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RESEARCH PAPER · Inorganic Chemistry · 2011

Metal–Organic-Framework-Type 1D-Channel Open Network of a Tetravalent Uranium Trimesate

Christophe Volkringer, Ionut Mihalcea, Jean‐François Vigier, A. Beaurain, Marc Visseaux, Thierry Loiseau

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Metal–Organic-Framework-Type 1D-Channel Open Network of a Tetravalent Uranium TrimesateOriginalSolution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products372Chiral uranyl-organic compounds assembled with achiral furandicarboxylic acid by spontaneous resolution45Three‐Dimensional MOF‐Type Architectures with Tetravalent Uranium Hexanuclear Motifs (U6O8)127Synthesis of Differently Substituted tacn‐Based Ligands: Towards the Control of Solubility and Electronic and Steric Properties of Uranium Coordination Complexes15Mixed Formate-Dicarboxylate Coordination Polymers with Tetravalent Uranium: Occurrence of Tetranuclear {U4O4} and Hexanuclear {U6O4(OH)4} Motifs66The crystal chemistry of uranium carboxylates394Isolation of the Large {Actinide}38 Poly-oxo Cluster with Uranium94Crystal structures of tetravalent uranium fluorides obtained in the presence of hydrazine from uranyl source7Redox and environmentally relevant aspects of actinide(IV) coordination chemistry113Room temperature crystallization of trichlorodioxouranate [UO2Cl3(L)] species in molecular assemblies involving aliphatic dicarboxylate linkers18A Novel Bismuth‐Based Metal–Organic Framework for High Volumetric Methane and Carbon Dioxide Adsorption80Coordination polymers of uranium( iv ) terephthalates42A family of 3D UO 2 2+ –5-X-1,3-dicarboxylate (X = –H, –NO 2 , –NH 2 , –OH) hybrid materials: structural relevance with variation of substituent groups and photochemical properties29B-α-[AsW 9 O 33 ] 9− polyoxometalates incorporating hexanuclear uranium {U 6 O 8 }-like clusters bearing the U IV form or unprecedented mixed valence U IV /U VI involving direct U VI O–U IV bonding27Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System143Solvothermal Synthesis of Tetravalent Uranium with Isophthalate or Pyromellitate Ligands13Stabilization of Tetravalent 4f (Ce), 5d (Hf), or 5f (Th, U) Clusters by the [α-SiW 9 O 34 ] 10– Polyoxometalate49Ex‐Situ Kinetic Investigations of the Formation of the Poly‐Oxo Cluster U3827Etude du paramagnétisme des actinides en solution0Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers34Influence of the pH on the Condensation of Tetravalent Cerium Cations in Association with [α‐SiW9O34]10– Leading to the Formation of a Ce6O4(OH)4 Core17Inorganic Synthesis of Actinides3Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium34Thorium aspartate tetrahydrate precursor to ThO 2 : Comparison of hydrothermal and thermal conversions27U(IV) Aqueous Speciation from the Monomer to UO2 Nanoparticles: Two Levels of Control from Zwitterionic Glycine Ligands51Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters16Stress compensation in an extended series of lanthanide 2-sulfonatoterephthalates [Ln(TPSO3)(H2O)2]n (Ln = Ce − Lu, except Pm)11A mesoporous cationic thorium-organic framework that rapidly traps anionic persistent organic pollutants409Conversion of lanthanide glutarate chlorides with interstitial THF into lanthanide glutarates with unprecedented topologies5Synthèse et étude cristallochimique de carboxylates d'actinides tétravalents (Th, U, Np) : polymères de coordination et entités moléculaires à haute nucléarité0Actinide-based MOFs: a middle ground in solution and solid-state structural motifs110Anionic uranyl oxyfluorides as a bifunctional platform for highly selective ion-exchange and photocatalytic degradation of organic dyes13Formation of a new type of uranium( iv ) poly-oxo cluster {U 38 } based on a controlled release of water via esterification reaction44Molecular Assemblies of a Series of Mixed Tetravalent Uranium and Trivalent Lanthanide Complexes Associated with the Dipicolinate Ligand, in Aqueous Medium10In Situ Reduction from Uranyl Ion into a Tetravalent Uranium Trimer and Hexamer Featuring Ion-Exchange Properties and the Alexandrite Effect16Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates42Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc) 2 followed by the formation of molecular poly-oxo cluster {U 14 } containing hemimellitate uranium( iv )14Chemistry of Actinide Centers in Heterogeneous Catalytic Transformations of Small Molecules73Robust Corrole-Based Metal–Organic Frameworks with Rare 9-Connected Zr/Hf-Oxo Clusters120Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands34Solubilité et fluoration d’oxydes d’uranium en milieu liquide ionique0Two New Coordination Polymers with UO22+ Units and Fluorinated Aromatic Carboxylate Linkers3Unexpected Roles of Alkali-Metal Cations in the Assembly of Low-Valent Uranium Sulfate Molecular Complexes15A Redox-Innocent Uranium(IV)-Quinoid Metal-Organic Framework8Coordination Chemistry of Actinide Nitrates with Cyclic Amide Derivatives for the Development of the Nuclear Fuel Materials Selective Precipitation (NUMAP) Reprocessing Method15Isomerism in Benzenetricarboxylates: Variations in the Formation of Coordination Polymers with Uranyl Ion12Contrasting Structure-Directing Effects in the Uranyl–Phthalate/Isophthalate Isomer Systems19Conception et élaboration de matériaux hybrides à base d'oxydes d'uranium et de thorium0An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145Fluorite-like hydrolyzed hexanuclear coordination clusters of Zr(IV) and Hf(IV) with syn-syn bridging N,N,N-trimethylglycine in soft crystal structures exhibiting cold-crystallization8Characterization of a Hexanuclear Plutonium(IV) Nanostructure in an Acetate Solution via Visible–Near Infrared Absorption Spectroscopy, Extended X-ray Absorption Fine Structure Spectroscopy, and Density Functional Theory15Uranium(IV) and Thorium(IV) Coordination Polymers Based on Tritopic Carboxylic Acids2Ultrastarke Elektron‐Phonon‐Kopplung in Uran‐organischen Gerüstverbindungen führt zu einer inversen Temperaturabhängigkeit der Lumineszenz0Ultrastrong Electron‐Phonon Coupling in Uranium‐Organic Frameworks Leading to Inverse Luminescence Temperature Dependence13Engineered Sorbents for Selective Uranium Sequestration from Seawater22Connecting metal-organic framework synthesis to applications using multimodal machine learning40

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  1. Solution and Solid-State Structural Chemistry of Actinide Hydrates and Their Hydrolysis and Condensation Products

    Chemical Reviews · 2012-10-29

    Karah E. Knope, L. Soderholm

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  2. Chiral uranyl-organic compounds assembled with achiral furandicarboxylic acid by spontaneous resolution

    Chemical Communications · 2013-01-01

    Hao Wang, Ze Chang, Yue Li, Rongmei Wen, Xian‐He Bu

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  3. Three‐Dimensional MOF‐Type Architectures with Tetravalent Uranium Hexanuclear Motifs (U6O8)

    Chemistry - A European Journal · 2013-01-16

    Clément Falaise, Christophe Volkringer, Jean‐François Vigier, Natacha Henry, A. Beaurain, Thierry Loiseau

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  4. Synthesis of Differently Substituted tacn‐Based Ligands: Towards the Control of Solubility and Electronic and Steric Properties of Uranium Coordination Complexes

    European Journal of Inorganic Chemistry · 2013-04-03

    Alexey V. Nizovtsev, Andreas Scheurer, Boris Kosog, Frank W. Heinemann, Karsten Meyer

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  5. Mixed Formate-Dicarboxylate Coordination Polymers with Tetravalent Uranium: Occurrence of Tetranuclear {U4O4} and Hexanuclear {U6O4(OH)4} Motifs

    Crystal Growth & Design · 2013-06-19

    Clément Falaise, Christophe Volkringer, Thierry Loiseau

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  6. The crystal chemistry of uranium carboxylates

    Coordination Chemistry Reviews · 2013-09-08

    Thierry Loiseau, Ionut Mihalcea, Natacha Henry, Christophe Volkringer

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  7. Isolation of the Large {Actinide}38 Poly-oxo Cluster with Uranium

    Journal of the American Chemical Society · 2013-10-11

    Clément Falaise, Christophe Volkringer, Jean‐François Vigier, A. Beaurain, Pascal Roussel, Pierre Rabu, Thierry Loiseau

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  8. Crystal structures of tetravalent uranium fluorides obtained in the presence of hydrazine from uranyl source

    Journal of Fluorine Chemistry · 2014-01-03

    Jacob Olchowka, Christophe Volkringer, Natacha Henry, Thierry Loiseau

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  9. Redox and environmentally relevant aspects of actinide(IV) coordination chemistry

    Coordination Chemistry Reviews · 2014-01-08

    Louise S. Natrajan, Adam N. Swinburne, Michael B. Andrews, Simon Randall, S.L. Heath

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  10. Room temperature crystallization of trichlorodioxouranate [UO2Cl3(L)] species in molecular assemblies involving aliphatic dicarboxylate linkers

    Inorganic Chemistry Communications · 2014-03-16

    Ionut Mihalcea, Clément Falaise, Christophe Volkringer, Natacha Henry, Thierry Loiseau

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  11. A Novel Bismuth‐Based Metal–Organic Framework for High Volumetric Methane and Carbon Dioxide Adsorption

    Chemistry - A European Journal · 2014-05-14

    Mathew Savage, Sihai Yang⧫, Mikhail V. Suyetin, Elena Besley, William Lewis, Alexander J. Blake, Sarah A. Barnett, Martin W. Schröder

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  12. Coordination polymers of uranium( iv ) terephthalates

    Dalton Transactions · 2014-11-11

    Clément Falaise, Ayalew H. Assen, Ionut Mihalcea, Christophe Volkringer, Adel Mesbah, Nicolas Dacheux, Thierry Loiseau

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  13. A family of 3D UO 2 2+ –5-X-1,3-dicarboxylate (X = –H, –NO 2 , –NH 2 , –OH) hybrid materials: structural relevance with variation of substituent groups and photochemical properties

    CrystEngComm · 2015-01-01

    Xiang-Sheng Zhai, Wen-Gang Zhu, Wei Xu, Yajing Huang, Yue‐Qing Zheng

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  14. B-α-[AsW 9 O 33 ] 9− polyoxometalates incorporating hexanuclear uranium {U 6 O 8 }-like clusters bearing the U IV form or unprecedented mixed valence U IV /U VI involving direct U VI O–U IV bonding

    Dalton Transactions · 2015-01-01

    Sylvain Duval, Sophie Sobanska, Pascal Roussel, Thierry Loiseau

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  15. Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System

    Inorganic Chemistry · 2015-02-10

    Clément Falaise, Jean-Sébastien Charles, Christophe Volkringer, Thierry Loiseau

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  16. Solvothermal Synthesis of Tetravalent Uranium with Isophthalate or Pyromellitate Ligands

    European Journal of Inorganic Chemistry · 2015-05-27

    Clément Falaise, Jason Delille, Christophe Volkringer, Thierry Loiseau

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  17. Stabilization of Tetravalent 4f (Ce), 5d (Hf), or 5f (Th, U) Clusters by the [α-SiW 9 O 34 ] 10– Polyoxometalate

    Inorganic Chemistry · 2015-08-24

    Sylvain Duval, Sébastien Béghin, Clément Falaise, Xavier Trivelli, Pierre Rabu, Thierry Loiseau

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  18. Ex‐Situ Kinetic Investigations of the Formation of the Poly‐Oxo Cluster U38

    Chemistry - A European Journal · 2015-09-29

    Clément Falaise, Christophe Volkringer, Christoph Hennig, Thierry Loiseau

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  19. Etude du paramagnétisme des actinides en solution

    Unknown journal · 2015-11-19

    Matthieu Autillo

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  20. Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers

    Crystal Growth & Design · 2016-01-15

    Nicolas P. Martin, Christophe Volkringer, Clément Falaise, Natacha Henry, Thierry Loiseau

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  21. Influence of the pH on the Condensation of Tetravalent Cerium Cations in Association with [α‐SiW9O34]10– Leading to the Formation of a Ce6O4(OH)4 Core

    European Journal of Inorganic Chemistry · 2016-09-06

    Sylvain Duval, Xavier Trivelli, Pascal Roussel, Thierry Loiseau

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  22. Inorganic Synthesis of Actinides

    Elsevier eBooks · 2017-01-01

    Wei‐Qun Shi, L. Mei, Zhifang Chai

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  23. Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium

    Inorganic Chemistry · 2017-02-16

    Nicolas P. Martin, Juliane März, Christophe Volkringer, Natacha Henry, Christoph Hennig, Atsushi Ikeda‐Ohno, Thierry Loiseau

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  24. Thorium aspartate tetrahydrate precursor to ThO 2 : Comparison of hydrothermal and thermal conversions

    Journal of Nuclear Materials · 2017-02-23

    Nicolas Clavier, J. Maynadié, Adel Mesbah, J. Hidalgo, R. Lauwerier, G.I. Nkou Bouala, Sandra Parrès-Maynadié, Daniel J.M. Meyer, Nicolas Dacheux, Renaud Podor

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  25. U(IV) Aqueous Speciation from the Monomer to UO2 Nanoparticles: Two Levels of Control from Zwitterionic Glycine Ligands

    Inorganic Chemistry · 2017-05-16

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  26. Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters

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  27. Stress compensation in an extended series of lanthanide 2-sulfonatoterephthalates [Ln(TPSO3)(H2O)2]n (Ln = Ce − Lu, except Pm)

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  28. A mesoporous cationic thorium-organic framework that rapidly traps anionic persistent organic pollutants

    Nature Communications · 2017-11-01

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  29. Conversion of lanthanide glutarate chlorides with interstitial THF into lanthanide glutarates with unprecedented topologies

    Inorganica Chimica Acta · 2017-11-26

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  30. Synthèse et étude cristallochimique de carboxylates d'actinides tétravalents (Th, U, Np) : polymères de coordination et entités moléculaires à haute nucléarité

    Unknown journal · 2017-12-07

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  31. Actinide-based MOFs: a middle ground in solution and solid-state structural motifs

    Chemical Communications · 2018-01-01

    Ekaterina A. Dolgopolova, Allison M. Rice, Natalia B. Shustova

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  32. Anionic uranyl oxyfluorides as a bifunctional platform for highly selective ion-exchange and photocatalytic degradation of organic dyes

    Dalton Transactions · 2018-01-01

    Zenghui Yue, Jian Hung Lin, Mark A. Silver, Ling Han, Xiaoyun Li, Jing Zhou, Xiao-Jing Guo, Hongliang Bao, Yuying Huang, Jian‐Qiang Wang

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  33. Formation of a new type of uranium( iv ) poly-oxo cluster {U 38 } based on a controlled release of water via esterification reaction

    Chemical Science · 2018-01-01

    Nicolas P. Martin, Christophe Volkringer, Natacha Henry, Xavier Trivelli, Grégory Stoclet, Atsushi Ikeda‐Ohno, Thierry Loiseau

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  34. Molecular Assemblies of a Series of Mixed Tetravalent Uranium and Trivalent Lanthanide Complexes Associated with the Dipicolinate Ligand, in Aqueous Medium

    Crystal Growth & Design · 2018-03-02

    Nicolas P. Martin, Christophe Volkringer, Natacha Henry, Sylvain Duval, Dimitrije Mara, Rik Van Deun, Thierry Loiseau

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  35. In Situ Reduction from Uranyl Ion into a Tetravalent Uranium Trimer and Hexamer Featuring Ion-Exchange Properties and the Alexandrite Effect

    Inorganic Chemistry · 2018-05-24

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  36. Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates

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  37. Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc) 2 followed by the formation of molecular poly-oxo cluster {U 14 } containing hemimellitate uranium( iv )

    RSC Advances · 2019-01-01

    Maxime Dufaye, Nicolas P. Martin, Sylvain Duval, Christophe Volkringer, Atsushi Ikeda‐Ohno, Thierry Loiseau

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  38. Chemistry of Actinide Centers in Heterogeneous Catalytic Transformations of Small Molecules

    ACS Catalysis · 2019-04-10

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  39. Robust Corrole-Based Metal–Organic Frameworks with Rare 9-Connected Zr/Hf-Oxo Clusters

    Journal of the American Chemical Society · 2019-08-21

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  40. Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands

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  41. Solubilité et fluoration d’oxydes d’uranium en milieu liquide ionique

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  42. Two New Coordination Polymers with UO22+ Units and Fluorinated Aromatic Carboxylate Linkers

    Zeitschrift für anorganische und allgemeine Chemie · 2019-12-28

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  43. Unexpected Roles of Alkali-Metal Cations in the Assembly of Low-Valent Uranium Sulfate Molecular Complexes

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  44. A Redox-Innocent Uranium(IV)-Quinoid Metal-Organic Framework

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  45. Coordination Chemistry of Actinide Nitrates with Cyclic Amide Derivatives for the Development of the Nuclear Fuel Materials Selective Precipitation (NUMAP) Reprocessing Method

    European Journal of Inorganic Chemistry · 2020-07-22

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  46. Isomerism in Benzenetricarboxylates: Variations in the Formation of Coordination Polymers with Uranyl Ion

    Crystal Growth & Design · 2020-09-21

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  47. Contrasting Structure-Directing Effects in the Uranyl–Phthalate/Isophthalate Isomer Systems

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  48. Conception et élaboration de matériaux hybrides à base d'oxydes d'uranium et de thorium

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  49. An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application

    Coordination Chemistry Reviews · 2021-07-07

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  50. Fluorite-like hydrolyzed hexanuclear coordination clusters of Zr(IV) and Hf(IV) with syn-syn bridging N,N,N-trimethylglycine in soft crystal structures exhibiting cold-crystallization

    Inorganica Chimica Acta · 2021-09-17

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