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RESEARCH PAPER · Inorganic Chemistry · 2008

An Open-Framework Thorium Sulfate Hydrate with 11.5 Å Voids

Richard E. Wilson, S. Skanthakumar, Karah E. Knope, Christopher L. Cahill, L. Soderholm

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An Open-Framework Thorium Sulfate Hydrate with 11.5 Å VoidsOriginalChemInform Abstract: An Open‐Framework Thorium Sulfate Hydrate with 11.5 Å Voids.0NDTB‐1: A Supertetrahedral Cationic Framework That Removes TcO4− from Solution270NDTB‐1: A Supertetrahedral Cationic Framework That Removes TcO4− from Solution37Amine templated two- and three-dimensional uranyl sulfates24Crystal chemistry of thorium nitrates and chromates23Actinyl Compounds with Hexavalent Elements (S, Cr, Se, Mo) – Structural Diversity, Nanoscale Chemistry, and Cellular Automata Modeling69Technetium‐99 MAS NMR Spectroscopy of a Cationic Framework Material that Traps TcO4− Ions57Technetium‐99 MAS NMR Spectroscopy of a Cationic Framework Material that Traps TcO4− Ions11A Slow Leak Synthetic Route to Organically Templated Gallium Sulfates8Advances in actinide solid-state and coordination chemistry37Recent progress in actinide borate chemistry94Synthesis, characterization and magnetic properties of four new organically templated metal sulfates [C5H14N2][MII(H2O)6](SO4)2, (MII = Mn, Fe, Co, Ni)35Th3(SO4)6(H2O)6∙H2O0Metal Cation Induced Modulation of the Photophysical Properties of a Platinum(II) Complex Featuring a Dipicolylanilino–Acetylide Ligand21The crystal chemistry of four thorium sulfates28Structural Periodicity in Plutonium(IV) Sulfates29Synthesis and Characterization of Thorium(IV) Sulfates39Selectivity, Kinetics, and Efficiency of Reversible Anion Exchange with TcO4− in a Supertetrahedral Cationic Framework176Two Unusual Chiral Lanthanide–Sulfate Frameworks with Helical Tubes and Channels Constructed from Interweaving Two Double-Helical Chains26Uranium(IV) Sulfates: Investigating Structural Periodicity in the Tetravalent Actinides26Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products372Comparisons of Plutonium, Thorium, and Cerium Tellurite Sulfates41The structural transformation of monoclinic [(R)-C5H14N2][Cu(SO4)2(H2O)4]·2H2O into orthorhombic [(R)-C5H14N2]2[Cu(H2O)6](SO4)3: crystal structures and thermal behavior3A novel nonanuclear hafnium oxide–hydroxide–sulphate cluster crystallised from aqueous solution29Exploring Actinide Materials Through Synchrotron Radiation Techniques104Remarkable Selectivity and Photo‐Cytotoxicity of an Oxidovanadium(IV) Complex of Curcumin in Visible Light35Organically templated linear metal sulfites2In Situ Hydrothermal Synthesis, Crystal Structure, and Properties of a New Inorganic Holmium–Sulfate Coordination Polymer0Insights into the new Th (IV) sulfate fluoride complex: Synthesis, crystal structures, and temperature dependent spectroscopic properties8Th3[Th6(OH)4O4(H2O)6](SO4)12(H2O)13: A Self-Assembled Microporous Open-Framework Thorium Sulfate32Thorium coordination: A comprehensive review based on coordination number96Inorganic Synthesis of Actinides3Linking Solution Structures and Energetics: Thorium Nitrate Complexes17Probing the Influence of Acidity and Temperature to Th(IV) on Hydrolysis, Nucleation, and Structural Topology16Complex Inorganic Actinide Materials1Exploring Actinide Materials through Synchrotron Radiation Techniques4In Situ Reduction from Uranyl Ion into a Tetravalent Uranium Trimer and Hexamer Featuring Ion-Exchange Properties and the Alexandrite Effect16Thorium Oxo‐Clusters as Building Blocks for Open Frameworks37Thermochemical study of tetravalent metal sulfate tetrahydrates: A4+(SO4)2(H2O)4 (A4+ = Zr, Ce, U)4Compréhension des phénomènes d’hydratation et de déshydratation de composés d’actinides0Unexpected Roles of Alkali-Metal Cations in the Assembly of Low-Valent Uranium Sulfate Molecular Complexes15Structural Variations in Complex Sodium Thorium Arsenates9

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  1. ChemInform Abstract: An Open‐Framework Thorium Sulfate Hydrate with 11.5 Å Voids.

    ChemInform · 2008-12-12

    Richard E. Wilson, S. Skanthakumar, Karah E. Knope, Christopher L. Cahill, L. Soderholm

    Read original paper ↗ ·

  2. NDTB‐1: A Supertetrahedral Cationic Framework That Removes TcO4− from Solution

    Angewandte Chemie International Edition · 2009-12-28

    Shuao Wang, Evgeny V. Alekseev, Juan Diwu, William H. Casey, Brian L. Phillips, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  3. NDTB‐1: A Supertetrahedral Cationic Framework That Removes TcO4− from Solution

    Angewandte Chemie · 2009-12-28

    Shuao Wang, Evgeny V. Alekseev, Juan Diwu, William H. Casey, Brian L. Phillips, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  4. Amine templated two- and three-dimensional uranyl sulfates

    Dalton Transactions · 2010-01-01

    Mohan Singh Bharara, Anne E. V. Gorden

    Read original paper ↗ ·

  5. Crystal chemistry of thorium nitrates and chromates

    Journal of Solid State Chemistry · 2010-05-06

    Ginger E. Sigmon, Peter Carman Burns

    Read original paper ↗ ·

  6. Actinyl Compounds with Hexavalent Elements (S, Cr, Se, Mo) – Structural Diversity, Nanoscale Chemistry, and Cellular Automata Modeling

    European Journal of Inorganic Chemistry · 2010-05-25

    Sergey V. Krivovichev

    Read original paper ↗ ·

  7. Technetium‐99 MAS NMR Spectroscopy of a Cationic Framework Material that Traps TcO4− Ions

    Angewandte Chemie International Edition · 2010-07-15

    Ping Yu, Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, David T Hobbs, Thomas E. Albrecht‐Schmitt, Brian L. Phillips, William H. Casey

    Read original paper ↗ ·

  8. Technetium‐99 MAS NMR Spectroscopy of a Cationic Framework Material that Traps TcO4− Ions

    Angewandte Chemie · 2010-07-15

    Ping Yu, Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, David T Hobbs, Thomas E. Albrecht‐Schmitt, Brian L. Phillips, William H. Casey

    Read original paper ↗ ·

  9. A Slow Leak Synthetic Route to Organically Templated Gallium Sulfates

    Crystal Growth & Design · 2010-09-08

    Elizabeth A. Kaufman, Mat­thias Zeller, Alexander J. Norquist

    Read original paper ↗ ·

  10. Advances in actinide solid-state and coordination chemistry

    MRS Bulletin · 2010-11-01

    Peter Carman Burns, Yasuhisa Ikeda, Ken Czerwinski

    Read original paper ↗ ·

  11. Recent progress in actinide borate chemistry

    Chemical Communications · 2011-01-01

    Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  12. Synthesis, characterization and magnetic properties of four new organically templated metal sulfates [C5H14N2][MII(H2O)6](SO4)2, (MII = Mn, Fe, Co, Ni)

    Dalton Transactions · 2011-01-01

    Fadhel Hajlaoui, Houcine Naı̈li, S. Yahyaoui, Mark M. Turnbull, Tahar Mhiri, Thierry Bataille B

    Read original paper ↗ ·

  13. Th3(SO4)6(H2O)6∙H2O

    Numerical data and functional relationships in science and technology. Group III, Condensed matter · 2011-01-01

    Pierre Villars, Karin CENZUAL, J.L.C. Daams, Roman E. GLADYSHEVSKII, O. Shcherban, Vitaly Dubenskyy, V. Kuprysyuk, Igor SAVYSYUK, R. Zaremba

    Read original paper ↗ ·

  14. Metal Cation Induced Modulation of the Photophysical Properties of a Platinum(II) Complex Featuring a Dipicolylanilino–Acetylide Ligand

    European Journal of Inorganic Chemistry · 2011-01-26

    Pierre‐Henri Lanoë, Jean‐Luc Fillaut, Véronique Guerchais, Hubert Le Bozec, J. A. Gareth Williams

    Read original paper ↗ ·

  15. The crystal chemistry of four thorium sulfates

    Journal of Solid State Chemistry · 2011-04-23

    Amanda J. Albrecht, Ginger E. Sigmon, L. Moore-Shay, Rebecca Wei, Colleen M. Dawes, Jennifer E. S. Szymanowski, Peter Carman Burns

    Read original paper ↗ ·

  16. Structural Periodicity in Plutonium(IV) Sulfates

    Inorganic Chemistry · 2011-05-18

    Richard E. Wilson

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  17. Synthesis and Characterization of Thorium(IV) Sulfates

    Inorganic Chemistry · 2011-08-03

    Karah E. Knope, Richard E. Wilson, S. Skanthakumar, L. Soderholm

    Read original paper ↗ ·

  18. Selectivity, Kinetics, and Efficiency of Reversible Anion Exchange with TcO4− in a Supertetrahedral Cationic Framework

    Advanced Functional Materials · 2012-03-20

    Shuao Wang, Ping Yu, Bryant A. Purse, Matthew J. Orta, Juan Diwu, William H. Casey, Brian L. Phillips, Evgeny V. Alekseev, Wulf Depmeier, David T Hobbs, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  19. Two Unusual Chiral Lanthanide–Sulfate Frameworks with Helical Tubes and Channels Constructed from Interweaving Two Double-Helical Chains

    Crystal Growth & Design · 2012-03-23

    Wen-Hua Wang, Han‐Rui Tian, Zhi-Chao Zhou, Yun‐Long Feng, Jian‐Wen Cheng

    Read original paper ↗ ·

  20. Uranium(IV) Sulfates: Investigating Structural Periodicity in the Tetravalent Actinides

    Inorganic Chemistry · 2012-08-21

    David D. Schnaars, Richard E. Wilson

    Read original paper ↗ ·

  21. Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products

    Chemical Reviews · 2012-10-29

    Karah E. Knope, L. Soderholm

    Read original paper ↗ ·

  22. Comparisons of Plutonium, Thorium, and Cerium Tellurite Sulfates

    Inorganic Chemistry · 2013-03-25

    Jian Hung Lin, Justin N. Cross, Juan Diwu, Nathan A. Meredith, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  23. The structural transformation of monoclinic [(R)-C5H14N2][Cu(SO4)2(H2O)4]·2H2O into orthorhombic [(R)-C5H14N2]2[Cu(H2O)6](SO4)3: crystal structures and thermal behavior

    Phase Transitions · 2013-05-23

    Salem Saïd, Noureddine Mhadhbi, Fadhel Hajlaoui, S. Yahyaoui, Alexander J. Norquist, Tahar Mhiri, Thierry Bataille B, Houcine Naı̈li

    Read original paper ↗ ·

  24. A novel nonanuclear hafnium oxide–hydroxide–sulphate cluster crystallised from aqueous solution

    Chemical Communications · 2013-11-29

    Ali Kalaji, L. Soderholm

    Read original paper ↗ ·

  25. Exploring Actinide Materials Through Synchrotron Radiation Techniques

    Advanced Materials · 2014-08-28

    Wei‐Qun Shi, Li‐Yong Yuan, Cong‐Zhi Wang, Lin Wang, Lei Mei, Chengliang Xiao, Li Zhang, Zi‐Jie Li, Yuliang Zhao, Zhifang Chai

    Read original paper ↗ ·

  26. Remarkable Selectivity and Photo‐Cytotoxicity of an Oxidovanadium(IV) Complex of Curcumin in Visible Light

    European Journal of Inorganic Chemistry · 2014-12-23

    Samya Banerjee, Akanksha Dixit, Anjali Anoop Karande, Akhil Ranjan Chakravarty

    Read original paper ↗ ·

  27. Organically templated linear metal sulfites

    RSC Advances · 2015-01-01

    Ranjay K. Tiwari, Jitendra Kumar, J. N. Behera

    Read original paper ↗ ·

  28. In Situ Hydrothermal Synthesis, Crystal Structure, and Properties of a New Inorganic Holmium–Sulfate Coordination Polymer

    Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry · 2015-02-10

    Zhao-Hao Li, Dong-Feng Hong, Sha Li, Lina Ning, Wenjing Feng

    Read original paper ↗ ·

  29. Insights into the new Th (IV) sulfate fluoride complex: Synthesis, crystal structures, and temperature dependent spectroscopic properties

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2015-04-25

    Yanyan Zhao, Chunxiang Wang, Jing Su, Yaxing Wang, Yanlong Wang, Shuao Wang, Juan Diwu, Zhi‐Hong Liu

    Read original paper ↗ ·

  30. Th3[Th6(OH)4O4(H2O)6](SO4)12(H2O)13: A Self-Assembled Microporous Open-Framework Thorium Sulfate

    Inorganic Chemistry · 2016-09-26

    Jian Hung Lin, Geng Bang Jin, L. Soderholm

    Read original paper ↗ ·

  31. Thorium coordination: A comprehensive review based on coordination number

    Coordination Chemistry Reviews · 2016-11-19

    Charmaine D. Tutson, Anne E. V. Gorden

    Read original paper ↗ ·

  32. Inorganic Synthesis of Actinides

    Elsevier eBooks · 2017-01-01

    Wei‐Qun Shi, L. Mei, Zhifang Chai

    Read original paper ↗ ·

  33. Linking Solution Structures and Energetics: Thorium Nitrate Complexes

    The Journal of Physical Chemistry B · 2017-08-17

    S. Skanthakumar, Geng Bang Jin, Jian Hung Lin, Valérie Vallet, L. Soderholm

    Read original paper ↗ ·

  34. Probing the Influence of Acidity and Temperature to Th(IV) on Hydrolysis, Nucleation, and Structural Topology

    Inorganic Chemistry · 2017-11-08

    Jian Hung Lin, Meiying Qie, Linjuan Zhang, Xiaomei Wang, Yue‐Jian Lin, Wei Liu, Hongliang Bao, Jian‐Qiang Wang

    Read original paper ↗ ·

  35. Complex Inorganic Actinide Materials

    Unknown journal · 2018-01-12

    Matthew L. Marsh, Thomas E. Albrecht‐Schmitt

    Read original paper ↗ ·

  36. Exploring Actinide Materials through Synchrotron Radiation Techniques

    Unknown journal · 2018-02-16

    Wei‐Qun Shi, Li‐Yong Yuan, Cong‐Zhi Wang, Lin Wang, Lei Mei, Chengliang Xiao, Li Zhang, Zi‐Jie Li, Yuliang Zhao, Zhifang Chai

    Read original paper ↗ ·

  37. In Situ Reduction from Uranyl Ion into a Tetravalent Uranium Trimer and Hexamer Featuring Ion-Exchange Properties and the Alexandrite Effect

    Inorganic Chemistry · 2018-05-24

    Jian Hung Lin, Zenghui Yue, Mark A. Silver, Meiying Qie, Xiaomei Wang, Wei Liu, Xiao Lin, Hongliang Bao, Linjuan Zhang, Shuao Wang, Jian‐Qiang Wang

    Read original paper ↗ ·

  38. Thorium Oxo‐Clusters as Building Blocks for Open Frameworks

    Chemistry - A European Journal · 2018-07-10

    Clément Falaise, Károly Kozma, May Nyman

    Read original paper ↗ ·

  39. Thermochemical study of tetravalent metal sulfate tetrahydrates: A4+(SO4)2(H2O)4 (A4+ = Zr, Ce, U)

    Journal of Solid State Chemistry · 2019-04-25

    Lei Zhang, Haylie L. Lobeck, Ewa A. Dzik, Ginger E. Sigmon, Peter Carman Burns

    Read original paper ↗ ·

  40. Compréhension des phénomènes d’hydratation et de déshydratation de composés d’actinides

    Unknown journal · 2019-12-09

    Artem Belonosov

    Read original paper ↗ ·

  41. Unexpected Roles of Alkali-Metal Cations in the Assembly of Low-Valent Uranium Sulfate Molecular Complexes

    Inorganic Chemistry · 2020-02-04

    Zenghui Yue, Xiaofeng Guo, Mei‐Ling Feng, Yue‐Jian Lin, Yu Ju, Xiao Lin, Zhi‐Hui Zhang, Xiao-Jing Guo, Jian Hung Lin, Yuying Huang, Jian‐Qiang Wang

    Read original paper ↗ ·

  42. Structural Variations in Complex Sodium Thorium Arsenates

    European Journal of Inorganic Chemistry · 2020-07-28

    Yucheng Hao, Evgeny V. Alekseev, Vladislav V. Klepov, Na Yu

    Read original paper ↗ ·
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