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RESEARCH PAPER · Inorganic Chemistry · 2013

Crystal Growth, Structure, Polarization, and Magnetic Properties of Cesium Vanadate, Cs2V3O8: A Structure–Property Study

Jeongho Yeon, Athena S. Sefat, T. Thao Tran, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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Crystal Growth, Structure, Polarization, and Magnetic Properties of Cesium Vanadate, Cs2V3O8: A Structure–Property StudyOriginalChemInform Abstract: Crystal Growth, Structure, Polarization, and Magnetic Properties of Cesium Vanadate, Cs2V3O8: A Structure—Property Study.0U3F12(H2O), a Noncentrosymmetric Uranium(IV) Fluoride Prepared via a Convenient In Situ Route That Creates U4+ under Mild Hydrothermal Conditions38The role of dipole moment in determining the nonlinear optical behavior of materials: ab initio studies on quaternary molybdenum tellurite crystals123A New Cesium Pentaborate with New B10O19 Building Blocks13Application of a Mild Hydrothermal Approach Containing an in Situ Reduction Step to the Growth of Single Crystals of the Quaternary U(IV)-Containing Fluorides Na4MU6F30 (M = Mn2+, Co2+, Ni2+, Cu2+, and Zn2+) Crystal Growth, Structures, and Magnetic Properties60Observation of Multiple Crystal-to-Crystal Transitions in a New Reduced Vanadium Oxalate Hybrid Material, Ba3[(VO)2(C2O4)5(H2O)6]·(H2O)3, Prepared via a Mild, Two-Step Hydrothermal Method27First-principles investigation of the electronic structure and magnetic properties of multiferroic PrMn2O51Crystal Growth of Four Oxovanadium(IV) Tartrates Prepared via a Mild Two-Step Hydrothermal Method: Observation of Spin-Dimer Behavior and Second Harmonic Generation28Synthesis, Crystal Structure and Properties of the Strontium Vanadate Fluoride Sr5(VO4)3F12Synthesis of the Layered Quaternary Uranium-Containing Oxide Cs2Mn3U6O22 and Characterization of its Magnetic Properties6Synthesis, characterization, and properties of reduced europium molybdates and tungstates21Single crystal growth and characterization of the first reduced lanthanum molybdenum oxychloride, La20Mo12O63Cl4, with an unusual trigonal prismatic MoO6 unit14Synthesis of anhydrous K2TiOF4 via a mild hydrothermal method8High-Temperature Salt Flux Crystal Growth of New Lanthanide Molybdenum Oxides, Ln5Mo2O12 Ln = Eu, Tb, Dy, Ho, and Er: Magnetic Coupling within Mixed Valent Mo(IV/V) Rutile-Like Chains22Density functional theory calculations, growth, structure, and optical properties of birefringent LiNaV2O69High-pressure behaviour of Cs2V3O8 fresnoite4Single crystal growth and characterization of NaxLn1−xMoO4, Ln=La, Ce, Pr, Nd, Sm, and Eu (x=0.397–0.499)9Oxygen Anion Solubility as a Factor in Molten Flux Crystal Growth, Synthesis, and Characterization of Four New Reduced Lanthanide Molybdenum Oxides: Ce4.918(3)Mo3O16, Pr4.880(3)Mo3O16, Nd4.910(3)Mo3O16, and Sm4.952(3)Mo3O1615Crystal growth, structure, and properties, of a new oxovanadium(IV) phosphate material, [H2en]4[V7P8O35(OH)6(H2O)]·3H2O prepared via a mild one step hydrothermal route4Where Do New Materials Come From? Neither the Stork nor the Birds and the Bees! In Search of the Next “First Material”1Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold51A fresnoite-structure-related mixed valent titanium(III/IV) chlorosilicate, Ba3Ti2Si4O14Cl: A flux crystal growth route to Ti(III) containing oxides11One-step mild hydrothermal method to prepare low valent sodium vanadium(III) monohydrogenphosphate: NaV(HPO4)24pH Driven Hydrothermal Syntheses of Neodymium Sulfites and Mixed Sulfate-Sulfites7Understanding the formation thermodynamics of fresnoitic trivanadates: DFT calculations and soft base hydrolysis synthesis0Synthesis, crystal structure, thermal, photoluminescent and magnetic properties of a new material: Na2[Ni(C2O4)2(H2O)2].6H2O4Giant Enhancement of Second Harmonic Generation Accompanied by the Structural Transformation of 7‐Fold to 8‐Fold Interpenetrated Metal–Organic Frameworks (MOFs)94Giant Enhancement of Second Harmonic Generation Accompanied by the Structural Transformation of 7‐Fold to 8‐Fold Interpenetrated Metal–Organic Frameworks (MOFs)35Redetermination of diammonium trivanadate, (NH4)2V3O88Polymorphism and Molten Nitrate Salt-Assisted Single Crystal to Single Crystal Ion Exchange in the Cesium Ferrogermanate Zeotype: CsFeGeO412Sodium Transition Metal Vanadates from Hydrothermal Brines: Synthesis and Characterization of NaMn4(VO4)3, Na2Mn3(VO4)3, and Na2Co3(VO4)2(OH)210Stuffed Tridymite Structures: Synthesis, Structure, Second Harmonic Generation, Optical, and Multiferroic Properties14Preparation of PrVO4 by Sol-Gel Method and Its Photocatalytic Activity5Investigation of Metastable Low Dimensional Halometallates5Designing new polar materials1New quinary cesium vanadium (IV) fluorophosphates, CsVOF(PO3F) and CsV2O2F(PO3F)2·H2O3Incommensurate structures and radiation damage in Rb 2 V 3 O 8 and K 2 V 3 O 8 mixed-valence vanadate fresnoites5Three in one: a cadmium bismuth vanadate NLO crystal exhibiting a large second-harmonic generation response and enhanced birefringence12Exploring quaternary vanadates containing alkali metals, alkaline earth metals, and [VO 4 ] in the quest for nonlinear optical materials1Nanoscale doping and mixing of binary oxide thin films: concepts, properties and applications2

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  1. ChemInform Abstract: Crystal Growth, Structure, Polarization, and Magnetic Properties of Cesium Vanadate, Cs2V3O8: A Structure—Property Study.

    ChemInform · 2013-07-01

    Jeongho Yeon, Athena S. Sefat, T. Thao Tran, P. Shiv Halasyamani, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  2. U3F12(H2O), a Noncentrosymmetric Uranium(IV) Fluoride Prepared via a Convenient In Situ Route That Creates U4+ under Mild Hydrothermal Conditions

    Inorganic Chemistry · 2013-07-08

    Jeongho Yeon, Mark D. Smith, Athena S. Sefat, T. Thao Tran, P. Shiv Halasyamani, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  3. The role of dipole moment in determining the nonlinear optical behavior of materials: ab initio studies on quaternary molybdenum tellurite crystals

    Journal of Materials Chemistry C · 2013-11-06

    Xingxing Jiang, Sangen Zhao, Zheshuai Lin, Junhua Luo, Paul D. Bristowe, Xiangguo Guan, Chuangtian Chen

    Read original paper ↗ ·

  4. A New Cesium Pentaborate with New B10O19 Building Blocks

    Inorganic Chemistry · 2014-02-14

    Anqing Jiao, Hongwei Yu, Hongping Wu, Shilie Pan, Xingwen Zhang

    Read original paper ↗ ·

  5. Application of a Mild Hydrothermal Approach Containing an in Situ Reduction Step to the Growth of Single Crystals of the Quaternary U(IV)-Containing Fluorides Na4MU6F30 (M = Mn2+, Co2+, Ni2+, Cu2+, and Zn2+) Crystal Growth, Structures, and Magnetic Properties

    Journal of the American Chemical Society · 2014-03-04

    Jeongho Yeon, Mark D. Smith, Joshua H. Tapp, Angela Möller, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  6. Observation of Multiple Crystal-to-Crystal Transitions in a New Reduced Vanadium Oxalate Hybrid Material, Ba3[(VO)2(C2O4)5(H2O)6]·(H2O)3, Prepared via a Mild, Two-Step Hydrothermal Method

    Crystal Growth & Design · 2014-08-19

    Dileka Abeysinghe, Mark D. Smith, Jeongho Yeon, Gregory W. Morrison, Hans‐Conrad zur Loye

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  7. First-principles investigation of the electronic structure and magnetic properties of multiferroic PrMn2O5

    Computational Materials Science · 2014-09-06

    Jianwei Zhang, Lishuo Gao, Y.X. Li, Ben Xu, K.L. Yao

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  8. Crystal Growth of Four Oxovanadium(IV) Tartrates Prepared via a Mild Two-Step Hydrothermal Method: Observation of Spin-Dimer Behavior and Second Harmonic Generation

    Inorganic Chemistry · 2015-03-31

    Anthony J. Cortese, Branford O. Wilkins, Mark D. Smith, Jeongho Yeon, Gregory W. Morrison, T. Thao Tran, P. Shiv Halasyamani, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  9. Synthesis, Crystal Structure and Properties of the Strontium Vanadate Fluoride Sr5(VO4)3F

    Zeitschrift für anorganische und allgemeine Chemie · 2015-04-22

    Fangyuan Zhang, Fangyuan Zhang, Fangfang Zhang, Fangfang Zhang, Qun Jing, Shilie Pan, Zhihua Yang, Dianzeng Jia

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  10. Synthesis of the Layered Quaternary Uranium-Containing Oxide Cs2Mn3U6O22 and Characterization of its Magnetic Properties

    Inorganic Chemistry · 2015-05-08

    Cory Michael Read, Elijah E. Gordon, Mark D. Smith, Jeongho Yeon, Gregory W. Morrison, Myung‐Hwan Whangbo, Hans‐Conrad zur Loye

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  11. Synthesis, characterization, and properties of reduced europium molybdates and tungstates

    Journal of Solid State Chemistry · 2015-05-18

    Dileka Abeysinghe, Birgit Gerke, Gregory W. Morrison, Chun H. Hsieh, Mark D. Smith, Rainer Pöttgen, Thomas M. Makris, Hans‐Conrad zur Loye

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  12. Single crystal growth and characterization of the first reduced lanthanum molybdenum oxychloride, La20Mo12O63Cl4, with an unusual trigonal prismatic MoO6 unit

    Solid State Sciences · 2015-07-30

    Anthony J. Cortese, Branford O. Wilkins, Mark D. Smith, Gregory W. Morrison, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  13. Synthesis of anhydrous K2TiOF4 via a mild hydrothermal method

    Solid State Sciences · 2015-08-18

    Justin B. Felder, Jeongho Yeon, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  14. High-Temperature Salt Flux Crystal Growth of New Lanthanide Molybdenum Oxides, Ln5Mo2O12 Ln = Eu, Tb, Dy, Ho, and Er: Magnetic Coupling within Mixed Valent Mo(IV/V) Rutile-Like Chains

    Inorganic Chemistry · 2015-12-02

    Anthony J. Cortese, Dileka Abeysinghe, Branford O. Wilkins, Mark D. Smith, Gregory W. Morrison, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  15. Density functional theory calculations, growth, structure, and optical properties of birefringent LiNaV2O6

    Journal of materials research/Pratt's guide to venture capital sources · 2016-02-12

    Qingrong Kong, Yun Mo Yang, Lili Liu, Qiang Bian, Bing‐Hua Lei, Linping Li, Zhihua Yang, Zhi Su, Shilie Pan

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  16. High-pressure behaviour of Cs2V3O8 fresnoite

    Journal of Solid State Chemistry · 2016-03-26

    Andrzej Grzechnik, Jeongho Yeon, Hans‐Conrad zur Loye, Karen Friese

    Read original paper ↗ ·

  17. Single crystal growth and characterization of NaxLn1−xMoO4, Ln=La, Ce, Pr, Nd, Sm, and Eu (x=0.397–0.499)

    Journal of Solid State Chemistry · 2016-05-09

    Anthony J. Cortese, Dileka Abeysinghe, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  18. Oxygen Anion Solubility as a Factor in Molten Flux Crystal Growth, Synthesis, and Characterization of Four New Reduced Lanthanide Molybdenum Oxides: Ce4.918(3)Mo3O16, Pr4.880(3)Mo3O16, Nd4.910(3)Mo3O16, and Sm4.952(3)Mo3O16

    Crystal Growth & Design · 2016-07-06

    Anthony J. Cortese, Dileka Abeysinghe, Branford O. Wilkins, Mark D. Smith, Vitaly A. Rassolov, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  19. Crystal growth, structure, and properties, of a new oxovanadium(IV) phosphate material, [H2en]4[V7P8O35(OH)6(H2O)]·3H2O prepared via a mild one step hydrothermal route

    Solid State Sciences · 2016-08-07

    Anthony J. Cortese, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  20. Where Do New Materials Come From? Neither the Stork nor the Birds and the Bees! In Search of the Next “First Material”

    Scholar Commons (University of South Carolina) · 2017-01-01

    Gregory W. Morrison, Dileka Abeysinghe, Justin B. Felder, Shani Egodawatte, Timothy Ferreira, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  21. Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold

    Crystal Growth & Design · 2017-03-30

    Zhaohui Chen, Zhizhong Zhang, Xiaoyu Dong, Yunjing Shi, Yaqin Liu, Qun Jing

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  22. A fresnoite-structure-related mixed valent titanium(III/IV) chlorosilicate, Ba3Ti2Si4O14Cl: A flux crystal growth route to Ti(III) containing oxides

    Journal of Solid State Chemistry · 2017-03-31

    Dileka Abeysinghe, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  23. One-step mild hydrothermal method to prepare low valent sodium vanadium(III) monohydrogenphosphate: NaV(HPO4)2

    Solid State Sciences · 2017-05-04

    Dileka Abeysinghe, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  24. pH Driven Hydrothermal Syntheses of Neodymium Sulfites and Mixed Sulfate-Sulfites

    Crystal Growth & Design · 2018-08-03

    Jakob T. Dovgan, Matthew J. Polinski, Brandon Q. Mercado, Eric M. Villa

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  25. Understanding the formation thermodynamics of fresnoitic trivanadates: DFT calculations and soft base hydrolysis synthesis

    Journal of Physics and Chemistry of Solids · 2018-08-28

    Galina S. Zakharova, Andrey N. Enyashin, N. V. Podval’naya, R.S. Gorodetsky, Н. И. Кадырова, Qi Zhu

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  26. Synthesis, crystal structure, thermal, photoluminescent and magnetic properties of a new material: Na2[Ni(C2O4)2(H2O)2].6H2O

    Journal of Molecular Structure · 2018-10-06

    M. Narsimhulu, G. Anil Kumar, G. Bhargavi, B. Srinivas, Khalid Hussain

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  27. Giant Enhancement of Second Harmonic Generation Accompanied by the Structural Transformation of 7‐Fold to 8‐Fold Interpenetrated Metal–Organic Frameworks (MOFs)

    Angewandte Chemie International Edition · 2019-10-01

    Zhihui Chen, Gianpiero Gallo, Vaishali A. Sawant, Tianxiang Zhang, Menglong Zhu, Liangliang Liang, Anjana Chanthapally, Geetha Bolla, Hong Sheng Quah, Xiaogang Liu, Kian Ping Loh, Robert E. Dinnebier, Qing‐Hua Xu, Jagadese J. Vittal

    Read original paper ↗ ·

  28. Giant Enhancement of Second Harmonic Generation Accompanied by the Structural Transformation of 7‐Fold to 8‐Fold Interpenetrated Metal–Organic Frameworks (MOFs)

    Angewandte Chemie · 2019-10-01

    Zhihui Chen, Gianpiero Gallo, Vaishali A. Sawant, Tianxiang Zhang, Menglong Zhu, Liangliang Liang, Anjana Chanthapally, Geetha Bolla, Hong Sheng Quah, Xiaogang Liu, Kian Ping Loh, Robert E. Dinnebier, Qing‐Hua Xu, Jagadese J. Vittal

    Read original paper ↗ ·

  29. Redetermination of diammonium trivanadate, (NH4)2V3O8

    IUCrData · 2020-04-09

    Aarón Pérez-Benı́tez, Sylvain Bernès

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  30. Polymorphism and Molten Nitrate Salt-Assisted Single Crystal to Single Crystal Ion Exchange in the Cesium Ferrogermanate Zeotype: CsFeGeO4

    Inorganic Chemistry · 2020-07-02

    Mohammad Usman, Vancho Kocevski, Mark D. Smith, Gregory W. Morrison, Weiguo Zhang, Theodore M. Besmann, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  31. Sodium Transition Metal Vanadates from Hydrothermal Brines: Synthesis and Characterization of NaMn4(VO4)3, Na2Mn3(VO4)3, and Na2Co3(VO4)2(OH)2

    European Journal of Inorganic Chemistry · 2020-08-10

    Tiffany M. Smith Pellizzeri, Gregory W. Morrison, Colin D. McMillen, Hans‐Conrad zur Loye, Joseph W. Kolis

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  32. Stuffed Tridymite Structures: Synthesis, Structure, Second Harmonic Generation, Optical, and Multiferroic Properties

    Chemistry - A European Journal · 2020-11-24

    Anupam Bhim, Jean‐Pascal Sutter, Jagannatha Gopalakrishnan, Srinivasan Natarajan

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  33. Preparation of PrVO4 by Sol-Gel Method and Its Photocatalytic Activity

    Integrated ferroelectrics · 2021-07-24

    Ruipeng Hou, Haifeng Chen, Yifan Zhou, Liqin Zhang, Shouquan Sun, Xuezhi Wei, Peisong Tang

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  34. Investigation of Metastable Low Dimensional Halometallates

    Molecules · 2022-01-03

    Navindra Keerthisinghe, Matthew S. Christian, Anna A. Berseneva, Gregory W. Morrison, Vladislav V. Klepov, Mark D. Smith, Hans‐Conrad zur Loye

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  35. Designing new polar materials

    Elsevier eBooks · 2022-01-28

    Emma E. McCabe

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  36. New quinary cesium vanadium (IV) fluorophosphates, CsVOF(PO3F) and CsV2O2F(PO3F)2·H2O

    Journal of Solid State Chemistry · 2022-06-05

    Xinan Zhang, Yanling Jin, Wenxuan Zhu, Dan Chen, Qingqing Huang, Yaping Li, Minfeng Lü

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  37. Incommensurate structures and radiation damage in Rb 2 V 3 O 8 and K 2 V 3 O 8 mixed-valence vanadate fresnoites

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2023-02-17

    Andrzej Grzechnik, Václav Petříček, Dmitry Chernyshov, Charles J. McMonagle, Tobias Geise, Hend Shahed, Karen Friese

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  38. Three in one: a cadmium bismuth vanadate NLO crystal exhibiting a large second-harmonic generation response and enhanced birefringence

    Inorganic Chemistry Frontiers · 2024-01-01

    Shuya Liu, Conggang Li, Jinmiao Jiao, Yuheng She, Tinghui Zhang, Dianxing Ju, Ning Ye, Zhanggui Hu, Yicheng Wu

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  39. Exploring quaternary vanadates containing alkali metals, alkaline earth metals, and [VO 4 ] in the quest for nonlinear optical materials

    CrystEngComm · 2025-01-01

    Xiaoming Wang, Qiuyuan Feng, Ketian Hou, Wei Wei, Juanjuan Lu, Lai Wei, Feng Zhang

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  40. Nanoscale doping and mixing of binary oxide thin films: concepts, properties and applications

    Journal of Physics Condensed Matter · 2026-01-23

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