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RESEARCH PAPER · Inorganic Chemistry · 2012

From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange

Weiting Yang, Hongyue Wu, Run-Xue Wang, Qing‐Jiang Pan, Zhong‐Ming Sun, Hongjie Zhang

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From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion ExchangeOriginalChiral uranyl-organic compounds assembled with achiral furandicarboxylic acid by spontaneous resolution45Mono- and dinuclear uranyl(VI) complexes with chiral Schiff base ligand30Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies75Two Systems of [DabcoH2]2+/[PipH2]2+–Uranyl–Oxalate Showing Reversible Crystal-to-Crystal Transformations Controlled by the Diammonium/Uranyl/Oxalate Ratios in Aqueous Solutions ([DabcoH2]2+ = 1,4-Diazabicyclo-[2.2.2]-octaneH2 and [PipH2]2+ = PiperazineH2)23Syntheses, structures and luminescent properties of two organic templated uranyl phosphonates18Syntheses and Structures of Uranyl Ethylenediphosphonates: From Layers to Elliptical Nanochannels33Flexible Diphosphonic Acids for the Isolation of Uranyl Hybrids with Heterometallic UVI═O—ZnII Cation–Cation Interactions34Synthesis, Structures, and Properties of Uranyl Hybrids Constructed by a Variety of Mono- and Polycarboxylic Acids70ZINC, CADMIUM AND LEAD DIPHOSPHONATES: SYNTHESES, STRUCTURES AND LUMINESCENT PROPERTIES AND THEIR POTENTIAL AS SOFT-OXOMETALATE PRECURSORS1Structure tuning of metal phosphonates: Syntheses, structures and characterizations of two new lead (II) trisphosphonates9Molecular and Polymeric Uranyl and Thorium Complexes with Sulfonate‐Containing Ligands33Isolation of a series of uranium organophosphinates11MOFs of Uranium and the Actinides95Syntheses, structures, luminescence and molecular recognition properties of four new cadmium carboxyphosphonates with 2D layered and 3D supramolecular structures36Structural Variation within Heterometallic Uranyl Hybrids Based on Flexible Alkyldiphosphonate Ligands40Three New Silver Uranyl Diphosphonates: Structures and Properties23Postsynthetic Rearrangement/Metalation as a Route to Bimetallic Uranyl Coordination Polymers: Syntheses, Structures, and Luminescence70Tuning the structure of metal phosphonates using uncoordinating methyl group: syntheses, structures and properties of a series of metal diphosphonates22A new organically templated open-framework uranyl ethylenediphosphonate6Photocatalytic Application of 4f–5f Inorganic–Organic Frameworks: Influence of Lanthanide Contraction on the Structure and Functional Properties of a Series of Uranyl–Lanthanide Complexes34CuPYDC Metalloligands and Postsynthetic Rearrangement/Metalation as Routes to Bimetallic Uranyl Containing Hybrid Materials: Syntheses, Structures, and Fluorescence37Two new two-dimensional layered uranyl-bearing polycarboxylates from semi-rigid tetracarboxylic acids15Investigation of the structure variation of metal diphosphonates with the changing of N-donor auxiliary ligands and their properties12Five solvent-induced cadmium coordination polymers (CPs) based on the same mixed ligands58Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers46A family of 3D UO 2 2+ –5-X-1,3-dicarboxylate (X = –H, –NO 2 , –NH 2 , –OH) hybrid materials: structural relevance with variation of substituent groups and photochemical properties29Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Two novel uranyl complexes of a semi-rigid aromatic tetracarboxylic acid supported by an organic base as an auxiliary ligand or a templating agent: an experimental and theoretical exploration16Hybrid Materials Based on Multifunctional Phosphonic Acids4Probing the Influence of Phosphonate Bonding Modes to Uranium(VI) on Structural Topology and Stability: A Complementary Experimental and Computational Investigation51Multidimensional (0D to 3D) Alkaline-Earth Metal Diphosphonates: Synthesis, Structural Diversity, and Luminescence Properties17Structural chemistry of uranium phosphonates143Tetranuclear Uranyl Polyrotaxanes: Preferred Selectivity toward Uranyl Tetramer for Stabilizing a Flexible Polyrotaxane Chain Exhibiting Weakened Supramolecular Inclusion28Structural and spectroscopic characterization of two new layered uranyl(VI) p-xylenediphosphonate compounds synthesized via ionothermal method13Multifunctional Uranyl Hybrid Materials: Structural Diversities as a Function of pH, Luminescence with Potential Nitrobenzene Sensing, and Photoelectric Behavior as p-type Semiconductors56Three Metal(II) Diphosphonates with d 10 Electron Configuration: Structural, Fluorescent and Electrochemical Studies4Silver Ion-Mediated Heterometallic Three-Fold Interpenetrating Uranyl–Organic Framework52First three-dimensional actinide polyrotaxane framework mediated by windmill-like six-connected oligomeric uranyl: dual roles of the pseudorotaxane precursor19Metal–organic coordination architectures of bis(N-imidazolyl) pyridazine: Syntheses, structures, emission and photocatalytic properties16Synthesis, structure, luminescence and photocatalytic properties of an uranyl-2,5-pyridinedicarboxylate coordination polymer32Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework31Construction of Uranyl Organic Hybrids by Phosphonate and in Situ Generated Carboxyphosphonate Ligands39A new uranyl triphosphonate constructed from semi-rigid triphosphonate ligand: New method for the construction of higher dimensional uranyl phosponates6Exploring New Assembly Modes of Uranyl Terephthalate: Templated Syntheses and Structural Regulation of a Series of Rare 2D → 3D Polycatenated Frameworks39Two new uranyl complexes as visible light driven photocatalysts for degradation of tetracycline14Novel Viologen Derivative Based Uranyl Coordination Polymers Featuring Photochromic Behaviors61Fabrication of New Uranyl Phosphonates by Varying Quaternary Ammonium Cation: Synthesis, Structure, Luminescent Properties, and Single-Crystal to Single-Crystal Transformation18Li 6 Na 3 Sr 14 Al 11 P 22 O 90 : an oxo-centered Al 3 cluster based phosphate constructed from two types of (3,6)-connected kgd layers7An easily synthesized microporous framework material for the selective capture of radioactive Cs + and Sr 2+ ions119Construction of uranyl phosphonates from multifunctional zwitterionic ligands6Porous Anionic Uranyl–Organic Networks for Highly Efficient Cs + Adsorption and Investigation of the Mechanism88A supramolecular uranyl phosphonate [BTEA]2[(UO2)2(1,3-pbpH2)2F2]: Synthesis, structure, and spectroscopic characterization8Conformational 2-Fold Interpenetrated Uranyl Supramolecular Isomers Based on (6,3) Sheet Topology: Structure, Luminescence, and Ion Exchange37Structural Tuning and Sensitization of Uranyl Phosphonates by Incorporation of Countercations into the Framework16Various Silver Phosphinate Inorganic Architectures in Three-Dimensional Frameworks with Argentophilic Interactions17Two uranyl-copper(II) bimetallic coordination polymers containing trans-3,3(pyridyl)acrylic acid: Structural variance through synthetic subtleties9Metal‐Carboxyl Helical Chain Secondary Units Supported Ion‐Exchangeable Anionic Uranyl–Organic Framework15The role of 1-ethyl-3-methylimidazolium diethyl phosphate ionic liquid in uranyl phosphate compounds7A highly stable polyoxovanadate-based Cu( i )–MOF for the carboxylative cyclization of CO 2 with propargylic alcohols at room temperature72A novel polyoxovanadate-based Co-MOF: highly efficient and selective oxidation of a mustard gas simulant by two-site synergetic catalysis82The presence of mixed-valent silver in the uranyl phenylenediphosphonate framework5Investigation on Three Dimensional Hybrid Organic–Inorganic β-ZnTe(en)0.5 Flowerlike Structures and Corresponding Mesoporous PbTe Flowerlike Microcrystals3Uranyl Phosphonates with Multiple Uranyl Coordination Geometries and Low Temperature Phase Transition14Variability of Uranyl Carboxylates from Rigid Terophenyldicarboxylic Acid Ligands17Controlling the secondary assembly of porous anionic uranyl–organic polyhedra through organic cationic templates5Hollow Lindqvist-like-Shaped {V6} Cluster-Based Metal–Organic Framework for the Highly Efficient Detoxification of Mustard Gas Simulant56Robust and Flexible Thioantimonate Materials for Cs+ Remediation with Distinctive Structural Transformation: A Clear Insight into the Ion-Exchange Mechanism28Structural and electronic properties of the metal cluster‐based compounds including high concentration of solvent molecules53D Uranyl Organic Frameworks Supported by Rigid Octadentate Carboxylate Ligand: Synthesis, Structure Diversity, and Luminescence Properties8Controllable Synthesis of Mesoporous Cu7Te4 Flowerlike Structures by Cation-Exchange Method and Their Thermoelectric Properties3State-of-the-art progress for the selective crystallization of actinides, synthesis of actinide compounds and their functionalization20Lanthanide–uranyl phosphonates constructed from diethyl ((phenylsulfonyl)methyl)phosphonate4A 3D uranyl phosphonate framework: Structure, characterization, and fluorescence performance6Regulating the Porosity of Uranyl Phosphonate Frameworks with Quaternary Ammonium: Structure, Characterization, and Fluorescent Temperature Sensors11Unique porous framework constructed by uranyl phosphonate with high structural stability and preferential ion exchange capacity2Structural variation in Uranyl-Phosphonate networks utilizing tetrahedral Silicon-Centered phosphonate linkers2Layered metal phosphonates: Structures and properties7Mild Hydrothermal Crystal Growth of Two Luminescing Uranyl Phosphates Exhibiting an Autunite-Type Sheet Structure3MOFClassifier: A Machine Learning Approach for Validating Computation-Ready Metal–Organic Frameworks17Alkali Metal-Directed Assembly and Structural Characterization of Layered Uranyl Tetrakisphosphonates2Porous and functional metal phosphonate frameworks0

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  1. Chiral uranyl-organic compounds assembled with achiral furandicarboxylic acid by spontaneous resolution

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  2. Mono- and dinuclear uranyl(VI) complexes with chiral Schiff base ligand

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  3. Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies

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  4. Two Systems of [DabcoH2]2+/[PipH2]2+–Uranyl–Oxalate Showing Reversible Crystal-to-Crystal Transformations Controlled by the Diammonium/Uranyl/Oxalate Ratios in Aqueous Solutions ([DabcoH2]2+ = 1,4-Diazabicyclo-[2.2.2]-octaneH2 and [PipH2]2+ = PiperazineH2)

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  5. Syntheses, structures and luminescent properties of two organic templated uranyl phosphonates

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  6. Syntheses and Structures of Uranyl Ethylenediphosphonates: From Layers to Elliptical Nanochannels

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  7. Flexible Diphosphonic Acids for the Isolation of Uranyl Hybrids with Heterometallic UVI═O—ZnII Cation–Cation Interactions

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  8. Synthesis, Structures, and Properties of Uranyl Hybrids Constructed by a Variety of Mono- and Polycarboxylic Acids

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  9. ZINC, CADMIUM AND LEAD DIPHOSPHONATES: SYNTHESES, STRUCTURES AND LUMINESCENT PROPERTIES AND THEIR POTENTIAL AS SOFT-OXOMETALATE PRECURSORS

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  10. Structure tuning of metal phosphonates: Syntheses, structures and characterizations of two new lead (II) trisphosphonates

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  11. Molecular and Polymeric Uranyl and Thorium Complexes with Sulfonate‐Containing Ligands

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  12. Isolation of a series of uranium organophosphinates

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  13. MOFs of Uranium and the Actinides

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  14. Syntheses, structures, luminescence and molecular recognition properties of four new cadmium carboxyphosphonates with 2D layered and 3D supramolecular structures

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  15. Structural Variation within Heterometallic Uranyl Hybrids Based on Flexible Alkyldiphosphonate Ligands

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  16. Three New Silver Uranyl Diphosphonates: Structures and Properties

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  17. Postsynthetic Rearrangement/Metalation as a Route to Bimetallic Uranyl Coordination Polymers: Syntheses, Structures, and Luminescence

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  18. Tuning the structure of metal phosphonates using uncoordinating methyl group: syntheses, structures and properties of a series of metal diphosphonates

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  19. A new organically templated open-framework uranyl ethylenediphosphonate

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  20. Photocatalytic Application of 4f–5f Inorganic–Organic Frameworks: Influence of Lanthanide Contraction on the Structure and Functional Properties of a Series of Uranyl–Lanthanide Complexes

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  21. CuPYDC Metalloligands and Postsynthetic Rearrangement/Metalation as Routes to Bimetallic Uranyl Containing Hybrid Materials: Syntheses, Structures, and Fluorescence

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  22. Two new two-dimensional layered uranyl-bearing polycarboxylates from semi-rigid tetracarboxylic acids

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  23. Investigation of the structure variation of metal diphosphonates with the changing of N-donor auxiliary ligands and their properties

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  24. Five solvent-induced cadmium coordination polymers (CPs) based on the same mixed ligands

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  25. Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers

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  32. Multidimensional (0D to 3D) Alkaline-Earth Metal Diphosphonates: Synthesis, Structural Diversity, and Luminescence Properties

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  33. Structural chemistry of uranium phosphonates

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  34. Tetranuclear Uranyl Polyrotaxanes: Preferred Selectivity toward Uranyl Tetramer for Stabilizing a Flexible Polyrotaxane Chain Exhibiting Weakened Supramolecular Inclusion

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  35. Structural and spectroscopic characterization of two new layered uranyl(VI) p-xylenediphosphonate compounds synthesized via ionothermal method

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  36. Multifunctional Uranyl Hybrid Materials: Structural Diversities as a Function of pH, Luminescence with Potential Nitrobenzene Sensing, and Photoelectric Behavior as p-type Semiconductors

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  37. Three Metal(II) Diphosphonates with d 10 Electron Configuration: Structural, Fluorescent and Electrochemical Studies

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  38. Silver Ion-Mediated Heterometallic Three-Fold Interpenetrating Uranyl–Organic Framework

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  39. First three-dimensional actinide polyrotaxane framework mediated by windmill-like six-connected oligomeric uranyl: dual roles of the pseudorotaxane precursor

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  41. Synthesis, structure, luminescence and photocatalytic properties of an uranyl-2,5-pyridinedicarboxylate coordination polymer

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  42. Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework

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  43. Construction of Uranyl Organic Hybrids by Phosphonate and in Situ Generated Carboxyphosphonate Ligands

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  44. A new uranyl triphosphonate constructed from semi-rigid triphosphonate ligand: New method for the construction of higher dimensional uranyl phosponates

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  45. Exploring New Assembly Modes of Uranyl Terephthalate: Templated Syntheses and Structural Regulation of a Series of Rare 2D → 3D Polycatenated Frameworks

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  46. Two new uranyl complexes as visible light driven photocatalysts for degradation of tetracycline

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  47. Novel Viologen Derivative Based Uranyl Coordination Polymers Featuring Photochromic Behaviors

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  48. Fabrication of New Uranyl Phosphonates by Varying Quaternary Ammonium Cation: Synthesis, Structure, Luminescent Properties, and Single-Crystal to Single-Crystal Transformation

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  49. Li 6 Na 3 Sr 14 Al 11 P 22 O 90 : an oxo-centered Al 3 cluster based phosphate constructed from two types of (3,6)-connected kgd layers

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  50. An easily synthesized microporous framework material for the selective capture of radioactive Cs + and Sr 2+ ions

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