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RESEARCH PAPER · Crystal Growth & Design · 2008

Pyrazinetetracarboxylic Acid as an Assembler Ligand in Uranyl−Organic Frameworks

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Pyrazinetetracarboxylic Acid as an Assembler Ligand in Uranyl−Organic FrameworksOriginalChapter 6.2 Six-membered ring systems: Diazines and benzo derivatives13Hydrothermal synthesis of uranyl–organic frameworks with pyrazine-2,3-dicarboxylate linkers52Uranyl−Organic Frameworks with 1,2,3,4-Butanetetracarboxylate and 1,2,3,4-Cyclobutanetetracarboxylate Ligands70Uranyl Ion Complexes with Cucurbit[n]urils (n = 6, 7, and 8): A New Family of Uranyl-Organic Frameworks127Two novel uranyl–organic frameworks with cyclohexane-1,3-dicarboxylate ligands40Uranyl Ion Complexes with Cucurbit[5]uril: from Molecular Capsules to Uranyl-Organic Frameworks103Chapter 6.2: Six-Membered Ring Systems: Diazines and Benzo Derivatives21ds-Block metal ions catalyzed decarboxylation of pyrazine-2,3,5,6-tetracarboxylic acid and the complexes obtained from hydrothermal reactions and novel water clusters25Novel lanthanide coordination polymers based on bis-tridentate chelator pyrazine-2,3,5,6-tetracarboxylate with nano-channels and water clusters28Uranyl–organic bilayer assemblies with flexible aromatic di-, tri- and tetracarboxylic acids55Two uranyl–organic frameworks with pyridinecarboxylate ligands. A novel heterometallic uranyl–copper(II) complex with a cation–cation interaction57A Nanosized Uranyl Camphorate Cage and its Use as a Building Unit in a Metal−Organic Framework47Uranyl Ion Complexation by Cucurbiturils in the Presence of Perrhenic, Phosphoric, or Polycarboxylic Acids. Novel Mixed-Ligand Uranyl−Organic Frameworks79A versatile V-shaped tetracarboxylate building block for constructing mixed-ligand Co(ii) and Mn(ii) complexes incorporating various N-donor co-ligands644-Carboxylphthalhydrazidate-bridged layered Pb(ii) coordination polymers30Equatorial ligand substitution by hydroxide in uranyl Pacman complexes of a Schiff-base pyrrole macrocycle20Lanthanide–organic assemblies with pyrazinetetracarboxylic and benzophenone-3,3′,4,4′-tetracarboxylic acids18Uranyl–organic assemblies with the macrocyclic ligand 1,4,8,11-tetraazacyclotetradecane-1,4,8,11-tetraacetate (TETA)34The Visualized Polarity-Sensitive Magnetic Nanoparticles6Alkali Metal Ion Complexes with Pyrazinetetracarboxylate: Two- and Three-Dimensional Frameworks18Fe(III) and cobalt(II) coordination compounds of 5-bromo-6-methyl-2-morpholinepyrimidinium-4-amine pyridine-2,6-dicarboxylate32Uranyl−Organic Assemblies with Acetate-Bearing Phenyl- and Cyclohexyl-Based Ligands45Tetrameric entity resulting from two distinct dinuclear uranyl-centered motifs bridged through μ2-OH and pyridazine-3,6-dicarboxylate26One-dimensional uranium–organic coordination polymers: crystal and electronic structures of uranyl-diacetohydroxamate19Uranyl Ion Complexation by Aliphatic Dicarboxylic Acids in the Presence of Cucurbiturils as Additional Ligands or Structure-Directing Agents124Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds412Uranyl–Alkali Metal Ion Heterometallic Complexes with Cucurbit[6]uril and a Sulfonated Catechol67Uranyl–organic one- and two-dimensional assemblies with 2,2′-bipyridine-3,3′-dicarboxylic, biphenyl-3,3′,4,4′-tetracarboxylic and bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acids50Coordination Polymers and Frameworks in Uranyl Ion Complexes with Sulfonates and Cucurbit[6]uril32Nucleobase assemblies supported by uranyl cation coordination and other non-covalent interactions3Two novel 3D microporous heterometallic 3d–4f coordination frameworks with unique (7, 8)-connected topology: Synthesis, crystal structure and magnetic properties14Two Types of New Three-Dimensional d–f Heterometallic Coordination Polymers Based on 2-(Pyridin-3-yl)-1H-Imidazole-4,5-Dicarboxylate and Oxalate Ligands: Syntheses, Structures, Luminescence, and Magnetic Properties63Effect of lanthanide contraction on structures of lanthanide coordination polymers based on 5-aminoisophthalic acid and oxalate15Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures418Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers82An exploration of homo- and heterometallic UO 2 2+ hybrid materials containing chelidamic acid: synthesis, structure, and luminescence studies32One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids29Uranyl–3d block metal ion heterometallic carboxylate complexes including additional chelating nitrogen donors37New pyridine-2,3,5,6-tetracarboxylato (H4pdtc) complexes: Synthesis, crystal structures and magnetic properties of K2[Mn(H2O)(pdtc)]·3H2O 1, Na2[M3(H2O)6(pdtc)2]·6H2O (M=Mn 2, Co 3)5The crystal chemistry of uranium carboxylates394Molecular and Polymeric Uranyl and Thorium Complexes with Sulfonate‐Containing Ligands33Chiral one- to three-dimensional uranyl–organic assemblies from (1R,3S)-(+)-camphoric acid47MOFs of Uranium and the Actinides95Uranyl–Organic Frameworks with Polycarboxylates: Unusual Effects of a Coordinating Solvent77Novel 3D Alkali–Lanthanide Heterometal–Organic Frameworks with Pyrazine-2,3,5,6-tetracarboxylic Acid: Synthesis, Structure, and Magnetism28Synthesis, crystal structure and spectroscopic studies of some organic/inorganic hybrid materials containing isostructural monomeric uranyl complexes bridged by bipyridyl typed ligands16Photocatalytic Application of 4f–5f Inorganic–Organic Frameworks: Influence of Lanthanide Contraction on the Structure and Functional Properties of a Series of Uranyl–Lanthanide Complexes34Uranyl Ion Complexes with trans‐3‐(3‐Pyridyl)acrylic Acid Including a Uranyl–Copper(II) Heterometallic Framework21Hydrothermal syntheses and crystal structures of four novel lanthanide(III) complexes based on two mixed N,O-donor ligands9A family of uranyl-aromatic dicarboxylate (pht-, ipa-, tpa-) framework hybrid materials: photoluminescence, surface photovoltage and dye adsorption31Complex three-dimensional lanthanide metal–organic frameworks with variable coordination spheres based on pyrazine-2,3,5,6-tetracarboxylate5Structural Variations in the Uranyl/4,4′-Biphenyldicarboxylate System. Rare Examples of 2D → 3D Polycatenated Uranyl–Organic Networks78Multifunctional Uranyl Hybrid Materials: Structural Diversities as a Function of pH, Luminescence with Potential Nitrobenzene Sensing, and Photoelectric Behavior as p-type Semiconductors56Uranyl Ion Complexes with Long-Chain Aliphatic α,ω-Dicarboxylates and 3d-Block Metal Counterions34Entangled Uranyl Organic Frameworks with (10,3)-b Topology and Polythreading Network: Structure, Luminescence, and Computational Investigation43Exploring Crystal Engineering for Porous Uranyl–Organic Frameworks: Insight into Hydrolysis and In Situ Reaction, Structural Variation‐Dependent Physical Properties6Hydrothermal Crystallization of Uranyl Coordination Polymers Involving an Imidazolium Dicarboxylate Ligand: Effect of pH on the Nuclearity of Uranyl-Centered Subunits38Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species93Two uranyl heterocyclic carboxyl compounds with fluorescent properties as high sensitivity and selectivity optical detectors for nitroaromatics13Syntheses, structures, and photocatalytic properties of two new one-dimensional chain transition metal complexes with mixed N,O-donor ligands191-D calcium, 2-D zinc and 3-D manganese coordination polymers derived from pyrazine-2,3,5,6-tetracarboxylic acid9Interpenetrated Uranyl–Organic Frameworks with bor and pts Topology: Structure, Spectroscopy, and Computation40Redox Behavior of a Dinuclear Ruthenium(II) Complex Bearing an Uncommon Bridging Ligand: Insights from High-Pressure Electrochemistry14Porous Anionic Uranyl–Organic Networks for Highly Efficient Cs + Adsorption and Investigation of the Mechanism88Lanthanide(III) complex metal-organic frameworks with a phenanthroline-carboxylate derivate and 2,5-thiophenedicarboxylate coligand: hydrothermal synthesis, crystal structure, and high thermostability0Crown Ethers and Their Alkali Metal Ion Complexes as Assembler Groups in Uranyl–Organic Coordination Polymers with cis-1,3-, cis-1,2-, and trans-1,2-Cyclohexanedicarboxylates34Conformational 2-Fold Interpenetrated Uranyl Supramolecular Isomers Based on (6,3) Sheet Topology: Structure, Luminescence, and Ion Exchange37Chain-like uranyl-coordination polymer as a bright green light emitter for sensing and sunlight driven photocatalysis8Crystal structures of [(μ2-L1)dibromidodicopper(II)] dibromide and poly[[(μ2-L1)diiodidodicopper(I)]-di-μ-iodido-dicopper(I)], where L1 is 2,5,8,11,14,17-hexathia-[9.9](2,6,3,5)-pyrazinophane1Stabilization of Photocatalytically Active Uranyl Species in a Uranyl–Organic Framework for Heterogeneous Alkane Fluorination Driven by Visible Light43Controlling Cation‐Cation Interactions in Uranyl Coordination Dimers by Varying the Length of the Dicarboxylate Linker4Optimizing Photoluminescence Quantum Yields in Uranyl Dicarboxylate Complexes: Further Investigations of 2,5‐, 2,6‐ and 3,5‐Pyridinedicarboxylates and 2,3‐Pyrazinedicarboxylate13Highlighting Recent Crystalline Engineering Aspects of Luminescent Coordination Polymers Based on F-Elements and Ditopic Aliphatic Ligands5Anionic uranyl ion complexes with pyrazinetetracarboxylate: Influence of structure-directing cations1

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  1. Chapter 6.2 Six-membered ring systems: Diazines and benzo derivatives

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  3. Uranyl−Organic Frameworks with 1,2,3,4-Butanetetracarboxylate and 1,2,3,4-Cyclobutanetetracarboxylate Ligands

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  4. Uranyl Ion Complexes with Cucurbit[n]urils (n = 6, 7, and 8): A New Family of Uranyl-Organic Frameworks

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  5. Two novel uranyl–organic frameworks with cyclohexane-1,3-dicarboxylate ligands

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  6. Uranyl Ion Complexes with Cucurbit[5]uril: from Molecular Capsules to Uranyl-Organic Frameworks

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  7. Chapter 6.2: Six-Membered Ring Systems: Diazines and Benzo Derivatives

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  8. ds-Block metal ions catalyzed decarboxylation of pyrazine-2,3,5,6-tetracarboxylic acid and the complexes obtained from hydrothermal reactions and novel water clusters

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  12. A Nanosized Uranyl Camphorate Cage and its Use as a Building Unit in a Metal−Organic Framework

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  13. Uranyl Ion Complexation by Cucurbiturils in the Presence of Perrhenic, Phosphoric, or Polycarboxylic Acids. Novel Mixed-Ligand Uranyl−Organic Frameworks

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  14. A versatile V-shaped tetracarboxylate building block for constructing mixed-ligand Co(ii) and Mn(ii) complexes incorporating various N-donor co-ligands

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  15. 4-Carboxylphthalhydrazidate-bridged layered Pb(ii) coordination polymers

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  16. Equatorial ligand substitution by hydroxide in uranyl Pacman complexes of a Schiff-base pyrrole macrocycle

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  17. Lanthanide–organic assemblies with pyrazinetetracarboxylic and benzophenone-3,3′,4,4′-tetracarboxylic acids

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  18. Uranyl–organic assemblies with the macrocyclic ligand 1,4,8,11-tetraazacyclotetradecane-1,4,8,11-tetraacetate (TETA)

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  19. The Visualized Polarity-Sensitive Magnetic Nanoparticles

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  20. Alkali Metal Ion Complexes with Pyrazinetetracarboxylate: Two- and Three-Dimensional Frameworks

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  21. Fe(III) and cobalt(II) coordination compounds of 5-bromo-6-methyl-2-morpholinepyrimidinium-4-amine pyridine-2,6-dicarboxylate

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  22. Uranyl−Organic Assemblies with Acetate-Bearing Phenyl- and Cyclohexyl-Based Ligands

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  23. Tetrameric entity resulting from two distinct dinuclear uranyl-centered motifs bridged through μ2-OH and pyridazine-3,6-dicarboxylate

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  24. One-dimensional uranium–organic coordination polymers: crystal and electronic structures of uranyl-diacetohydroxamate

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  26. Extended Structures and Physicochemical Properties of Uranyl–Organic Compounds

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  28. Uranyl–organic one- and two-dimensional assemblies with 2,2′-bipyridine-3,3′-dicarboxylic, biphenyl-3,3′,4,4′-tetracarboxylic and bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acids

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  30. Nucleobase assemblies supported by uranyl cation coordination and other non-covalent interactions

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  35. Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers

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  37. One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids

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  38. Uranyl–3d block metal ion heterometallic carboxylate complexes including additional chelating nitrogen donors

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  39. New pyridine-2,3,5,6-tetracarboxylato (H4pdtc) complexes: Synthesis, crystal structures and magnetic properties of K2[Mn(H2O)(pdtc)]·3H2O 1, Na2[M3(H2O)6(pdtc)2]·6H2O (M=Mn 2, Co 3)

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  49. Hydrothermal syntheses and crystal structures of four novel lanthanide(III) complexes based on two mixed N,O-donor ligands

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