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RESEARCH PAPER · Accounts of Chemical Research · 2011

Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds

Kai‐Xue Wang, Jie‐Sheng Chen

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Extended Structures and Physicochemical Properties of Uranyl–Organic CompoundsOriginalIn situ oxalate formation during hydrothermal synthesis of uranyl hybrid materials50Crystal Engineering with the Uranyl Cation III. Mixed Aliphatic Dicarboxylate/Aromatic Dipyridyl Coordination Polymers: Synthesis, Structures, and Speciation74Syntheses, Structures, Photoluminescence, and Gas Adsorption of Rare Earth–Organic Frameworks Based on a Flexible Tricarboxylate44Coordination Polymers and Frameworks in Uranyl Ion Complexes with Sulfonates and Cucurbit[6]uril32Advanced Nanoarchitectures for Solar Photocatalytic Applications2373Uranyl–Pyromellitate Coordination Polymers: Toward Three-Dimensional Open Frameworks with Large Channel Systems83Utilizing hydrogen bonds and halogen–halogen interactions in the design of uranyl hybrid materials66Charge Transfer Vibronic Transitions in Uranyl Tetrachloride Compounds43Uranyl and/or Rare-Earth Mellitates in Extended Organic–Inorganic Networks: A Unique Case of Heterometallic Cation–Cation Interaction with UVI═O–LnIII Bonding (Ln = Ce, Nd)117A novel 3D (3,5)-connected metal–organic framework based on a flexible hexacarboxylate6The actinides1Uranyl and mixed uranyl–lanthanide complexes with p-sulfonatocalix[4]arene29Uranyl–lanthanide heterometallic assemblies with 1,2-ethanedisulfonate and cucurbit[6]uril ligands413-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials76Single-site photocatalysts with a porous structure20Giant regular polyhedra from calixarene carboxylates and uranyl208Uranyl Hybrid Material Derived from In Situ Ligand Synthesis: Formation, Structure, and an Unusual Phase Transformation36Uranyl Hybrid Material Derived from In Situ Ligand Synthesis: Formation, Structure, and an Unusual Phase Transformation7Syntheses, structures and luminescent properties of two one-dimensional uranium oxyfluorides12Syntheses, structures and photoluminescent properties of three new coordination polymers based on semirigid zwitterionic ligand9Metal-dependent assemblies of an unusual pentanuclear cadmium cluster and a fascinating 3D 4-connected lead-containing framework7Nanomaterials and nanotechnologies in nuclear energy chemistry46Tailor-Made Zinc Uranyl Diphosphonates from Layered to Framework Structures46Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures418Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers82Synthesis, structure and photocatalytic property of a novel 3D (3,8)-connected metal–organic framework based on a flexible triphosphonate and a pentanuclear Cu(II) unit21Series of Mixed Uranyl–Lanthanide (Ce, Nd) Organic Coordination Polymers with Aromatic Polycarboxylates Linkers92From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange82Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products372New Reactivity of the Uranyl(VI) Ion116Four Novel Oxomolybdenum-Organodiphosphonate Hybrids in the Presence of Cu(II)–Organonitrogen Building Blocks: Synthesis, Crystal Structures, and Surface Photovoltage Properties27Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate71Structural Observations of Heterometallic Uranyl Copper(II) Carboxylates and Their Solid‐State Topotactic Transformation upon Dehydration63An exploration of homo- and heterometallic UO 2 2+ hybrid materials containing chelidamic acid: synthesis, structure, and luminescence studies32Chiral uranyl-organic compounds assembled with achiral furandicarboxylic acid by spontaneous resolution45Fabrication of a PANI/CPs composite material: a feasible method to enhance the photocatalytic activity of coordination polymers19Fabrication of Ag/CPs composite material, an effective strategy to improve the photocatalytic performance of coordination polymers under visible irradiation14Lanthanide coordination polymers with hexa-carboxylate ligands derived from cyclotriphosphazene as bridging linkers: synthesis, thermal and luminescent properties33One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids29Two new uranyl fluoride complexes with UVIO–alkali (Na, Cs) interactions: Experimental and theoretical studies9Uranyl–3d block metal ion heterometallic carboxylate complexes including additional chelating nitrogen donors37Uranyl–copper(ii) heterometallic oxalate complexes: coordination polymers and frameworks47Three‐Dimensional MOF‐Type Architectures with Tetravalent Uranium Hexanuclear Motifs (U6O8)127Synthesis, Structures, and Luminescent Properties of Uranyl Terpyridine Aromatic Carboxylate Coordination Polymers85Synthesis, Structural Characterization, and Dehydration Analysis of Uranyl Zinc Mellitate, (UO2)Zn(H2O)4(H2mel)·2H2O31Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies75Two Systems of [DabcoH2]2+/[PipH2]2+–Uranyl–Oxalate Showing Reversible Crystal-to-Crystal Transformations Controlled by the Diammonium/Uranyl/Oxalate Ratios in Aqueous Solutions ([DabcoH2]2+ = 1,4-Diazabicyclo-[2.2.2]-octaneH2 and [PipH2]2+ = PiperazineH2)23Syntheses, structures and luminescent properties of two organic templated uranyl phosphonates18Hybrid Uranyl Arsonate Coordination Nanocages18Syntheses and Structures of Uranyl Ethylenediphosphonates: From Layers to Elliptical Nanochannels33The first uranyl complexes with valerate ions20Complexation of Uranyl and Rare-Earth Ions by a Fluorinated Tetracarboxylate. Formation of a Layered Assembly and Three-Dimensional Frameworks34A Uranyl Hybrid Compound Designed from Urea‐Bearing Dipropionic Acid16Mixed Formate-Dicarboxylate Coordination Polymers with Tetravalent Uranium: Occurrence of Tetranuclear {U4O4} and Hexanuclear {U6O4(OH)4} Motifs66PANI/CPs composite material, a new type of coordination polymer based composite material: Fabrication and photocatalytic property study172,2′‐Bipyridine and 1,10‐Phenanthroline as Coligands or Structure‐Directing Agents in Uranyl–Organic Assemblies with Polycarboxylic Acids56Photocatalytic activity of PANI loaded coordination polymer composite materials: Photoresponse region extension and quantum yields enhancement via the loading of PANI nanofibers on surface of coordination polymer21Series of Uranyl-4,4′-biphenyldicarboxylates and an Occurrence of a Cation–Cation Interaction: Hydrothermal Synthesis and in Situ Raman Studies36The crystal chemistry of uranium carboxylates394Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties29Synthesis, Structures, and Properties of Uranyl Hybrids Constructed by a Variety of Mono- and Polycarboxylic Acids70Isolation of thorium benzoate polytypes with discrete ThO8 square antiprismatic units involved in chain-like assemblies16Molecular and Polymeric Uranyl and Thorium Complexes with Sulfonate‐Containing Ligands33The exploration of supramolecular interactions stemming from the [UO 2 (NCS) 4 (H 2 O)] 2− tecton and substituted pyridinium cations37Synthesis, crystal structure, photoluminescence property and photoelectronic behavior of two uranyl-organic frameworks constructed from 1, 2, 4, 5-benzenetetracarboxylic acid as ligand34Chiral one- to three-dimensional uranyl–organic assemblies from (1R,3S)-(+)-camphoric acid47High valence 3p and transition metal based MOFs605Isolation of a series of uranium organophosphinates11MOFs of Uranium and the Actinides95Photocatalytic activity of transition-metal-ion-doped coordination polymer (CP): photoresponse region extension and quantum yields enhancement via doping of transition metal ions into the framework of CPs44The first case of an actinide polyrotaxane incorporating cucurbituril: a unique ‘dragon-like’ twist induced by a specific coordination pattern of uranium51Two novel oxovanadium–organophosphonate hybrids with a 3D supramolecular structure: synthesis, crystal structures, surface photovoltage and luminescent properties8Solvothermal synthesis, crystal structure and photoluminescent property of a novel 3D [Ca2(HCOO)2(nds)(H2O)2] n8Uranyl–Organic Frameworks with Polycarboxylates: Unusual Effects of a Coordinating Solvent77Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules60Structural Variation within Heterometallic Uranyl Hybrids Based on Flexible Alkyldiphosphonate Ligands40A Highly Adjustable Coordination System: Nanotubular and Molecular Cage Species in Uranyl Ion Complexes with Kemp’s Triacid46Postsynthetic Rearrangement/Metalation as a Route to Bimetallic Uranyl Coordination Polymers: Syntheses, Structures, and Luminescence70Synthesis and characterization of 1-D uranyl thiodigycolate coordination polymers10Room temperature crystallization of trichlorodioxouranate [UO2Cl3(L)] species in molecular assemblies involving aliphatic dicarboxylate linkers18Increasing Complexity in the Uranyl Ion–Kemp’s Triacid System: From One- and Two-Dimensional Polymers to Uranyl–Copper(II) Dodeca- and Hexadecanuclear Species47A Family of UO22+–5-Nitro-1,3-dicarboxylate Hybrid Materials: Structural Variation As a Function of pH and Structure Directing Species20A new organically templated open-framework uranyl ethylenediphosphonate6The influence of pressure on the structure of a 2D uranium(VI) carboxyphosphonoate compound11Syntheses, structures and fluorescent properties of cadmium coordination polymers based on 2,3′,5,5′-biphenyl tetracarboxylate and N-donor ancillary ligands19Photocatalytic Application of 4f–5f Inorganic–Organic Frameworks: Influence of Lanthanide Contraction on the Structure and Functional Properties of a Series of Uranyl–Lanthanide Complexes34CuPYDC Metalloligands and Postsynthetic Rearrangement/Metalation as Routes to Bimetallic Uranyl Containing Hybrid Materials: Syntheses, Structures, and Fluorescence37Uranyl Ion Complexes with all-cis-1,3,5-Cyclohexanetricarboxylate: Unexpected Framework and Nanotubular Assemblies55Copper(I) and Copper(II) Uranyl Heterometallic Hybrid Materials49Four new dinuclear uranyl complexes based on p- and m-toluic acid: Syntheses, structures, luminescent and photocatalytic properties21[(C 2 H 5 ) 4 N][U 2 O 4 (HCOO) 5 ], an Ammonium Uranyl Formate Framework Showing Para- to Ferro-Electric Transition: Synthesis, Structures, and Properties17Trace analysis of uranyl ion (UO22+) in aqueous solution by fluorescence turn-on detection via aggregation induced emission enhancement effect70Two new two-dimensional layered uranyl-bearing polycarboxylates from semi-rigid tetracarboxylic acids15Uranyl Ion Complexes with trans‐3‐(3‐Pyridyl)acrylic Acid Including a Uranyl–Copper(II) Heterometallic Framework21Exploring Actinide Materials Through Synchrotron Radiation Techniques104The First Family of Actinide Carboxyphosphinates: Two‐ and Three‐Dimensional Uranyl Coordination Polymers27Novel uranyl( vi ) complexes incorporating propylene-bridged salen-type N 2 O 2 -ligands: a structural and computational approach50Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers46UO 2 2+ -amino hybrid materials: structural variation and photocatalysis properties29Coordination polymers of uranium( iv ) terephthalates42Design, synthesis and structure of uranyl coordination polymers from 2-D layer to 3-D network structure2Incorporating Guest Molecules into Honeycomb Structures Constructed from Uranium(VI)-Polycarboxylates: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye91Complexation of uranyl ions by N-(sulfoethyl)-iminodiacetic acid: Hydrothermal synthesis, luminescence, and uranyl sequestration1Combining coordination and supramolecular chemistry to explore uranyl assembly in the solid state51A family of 3D UO 2 2+ –5-X-1,3-dicarboxylate (X = –H, –NO 2 , –NH 2 , –OH) hybrid materials: structural relevance with variation of substituent groups and photochemical properties29Design and synthesis of a chiral uranium-based microporous metal organic framework with high SHG efficiency and sequestration potential for low-valent actinides58Facile synthesis of a Ag( i )-doped coordination polymer with enhanced catalytic performance in the photodegradation of azo dyes in water127Graphene oxide coated coordination polymer nanobelt composite material: a new type of visible light active and highly efficient photocatalyst for Cr( vi ) reduction14Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5New approaches to the degradation of organic dyes, and nitro- and chloroaromatics using coordination polymers as photocatalysts83Solvent effects in solvo-hydrothermal synthesis of uranyl ion complexes with 1,3-adamantanediacetate33Supramolecular inclusion-based molecular integral rigidity: a feasible strategy for controlling the structural connectivity of uranyl polyrotaxane networks46Synthetic, structural, and luminescence study of uranyl coordination polymers containing chelating terpyridine and trispyridyltriazine ligands34The first case of actinide triple helices: pH-dependent structural evolution and kinetically-controlled transformation of two supramolecular conformational isomers40Two novel uranyl complexes of a semi-rigid aromatic tetracarboxylic acid supported by an organic base as an auxiliary ligand or a templating agent: an experimental and theoretical exploration16Loading of a Coordination Polymer Nanobelt on a Functional Carbon Fiber: A Feasible Strategy for Visible‐Light‐Active and Highly Efficient Coordination‐Polymer‐Based Photocatalysts25A New 3D Pb(II) Inorganic–Organic Hybrid Framework Based on Terephthalate Acid with the Inorganic Pb–O–Pb Connectivity1Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System143Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties68Comparison of uranium(VI) and thorium(IV) coordination polymers with p-toluenesulfonic acid16Heterometallic zinc uranium oxyfluorides incorporating imidazole ligands3Structural variations in terbium(III) complexes with 1,3-adamantanedicarboxylate and diverse co-ligands10Uranyl-Promoted Peroxide Generation: Synthesis and Characterization of Three Uranyl Peroxo [(UO 2 ) 2 (O 2 )] Complexes42Umbellate Distortions of the Uranyl Coordination Environment Result in a Stable and Porous Polycatenated Framework That Can Effectively Remove Cesium from Aqueous Solutions449Solvothermal Synthesis of Tetravalent Uranium with Isophthalate or Pyromellitate Ligands13Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers53Structural chemistry of uranium phosphonates143Two-dimensional assemblies in f-element ion (UO22+, Yb3+) complexes with two cyclohexyl-based polycarboxylates21Uranyl Ion Complexes with 1,1′-Biphenyl-2,2′,6,6′-tetracarboxylic Acid: Structural and Spectroscopic Studies of One- to Three-Dimensional Assemblies36Two Uranyl Complexes with Pyromellitic Acid. A Heterometallic Complex with U=O–CuII Interaction7Unexpected cis-dioxido uranyl carboxylate compound: Synthesis, characterization and photocatalytic activity of uranyl-succinate complexes17Structural Variations in the Uranyl/4,4′-Biphenyldicarboxylate System. Rare Examples of 2D → 3D Polycatenated Uranyl–Organic Networks78Synthesis, Structure, and Photoluminescence Properties of an Organically‐Templated Uranyl Selenite3Uranyl Carboxyphosphonates Derived from Hydrothermal in Situ Ligand Reaction: Syntheses, Structures, and Computational Investigations25An Efficient p–n Heterojunction Photocatalyst Constructed from a Coordination Polymer Nanoplate and a Partically Reduced Graphene Oxide for Visible‐Light Hydrogen Production27Multifunctional Uranyl Hybrid Materials: Structural Diversities as a Function of pH, Luminescence with Potential Nitrobenzene Sensing, and Photoelectric Behavior as p-type Semiconductors56Self-assembly of [UO2X4]2− (X=Cl, Br) dianions with γ substituted pyridinium cations: Structural systematics and fluorescence properties45Chemical‐Bond‐Mediated p–n Heterojunction Photocatalyst Constructed from Coordination Polymer Nanoparticles and a Conducting Copolymer: Visible‐Light Active and Highly Efficient13Silver Ion-Mediated Heterometallic Three-Fold Interpenetrating Uranyl–Organic Framework52A Family of Uranyl Coordination Polymers Containing O-Donor Dicarboxylates and Trispyridyltriazine Guests36The templated synthesis of a unique type of tetra-nuclear uranyl-mediated two-fold interpenetrating uranyl–organic framework36Probing the Influence of N‐Donor Capping Ligands on Supramolecular Assembly in Molecular Uranyl Materials45Layered and three-dimensional uranyl–organic assemblies with 4,4′-oxidiphthalic acid4A family of uranium–carboxylic acid hybrid materials: synthesis, structure and mixed-dye selective adsorption17A series of pyridyl-amide-based Zn II /Cd II coordination polymers and their polypyrrole-functionalized composite materials for tuning their photocatalytic properties13An investigation of the interactions of Eu 3+ and Am 3+ with uranyl minerals: implications for the storage of spent nuclear fuel21Anchoring flexible uranyl dicarboxylate chains through stacking interactions of ancillary ligands on chiral U( vi ) centres37Counter-ion control of structure in uranyl ion complexes with 2,5-thiophenedicarboxylate39First three-dimensional actinide polyrotaxane framework mediated by windmill-like six-connected oligomeric uranyl: dual roles of the pseudorotaxane precursor19

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  2. Crystal Engineering with the Uranyl Cation III. Mixed Aliphatic Dicarboxylate/Aromatic Dipyridyl Coordination Polymers: Synthesis, Structures, and Speciation

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  5. Advanced Nanoarchitectures for Solar Photocatalytic Applications

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  7. Utilizing hydrogen bonds and halogen–halogen interactions in the design of uranyl hybrid materials

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  8. Charge Transfer Vibronic Transitions in Uranyl Tetrachloride Compounds

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  9. Uranyl and/or Rare-Earth Mellitates in Extended Organic–Inorganic Networks: A Unique Case of Heterometallic Cation–Cation Interaction with UVI═O–LnIII Bonding (Ln = Ce, Nd)

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  11. The actinides

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  14. 3-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials

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  16. Giant regular polyhedra from calixarene carboxylates and uranyl

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  19. Syntheses, structures and luminescent properties of two one-dimensional uranium oxyfluorides

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  22. Nanomaterials and nanotechnologies in nuclear energy chemistry

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  36. Fabrication of a PANI/CPs composite material: a feasible method to enhance the photocatalytic activity of coordination polymers

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  37. Fabrication of Ag/CPs composite material, an effective strategy to improve the photocatalytic performance of coordination polymers under visible irradiation

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  38. Lanthanide coordination polymers with hexa-carboxylate ligands derived from cyclotriphosphazene as bridging linkers: synthesis, thermal and luminescent properties

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  39. One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids

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  40. Two new uranyl fluoride complexes with UVIO–alkali (Na, Cs) interactions: Experimental and theoretical studies

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  41. Uranyl–3d block metal ion heterometallic carboxylate complexes including additional chelating nitrogen donors

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  42. Uranyl–copper(ii) heterometallic oxalate complexes: coordination polymers and frameworks

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  43. Three‐Dimensional MOF‐Type Architectures with Tetravalent Uranium Hexanuclear Motifs (U6O8)

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  44. Synthesis, Structures, and Luminescent Properties of Uranyl Terpyridine Aromatic Carboxylate Coordination Polymers

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  45. Synthesis, Structural Characterization, and Dehydration Analysis of Uranyl Zinc Mellitate, (UO2)Zn(H2O)4(H2mel)·2H2O

    European Journal of Inorganic Chemistry · 2013-02-08

    Jacob Olchowka, Christophe Volkringer, Natacha Henry, Thierry Loiseau

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  46. Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies

    Inorganic Chemistry · 2013-02-21

    Weiting Yang, Tao Tian, Hongyue Wu, Qing‐Jiang Pan, Song Dang, Zhong‐Ming Sun

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  47. Two Systems of [DabcoH2]2+/[PipH2]2+–Uranyl–Oxalate Showing Reversible Crystal-to-Crystal Transformations Controlled by the Diammonium/Uranyl/Oxalate Ratios in Aqueous Solutions ([DabcoH2]2+ = 1,4-Diazabicyclo-[2.2.2]-octaneH2 and [PipH2]2+ = PiperazineH2)

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    Lühua Wang, Ran Shang, Zhong Zheng, Chunli Liu, Zhe‐Ming Wang

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  48. Syntheses, structures and luminescent properties of two organic templated uranyl phosphonates

    Inorganic Chemistry Communications · 2013-05-10

    Hongyue Wu, Yuqin Ma, Xiuwu Zhang, Hongwei Zhang, Xiuyun Yang, Yunhui Li, Hao Wang, Shuang Yao, Weiting Yang

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  49. Hybrid Uranyl Arsonate Coordination Nanocages

    Inorganic Chemistry · 2013-05-16

    Pius O. Adelani, Ginger E. Sigmon, Peter Carman Burns

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  50. Syntheses and Structures of Uranyl Ethylenediphosphonates: From Layers to Elliptical Nanochannels

    Inorganic Chemistry · 2013-05-23

    Tao Tian, Weiting Yang, Hao Wang, Song Dang, Qing‐Jiang Pan, Zhong‐Ming Sun

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