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RESEARCH PAPER · Chemical Reviews · 2013

Anion-Centered Tetrahedra in Inorganic Compounds

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Anion-Centered Tetrahedra in Inorganic CompoundsOriginalPossible cationic ordering in bismuth oxide phosphates2Possible cationic ordering in bismuth oxide phosphates0ChemInform Abstract: Anion‐Centered Tetrahedra in Inorganic Compounds0Special ∞1[OPb2] Chains and ∞1[O2Pb3] Ribbons Based on OPb4 Anion-Centered Tetrahedra in Pb2(O4Pb8)(BO3)3Br3 and Pb2(O8Pb12)(BO3)2Br614Synthesis and Modular Structural Architectures of Mineralogically Inspired Novel Complex Pb Oxyhalides25Cannonite [Bi2O(SO4)(OH)2] from Alfenza (Crodo, Italy): crystal structure and morphology10Crystal structure of a novel synthetic compound, Pb2O(OH)I, and structure refinement of ‘iodolaurionite’, Pb(OH)I: hydroxo- and oxocentred units in Pb minerals and synthetic compounds10Multidimensional Open-Frameworks: Combinations of One-Dimensional Channels and Two-Dimensional Layers in Novel Bi/M Oxo-Chlorides17Welche anorganischen Strukturen sind am komplexesten?11Which Inorganic Structures are the Most Complex?218Labile Degree of Disorder in Bismuth-Oxophosphate Compounds: Illustration through Three New Structural Types15Competitive coordination control of the AIE and micro states of supramolecular gel: an efficient approach for reversible dual-channel stimuli-response materials51Rationally designed anion-responsive-organogels: sensing F − via reversible color changes in gel–gel states with specific selectivity54Structural insights for the design of new borate–phosphates: synthesis, crystal structure and optical properties of Pb 4 O(BO 3 )(PO 4 ) and Bi 4 O 3 (BO 3 )(PO 4 )36Nicksobolevite, Cu7(SeO3)2O2Cl6, a new complex copper oxoselenite chloride from Tolbachik fumaroles, Kamchatka peninsula, Russia25Structural complexity of lead silicates: Crystal structure of Pb21[Si7O22]2[Si4O13] and its comparison to hyttsjoite43Chirality of structure and magnetism in the magnetoelectric compound Cu2OSeO329Revised Bi/M Layered Oxo-Sulfate (M = Co, Cu): A Structural and Magnetic Study19Double Metal Ions Competitively Control the Guest‐Sensing Process: A Facile Approach to Stimuli‐Responsive Supramolecular Gels92The structure hierarchy hypothesis44Favreauite, a new selenite mineral from the El Dragón mine, Bolivia26A new anion-deficient fluorite-related superstructure of Bi28V8O6210Rationally designed supramolecular organogel dual-channel sense F− under gel–gel states via ion-controlled AIE26Investigation of New Alkali Bismuth Oxosulfates and Oxophosphates with Original Topologies of Oxo-Centered Units8Unique thallium mineralization in the fumaroles of Tolbachik volcano, Kamchatka Peninsula, Russia. I. Markhininite, TlBi(SO4)223A novel supramolecular metallogel-based high-resolution anion sensor array234A facile strategy to adjust the density of planar triangle units in lead borate–nitrates16Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Oxocentered Cu( ii ) lead selenite honeycomb lattices hosting Cu( i )Cl 2 groups obtained by chemical vapor transport reactions25Multiarylpolycarboxylate-Mediated Hybrid Cobalt Phosphate Frameworks with Supramolecular Zeolitic Topology and Unusual I2O2 Connectivity17A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π‐Conjugated Planar Triangular Units287Charge distribution as a tool to investigate structural details. III. Extension to description in terms of anion-centred polyhedra30A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π‐Conjugated Planar Triangular Units59Growth, structure, and optical properties of a self-activated crystal: Na3Nd9O3(BO3)815Emulating exhalative chemistry: synthesis and structural characterization of ilinskite, Na[Cu5O2](SeO3)2Cl3, and its K-analogue34High-temperature order–disorder phase transition in nacaphite, Na2CaPO4F17Synthesis, crystal structure, high-temperature behavior and magnetic properties of CoBiO(AsO4), a Co analogue of paganoite9Growth, structure, and optical properties of a self-activated crystal: Na2Nd2O(BO3)211Hydrothermal Studies in the System Hg/Se/Te/O: The First TeIV/SeVI Oxocompounds Hg3SeTe2O10 and Hg3SeTe4O14, and the Mixed‐valent Hg5Se2O812Two Hexagonal Series of Lanthanoid(III) Oxide Fluoride Selenides: M 6 O 2 F 8 Se 3 ( M = La – Nd) and M 2 OF 2 Se ( M = Nd, Sm, Gd – Ho)9New bismuth borophosphate Bi4BPO10: Synthesis, crystal structure, optical and band structure analysis5Synthesis and crystal structure of Bi6(Bi0.5Cu0.5)V2O15+1The crystal structure and composition of pottsite, (Pb3xBi4-2x)(VO4)4·H2O (0.8 x < 1.0)1Synthesis, crystal structures and properties of lead phosphite compounds27Hydrothermal synthesis, structure, and property characterization of rare earth silicate compounds: NaBa3Ln3Si6O20 (Ln = Y, Nd, Sm, Eu, Gd)14Fluorite-related one-dimensional units in natural bismuth oxysulfates: the crystal structures of Bi14O16(SO4)5and Bi30O33(SO4)9(AsO4)22Yeomanite, Pb2O(OH)Cl, a new chain-structured Pb oxychloride from Merehead Quarry, Somerset, England6Interlayer Communication in Aurivillius Vanadate to Enable Defect Structures and Charge Ordering12Structural Evolution from 0D Units to 3D Frameworks in Pb Oxyhalides: Unexpected Strongly Corrugated Layers in Pb7O6Br219Sodalite-like rare-earth carbonates: a study of structural transformation and diluted magnetism11Crystallography with synchrotron light2Pb4(OH)4(BrO3)3(NO3): An Example of SHG Crystal in Metal Bromates Containing π-Conjugated Planar Triangle59Crystal Structure of Mixed-metal Phosphite,Pb2Ga(HPIIIO3)3(PVO3)0Efficient sensing of fluoride ions in water using a novel water soluble self-assembled supramolecular sensor based on pillar[5]arene20Rationally introduce multi-competitive binding interactions in supramolecular gels: a simple and efficient approach to develop multi-analyte sensor array314Pathways for synthesis of new selenium-containing oxo-compounds: Chemical vapor transport reactions, hydrothermal techniques and evaporation method19On the Use of Dynamical Diffraction Theory To Refine Crystal Structure from Electron Diffraction Data: Application to KLa5O5(VO4)2, a Material with Promising Luminescent Properties21Synthesis and thermal behavior of Fe3O2(BO4) oxoborate11Topological features in crystal structures: a quotient graph assisted analysis of underlying nets and their embeddings23Dimers of oxocentred [OCu4]6+ tetrahedra in two novel copper selenite chlorides, K[Cu3O](SeO3)2Cl and Na2[Cu7O2] (SeO3)4Cl4, and related minerals and inorganic compounds20The relationship between mineral composition, crystal structure and paragenetic sequence: the case of secondary Te mineralization at the Bird Nest drift, Otto Mountain, California, USA30Rich Non-centrosymmetry in a Na–U–Te Oxo-System Achieved under Extreme Conditions13A review of the structural architecture of tellurium oxycompounds170Synthesis, structure, and electronic structure calculation of a new centrosymmetric borate Pb2O[BO2(OH)] based on anion-centered OPb4 tetrahedra6Synthesis, Characterization, and Theoretical Studies of (Pb4O)Pb2B6O14: A New Lead(II) Borate with Isolated Oxygen-Centered Pb4O Tetrahedra and Large Second Harmonic Generation Response41ABiO2X (A = Cd, Ca, Sr, Ba, Pb; X = halogen) Sillen X1 Series: Polymorphism Versus Optical Properties49The crystal structure of gianellaite, [(NHg2)2](SO4)(H2O)x, a framework of (NHg4) tetrahedra with ordered (SO4) groups in the interstices6Lead Oxychloride Borates Obtained under Extreme Conditions15Structure description, interpretation and classification in mineralogical crystallography50Porous layered and open-framework mixed-valence copper tellurites9The magnetic and electronic properties of oxyselenides—influence of transition metal ions and lanthanides29Hydrothermal synthesis of a new lead(II) borate (Pb4O)Pb2B6O14-II5Frustrated Antiferromagnetic Spin Chains of Edge-Sharing Tetrahedra in Volcanic Minerals K3Cu3(Fe0.82Al0.18)O2(SO4)4 and K4Cu4O2(SO4)4MeCl10Synthesis, crystal structure, vibrational spectroscopy and expected magnetic properties of a new bismuth nickel phosphate Ni(BiO) 2 (PO 4 )(OH) with a namibite-type structure10Hg4O3[ReO4]2, Featuring a 2D Polycationic Framework [Hg4O3]2+ with Tetrahedral Rhenate(VII) Anions Embedded1Original oxo-centered bismuth oxo-arsenates; critical effect of PO 4 for AsO 4 substitution7Chemical vapor transport and solid-state exchange synthesis of new copper selenite bromides6A benzimidazole functionalized NDI derivative for recyclable fluorescent detection of cyanide in water18A novel supramolecular organogel based on acylhydrazone functionalized pillar[5]arene acts as an I − responsive smart material35A novel water soluble chemosensor based on carboxyl functionalized NDI derivatives for selective detection and facile removal of mercury( ii )20New lead( ii ) borates in the PbO/PbF 2 /H 3 BO 3 ternary phase diagram: syntheses and structures of β-Pb 6 B 10 O 21 and Pb 4 B 8 O 164Novel multi-analyte responsive ionic supramolecular gels based on pyridinium functionalized-naphthalimide32Novel supramolecular sensors constructed from pillar[5]arene and a naphthalimide for efficient detection of Fe 3+ and F − in water11Structure description, interpretation and classification in structural mineralogy5Synthesis and crystal structure of β-CuSe2O5, a new polymorph of copper diselenite8Copper oxosulphates from fumaroles of Tolbachik volcano: puninite, Na2 Cu3 O(SO4)3 –a new mineral species and structure refinements of kamchatkite and alumoklyuchevskite45[O2Pb3]2(BO3)Br: An Oxidoborate Oxide Bromide with the ∞1[O2Pb3] Double Chains Based on Edge‐sharing OPb4 Tetrahedra2Bismuth and vanadate activators in BiMVO5 (M=Ca, Mg, Cd) phases: Structural, electronic and optical specificities12Roymillerite, Pb24Mg9(Si9AlO28)(SiO4)(BO3)(CO3)10(OH)14O4, a new mineral: mineralogical characterization and crystal chemistry10The first layer potassium–bismuth-nickel oxophosphate KBi4Ni2(PO4)3O4: Synthesis, crystal structure, and expected magnetic properties5[Pb2F2](SeO4): a heavier analogue of grandreefite, the first layered fluoride selenate7One disorder out of two orders: Synthesis and crystal structures of cation-ordered PbNaF 2 NO 3 , anion-ordered Pb 2 OFNO 3 , and continuous disordered (Pb, Na) 2 (O,F) 2-δ NO 3 solid solution with Sillén-derived structures4A novel water soluble self-assembled supramolecular sensor based on pillar[5]arene for fluorescent detection CN− in water30Polar BaCl(ClO4)·H2O layered chloride perchlorate7Die Europium(II)-Oxidhalogenide Eu2OBr2 und Eu2OI24Bonding Scheme and Optical Properties in BiM2O2(PO4) (M=Cd, Mg, Zn); Experimental and Theoretical Analysis9High‐Pressure Synthesis and Single‐Crystal Structure Elucidation of the Indium Oxide‐Borate In4O2B2O74The Mixed-Metal Oxochromates(VI) Cd(HgI2)2(HgII)3O4(CrO4)2, Cd(HgII)4O4(CrO4) and Zn(HgII)4O4(CrO4)—Examples of the Different Crystal Chemistry within the Zinc Triad0Oxocentered Units in Three Novel Rb‐Containing Copper Compounds Prepared by CVT Reaction Method2Carboxyphenyl-terpyridine-based series of gels for procedural visual recognition of multi-anions6Grootfonteinite, Pb3O(CO3)2, a new mineral species from the Kombat Mine, Namibia, merotypically related to hydrocerussite6A water-soluble fluorescent chemosensor based on Asp functionalized naphthalimide for successive detection Fe3+ and H2PO4−12Magnetism of coupled spin tetrahedra in ilinskite-type KCu5O2(SeO3)2Cl324Undulated oxo-centered layers in PbLn3O4(VO4) (Ln= La and Nd) and relationship with Nd4O4(GeO4)1Spin-frustrated pyrochlore chains in the volcanic mineral kamchatkite (KCu3OCl(SO4)2)7Hydrocerussite-related minerals and materials: structural principles, chemical variations and infrared spectroscopy48Se–Cl Interactions in Selenite Chlorides: A Theoretical Study10Compressibility of BiCu2PO6: Polymorphism against S = 1/2 Magnetic Spin Ladders9Itelmenite, Na2CuMg2(SO4)4, a new anhydrous sulfate mineral from the Tolbachik volcano21Somersetite, Pb8O(OH)4(CO3)5, a new complex hydrocerussite-related mineral from the Mendip Hills, England3Bi3(PO4)O3, the Simplest Bismuth(III) Oxophosphate: Synthesis, IR Spectroscopy, Crystal Structure, and Structural Complexity8Structural, thermal, and IR studies of β-[Nd2O2](CrO4), an unexpected analog of a slag phase [Ba2F2](S6+O3S2−)6CdBiO2NO3, a new layered bismuth oxide nitrate3Fumarolic arsenates − a special type of arsenic mineralization99Antiferromagnetic spin-frustrated layers of corner-sharing Cu 4 tetrahedra on the kagome lattice in volcanic minerals Cu 5 O 2 (VO 4 ) 2 (CuCl), NaCu 5 O 2 (SeO 3 ) 2 Cl 3 , and K 2 Cu 5 Cl 8 (OH) 4 ·2H 2 O16Cryptochalcite, K2Cu5O(SO4)5, and cesiodymite, CsKCu5O(SO4)5, two new isotypic minerals and the K–Cs isomorphism in this solid-solution series21Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities89New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. X. Edtollite, K2NaCu5Fe3+O2(AsO4)4, and alumoedtollite, K2NaCu5AlO2(AsO4)416Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides7Twinning in chalcostibite revisited4The Birth of a New Crystallochemistry on a Volcano2A structure hierarchy for silicate minerals: sheet silicates55Reversible hydration/dehydration and thermal expansion of euchlorine, ideally KNaCu3O(SO4)320Sm 3 O 2 Sm[SeO 3 ] 4 and Sm 3 O 2 Cl[SeO 3 ] 2 : A Monoclinic Form of Samarium Oxide Oxoselenate(IV) and a Samarium Oxide Chloride Oxoselenate(IV) both with 1 ∞ {[O 2 Sm 3 ] 5+ } Chains4Jahn–Teller distortion and thermal expansion anisotropy: temperature-dependent behavior of lindgrenite, Cu3(MoO4)2(OH)2, szenicsite, Cu3(MoO4)(OH)4, and cupromolybdite, Cu3O(MoO4)25Copper–lead selenite bromides: a new large family of compounds partly having Cu2+ substructures derivable from kagome nets10Copper minerals from volcanic exhalations – a unique family of natural compounds: crystal-chemical review35Modification strategies for enhancing the visible light responsive photocatalytic activity of the BiPO 4 nano-based composite photocatalysts44[Ba 13 Sb 36 Cl 34 O 54 ] 8− : high-nuclearity cluster for the assembly of nanocluster-based compounds11Identification and optical features of the Pb 4 Ln 2 O 7 series (Ln = La, Gd, Sm, Nd); genuine 2D-van der Waals oxides1Pb4B6O13: A Polar Lead Oxyborate with Uncommon ∞(B6O12)6– Layers Exhibiting a Large Second Harmonic Generation Response15(CsX)Cu5O2(PO4)2 (X = Cl, Br, I): A Family of Cu2+ S = 1/2 Compounds with Capped-Kagomé Networks Composed of OCu4 Units45A Lysosome-Targetable Fluorescence Sensor for Ultrasensitive Detection of Hg2+in Living Cells and Real Samples27New Lead Orthosilicate {Pb4(О(ОН)2)}[SiO4] with a Framework of Anion-Centered Pb Tetrahedra Related to Sodalite3Synthesis, crystal structure, spectroscopic properties, and thermal behavior of rare-earth oxide selenates, Ln2O2SeO4 (Ln = La, Pr, Nd): The new perspectives of solid-state double-exchange synthesis7Aleutite [Cu5O2](AsO4)(VO4)·(Cu0.5□0.5)Cl, a new complex salt-inclusion mineral with Cu2+substructure derived from a Kagome-net27Dokuchaevite, Cu8O2(VO4)3Cl3, a new mineral with remarkably diverse Cu2+ mixed-ligand coordination environments16Crystal-chemical study of ecdemite from Harstigen, a new natural member of the layered lead oxyhalides group4Erikjonssonite, (Pb32O21)[(V,Si,Mo,As)O4]4Cl9, a new mineral from the Kombat mine and structural classification of layered lead oxychlorides related to litharge8Selenium Minerals: Structural and Chemical Diversity and Complexity23Rb2CaCu6(PO4)4O2, a novel oxophosphate with a shchurovskyite-type topology: synthesis, structure, magnetic properties and crystal chemistry of rubidium copper phosphates5RbSbO3: A Simple Structure with Complex Polytypism2Copper Minerals at Vesuvius Volcano (Southern Italy): A Mineralogical Review35Bi2O2SO4, a new representative of the grandreefite structure type17Elasmochloite, Na3Cu6BiO4(SO4)5, a new fumarolic mineral from the Tolbachik volcano, Kamchatka, Russia6Alkali-earth metal lead( ii ) oxyhalide Ba 27 Pb 8 O 8 Cl 54 exhibiting interesting [Pb 4 Ba 4 O 4 ] 8+ species8High pressure exploration in the Li–Ln–V–O system2Layered electrides as fluoride intercalation anodes32Cu9O2(VO4)4Cl2, the First Copper Oxychloride Vanadate: Mineralogically Inspired Synthesis and Magnetic Behavior23

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  3. ChemInform Abstract: Anion‐Centered Tetrahedra in Inorganic Compounds

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  18. Revised Bi/M Layered Oxo-Sulfate (M = Co, Cu): A Structural and Magnetic Study

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  20. The structure hierarchy hypothesis

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  25. Unique thallium mineralization in the fumaroles of Tolbachik volcano, Kamchatka Peninsula, Russia. I. Markhininite, TlBi(SO4)2

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  47. Fluorite-related one-dimensional units in natural bismuth oxysulfates: the crystal structures of Bi14O16(SO4)5and Bi30O33(SO4)9(AsO4)2

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  48. Yeomanite, Pb2O(OH)Cl, a new chain-structured Pb oxychloride from Merehead Quarry, Somerset, England

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  49. Interlayer Communication in Aurivillius Vanadate to Enable Defect Structures and Charge Ordering

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  50. Structural Evolution from 0D Units to 3D Frameworks in Pb Oxyhalides: Unexpected Strongly Corrugated Layers in Pb7O6Br2

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