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RESEARCH PAPER · Journal of the American Chemical Society · 2012

Iodine Release and Recovery, Influence of Polyiodide Anions on Electrical Conductivity and Nonlinear Optical Activity in an Interdigitated and Interpenetrated Bipillared-Bilayer Metal–Organic Framework

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Iodine Release and Recovery, Influence of Polyiodide Anions on Electrical Conductivity and Nonlinear Optical Activity in an Interdigitated and Interpenetrated Bipillared-Bilayer Metal–Organic FrameworkOriginalControllable synthesis of a non-interpenetrating microporous metal–organic framework based on octahedral cage-like building units for highly efficient reversible adsorption of iodine73Crystal to crystal transformation induced a novel Cu(ii)-MOF with zigzag ⋯I3−⋯I3−⋯ chains15Fast capture and separation of, and luminescent probe for, pollutant chromate using a multi-functional cationic heterometal-organic framework247Layer by layer growth of nano porous lead(ii) coordination polymer on natural silk fibers and its application in removal and recovery of iodide21Solid-state single-crystal-to-single-crystal transformation from a 2D layer to a 3D framework mediated by lattice iodine release74Unique 3D CoII/ZnII-coordination polymers with (3,4,5)-connected self-penetrating topology: Syntheses, topological structures, luminescent and magnetic properties16Four Low-Dimensional Cobalt(II) Coordination Polymers Based on a New Isophthalic Acid Derivative: Syntheses, Crystal Structures, and Properties55Synthesis, Structures, and Properties of Two Three-Dimensional Metal–Organic Frameworks, Based on Concurrent Ligand Extension73A 2-dimensional cadmium(II) coordination polymer with the unique 4-fold interpenetrated (4,4) layered structure from a long bridging ligand1Unusual High Thermal Stablility of a 2D → 3D Polycatenated Fe(II) Metal–Organic Framework Showing Guest-Dependent Spin-Crossover Behavior and High Spin-Transition Temperature65A new Wells-Dawson polyoxometalate-based metal-organic hybrid decorated by the flexible bis-pyridyl-bis-amide ligand13Construction of monomers and chains assembled by 3d/4f metals and 4′-(4-carboxyphenyl)-2,2′:6′,2″-terpyridine27A novel one-dimensional silver cylinder stabilized by mixed 2-mercaptobenzoic acid and ethylenediamine ligands2Two- and Three-Dimensional Divalent Metal Coordination Polymers Constructed from a New Tricarboxylate Linker and Dipyridyl Ligands34Synthesis, structures, and luminescent properties of four new 3D lanthanide metal–organic frameworks with fluorescent whitener, 4,4′-biphenyldicarboxylate and 1,10-phenanthroline14Tuning MOF Stability and Porosity via Adding Rigid Pillars88A new three-dimensional metal–organic framework constructed from 9,10-anthracene dibenzoate and Cd( ii ) as a highly active heterogeneous catalyst for oxidation of alkylbenzenes43Halogen Bonding in Crystal Engineering36Recent Advances in Crystallography57Solution and Solid State Synthesis of the Discrete Polyiodide I73– under Modular Cation Templation36A new POM-templated metal–organic complex based on the flexible bis-pyridyl-bis-amide ligand3Biphase synthesis of a one-dimensional coordination polymer based on a dinuclear CdIIsecondary building unit and a novel semi-rigid dicarboxylate0Syntheses and Structures of Terpyridine‐Metal Complexes16Polycarboxylate anions effect on the structures of a series of transition metal-based coordination polymers: Syntheses, crystal structures and bioactivities19Structural diversity of Ag/3-nitrophthalate coordination polymers controlled by solvent and induction agent27Four New Cd(II) Coordination Polymers with Mixed Multidentate N-Donors and Biphenyl-Based Polycarboxylate Ligands: Syntheses, Structures, and Photoluminescent Properties208A Series of Lanthanide-Based Cluster Organic Frameworks Made of Heptanuclear Trigonal-Prismatic Cluster Units78Novel (4,8)-connected scu coordination framework constructed by tetrakis(4-benzoic acid)ethylene15A New Two-Dimensional NiII Coordination Polymer Constructed by CH3O-isophthalate and 1,6-bis(imidazol-1-yl)hexane: Synthesis, Structure, and Properties0Two New (3,6)-Connected Frameworks Based on an Unsymmetrical Tritopic Pyridyldicarboxylate Ligand and Co 2 Dimer: Structures, Magnetic, and Sorption Properties26A multifunctional helical Cu(i) coordination polymer with mechanochromic, sensing and photocatalytic properties285A New 3D Coordination Polymer of Bismuth with Nicotinic Acid N‐Oxide6A series of Cu(ii) and Cd(ii) coordination polymers constructed by 3,5-dinitrosalicylic acid and flexible bis(triazole) ligands containing different spacers34A series of MOFs based on a tricarboxylic acid and various N-donor ligands: syntheses, structures, and properties51Accumulation of versatile iodine species by a porous hydrogen-bonding Cu(ii) coordination framework72An unusual copper(i) halide-based metal–organic framework with a cationic framework exhibiting the release/adsorption of iodine, ion-exchange and luminescent properties76Assembly of Zn/Cd coordination polymers containing helixes or polycatenane structures tuned by the tri-pyridyl–bis-amide ligands with different spacer: syntheses, structures, photoluminescent and photocatalytic properties63Bi-porous metal–organic framework with hydrophilic and hydrophobic channels: selective gas sorption and reversible iodine uptake studies72Capture of iodine in highly stable metal–organic frameworks: a systematic study300Catenated Compounds – Group 17 – Polyhalides18Cobalt(ii), copper(ii), zinc(ii) and cadmium(ii) complexes based on dibenzimidazolyl bidentate ligands with alkanyl linkers: crystal structure, weak interactions and conformations38Eight Zn(ii) coordination networks based on flexible 1,4-di(1H-imidazol-1-yl)butane and different dicarboxylates: crystal structures, water clusters, and topologies81Fe2+-based layered porous coordination polymers and soft encapsulation of guests via redox activity36From achiral tetrazolate-based tectons to chiral coordination networks: effects of substituents on the structures and NLO properties18Iodine-templated assembly of an In(iii) complex with a single-crystal-to-single-crystal transition18Iodine-templated assembly of unprecedented 3d–4f metal–organic frameworks as photocatalysts for hydrogen generation105Metal-organic frameworks displaying single crystal-to-single crystal transformation through postsynthetic uptake of metal clusters78New metal–organic frameworks based on 2,5-thiophenedicarboxylate and pyridine- or imidazole-based spacers: syntheses, topological structures, and properties62One-dimensional channel-structured Eu-MOF for sensing small organic molecules and Cu2+ ion364Polyrotaxane frameworks containing N,N′,N′′-(4,4′,4′′-nitrilotris(4,1-phenylene))triisonicotinamide: structural and luminescent properties5Supramolecular isomerism, single-crystal to single-crystal transformation induced by release of in situ generated I2 between two supramolecular frameworks8Syntheses, crystal structures and thermal properties of six coordination polymers based on 2-(p-methylphenyl)-imidazole dicarboxylate15Syntheses, structures, and photoluminescent properties of a series of coordination polymers based on a new 2′-carboxybiphenyl-4-ylmethylaminodiacetic acid and different N-donor ligands18Thiadiazole-functional porous metal–organic framework as luminescent probe for Cd2+46Three pillared-layer 3d–4f heterometallic frameworks based on tetranuclear lanthanide clusters14Emulsion Copolymerization of Methyl Methacrylate/Butyl Acrylate/Iodine System to Monosize Rubbery Nanoparticles Containing Iodine and Triiodide Mixture18A 3-D lanthanide coordination polymer constructed from biphenyl-2,2′,6,6′-tetracarboxylic acid: synthesis of a trinodal (3,4,5)-connected topology and luminescence13Syntheses, Topological Structures, and Photoluminescences of Six New Zn(II) Coordination Polymers Based on Mixed Tripodal Imidazole Ligand and Varied Polycarboxylates155A Porous 4-Fold-Interpenetrated Chiral Framework Exhibiting Vapochromism, Single-Crystal-to-Single-Crystal Solvent Exchange, Gas Sorption, and a Poisoning Effect126Coordination Assembly of ZnII/CdII Terephthalate with Bis-Pyridinecarboxamide Tectons: Establishing Net Entanglements from [3 + 3] Interpenetration to High-Connected Self-Penetration34Post‐Synthetic Monovalent Central‐Metal Exchange, Specific I2 Sensing, and Polymerization of a Catalytic [3×3] Grid of [CuII5CuI4L6]⋅(I)2⋅13 H2O49Tracking the Formation of a Polynuclear Co 16 Complex and Its Elimination and Substitution Reactions by Mass Spectroscopy and Crystallography176Influence of solvent on the structures of two copper(II) coordination polymers with tetraiodoterephthalate: syntheses, crystal structures, and properties11Metal–Organic Frameworks Assembled From Erbium Tetramers and 2,5-Pyridinedicarboxylic Acid27An inorganic–organic hybrid material {[Dy2(SO4)(Himdc)2(H2O)5]·H2O}n featuring organic carboxylic acid and inorganic sulfate and luminescent property6Porphyrin-cucurbituril organic molecular porous material: Structure and iodine adsorption properties30A Highly Chemical and Thermal Stable Porous Metal–Organic Framework with Unusual 5-Connected zfy Topology16An Unusual Porous Metal–Organic Framework that Demonstrates the Highly Efficient Exchange of Metal Ions and the Reversible Adsorption of Iodine31Hydrothermal Synthesis, Structure and Bioactivity of Lamellar Cu(DMBC)2(H2O)2(DMBC:2-(3,5-Dimethylphenoxy)acetic Acid) Complex1Kinetic Assembly of a Thermally Stable Porous Coordination Network Based on Labile CuI Units and the Visualization of I 2 Sorption92Kinetic Assembly of a Thermally Stable Porous Coordination Network Based on Labile CuI Units and the Visualization of I2 Sorption24An eight-connected porous metal–organic framework based on hetero pentanuclear clusters20Synthesis, Structures, and Properties of Two Zinc(II) and Cadmium(II) Supramolecular Complexes Based on Diphenic Acid2A europium( iii ) based metal–organic framework: bifunctional properties related to sensing and electronic conductivity158Thermochemical Evidence for Strong Iodine Chemisorption by ZIF-8288Exploring the structural diversities and magnetic properties of copper( ii ) and manganese( ii ) complexes based on 5-methoxyisophthalate and flexible bis(imidazole) ligands79I62− Anion Composed of Two Asymmetric Triiodide Moieties: A Competition between Halogen and Hydrogen Bond50Constructing heterometallic frameworks with highly connected topology based on edge-to-edge hexanuclear lanthanide clusters22Solid-state structural transformation doubly triggered by reaction temperature and time in 3D metal-organic frameworks: great enhancement of stability and gas adsorption72Solvent or Temperature Induced Diverse Coordination Polymers of Silver(I) Sulfate and Bipyrazole Systems: Syntheses, Crystal Structures, Luminescence, and Sorption Properties88Five MOFs with different topologies based on anthracene functionalized tetracarboxylic acid: syntheses, structures, and properties36Iterative Mass Spectrometry and X-Ray Crystallography to Study Ion-Trapping and Rearrangements by a Flexible Cluster25Seven dicarboxylate-based coordination polymers with structural varieties and different solvent resistance properties derived from the introduction of small organic linkers18A polyrotaxane-like metal–organic framework exhibiting luminescent sensing of Eu 3+ cations and proton conductivity27Bilayer architecture based on hexanuclear heterometal cluster units5Effects of substituent groups on the structures and luminescence properties of 2D/3D Cd II complexes with mixed rigid and flexible carboxylate ligands21Highly efficient and reversible iodine capture using a metalloporphyrin-based conjugated microporous polymer232Influence of an amine group on the highly efficient reversible adsorption of iodine in two novel isoreticular interpenetrated pillared-layer microporous metal–organic frameworks110Spontaneous chiral resolution of a 3D (3,12)-connected MOF with an unprecedented ttt topology consisting of cubic [Cd4(μ3-OH)4] clusters and propeller-like ligands67Syntheses, crystal structures, photoluminescent/magnetic properties of four new coordination polymers based on 2,3′,4,5′-biphenyltetracarboxylic acid25Template-directed synthesis of metal–organic materials279Two luminescent Cu(i) coordination polymers based on the 1-(4-tetrazolephenyl)imidazole ligand for sensing of nitrobenzene43Ultrahigh iodine adsorption in porous organic frameworks292Luminescent Response of One Anionic Metal–Organic Framework Based on Novel Octa-nuclear Zinc Cluster to Exchanged Cations41Design, structure and luminescent properties of a novel two-dimensional Cd(II) coordination polymer constructed from in situ generated 1-methyl-2-(3H-[1–3]triazol-4-yl)-1H-benzoimidazole6Two Series of Sandwich Frameworks Based on Two Different Kinds of Nanosized Lanthanide(III) and Copper(I) Wheel Cluster Units33A Fluorescent Sensor for Highly Selective Detection of Nitroaromatic Explosives Based on a 2D, Extremely Stable, Metal–Organic Framework288A new PtS-type heterometallic compound constructed from biphenyl-3,3′,5,5′-tetracarboxylate: Synthesis, structure and luminescent property7Self‐assembly of Two 2D Copper(II) Coordination Networks with Tetrachloro‐1,3‐benzenedicarboxylate: Solvent Effects, Supramolecular Interactions, and Luminescence Behavior4A ‘kagome dual’ (kgd) sheet based on triangular rigid ligand: Synthesis, structure, photoluminescence and anion exchange properties10Silver(I)/Bipyrazole/Dicarboxylate Interpenetrated Coordination Networks: Spontaneous Chiral Resolution, Modulation of Topologies, Water Clusters, and Photoluminescences52Facile synthesis of POM@MOF embedded in SBA-15 as a steady catalyst for the hydroxylation of benzene50A unique 1D ribbon coordination polymer containing 2 + 1 trimeric copper(II) linked by in situ generated polynitrogen heterocyclic ligand as bridges: Synthesis, crystal structure and magnetism6Different dimensional coordination polymers with 4,4׳-oxybis(benzoate): Syntheses, structures and properties17Alkyl Ammonium Cation Stabilized Biocidal Polyiodides with Adaptable High Density and Low Pressure42Control of Crystalline Proton-Conducting Pathways by Water-Induced Transformations of Hydrogen-Bonding Networks in a Metal–Organic Framework270New photocatalyst for the degradation of organic dyes based on [Cu(ONCP)(4,4′-BPDA)1/2(H2O)·(4,4′-H2BPDA)]n11Pillared-Layer Cluster Organic Frameworks Constructed from Nanoscale Ln10 and Cu16 Clusters22Luminescent MOFs comprising mixed tritopic linkers and Cd(II)/Zn(II) nodes for selective detection of organic nitro compounds and iodine capture51Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal–Organic Framework Thin Film140Electrochemical Synthesis of a Microporous Conductive Polymer Based on a Metal–Organic Framework Thin Film30Two-Dimensional Coordination Polymers Comprising Mixed Tripodal Ligands for Selective Colorimetric Detection of Water and Iodine Capture56Immobilization of Volatile and Corrosive Iodine Monochloride (ICl) and I2 Reagents in a Stable Metal–Organic Framework51Multifunctional Cobalt(II) Coordination Polymers Tuned by Flexible Bis(pyridylamide) Ligands with Different Spacers and Polycarboxylates111Unprecedented Second‐Timescale Blue/Green Emissions and Iodine‐Uptake‐Induced Single‐Crystal‐to‐Single‐Crystal Transformation in ZnII/CdII Metal–Organic Frameworks154In silico screening of metal organic framework for iodine capture and storage58Urothermal Synthesis of a New Cd(II)-Terephthalate: Synthesis, Structure, CO2 Adsorption and Luminescent Properties3Three mixed-ligand coordination networks modulated by flexible N-donor ligands: syntheses, topological structures, and temperature-sensitive luminescence properties35A set of alkali and alkaline-earth coordination polymers based on the ligand 2-(1H-benzotriazol-1-yl) acetic acid: Effects the radius of metal ions on structures and properties20Cu3I7 Trimer and Cu4I8 Tetramer Based Cuprous Iodide Polymorphs for Efficient Photocatalysis and Luminescent Sensing: Unveiling Possible Hierarchical Assembly Mechanism101Polymorph Control of Luminescence Properties in Molecular Crystals of a Platinum and Organoarsenic Complex and Formation of Stable One-Dimensional Nanochannel27Cationic zinc (II) dimers and one dimensional coordination polymer from ionic carboxylic acid10Encapsulation of Various Guests by an Anionic In-Metal–Organic Framework Containing Tritopic BTB Ligand: Crystal Structure of Reichardt’s Dye Captured in an In-Metal–Organic Framework31The ionothermal synthesis, structure, and magnetism–structure relationship of two biphenyl tetracarboxylic acid-based metal–organic frameworks16Single-crystal growth of coordination networks via the gas phase and dependence of iodine encapsulation on the crystal size11Synthesis, Characterization and Antibacterial Properties of Nano-Porous Zn3(BTC)2·12H2O upon Silk Yarn Under Ultrasound Irradiation16Iodine and Halogen Bonding17Structural diversity of five new bitriazole-based complexes: luminescence, sorption, and magnetic properties71Synthesis of conjugated microporous polymer nanotubes with large surface areas as absorbents for iodine and CO 2 uptake227Thermally Robust 3-D Co-DpyDtolP-MOF with Hexagonally Oriented Micropores: Formation of Polyiodine Chains in a MOF Single Crystal48Highly Efficient Iodine Capture by Layered Double Hydroxides Intercalated with Polysulfides161Valence tautomerism and photodynamics observed in a dinuclear cobalt-tetraoxolene compound11Synthesis, structural versatility and magnetic properties of a series of copper( ii ) coordination polymers based on bipyrazole and various dicarboxylate ligands28Heterometallic transition metal clusters and cluster-supported coordination polymers derived from Tp- and Tp*-based Mo(W) sulfido precursors72Assembly of a Three-Dimensional Metal–Organic Framework with Copper(I) Iodide and 4-(Pyrimidin-5-yl) Benzoic Acid: Controlled Uptake and Release of Iodine62A stable metal–organic framework with suitable pore sizes and rich uncoordinated nitrogen atoms on the internal surface of micropores for highly efficient CO 2 capture90Coordination assemblies of seven metal-organic frameworks based on a bent connector: structural diversity and properties21Luminescent silver( i ) coordination architectures containing 2-aminopyrimidyl ligands36New luminescent porous coordination polymers with an acylamide-decorated linker for anion recognition and reversible I 2 accommodation13Raman spectroscopy study of new thia- and oxazinoquinolinium triodides44Recent advances in metal–organic frameworks based on pyridylbenzoate ligands: properties and applications19Solvent-controlled three families of Zn( ii ) coordination compounds: synthesis, crystal structure, solvent-induced structural transformation, supramolecular isomerism and photoluminescence81Structural diversity of coordination polymers controlled by the metal ion as the sole reaction variable14Syntheses, structures, gas adsorption and reversible iodine adsorption of two porous Cu( ii ) MOFs19Synthesis, structures, and theoretical investigation of three polyoxomolybdate-based compounds: self-assembly, fragment analysis, orbital interaction, and formation mechanism6Template controlled synthesis of cluster-based porous coordination polymers: crystal structure, magnetism and adsorption16The concept of mixed organic ligands in metal–organic frameworks: design, tuning and functions294Semi-rigid imidazolium carboxylate controlled structural topologies in zwitterionic coordination networks14Porous Supramolecular Networks Constructed of One-Dimensional Metal–Organic Chains: Carbon Dioxide and Iodine Capture74Reversible flexible structural changes in multidimensional MOFs by guest molecules (I2, NH3) and thermal stimulation11

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  4. Layer by layer growth of nano porous lead(ii) coordination polymer on natural silk fibers and its application in removal and recovery of iodide

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