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RESEARCH PAPER · Crystal Growth & Design · 2011

Uranyl Ion Complexation by Aliphatic Dicarboxylic Acids in the Presence of Cucurbiturils as Additional Ligands or Structure-Directing Agents

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Uranyl Ion Complexation by Aliphatic Dicarboxylic Acids in the Presence of Cucurbiturils as Additional Ligands or Structure-Directing AgentsOriginalUranyl–Alkali Metal Ion Heterometallic Complexes with Cucurbit[6]uril and a Sulfonated Catechol67Novel Supramolecular Assemblies Based on Coordination of Samarium Cation to Cucurbit[5]uril45Crystal Engineering with the Uranyl Cation III. Mixed Aliphatic Dicarboxylate/Aromatic Dipyridyl Coordination Polymers: Synthesis, Structures, and Speciation74Uranyl–organic one- and two-dimensional assemblies with 2,2′-bipyridine-3,3′-dicarboxylic, biphenyl-3,3′,4,4′-tetracarboxylic and bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acids50Coordination and Supramolecular Self-Assemblies of Alkali and Alkaline Earth Metal Ions to Cucurbit[5]uril in the Presence of Nitrophenol34Coordination Polymers and Frameworks in Uranyl Ion Complexes with Sulfonates and Cucurbit[6]uril32Uranyl–Pyromellitate Coordination Polymers: Toward Three-Dimensional Open Frameworks with Large Channel Systems83Uranyl Ion Complexes with Ammoniobenzoates as Assemblers for Cucurbit[6]uril Molecules56Uranyl and/or Rare-Earth Mellitates in Extended Organic–Inorganic Networks: A Unique Case of Heterometallic Cation–Cation Interaction with UVI═O–LnIII Bonding (Ln = Ce, Nd)117“Liquid-like” type (COO−)2(H2O)10 anion water clusters in three-dimensional supramolecular structure of cucurbit[6]uril13Hydroquinone-assisted assembly of coordination polymers from lanthanides and cucurbit[5]uril44p-Hydroxybenzoic acid-assisted homochiral 1D-helical coordination polymers from calcium cations and cucurbit[5]uril36p-Hydroxybenzoic acid-induced formation of a novel framework based on direct coordination of caesium ions to cucurbit[8]uril30Uranyl–lanthanide heterometallic assemblies with 1,2-ethanedisulfonate and cucurbit[6]uril ligands41Syntheses, structures and luminescent properties of two one-dimensional uranium oxyfluorides12Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers82Series of Mixed Uranyl–Lanthanide (Ce, Nd) Organic Coordination Polymers with Aromatic Polycarboxylates Linkers92Macrocycle-based metal ion complexation: a study of the lanthanide contraction effect towards hexacyclohexanocucurbit[6]uil20Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate71Structural Observations of Heterometallic Uranyl Copper(II) Carboxylates and Their Solid‐State Topotactic Transformation upon Dehydration63An approach to networks based on coordination of alkyl-substituted cucurbit[5]urils and potassium ions34Cucurbit[n]uril-based coordination chemistry: from simple coordination complexes to novel poly-dimensional coordination polymers409Inorganic anion-aided coordination of lanthanide metal ions to cucurbituril and supramolecular self-assembly: potential applications in the separation of light lanthanides67Tetrachloride transition-metal dianion-induced coordination and supramolecular self-assembly of strontium dications to cucurbit[8]uril28The synthesis of networks based on the coordination of cucurbit[8]urils and alkali or alkaline earth ions in the presence of the polychloride transition-metal anions24Cucurbituril: A promising organic building block for the design of coordination compounds and beyond218Supramolecular assemblies based on the interaction of a copper dication with alky-substituted cucurbit[6]urils7One-Dimensional Coordination Polymers of Lanthanide Cations to Cucurbit[7]uril Built Using a Range of Tetrachloride Transition-Metal Dianion Structure Inducers33Copper glutarate coordination polymers with dipyridylamide ligands: Effect of donor disposition and steric bulk on structure12Coordination of Pentacyclohexanocucurbit[5]uril with Alkali Metal Ions and Supramolecular Self‐Assembly in the Absence and Presence of Inorganic Anions19Mixed Formate-Dicarboxylate Coordination Polymers with Tetravalent Uranium: Occurrence of Tetranuclear {U4O4} and Hexanuclear {U6O4(OH)4} Motifs66Series of Uranyl-4,4′-biphenyldicarboxylates and an Occurrence of a Cation–Cation Interaction: Hydrothermal Synthesis and in Situ Raman Studies36The crystal chemistry of uranium carboxylates394Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties29Crystalline Hybrid Solid Materials of Palladium and Decamethylcucurbit[5]uril as Recoverable Precatalysts for Heck Cross‐Coupling Reactions19The exploration of supramolecular interactions stemming from the [UO 2 (NCS) 4 (H 2 O)] 2− tecton and substituted pyridinium cations37Supramolecular Interactions in PuO2Cl42– and PuCl62– Complexes with Protonated Pyridines: Synthesis, Crystal Structures, and Raman Spectroscopy33Synthesis, crystal structure, photoluminescence property and photoelectronic behavior of two uranyl-organic frameworks constructed from 1, 2, 4, 5-benzenetetracarboxylic acid as ligand34MOFs of Uranium and the Actinides95The first case of an actinide polyrotaxane incorporating cucurbituril: a unique ‘dragon-like’ twist induced by a specific coordination pattern of uranium51Uranyl–Organic Frameworks with Polycarboxylates: Unusual Effects of a Coordinating Solvent77Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules60Postsynthetic Rearrangement/Metalation as a Route to Bimetallic Uranyl Coordination Polymers: Syntheses, Structures, and Luminescence70Room temperature crystallization of trichlorodioxouranate [UO2Cl3(L)] species in molecular assemblies involving aliphatic dicarboxylate linkers18Cucurbituril‐Based Supramolecular Self‐Assemblies Formed in the Presence of Alkali Metal and Cadmium Ions22Increasing Complexity in the Uranyl Ion–Kemp’s Triacid System: From One- and Two-Dimensional Polymers to Uranyl–Copper(II) Dodeca- and Hexadecanuclear Species47A Family of UO22+–5-Nitro-1,3-dicarboxylate Hybrid Materials: Structural Variation As a Function of pH and Structure Directing Species20Photocatalytic Application of 4f–5f Inorganic–Organic Frameworks: Influence of Lanthanide Contraction on the Structure and Functional Properties of a Series of Uranyl–Lanthanide Complexes34Copper(I) and Copper(II) Uranyl Heterometallic Hybrid Materials49Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers46Design, synthesis and structure of uranyl coordination polymers from 2-D layer to 3-D network structure2A family of 3D UO 2 2+ –5-X-1,3-dicarboxylate (X = –H, –NO 2 , –NH 2 , –OH) hybrid materials: structural relevance with variation of substituent groups and photochemical properties29A family of uranyl-aromatic dicarboxylate (pht-, ipa-, tpa-) framework hybrid materials: photoluminescence, surface photovoltage and dye adsorption31Complexation of Eu( iii ) with Cucurbit[n]uril, n = 5 and 7: A Thermodynamic and Structural Study10Coordination Polymers of Cucurbit[n]urils with Metal Ions0Homochiral 3D coordination polymer with unprecedented three-directional helical topology from achiral precursor: synthesis, crystal structure, and luminescence properties of uranyl succinate metal–organic framework24Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Solvent effects in solvo-hydrothermal synthesis of uranyl ion complexes with 1,3-adamantanediacetate33The first case of actinide triple helices: pH-dependent structural evolution and kinetically-controlled transformation of two supramolecular conformational isomers40Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System143Macrocycle-based metal-organic frameworks152Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties68Second‐Sphere Complexation of Thorium(IV) by Cucurbit[6]uril with Included Perrhenate Counterions – Crystal Structure and Hirshfeld Surface Analysis11Interaction of Ln3+ with Methyl‐Substituted Cucurbit[n]urils (n=5,6) Derived from 3α‐Methyl Glycoluril13Structural variations in terbium(III) complexes with 1,3-adamantanedicarboxylate and diverse co-ligands10Solvothermal Synthesis of Tetravalent Uranium with Isophthalate or Pyromellitate Ligands13Tetranuclear Uranyl Polyrotaxanes: Preferred Selectivity toward Uranyl Tetramer for Stabilizing a Flexible Polyrotaxane Chain Exhibiting Weakened Supramolecular Inclusion28Two-dimensional assemblies in f-element ion (UO22+, Yb3+) complexes with two cyclohexyl-based polycarboxylates21Structural Variations in the Uranyl/4,4′-Biphenyldicarboxylate System. Rare Examples of 2D → 3D Polycatenated Uranyl–Organic Networks78Multifunctional Uranyl Hybrid Materials: Structural Diversities as a Function of pH, Luminescence with Potential Nitrobenzene Sensing, and Photoelectric Behavior as p-type Semiconductors56A New Form of Triple-Stranded Helicate Found in Uranyl Complexes of Aliphatic α,ω-Dicarboxylates34The templated synthesis of a unique type of tetra-nuclear uranyl-mediated two-fold interpenetrating uranyl–organic framework36A family of uranium–carboxylic acid hybrid materials: synthesis, structure and mixed-dye selective adsorption17Adducts of aqua complexes of Ln 3+ with hexahydroxyhexamethylcucurbit[6]uril: potential application in the isolation of heavy lanthanides7Anchoring flexible uranyl dicarboxylate chains through stacking interactions of ancillary ligands on chiral U( vi ) centres37First three-dimensional actinide polyrotaxane framework mediated by windmill-like six-connected oligomeric uranyl: dual roles of the pseudorotaxane precursor19From Helicates to Borromean Links: Chain Length Effect in Uranyl Ion Complexes of Aliphatic α,ω-Dicarboxylates21Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers34Uranyl Ion Complexes with Long-Chain Aliphatic α,ω-Dicarboxylates and 3d-Block Metal Counterions34Counterion-Induced Variations in the Dimensionality and Topology of Uranyl Pimelate Complexes41A 1,3‐Capped Calix[4] Conjugate Possessing an Amine Moiety as an Anion Receptor: Reversible Anion Sensing Detected by Spectroscopy and Characterization of the Supramolecular Features by Microscopy15Coordination of lanthanide cations to a symmetrical dicyclohexanocucurbit[6]uril in the presence of tetrachlorozincate facilitates isolation of lighter lanthanides6Modulation of the Structure and Properties of Uranyl Ion Coordination Polymers Derived from 1,3,5-Benzenetriacetate by Incorporation of Ag(I) or Pb(II)46Exploring Crystal Engineering for Porous Uranyl–Organic Frameworks: Insight into Hydrolysis and In Situ Reaction, Structural Variation‐Dependent Physical Properties6An Unprecedented Two‐Fold Nested Super‐Polyrotaxane: Sulfate‐Directed Hierarchical Polythreading Assembly of Uranyl Polyrotaxane Moieties17Coordination of cucurbit [6]uril and its alkyl-substituted derivatives with the lanthanum cation and the supramolecular assemblies formed with the aid of inorganic anions7Complexation of Uranyl Ion with Sulfonates: One‐ to Three‐Dimensional Assemblies with 1,5‐ and 2,7‐Naphthalenedisulfonates15Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species93The crystalline α,ω-dicarboxylate metal complex with the longest aliphatic chain to date: uranyl 1,15-pentadecanedioate10Two uranyl heterocyclic carboxyl compounds with fluorescent properties as high sensitivity and selectivity optical detectors for nitroaromatics13Potassium and magnesium succinatouranilates – Synthesis and crystal structure12AgI and PbII as Additional Assembling Cations in Uranyl Coordination Polymers and Frameworks44Mixed-Ligand Uranyl Polyrotaxanes Incorporating a Sulfate/Oxalate Coligand: Achieving Structural Diversity via pH-Dependent Competitive Effect29Uranyl Complexes as Scaffolding or Spacers for Cucurbit[6]uril Molecules in Homo‐ and Heterometallic Species, Including a Uranyl–Lanthanide Complex13Use of Zwitterionic Ligands in Uranyl Hybrid Materials: Explorations on the Structural Features that Control Water Ordering and Mobility6Interpenetrated Uranyl–Organic Frameworks with bor and pts Topology: Structure, Spectroscopy, and Computation40Mg, Ca and Ba glutaratouranylates – Synthesis and structure9Supramolecular and Macrocyclic Chemistry of the Actinides2Complexation of U(VI) with Cucurbit[5]uril: Thermodynamic and Structural investigation in aqueous medium8Structure-Directing Effects of Counterions in Uranyl Ion Complexes with Long-Chain Aliphatic α,ω-Dicarboxylates: 1D to Polycatenated 3D Species31CB[n]-Based Coordination Chemistry0Outer surface interactions to drive cucurbit[8]uril-based supramolecular frameworks: possible application in gold recovery49Irradiation and isolation of fission products from uranium metal–organic frameworks13A Uranyl Metal Organic Framework Arising from the Coordination of a Partially Hydrolyzed Tetrauranyl Node with the Tautomerically Diverse 1,4-(Diamidoximyl)benzene Ligand11A series of uranium-organic frameworks: Crucial role of the protonation ability of auxiliary ligands15Coordination Chemistry of Cucurbiturils0Noncomplexed Cucurbituril-Mediated Structural Evolution of Layered Uranyl Terephthalate Compounds13CB[n]-Based Coordination Chemistry0Thorium(IV) and Uranium(IV) Complexes with Cucurbit[8]Uril: Supramolecular Structures Via Direct Coordination and Second-Shell Interactions4Cucurbit[ n ]uril‐Based Supramolecular Frameworks Assembled through Outer‐Surface Interactions43Cucurbit[ n ]uril‐Based Supramolecular Frameworks Assembled through Outer‐Surface Interactions157Expanding uranyl dicyanoaurate coordination polymers into the second and third dimensions4Multifunctional Inorganic‐Organic U‐MOF Materials with Nitrogen Heterocyclic Carboxylate: Synthesis, Structure and Properties11Metal-Mediated Protein–Cucurbituril Crystalline Architectures16Assemblies of cucurbit[6]uril-based coordination complexes with disulfonate ligands: from discrete complexes to one- and two-dimensional polymers10Cucurbit[n]uril/metal ion complex-based frameworks and their potential applications43Temperature‐Triggered Structural Dynamics of Non‐Coordinating Guest Moieties in a Fluorescent Actinide Polyrotaxane Framework10Plumbing the uncertainties of solvothermal synthesis involving uranyl ion carboxylate complexes94-(Ammoniomethyl)benzoate, a protic zwitterionic bifunctional linker in uranyl ion carboxylate complexes5Bifunctional ligands in uranyl chemistry: Metalloligands and zwitterions26Construction of Cucurbit[6]uril-Based Coordination Polymers Incorporating Multiaromatic Ligands with Amide Linkages and Their Iodine Adsorption Properties3The highest nuclearity 5f-metal/oxime cluster: Synthesis, structure and properties of a tetranuclear uranyl compound1Reactions of U(DMSO) 8 (ClO 4 ) 4 with Terpyridine Yield Dimeric Hydrolysis Products and Induce C–C Coupling0

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  1. Uranyl–Alkali Metal Ion Heterometallic Complexes with Cucurbit[6]uril and a Sulfonated Catechol

    Crystal Growth & Design · 2011-06-09

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  2. Novel Supramolecular Assemblies Based on Coordination of Samarium Cation to Cucurbit[5]uril

    Inorganic Chemistry · 2011-07-15

    Kai Chen, Li‐Li Liang, Yun‐Qian Zhang, Qian‐Jiang Zhu, Sai‐Feng Xue, Zhu Tao

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  3. Crystal Engineering with the Uranyl Cation III. Mixed Aliphatic Dicarboxylate/Aromatic Dipyridyl Coordination Polymers: Synthesis, Structures, and Speciation

    Crystal Growth & Design · 2011-10-06

    Andrew T. Kerr, Christopher L. Cahill

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  4. Uranyl–organic one- and two-dimensional assemblies with 2,2′-bipyridine-3,3′-dicarboxylic, biphenyl-3,3′,4,4′-tetracarboxylic and bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acids

    CrystEngComm · 2011-10-10

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  5. Coordination and Supramolecular Self-Assemblies of Alkali and Alkaline Earth Metal Ions to Cucurbit[5]uril in the Presence of Nitrophenol

    Crystal Growth & Design · 2011-10-25

    Kai Chen, Xing Feng, Li‐Li Liang, Yun‐Qian Zhang, Qian‐Jiang Zhu, Sai‐Feng Xue, Zhu Tao

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  6. Coordination Polymers and Frameworks in Uranyl Ion Complexes with Sulfonates and Cucurbit[6]uril

    Crystal Growth & Design · 2011-10-26

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  7. Uranyl–Pyromellitate Coordination Polymers: Toward Three-Dimensional Open Frameworks with Large Channel Systems

    Crystal Growth & Design · 2011-12-07

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  8. Uranyl Ion Complexes with Ammoniobenzoates as Assemblers for Cucurbit[6]uril Molecules

    Crystal Growth & Design · 2011-12-16

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  9. Uranyl and/or Rare-Earth Mellitates in Extended Organic–Inorganic Networks: A Unique Case of Heterometallic Cation–Cation Interaction with UVI═O–LnIII Bonding (Ln = Ce, Nd)

    Journal of the American Chemical Society · 2011-12-29

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  10. “Liquid-like” type (COO−)2(H2O)10 anion water clusters in three-dimensional supramolecular structure of cucurbit[6]uril

    CrystEngComm · 2012-01-01

    Xuzhuo Sun, Bo Li, Chunlan Xia, Xiaohai Zhou, Haibo Zhang

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  11. Hydroquinone-assisted assembly of coordination polymers from lanthanides and cucurbit[5]uril

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  12. p-Hydroxybenzoic acid-assisted homochiral 1D-helical coordination polymers from calcium cations and cucurbit[5]uril

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  13. p-Hydroxybenzoic acid-induced formation of a novel framework based on direct coordination of caesium ions to cucurbit[8]uril

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  14. Uranyl–lanthanide heterometallic assemblies with 1,2-ethanedisulfonate and cucurbit[6]uril ligands

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  15. Syntheses, structures and luminescent properties of two one-dimensional uranium oxyfluorides

    Inorganic Chemistry Communications · 2012-06-12

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  16. Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers

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    Ionut Mihalcea, Natacha Henry, Till Bousquet, Christophe Volkringer, Thierry Loiseau

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  17. Series of Mixed Uranyl–Lanthanide (Ce, Nd) Organic Coordination Polymers with Aromatic Polycarboxylates Linkers

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  18. Macrocycle-based metal ion complexation: a study of the lanthanide contraction effect towards hexacyclohexanocucurbit[6]uil

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  19. Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate

    Inorganic Chemistry · 2012-12-07

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  20. Structural Observations of Heterometallic Uranyl Copper(II) Carboxylates and Their Solid‐State Topotactic Transformation upon Dehydration

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  21. An approach to networks based on coordination of alkyl-substituted cucurbit[5]urils and potassium ions

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  22. Cucurbit[n]uril-based coordination chemistry: from simple coordination complexes to novel poly-dimensional coordination polymers

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  23. Inorganic anion-aided coordination of lanthanide metal ions to cucurbituril and supramolecular self-assembly: potential applications in the separation of light lanthanides

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  24. Tetrachloride transition-metal dianion-induced coordination and supramolecular self-assembly of strontium dications to cucurbit[8]uril

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  25. The synthesis of networks based on the coordination of cucurbit[8]urils and alkali or alkaline earth ions in the presence of the polychloride transition-metal anions

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  26. Cucurbituril: A promising organic building block for the design of coordination compounds and beyond

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  27. Supramolecular assemblies based on the interaction of a copper dication with alky-substituted cucurbit[6]urils

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  28. One-Dimensional Coordination Polymers of Lanthanide Cations to Cucurbit[7]uril Built Using a Range of Tetrachloride Transition-Metal Dianion Structure Inducers

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  29. Copper glutarate coordination polymers with dipyridylamide ligands: Effect of donor disposition and steric bulk on structure

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  30. Coordination of Pentacyclohexanocucurbit[5]uril with Alkali Metal Ions and Supramolecular Self‐Assembly in the Absence and Presence of Inorganic Anions

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  31. Mixed Formate-Dicarboxylate Coordination Polymers with Tetravalent Uranium: Occurrence of Tetranuclear {U4O4} and Hexanuclear {U6O4(OH)4} Motifs

    Crystal Growth & Design · 2013-06-19

    Clément Falaise, Christophe Volkringer, Thierry Loiseau

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  32. Series of Uranyl-4,4′-biphenyldicarboxylates and an Occurrence of a Cation–Cation Interaction: Hydrothermal Synthesis and in Situ Raman Studies

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    Paula M. Cantos, Laurent J. Jouffret, Richard E. Wilson, Peter Carman Burns, Christopher L. Cahill

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  33. The crystal chemistry of uranium carboxylates

    Coordination Chemistry Reviews · 2013-09-08

    Thierry Loiseau, Ionut Mihalcea, Natacha Henry, Christophe Volkringer

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  34. Uranyl Coordination Polymers Incorporating η5-Cyclopentadienyliron-Functionalized η6-Phthalate Metalloligands: Syntheses, Structures and Photophysical Properties

    Journal of Inorganic and Organometallic Polymers and Materials · 2013-10-05

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  35. Crystalline Hybrid Solid Materials of Palladium and Decamethylcucurbit[5]uril as Recoverable Precatalysts for Heck Cross‐Coupling Reactions

    Chemistry - A European Journal · 2013-10-07

    Hongfang Li, Jian Lü, Jingxiang Lin, Yuan‐Biao Huang, Minna Cao, Rong Cao

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  36. The exploration of supramolecular interactions stemming from the [UO 2 (NCS) 4 (H 2 O)] 2− tecton and substituted pyridinium cations

    CrystEngComm · 2013-12-06

    Robert G. Surbella, Christopher L. Cahill

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  37. Supramolecular Interactions in PuO2Cl42– and PuCl62– Complexes with Protonated Pyridines: Synthesis, Crystal Structures, and Raman Spectroscopy

    Inorganic Chemistry · 2013-12-13

    Richard E. Wilson, David D. Schnaars, Michael B. Andrews, Christopher L. Cahill

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  38. Synthesis, crystal structure, photoluminescence property and photoelectronic behavior of two uranyl-organic frameworks constructed from 1, 2, 4, 5-benzenetetracarboxylic acid as ligand

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2013-12-19

    Yanan Hou, Yong‐Heng Xing, Feng‐Ying Bai, Qing‐Lin Guan, Xuan Wang, Rui Zhang, Zhan Shi

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  39. MOFs of Uranium and the Actinides

    Structure and bonding · 2014-01-01

    Juan Su, Jiesheng Chen

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  40. The first case of an actinide polyrotaxane incorporating cucurbituril: a unique ‘dragon-like’ twist induced by a specific coordination pattern of uranium

    Chemical Communications · 2014-01-01

    Lei Mei, Qun‐Yan Wu, Cai‐Ming Liu, Yu-Liang Zhao, Zhifang Chai, Wei‐Qun Shi

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  41. Uranyl–Organic Frameworks with Polycarboxylates: Unusual Effects of a Coordinating Solvent

    Crystal Growth & Design · 2014-02-04

    P. Thuéry, Jack McB. Harrowfield

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  42. Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules

    European Journal of Inorganic Chemistry · 2014-02-06

    Ionut Mihalcea, Natacha Henry, Thierry Loiseau

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