mixtos.0Achieving and Stabilizing Uranyl Bending via Physical Pressure11A series of entangled MOFs constructed from flexible dipyridyl piperazine and rigid dicarboxylate: interpenetration, self-penetration, and polycatenation5Plumbing the uncertainties of solvothermal synthesis involving uranyl ion carboxylate complexes9

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  1. Homo- and heterometallic coordination polymers from the f elements

    CrystEngComm · 2006-12-04

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  2. Structural diversity and properties of M(ii) 4-carboxyl phenoxyacetate complexes with 0D-, 1D-, 2D- and 3D M-cpoa framework

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  4. Uranyl Ion Complexation by Citric and Citramalic Acids in the Presence of Diamines

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  5. Different aliphatic dicarboxylates affected assemble of new coordination polymers constructed from flexible–rigid mixed ligands

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  6. One- and Two-Dimensional Silver and Zinc Uranyl Phosphates Containing Bipyridyl Ligands

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  7. Structural Diversity and Potential Applications of Metal–Organic Coordination Polymers

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  8. Novel two-dimensional uranyl–organic assemblages in the citrate and d (–)-citramalate families

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  9. Affinity of the Highly Preorganized Ligand PDA (1,10-Phenanthroline-2,9-dicarboxylic acid) for Large Metal Ions of Higher Charge. A Crystallographic and Thermodynamic Study of PDA Complexes of Thorium(IV) and the Uranyl(VI) ion

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  17. Two novel uranyl–organic frameworks with cyclohexane-1,3-dicarboxylate ligands

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  20. A novel uranyl complex UO2(tci)(C3H5N2) · H2O: Synthesis, crystal structure and characterization

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  27. Homometallic Uranium(VI) Phosphonoacetates Containing Interlayer Dipyridines

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