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RESEARCH PAPER · Crystal Growth & Design · 2008

Uranyl Ion Complexes with Cucurbit[n]urils (n = 6, 7, and 8): A New Family of Uranyl-Organic Frameworks

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Uranyl Ion Complexes with Cucurbit[n]urils (n = 6, 7, and 8): A New Family of Uranyl-Organic FrameworksOriginalUranyl Ion Complexes with Cucurbit[5]uril: from Molecular Capsules to Uranyl-Organic Frameworks103Uranyl ion complexes of cucurbit[7]uril with zero-, one- and two-dimensionality62Uranyl-Lanthanide Heterometallic Complexes with Cucurbit[6]uril and Perrhenate Ligands94Lanthanide Complexes with Cucurbit[n]urils (n = 5, 6, 7) and Perrhenate Ligands: New Examples of Encapsulation of Perrhenate Anions83Homometallic Uranium(VI) Phosphonoacetates Containing Interlayer Dipyridines69Uranyl Ion Complexation by Cucurbiturils in the Presence of Perrhenic, Phosphoric, or Polycarboxylic Acids. Novel Mixed-Ligand Uranyl−Organic Frameworks79Synthesis and luminescent properties of the first series of lanthanide complexes based on sebacate and 2,5-pyridinedicarboxylate11Lanthanide(III) Coordination Polymers with Longer-Spanning Flexible Ligand: Synthesis, Crystal Structure and Luminescence Property8Trifluoromethanesulfonate Anion-linked Supramolecular Frameworks of Cucurbit[5]uril and Cucurbit[7]uril17Second-Sphere Tethering of Rare-Earth Ions to Cucurbit[6]uril by Iminodiacetic Acid Involving Carboxylic Group Encapsulation47Bis(nitrate)diaquauranyl( vi ) synthon to generate [1 × 2 + 1 × 1] and [1 × 1 + 1 × 1] co-crystalized 3d⋯5f self-assemblies41Direct coordination of metal ions to cucurbit[n]urils39Approach to 10-Unit “Bracelet” Frameworks Based on Coordination of Alkyl-Substituted Cucurbit[5]urils and Potassium Ions46Hydroquinone-induced framework based on direct coordination of rubidium ions to cucurbit[7]uril32Effects of Cocrystalline Subunits on the Supramolecular Chemistry of Me10Q[5]: From Simple Inorganic Anions to Cluster Anions26Revisiting the Uranyl-phthalate System: Isolation and Crystal Structures of Two Types of Uranyl−Organic Frameworks (UOF)78Uranyl Ion Complexation by Aliphatic Dicarboxylic Acids in the Presence of Cucurbiturils as Additional Ligands or Structure-Directing Agents124Uranyl–Alkali Metal Ion Heterometallic Complexes with Cucurbit[6]uril and a Sulfonated Catechol67Difference of Coordination between Alkali- and Alkaline-Earth-Metal Ions to a Symmetrical α,α′,δ,δ′-Tetramethylcucurbit[6]uril52Novel Supramolecular Assemblies Based on Coordination of Samarium Cation to Cucurbit[5]uril45Three-Dimensional Hybrid Framework Containing U2O13 Dimers Connected via Cation–Cation Interactions48Cucurbit[n]urils (n= 5–8): A Comprehensive Solid State Study191Coordination Polymers and Frameworks in Uranyl Ion Complexes with Sulfonates and Cucurbit[6]uril32Photochromic hybrid materials of cucurbituril and polyoxometalates as photocatalysts under visible light220Fluorescent Uranyl Ion Lidded Cucurbit[5]uril Capsule31Cucurbituril chemistry: a tale of supramolecular success934Uranyl Ion Complexes with Ammoniobenzoates as Assemblers for Cucurbit[6]uril Molecules56New types of hybrid solids of tetravanadate polyanions and cucurbituril24p-Hydroxybenzoic acid-induced formation of a novel framework based on direct coordination of caesium ions to cucurbit[8]uril30Uranyl–lanthanide heterometallic assemblies with 1,2-ethanedisulfonate and cucurbit[6]uril ligands41Can Functionalized Cucurbituril Bind Actinyl Cations Efficiently? A Density Functional Theory Based Investigation55Three‐Component Cucurbit[6]uril Framework with 1:2 Host‐Guest Motif and Dimeric Boric Acid3Nitrogen-rich Compounds of the Actinoids: Dioxouranium(VI) 5,5′-Azobis[tetrazolide] Pentahydrate and Its Unusually Small Uranyl Angle13Influence of the Organic Species and Oxoanion in the Synthesis of two Uranyl Sulfate Hydrates, (H3O)2[(UO2)2(SO4)3(H2O)]·7H2O and (H3O)2[(UO2)2(SO4)3(H2O)]·4H2O, and a Uranyl Selenate‐Selenite [C5H6N][(UO2)(SeO4)(HSeO3)]15Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures418Interaction of tetravalent actinides and Np(V) with some hydroxy carboxylic acids0Macrocycle-based metal ion complexation: a study of the lanthanide contraction effect towards hexacyclohexanocucurbit[6]uil20Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products372Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate71An approach to networks based on coordination of alkyl-substituted cucurbit[5]urils and potassium ions34Coordination nanotubes self-assembled from cucurbit[7]uril and lanthanide cations49Cucurbit[n]uril-based coordination chemistry: from simple coordination complexes to novel poly-dimensional coordination polymers409Inorganic anion-aided coordination of lanthanide metal ions to cucurbituril and supramolecular self-assembly: potential applications in the separation of light lanthanides67Tetrachloride transition-metal dianion-induced coordination and supramolecular self-assembly of strontium dications to cucurbit[8]uril28The synthesis of networks based on the coordination of cucurbit[8]urils and alkali or alkaline earth ions in the presence of the polychloride transition-metal anions24Cucurbituril: A promising organic building block for the design of coordination compounds and beyond218Synthesis, Structures, and Luminescent Properties of Uranyl Terpyridine Aromatic Carboxylate Coordination Polymers85Supramolecular assemblies based on the interaction of a copper dication with alky-substituted cucurbit[6]urils7A Dihalide–Decahydrate Cluster of [X2(H2O)10]2– in a Supramolecular Architecture of {[Na2(H2O)6(H2O@TMEQ[6])]·2(C6H5NO3)}X2(H2O)10 (TMEQ[6] = α,α′,δ,δ′-Tetramethylcucurbit[6]uril; X = Cl, Br)20One-Dimensional Coordination Polymers of Lanthanide Cations to Cucurbit[7]uril Built Using a Range of Tetrachloride Transition-Metal Dianion Structure Inducers33Coordination of Pentacyclohexanocucurbit[5]uril with Alkali Metal Ions and Supramolecular Self‐Assembly in the Absence and Presence of Inorganic Anions19A Uranyl Hybrid Compound Designed from Urea‐Bearing Dipropionic Acid16Designing Novel Nanomaterials through Functionalization of Carbon Nanotubes with Supramolecules for Application in Nuclear Waste Management15The crystal chemistry of uranium carboxylates394[CdCl 4 ] 2− anion-induced coordination of alkaline earth metal ions to cucurbit[7]uril, corresponding supramolecular self-assemblies and potential application32New lanthanide–CB[6] coordination compounds: relationships between the crystal structure and luminescent properties29The first case of an actinide polyrotaxane incorporating cucurbituril: a unique ‘dragon-like’ twist induced by a specific coordination pattern of uranium51Synthesis and characterization of 1-D uranyl thiodigycolate coordination polymers10Cucurbituril‐Based Supramolecular Self‐Assemblies Formed in the Presence of Alkali Metal and Cadmium Ions22Synthesis, crystal structure and spectroscopic studies of some organic/inorganic hybrid materials containing isostructural monomeric uranyl complexes bridged by bipyridyl typed ligands16Poly[(μ4-decanedioato)cobalt(II)]1Increasing Complexity in the Uranyl Ion–Kemp’s Triacid System: From One- and Two-Dimensional Polymers to Uranyl–Copper(II) Dodeca- and Hexadecanuclear Species47Uranyl Ion Complexes with all-cis-1,3,5-Cyclohexanetricarboxylate: Unexpected Framework and Nanotubular Assemblies55Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers46Design, synthesis and structure of uranyl coordination polymers from 2-D layer to 3-D network structure2A family of uranyl-aromatic dicarboxylate (pht-, ipa-, tpa-) framework hybrid materials: photoluminescence, surface photovoltage and dye adsorption31Coordination Polymers of Cucurbit[n]urils with Metal Ions0Copper coordination polymers from cavitand ligands: hierarchical spaces from cage and capsule motifs, and other topologies33Cucurbit[8]uril-mediated supramolecular photoswitching for self-preservation of mesoporous silica nanoparticle delivery system25High binding yet accelerated guest rotation within a cucurbit[7]uril complex. Toward paramagnetic gyroscopes and rolling nanomachines21Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Simple Coordination Complexes of Cucurbit[n]urils with Metal Ions0Synthesis and structure of R 2[UO2(NO3)2(NCS)2] (R = Rb or Cs)0Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties68Second‐Sphere Complexation of Thorium(IV) by Cucurbit[6]uril with Included Perrhenate Counterions – Crystal Structure and Hirshfeld Surface Analysis11Structural variations in terbium(III) complexes with 1,3-adamantanedicarboxylate and diverse co-ligands10Polynuclear Hydroxido-Bridged Complexes of Platinum(IV) with Terminal Nitrato Ligands32Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers53Tetranuclear Uranyl Polyrotaxanes: Preferred Selectivity toward Uranyl Tetramer for Stabilizing a Flexible Polyrotaxane Chain Exhibiting Weakened Supramolecular Inclusion28Facile fabrication of magnetic cucurbit[6]uril/graphene oxide composite and application for uranium removal116Anchoring flexible uranyl dicarboxylate chains through stacking interactions of ancillary ligands on chiral U( vi ) centres37Amidoximes as ligand functionalities for braided polymeric materials for the recovery of uranium from seawater40Uranyl Ion Complexes with Long-Chain Aliphatic α,ω-Dicarboxylates and 3d-Block Metal Counterions34Counterion-Induced Variations in the Dimensionality and Topology of Uranyl Pimelate Complexes41Coordination of lanthanide cations to a symmetrical dicyclohexanocucurbit[6]uril in the presence of tetrachlorozincate facilitates isolation of lighter lanthanides6First Cationic Uranyl–Organic Framework with Anion-Exchange Capabilities101Complexation of Uranyl Ion with Sulfonates: One‐ to Three‐Dimensional Assemblies with 1,5‐ and 2,7‐Naphthalenedisulfonates15Inorganic Synthesis of Actinides3Mixed-Ligand Uranyl Polyrotaxanes Incorporating a Sulfate/Oxalate Coligand: Achieving Structural Diversity via pH-Dependent Competitive Effect29Uranyl Complexes as Scaffolding or Spacers for Cucurbit[6]uril Molecules in Homo‐ and Heterometallic Species, Including a Uranyl–Lanthanide Complex13Exploring New Assembly Modes of Uranyl Terephthalate: Templated Syntheses and Structural Regulation of a Series of Rare 2D → 3D Polycatenated Frameworks39Inclusion and exclusion complexes of cucurbit[7]uril with silver cations11Influence of Pyrazine/Piperazine Based Guest Molecules in the Crystal Structures of Uranyl Thiophene Dicarboxylate Coordination Polymers: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye47Preparation and characterization of a novel single crystal of Th(IV) with cucurbit[6]uril7Use of Zwitterionic Ligands in Uranyl Hybrid Materials: Explorations on the Structural Features that Control Water Ordering and Mobility6Supramolecular and Macrocyclic Chemistry of the Actinides2Thorium(IV) and Uranium(IV) Complexes with Cucurbit[5]uril11CB[n]-Based Coordination Chemistry0Outer surface interactions to drive cucurbit[8]uril-based supramolecular frameworks: possible application in gold recovery49Uranyl Compounds Involving a Weakly Bonded Pseudorotaxane Linker: Combined Effect of pH and Competing Ligands on Uranyl Coordination and Speciation33Coordination Chemistry of Cucurbiturils0Thorium( iv ) and uranium( vi ) compounds of cucurbit[10]uril: from a one-dimensional nanotube to a supramolecular framework9Noncomplexed Cucurbituril-Mediated Structural Evolution of Layered Uranyl Terephthalate Compounds13CB[n]-Based Coordination Chemistry0Supramolecular assemblies controlled by cucurbit[ n ]uril size ( n = 6, 7, 8 and 10)7Thorium(IV) and Uranium(IV) Complexes with Cucurbit[8]Uril: Supramolecular Structures Via Direct Coordination and Second-Shell Interactions4Cucurbit[n]uril-calix[n]arene-based supramolecular frameworks assembled using the outer surface interactions of cucurbit[n]urils24Cucurbit[ n ]uril‐Based Supramolecular Frameworks Assembled through Outer‐Surface Interactions43Cucurbit[ n ]uril‐Based Supramolecular Frameworks Assembled through Outer‐Surface Interactions157Assemblies of cucurbit[6]uril-based coordination complexes with disulfonate ligands: from discrete complexes to one- and two-dimensional polymers10Uranyl Nitrates: By-Products of the Synthetic Experiments or Key Indicators of the Reaction Progress?5Cucurbit[n]uril/metal ion complex-based frameworks and their potential applications43Temperature‐Triggered Structural Dynamics of Non‐Coordinating Guest Moieties in a Fluorescent Actinide Polyrotaxane Framework10Crystal Chemistry and Structural Complexity of the Uranyl Carbonate Minerals and Synthetic Compounds27State-of-the-art progress for the selective crystallization of actinides, synthesis of actinide compounds and their functionalization20Impact of the proximity effect on uranyl coordination of conformationally variable weakly-bonded cucurbit[6]uril-bipyridinium pseudorotaxane2Facile fabrication of macroporous carbon materials with Cucurbit[6]uril as precursor/template and its application for uranium removal72D coordination polymers based on the interaction between cucurbit[5]uril and light lanthanide metal ions in the presence of copper salts, and use for the detection of nitrogenous bases5Uranyl-Tc( vii )/Tc( v ) hybrid clusters5Bifunctional ligands in uranyl chemistry: Metalloligands and zwitterions26What goes on in sub-critical solvothermal synthesis of metal ion complexes?2Molecular Stiffening by Macrocycle Clustering4Molecular Stiffening by Macrocycle Clustering0Tetravalent thorium and uranium complexes with cucurbit[6]uril: Direct coordination and second-shell interactions0Uranyl Recognition through Cucurbit[7]uril-Bipyridinium Carboxylate Pseudorotaxanes as Supramolecular Chelators0Synthesis and Characterization of Three-Dimensional Uranyl Coordination Polymers Containing Selenophene and Tellurophene Linkers0

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  1. Uranyl Ion Complexes with Cucurbit[5]uril: from Molecular Capsules to Uranyl-Organic Frameworks

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  2. Uranyl ion complexes of cucurbit[7]uril with zero-, one- and two-dimensionality

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  3. Uranyl-Lanthanide Heterometallic Complexes with Cucurbit[6]uril and Perrhenate Ligands

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  4. Lanthanide Complexes with Cucurbit[n]urils (n = 5, 6, 7) and Perrhenate Ligands: New Examples of Encapsulation of Perrhenate Anions

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  5. Homometallic Uranium(VI) Phosphonoacetates Containing Interlayer Dipyridines

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  6. Uranyl Ion Complexation by Cucurbiturils in the Presence of Perrhenic, Phosphoric, or Polycarboxylic Acids. Novel Mixed-Ligand Uranyl−Organic Frameworks

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  7. Synthesis and luminescent properties of the first series of lanthanide complexes based on sebacate and 2,5-pyridinedicarboxylate

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  8. Lanthanide(III) Coordination Polymers with Longer-Spanning Flexible Ligand: Synthesis, Crystal Structure and Luminescence Property

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  9. Trifluoromethanesulfonate Anion-linked Supramolecular Frameworks of Cucurbit[5]uril and Cucurbit[7]uril

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  10. Second-Sphere Tethering of Rare-Earth Ions to Cucurbit[6]uril by Iminodiacetic Acid Involving Carboxylic Group Encapsulation

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  11. Bis(nitrate)diaquauranyl( vi ) synthon to generate [1 × 2 + 1 × 1] and [1 × 1 + 1 × 1] co-crystalized 3d⋯5f self-assemblies

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  12. Direct coordination of metal ions to cucurbit[n]urils

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  13. Approach to 10-Unit “Bracelet” Frameworks Based on Coordination of Alkyl-Substituted Cucurbit[5]urils and Potassium Ions

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  14. Hydroquinone-induced framework based on direct coordination of rubidium ions to cucurbit[7]uril

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  16. Revisiting the Uranyl-phthalate System: Isolation and Crystal Structures of Two Types of Uranyl−Organic Frameworks (UOF)

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  17. Uranyl Ion Complexation by Aliphatic Dicarboxylic Acids in the Presence of Cucurbiturils as Additional Ligands or Structure-Directing Agents

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  18. Uranyl–Alkali Metal Ion Heterometallic Complexes with Cucurbit[6]uril and a Sulfonated Catechol

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  19. Difference of Coordination between Alkali- and Alkaline-Earth-Metal Ions to a Symmetrical α,α′,δ,δ′-Tetramethylcucurbit[6]uril

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  20. Novel Supramolecular Assemblies Based on Coordination of Samarium Cation to Cucurbit[5]uril

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  23. Coordination Polymers and Frameworks in Uranyl Ion Complexes with Sulfonates and Cucurbit[6]uril

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  24. Photochromic hybrid materials of cucurbituril and polyoxometalates as photocatalysts under visible light

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  25. Fluorescent Uranyl Ion Lidded Cucurbit[5]uril Capsule

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  26. Cucurbituril chemistry: a tale of supramolecular success

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  27. Uranyl Ion Complexes with Ammoniobenzoates as Assemblers for Cucurbit[6]uril Molecules

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  28. New types of hybrid solids of tetravanadate polyanions and cucurbituril

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  29. p-Hydroxybenzoic acid-induced formation of a novel framework based on direct coordination of caesium ions to cucurbit[8]uril

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  30. Uranyl–lanthanide heterometallic assemblies with 1,2-ethanedisulfonate and cucurbit[6]uril ligands

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  31. Can Functionalized Cucurbituril Bind Actinyl Cations Efficiently? A Density Functional Theory Based Investigation

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  32. Three‐Component Cucurbit[6]uril Framework with 1:2 Host‐Guest Motif and Dimeric Boric Acid

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  33. Nitrogen-rich Compounds of the Actinoids: Dioxouranium(VI) 5,5′-Azobis[tetrazolide] Pentahydrate and Its Unusually Small Uranyl Angle

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  34. Influence of the Organic Species and Oxoanion in the Synthesis of two Uranyl Sulfate Hydrates, (H3O)2[(UO2)2(SO4)3(H2O)]·7H2O and (H3O)2[(UO2)2(SO4)3(H2O)]·4H2O, and a Uranyl Selenate‐Selenite [C5H6N][(UO2)(SeO4)(HSeO3)]

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  35. Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures

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  36. Interaction of tetravalent actinides and Np(V) with some hydroxy carboxylic acids

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  37. Macrocycle-based metal ion complexation: a study of the lanthanide contraction effect towards hexacyclohexanocucurbit[6]uil

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  38. Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products

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  39. Sulfonate Complexes of Actinide Ions: Structural Diversity in Uranyl Complexes with 2-Sulfobenzoate

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  40. An approach to networks based on coordination of alkyl-substituted cucurbit[5]urils and potassium ions

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  41. Coordination nanotubes self-assembled from cucurbit[7]uril and lanthanide cations

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  42. Cucurbit[n]uril-based coordination chemistry: from simple coordination complexes to novel poly-dimensional coordination polymers

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  43. Inorganic anion-aided coordination of lanthanide metal ions to cucurbituril and supramolecular self-assembly: potential applications in the separation of light lanthanides

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  44. Tetrachloride transition-metal dianion-induced coordination and supramolecular self-assembly of strontium dications to cucurbit[8]uril

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  45. The synthesis of networks based on the coordination of cucurbit[8]urils and alkali or alkaline earth ions in the presence of the polychloride transition-metal anions

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