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RESEARCH PAPER · Angewandte Chemie International Edition · 2009

NDTB‐1: A Supertetrahedral Cationic Framework That Removes TcO4− from Solution

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NDTB‐1: A Supertetrahedral Cationic Framework That Removes TcO4− from SolutionOriginalCubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials113Further insights into intermediate- and mixed-valency in neptunium oxoanion compounds: structure and absorption spectroscopy of K2[(NpO2)3B10O16(OH)2(NO3)2]52Two cationic metal–organic frameworks based on cadmium and α,ω-alkanedisulfonate anions and their photoluminescent properties15How are Centrosymmetric and Noncentrosymmetric Structures Achieved in Uranyl Borates?52ChemInform Abstract: NDTB‐1: A Supertetrahedral Cationic Framework that Removes TcO4‐ from Solution.0Reversible Anion Exchange and Catalytic Properties of Two Cationic Metal−Organic Frameworks Based on Cu(I) and Ag(I)279Crystal chemistry of thorium nitrates and chromates23Comparison of Thorium(IV) and Uranium(VI) Carboxyphosphonates80Crystal Chemistry of the Potassium and Rubidium Uranyl Borate Families Derived from Boric Acid Fluxes49Yb3O(OH)6Cl·2H2O: An Anion-Exchangeable Hydroxide with a Cationic Inorganic Framework Structure69Technetium‐99 MAS NMR Spectroscopy of a Cationic Framework Material that Traps TcO4− Ions57Technetium‐99 MAS NMR Spectroscopy of a Cationic Framework Material that Traps TcO4− Ions11Synthesis, Structure, and Solid-State Transformation Studies of Phosphonoacetate Based Hybrid Compounds of Uranium and Thorium48Boronic Acid Flux Synthesis and Crystal Growth of Uranium and Neptunium Boronates and Borates: A Low-Temperature Route to the First Neptunium(V) Borate41Structure−Property Relationships in Lithium, Silver, and Cesium Uranyl Borates47Advances in actinide solid-state and coordination chemistry37From Minerals to Materials2Macrocyclic receptor for pertechnetate and perrhenate anions25Recent progress in actinide borate chemistry94Role of Anions and Reaction Conditions in the Preparation of Uranium(VI), Neptunium(VI), and Plutonium(VI) Borates56From Layered Structures to Cubic Frameworks: Expanding the Structural Diversity of Uranyl Carboxyphosphonates via the Incorporation of Cobalt55Surprising Coordination for Plutonium in the First Plutonium(III) Borate53Uranyl carboxyphosphonates that incorporate Cd(II)20K3Ln[OB(OH)2]2[HOPO3]2 (Ln=Yb, Lu): Layered rare-earth dihydrogen borate monohydrogen phosphates10K(NpO2)3(H2O)Cl4: A Channel Structure Assembled by Two- and Three-Center Cation–Cation Interactions of Neptunyl Cations23Functionalization of Borate Networks by the Incorporation of Fluoride: Syntheses, Crystal Structures, and Nonlinear Optical Properties of Novel Actinide Fluoroborates51Sr2[C6H3(CO2)3(NO3)]·DMF: One-Dimensional Nano-Channel in a New Non-Centrosymmetric Strontium–Organic Framework with High Thermal Stability31Structural Complexity of Barium Uranyl Arsenates: Synthesis, Structure, and Topology of Ba4[(UO2)2(As2O7)3], Ba3[(UO2)2(AsO4)2(As2O7)], and Ba5Ca[(UO2)8(AsO4)4O8]11Incorporation of iodate into uranyl borates and its implication for the immobilization of 129I in nuclear waste repositories10A New Paradigm for Anion Trapping in High Capacity and Selectivity: Crystal-to-Crystal Transformation of Cationic Materials279Bonding Changes in Plutonium(III) and Americium(III) Borates60Bonding Changes in Plutonium(III) and Americium(III) Borates12Copper Hydroxide Ethanedisulfonate: A Cationic Inorganic Layered Material for High‐Capacity Anion Exchange64Copper Hydroxide Ethanedisulfonate: A Cationic Inorganic Layered Material for High‐Capacity Anion Exchange15Immobilization, Trapping, and Anion Exchange of Perrhenate Ion Using Copper-Based Tripodal Complexes56Th2[BO4][PO4]: A RARE EXAMPLE OF AN ACTINIDE BORATE-PHOSPHATE9Interstitial Incorporation of Plutonium into a Low-Dimensional Potassium Borate6New Neptunium(V) Borates That Exhibit the Alexandrite Effect20Chiral uranium phosphonates constructed from achiral units with three-dimensional frameworks57Complex clover cross-sectioned nanotubules exist in the structure of the first uranium borate phosphate28Curium(III) Borate Shows Coordination Environments of Both Plutonium(III) and Americium(III) Borates49Curium(III) Borate Shows Coordination Environments of Both Plutonium(III) and Americium(III) Borates153-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials76Synthesis of Uranium Materials under Extreme Conditions: UO 2 [B 3 Al 4 O 11 (OH)], a Complex 3D Aluminoborate15Selectivity, Kinetics, and Efficiency of Reversible Anion Exchange with TcO4− in a Supertetrahedral Cationic Framework176Barium uranyl diphosphonates16Differentiating between Trivalent Lanthanides and Actinides115Relativistic Density Functional Study on Uranium(IV) and Thorium(IV) Oxide Clusters of Zonohedral Geometry13Anion Exchange of the Cationic Layered Material [Pb2F2]2+49A Cationic Antimonite Chain Templated by Sulfate: [Sb6O74+][(SO42–)2]9Tailor-Made Zinc Uranyl Diphosphonates from Layered to Framework Structures46Cerium(IV) Tellurite Halides [Ce2Te7O17]X2 (X = Cl– or Br–): The First Cerium-Containing Cationic Frameworks30Unusual Coordination for Plutonium(IV), Cerium(IV), and Zirconium(IV) in the Cationic Layered Materials [M2Te4O11]X2 (M = Pu, Ce, Zr; X = Cl, Br)29Bisactinyl halogenated complexes: relativistic density functional theory calculation and experimental synthesis9An unusual seven-connected lead borate constructed by different cluster building units of {B 6 } and {Pb 6 }19A New Family of Lanthanide Borate Halides with Unusual Coordination and a New Neodymium-Containing Cationic Framework14A Cationic Metal–Organic Solid Solution Based on Co(II) and Zn(II) for Chromate Trapping144Advances in Inorganic and Hybrid Ion Exchangers40High Structural Complexity of Potassium Uranyl Borates Derived from High-Temperature/High-Pressure Reactions32Facile Assembly of an Unusual Lead Borate with Different Cluster Building Units via a Hydrothermal Process38Novel Fundamental Building Blocks and Site Dependent Isomorphism in the First Actinide Borophosphates11High‐Pressure Synthesis and Characterization of the Actinide Borate Phosphate U2[BO4][PO4]15High‐Pressure Synthesis and Characterization of New Actinide Borates, AnB4O8 (An=Th, U)21Pb 4 Zn 2 B 10 O 21 : a congruently melting lead zinc borate with a novel [B 10 O 24 ] anionic group and an interesting [Pb 4 O 12 ] ∞ chain28MOFs of Uranium and the Actinides95Synthesis and characterisation of a new anion exchangeable layered hydroxyiodide4Two Cu-complex directed aluminoborates: from 2D layers to 3D frameworks16Unexpected Structural Complexity in Cesium Thorium Molybdates18Highly Distorted Uranyl Ion Coordination and One/Two-Dimensional Structural Relationship in the Ba2[UO2(TO4)2] (T = P, As) System: An Experimental and Computational Study19NaB3O5·0.5H2O and NH4NaB6O10: Two Cluster Open Frameworks with Chiral Quartz and Achiral Primitive Cubic Nets Constructed from Oxo Boron Cluster Building Units41Dynamic structural transformations of coordination supramolecular systems upon exogenous stimulation113Water-Stable Metal–Organic Frameworks for Fast and High Dichromate Trapping via Single-Crystal-to-Single-Crystal Ion Exchange314A new chiral uranyl phosphonate framework consisting of achiral building units generated from ionothermal reaction: structure and spectroscopy characterizations33Influence of extreme conditions on the formation and structures of caesium uranium( vi ) arsenates10Supramolecular inclusion-based molecular integral rigidity: a feasible strategy for controlling the structural connectivity of uranyl polyrotaxane networks46Further Insight into Uranium and Thorium Metaphosphate Chemistry and the Effect of Nd3+ Incorporation into Uranium(IV) Metaphosphate12Chemical and Structural Evolution in the Th–SeO 3 2– /SeO 4 2– System: from Simple Selenites to Cluster-Based Selenate Compounds29Erbium Hydroxide Ethanedisulfonate: A Cationic Layered Material with Organic Anion Exchange Capability15Applications of Supramolecular Anion Recognition1249PKU-3: An HCl-Inclusive Aluminoborate for Strecker Reaction Solved by Combining RED and PXRD40A Series of Aluminoborates Templated or Supported by Zinc–Amine Complexes51Boosting Proton Conductivity in Highly Robust 3D Inorganic Cationic Extended Frameworks through Ion Exchange with Dihydrogen Phosphate Anions19Creation of a new type of ion exchange material for rapid, high-capacity, reversible and selective ion exchange without swelling and entrainment103A new imidazolium-based polymeric ionic liquid gel with high adsorption capacity for perrhenate46Potassium uranyl borate 3D framework compound resulted from temperature directed hydroborate condensation: structure, spectroscopy, and dissolution studies7Removal of TcO 4 − ions from solution: materials and future outlook321Evaluation of f-element borate chemistry76Hydrolytically Stable Nanoporous Thorium Mixed Phosphite and Pyrophosphate Framework Generated from Redox-Active Ionothermal Reactions20Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs14Two-Dimensional Inorganic Cationic Network of Thorium Iodate Chloride with Unique Halogen–Halogen Bonds8Zirconium-Based Metal–Organic Framework for Removal of Perrhenate from Water206Removal of Pertechnetate‐Related Oxyanions from Solution Using Functionalized Hierarchical Porous Frameworks137Exfoliation of a two-dimensional cationic inorganic network as a new paradigm for high-capacity Cr VI -anion capture42Inorganic Synthesis of Actinides3Metal–organic frameworks for radionuclide sequestration from aqueous solution: a brief overview and outlook122Efficient and Selective Uptake of TcO 4 – by a Cationic Metal–Organic Framework Material with Open Ag + Sites415Extending Unique 1D Borate Chains to 3D Frameworks by Introducing Metallic Nodes44Exceptional Perrhenate/Pertechnetate Uptake and Subsequent Immobilization by a Low-Dimensional Cationic Coordination Polymer: Overcoming the Hofmeister Bias Selectivity217Efficient Removal of Anionic Radioactive Pollutant from Water Using Ordered Urea-Functionalized Mesoporous Polymeric Nanoparticle39Selenium Sequestration in a Cationic Layered Rare Earth Hydroxide: A Combined Batch Experiments and EXAFS Investigation118Porous Uranyl Borophosphates with Unique Three-Dimensional Open-Framework Structures36Identifying the Recognition Site for Selective Trapping of 99TcO4– in a Hydrolytically Stable and Radiation Resistant Cationic Metal–Organic Framework500Mild Periodic Acid Flux and Hydrothermal Methods for the Synthesis of Crystalline f-Element-Bearing Iodate Compounds20A mesoporous cationic thorium-organic framework that rapidly traps anionic persistent organic pollutants409Probing the Influence of Acidity and Temperature to Th(IV) on Hydrolysis, Nucleation, and Structural Topology16Synthesis and Study of the First Zeolitic Uranium Borate22Ultrastable, cationic three-dimensional lead bromide frameworks that intrinsically emit broadband white-light73Cationic two-dimensional inorganic networks of antimony oxide hydroxide for Lewis acid catalysis7Design and synthesis of metal hydroxide three-dimensional inorganic cationic frameworks1Metal–organic framework technologies for water remediation: towards a sustainable ecosystem480Metal–organic framework-based materials: superior adsorbents for the capture of toxic and radioactive metal ions1856Polymeric ionic liquid gels composed of hydrophilic and hydrophobic units for high adsorption selectivity of perrhenate35Structures and single crystal to single crystal transformations of cadmium frameworks using a flexible tripodal ligand6Towards high-efficiency sorptive capture of radionuclides in solution and gas149Efficient Capture of Perrhenate and Pertechnetate by a Mesoporous Zr Metal–Organic Framework and Examination of Anion Binding Motifs156A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions26Selective Anion Extraction and Recovery Using a FeII4L4 Cage148Selective Anion Extraction and Recovery Using a FeII4L4 Cage48Construction of uranyl phosphonates from multifunctional zwitterionic ligands6Efficient uptake of perrhenate/pertechnenate from aqueous solutions by the bifunctional anion-exchange resin120Recent advances about metal–organic frameworks in the removal of pollutants from wastewater611Covalent Organic Frameworks as a Decorating Platform for Utilization and Affinity Enhancement of Chelating Sites for Radionuclide Sequestration641Hydrothermal Synthesis, Study, and Classification of Microporous Uranium Silicates and Germanates18[Ag 2 M(Te 2 O 5 ) 2 ]SO 4 (M = Ce IV or Th IV ): A New Purely Inorganic d/f-Heterometallic Cationic Material12Unexpected Crystallographic Phase Transformation in Nonstoichiometric SrUO4–x: Reversible Oxygen Defect Ordering and Symmetry Lowering with Increasing Temperature18In Situ Reduction from Uranyl Ion into a Tetravalent Uranium Trimer and Hexamer Featuring Ion-Exchange Properties and the Alexandrite Effect16Immobilization of Alkali Metal Fluorides via Recrystallization in a Cationic Lamellar Material, [Th(MoO4)(H2O)4Cl]Cl·H2O3Thorium Oxo‐Clusters as Building Blocks for Open Frameworks37Rapid and selective capture of perrhenate anion from simulated groundwater by a mesoporous silica-supported anion exchanger9099TcO4− remediation by a cationic polymeric network361An inorganic-organic hybrid solid with B5O7(OH)3 clusters bridged and decorated by zinc–amine complexes1Formation of Open Framework Uranium Germanates: The Influence of Mixed Molten Flux and Charge Density Dependence in U-Silicate and U-Germanate Families19Quaternary Phosphonium Modified Hierarchically Macro/Mesoporous Silica for Fast Removal of Perrhenate32Actinides: Crystallography0Design Strategy for the Controlled Generation of Cationic Frameworks and Ensuing Anion-Exchange Capabilities15Construction of a cationic organic network for highly efficient removal of anionic contaminants from water34Expansion of the structural diversity of f-element bearing molybdate iodates: synthesis, structures, and optical properties19Li 2 Na 2 [B 12 O 19 (OH) 2 ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units8Mechanism unravelling for ultrafast and selective 99 TcO 4 − uptake by a radiation-resistant cationic covalent organic framework: a combined radiological experiment and molecular dynamics simulation study274Metal-organic frameworks for recognition and sequestration of toxic anionic pollutants9Performance of metal–organic frameworks for the adsorptive removal of potentially toxic elements in a water system: a critical review153Removal of toxic/radioactive metal ions by metal-organic framework-based materials20Ultra-highly selective trapping of perrhenate/pertechnetate by a flexible cationic coordination framework61Y 8 O(OH) 15 (CO 3 ) 3 Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework61Successful Decontamination of 99 TcO 4 − in Groundwater at Legacy Nuclear Sites by a Cationic Metal‐Organic Framework with Hydrophobic Pockets48Successful Decontamination of 99TcO4− in Groundwater at Legacy Nuclear Sites by a Cationic Metal‐Organic Framework with Hydrophobic Pockets267Opportunities of Porous Organic Polymers for Radionuclide Sequestration141A novel electroactive PPy/HKUST-1 composite film-coated electrode for the selective recovery of lithium ions with low concentrations in aqueous solutions65Anion-adaptive crystalline cationic material for 99TcO4− trapping138Optimizing radionuclide sequestration in anion nanotraps with record pertechnetate sorption206

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  1. Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials

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  2. Further insights into intermediate- and mixed-valency in neptunium oxoanion compounds: structure and absorption spectroscopy of K2[(NpO2)3B10O16(OH)2(NO3)2]

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  3. Two cationic metal–organic frameworks based on cadmium and α,ω-alkanedisulfonate anions and their photoluminescent properties

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  4. How are Centrosymmetric and Noncentrosymmetric Structures Achieved in Uranyl Borates?

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    Shuao Wang, Evgeny V. Alekseev, Jared T. Stritzinger, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  5. ChemInform Abstract: NDTB‐1: A Supertetrahedral Cationic Framework that Removes TcO4‐ from Solution.

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  6. Reversible Anion Exchange and Catalytic Properties of Two Cationic Metal−Organic Frameworks Based on Cu(I) and Ag(I)

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  7. Crystal chemistry of thorium nitrates and chromates

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  8. Comparison of Thorium(IV) and Uranium(VI) Carboxyphosphonates

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  9. Crystal Chemistry of the Potassium and Rubidium Uranyl Borate Families Derived from Boric Acid Fluxes

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  10. Yb3O(OH)6Cl·2H2O: An Anion-Exchangeable Hydroxide with a Cationic Inorganic Framework Structure

    Journal of the American Chemical Society · 2010-07-08

    Helen V. Goulding, Sarah E. Hulse, W. Clegg, Ross W. Harrington, Helen Y. Playford, Richard I. Walton, Andrew M. Fogg

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  11. Technetium‐99 MAS NMR Spectroscopy of a Cationic Framework Material that Traps TcO4− Ions

    Angewandte Chemie International Edition · 2010-07-15

    Ping Yu, Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, David T Hobbs, Thomas E. Albrecht‐Schmitt, Brian L. Phillips, William H. Casey

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  12. Technetium‐99 MAS NMR Spectroscopy of a Cationic Framework Material that Traps TcO4− Ions

    Angewandte Chemie · 2010-07-15

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  13. Synthesis, Structure, and Solid-State Transformation Studies of Phosphonoacetate Based Hybrid Compounds of Uranium and Thorium

    Inorganic Chemistry · 2010-07-27

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  14. Boronic Acid Flux Synthesis and Crystal Growth of Uranium and Neptunium Boronates and Borates: A Low-Temperature Route to the First Neptunium(V) Borate

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  15. Structure−Property Relationships in Lithium, Silver, and Cesium Uranyl Borates

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  16. Advances in actinide solid-state and coordination chemistry

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  17. From Minerals to Materials

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  18. Macrocyclic receptor for pertechnetate and perrhenate anions

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  19. Recent progress in actinide borate chemistry

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  20. Role of Anions and Reaction Conditions in the Preparation of Uranium(VI), Neptunium(VI), and Plutonium(VI) Borates

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  21. From Layered Structures to Cubic Frameworks: Expanding the Structural Diversity of Uranyl Carboxyphosphonates via the Incorporation of Cobalt

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  22. Surprising Coordination for Plutonium in the First Plutonium(III) Borate

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  23. Uranyl carboxyphosphonates that incorporate Cd(II)

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  24. K3Ln[OB(OH)2]2[HOPO3]2 (Ln=Yb, Lu): Layered rare-earth dihydrogen borate monohydrogen phosphates

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  25. K(NpO2)3(H2O)Cl4: A Channel Structure Assembled by Two- and Three-Center Cation–Cation Interactions of Neptunyl Cations

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  26. Functionalization of Borate Networks by the Incorporation of Fluoride: Syntheses, Crystal Structures, and Nonlinear Optical Properties of Novel Actinide Fluoroborates

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  27. Sr2[C6H3(CO2)3(NO3)]·DMF: One-Dimensional Nano-Channel in a New Non-Centrosymmetric Strontium–Organic Framework with High Thermal Stability

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  28. Structural Complexity of Barium Uranyl Arsenates: Synthesis, Structure, and Topology of Ba4[(UO2)2(As2O7)3], Ba3[(UO2)2(AsO4)2(As2O7)], and Ba5Ca[(UO2)8(AsO4)4O8]

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  29. Incorporation of iodate into uranyl borates and its implication for the immobilization of 129I in nuclear waste repositories

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  30. A New Paradigm for Anion Trapping in High Capacity and Selectivity: Crystal-to-Crystal Transformation of Cationic Materials

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  31. Bonding Changes in Plutonium(III) and Americium(III) Borates

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  32. Bonding Changes in Plutonium(III) and Americium(III) Borates

    Angewandte Chemie · 2011-08-18

    Matthew J. Polinski, Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  33. Copper Hydroxide Ethanedisulfonate: A Cationic Inorganic Layered Material for High‐Capacity Anion Exchange

    Angewandte Chemie International Edition · 2011-08-24

    Honghan Fei, Scott R. J. Oliver

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  34. Copper Hydroxide Ethanedisulfonate: A Cationic Inorganic Layered Material for High‐Capacity Anion Exchange

    Angewandte Chemie · 2011-08-24

    Honghan Fei, Scott R. J. Oliver

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  35. Immobilization, Trapping, and Anion Exchange of Perrhenate Ion Using Copper-Based Tripodal Complexes

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  36. Th2[BO4][PO4]: A RARE EXAMPLE OF AN ACTINIDE BORATE-PHOSPHATE

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  37. Interstitial Incorporation of Plutonium into a Low-Dimensional Potassium Borate

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  38. New Neptunium(V) Borates That Exhibit the Alexandrite Effect

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    Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  39. Chiral uranium phosphonates constructed from achiral units with three-dimensional frameworks

    Chemical Communications · 2012-01-01

    Juan Diwu, Thomas E. Albrecht‐Schmitt

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  40. Complex clover cross-sectioned nanotubules exist in the structure of the first uranium borate phosphate

    Chemical Communications · 2012-01-01

    Shijun Wu, Shuao Wang, Juan Diwu, Wulf Depmeier, Thomas Malcherek, Evgeny V. Alekseev, Thomas E. Albrecht‐Schmitt

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  41. Curium(III) Borate Shows Coordination Environments of Both Plutonium(III) and Americium(III) Borates

    Angewandte Chemie International Edition · 2012-01-13

    Matthew J. Polinski, Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, Guokui Liu, Richard Geoffrey Haire, Thomas E. Albrecht‐Schmitt

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  42. Curium(III) Borate Shows Coordination Environments of Both Plutonium(III) and Americium(III) Borates

    Angewandte Chemie · 2012-01-13

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  43. 3-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials

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    Hongyue Wu, Run-Xue Wang, Weiting Yang, Jinlei Chen, Zhong‐Ming Sun, Jun Li, Hongjie Zhang

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  44. Synthesis of Uranium Materials under Extreme Conditions: UO 2 [B 3 Al 4 O 11 (OH)], a Complex 3D Aluminoborate

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