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RESEARCH PAPER · Inorganic Chemistry · 2013

New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O22

Ying Wang, Shilie Pan, Xin Su, Zhihua Yang, Lingyun Dong, Min Zhang

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New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O22OriginalChemInform Abstract: New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4 and Noncentrosymmetric Rb4Mo5P2O22.0Exploring the influence of cationic skeletons on the arrangement of isolated BO 3 groups based on RbMgBO 3 , CsZn 4 (BO 3 ) 3 and Cs 4 Mg 4 (BO 3 ) 422Syntheses, structures and characterizations of Rb3Na(MO4)2 (M = Mo, W) crystals15The Effect of the Ratio of [M/(B+P)] on the Configuration of Anionic Groups: Synthesis of the Borate–Phosphate LiPb4(BO3)(PO4)215Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)31Three Alkali Metal Lead Orthophosphates – Syntheses, Crystal Structures and Properties of APbPO4 (A = K, Rb, Cs)20Synthesis, Crystal Structure, and Properties of the Sodium Molybdate Fluoride Na3MoO4F5Chiral polyoxomolybdate-based hybrid compounds obtained by spontaneous resolution: syntheses, structures and non-linear optical properties10Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A3B3CD2O14 Family148Syntheses, structural and characterizations of a new anhydrous mixed-metal phosphate1A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response384Introducing Chirality into Hybrid Clusters from an Achiral Ligand: Synthesis and Characterization of Polyoxomolybdates Containing a Benzylarsonate Group7(H 3 O)Ca 2 Zn 3.5 (PO 4 ) 4 and Ba 2 Cd 3 (PO 4 ) 2 (HPO 4 ) 2 : Syntheses, crystal structures and characterizations of two mixed metal phosphates12The enhancement of birefringence resulted from anionic dimensionality changes through adjusting cationic density14M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates16Li1.52Na4.48Cd8(PO4)2(P2O7)4: A new mixed-anion diphosphate containing four types of dimensions groups9Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24ALiZnP2O7 (A = Rb, Cs): Two Mixed Alkali Zinc Pyrophosphates Featuring a [Li2Zn2P4O20]14– Anionic Skeleton34Modulation of perovskite-related frameworks induced by alkaline earth metals in phosphate fluorides A 2 MPO 4 F (A = K, Rb; M = Ba, Ca)8Syntheses, structures, anomalous phase transition and optical properties of two new polymorphic α- and β-LiMoPO 611Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses67Further Example of Diphosphates: Synthesis and Characterization of K2Li2P2O72Syntheses, crystal structures, and characterizations of three new pyrophosphates CsNaZnP2O7, RbNaZnP2O7, and RbLiMgP2O710[NH4]12[(MoO2)2O(HPO4)2]4[PO4]Cl·0.5H2O: A mixed phosphomolybdate with nonlinear optical properties4Effets du molybdène dans les verres de phosphates : relations structure-propriétés0K 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups14Alignment of Polar Moieties Leading to Strong Second Harmonic Response in KCsMoP2O951Effect of Mo/P Ratios on Dimensions: Syntheses, Structures, and Properties of Three New Molybdophosphates10Chiral Template‐Driven Macroscopic Chirality Control: Structure‐Second‐Harmonic Generation Properties Relationship24K 2 ZnMoP 2 O 10 : a novel nonlinear optical molybdophosphate with a strong second harmonic generation response and moderate birefringence24RbMo 2 P 3 O 14 with large birefringence mainly induced by highly distorted [MoO 6 ] in uncommon [Mo 2 P 3 O 14 ] ∞ layers9A 6 Mo 2 P 4 O 19 (A = Rb, Cs) and Rb 2 MoP 2 O 9 : new molybdophosphates with distinct polyanionic configurations5K 2 MgMoP 2 O 10 and K 3 Mg 2 MoP 3 O 14 : two new molybdophosphates exhibiting different optical anisotropies induced by variable dimensionality of the anion framework4A new ultraviolet-transparent molybdate featuring a layered structure and moderate birefringence0Four noncentrosymmetric molybdophosphates discovered by a chemical substitution strategy4pH‐Regulated Ring‐Opening/Closing Transformation in Polyoxometalates Enables High‐Performance Nonlinear Optical Crystals1pH‐Regulated Ring‐Opening/Closing Transformation in Polyoxometalates Enables High‐Performance Nonlinear Optical Crystals14Ba 3 (MoO 2 F 3 )PO 4 F 2 : Rational Design and Synthesis of an Alkaline-Earth Phosphate Fluoride as a Birefringent Crystal1K 2 ZnMoP 2 O 10 : crystal growth, optical characterization, and structure–property insights into phase matching0

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  1. ChemInform Abstract: New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4 and Noncentrosymmetric Rb4Mo5P2O22.

    ChemInform · 2013-03-28

    Ying Wang, Shilie Pan, Xin Su, Zhihua Yang, Lingyun Dong, Min Zhang

    Read original paper ↗ ·

  2. Exploring the influence of cationic skeletons on the arrangement of isolated BO 3 groups based on RbMgBO 3 , CsZn 4 (BO 3 ) 3 and Cs 4 Mg 4 (BO 3 ) 4

    New Journal of Chemistry · 2014-01-01

    Zheng Wang, Min Zhang, Shilie Pan, Zhihua Yang, Hui Zhang, Bingbing Zhang, Ying Wang, Jing Kang, Xiaoxia Nina Lin

    Read original paper ↗ ·

  3. Syntheses, structures and characterizations of Rb3Na(MO4)2 (M = Mo, W) crystals

    Solid State Sciences · 2014-04-28

    Chunyan Bai, Lei Chen, Shilie Pan, Ying Wang, Zhihua Yang, Shujuan Han, Hongwei Yu, Yun Mo Yang, Fangyuan Zhang

    Read original paper ↗ ·

  4. The Effect of the Ratio of [M/(B+P)] on the Configuration of Anionic Groups: Synthesis of the Borate–Phosphate LiPb4(BO3)(PO4)2

    European Journal of Inorganic Chemistry · 2014-07-09

    Shengshi Huang, Hongwei Yu, Jian Wei Han, Shilie Pan, Qun Jing, Ying Wang, Lingyun Dong, Hongping Wu, Zhihua Yang, Xian Wang

    Read original paper ↗ ·

  5. Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)

    Dalton Transactions · 2015-01-01

    Shujuan Han, Ying Wang, Qun Jing, Hongping Wu, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·

  6. Three Alkali Metal Lead Orthophosphates – Syntheses, Crystal Structures and Properties of APbPO4 (A = K, Rb, Cs)

    European Journal of Inorganic Chemistry · 2015-02-18

    Shengshi Huang, Qun Jing, Jian Wei Han, Shilie Pan, Hongping Wu, Zhihua Yang

    Read original paper ↗ ·

  7. Synthesis, Crystal Structure, and Properties of the Sodium Molybdate Fluoride Na3MoO4F

    Zeitschrift für anorganische und allgemeine Chemie · 2015-03-20

    Xiangyu Zhang, Danni Li, Zhihua Yang, Hongping Wu, Shilie Pan

    Read original paper ↗ ·

  8. Chiral polyoxomolybdate-based hybrid compounds obtained by spontaneous resolution: syntheses, structures and non-linear optical properties

    New Journal of Chemistry · 2016-01-01

    Yujiao Hou, Haiyan An, Tieqi Xu, Sangen Zhao, Junhua Luo

    Read original paper ↗ ·

  9. Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A3B3CD2O14 Family

    Journal of the American Chemical Society · 2016-03-25

    Hongwei Yu, Joshua Young, Hongping Wu, Weiguo Zhang, James M. Rondinelli, P. Shiv Halasyamani

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  10. Syntheses, structural and characterizations of a new anhydrous mixed-metal phosphate

    Inorganica Chimica Acta · 2016-04-29

    Weilong Zhang, Hao Zhang, Zhangzhen He, Wen‐Dan Cheng

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  11. A New Deep-Ultraviolet Transparent Orthophosphate LiCs 2 PO 4 with Large Second Harmonic Generation Response

    Journal of the American Chemical Society · 2016-07-12

    Lin Li, Ying Wang, Bing‐Hua Lei, Shujuan Han, Zhihua Yang, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  12. Introducing Chirality into Hybrid Clusters from an Achiral Ligand: Synthesis and Characterization of Polyoxomolybdates Containing a Benzylarsonate Group

    European Journal of Inorganic Chemistry · 2017-03-20

    Meng‐Shu Liu, Wei‐Dong Yu, Qianwen Yan, Jun Yan

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  13. (H 3 O)Ca 2 Zn 3.5 (PO 4 ) 4 and Ba 2 Cd 3 (PO 4 ) 2 (HPO 4 ) 2 : Syntheses, crystal structures and characterizations of two mixed metal phosphates

    Journal of Solid State Chemistry · 2017-04-08

    Tong-Ying Chang, Chun‐Li Hu, Dong Yan, Jiang‐Gao Mao

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  14. The enhancement of birefringence resulted from anionic dimensionality changes through adjusting cationic density

    Journal of Alloys and Compounds · 2017-05-11

    Lili Liu, Yun Mo Yang, Zhihua Yang, Shilie Pan

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  15. M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates

    Crystal Growth & Design · 2017-08-16

    Tong-Ying Chang, Bing‐Ping Yang, Chun‐Li Hu, Dong Yan, Jiang‐Gao Mao

    Read original paper ↗ ·

  16. Li1.52Na4.48Cd8(PO4)2(P2O7)4: A new mixed-anion diphosphate containing four types of dimensions groups

    Inorganic Chemistry Communications · 2017-11-07

    Yuan Fang, Zhaohui Chen, Yunjing Shi, Wenyao Zhang, Xiaoyu Dong

    Read original paper ↗ ·

  17. Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O

    Inorganic Chemistry · 2018-07-19

    Yahui Li, Hongping Wu, Bingbing Zhang, Zhihua Yang, Guopeng Han, Shilie Pan

    Read original paper ↗ ·

  18. ALiZnP2O7 (A = Rb, Cs): Two Mixed Alkali Zinc Pyrophosphates Featuring a [Li2Zn2P4O20]14– Anionic Skeleton

    Inorganic Chemistry · 2018-08-20

    Zhaohui Chen, Yuan Fang, Wenyao Zhang, Wenqiang Chen, Xuefang Lu, Qun Jing, Ming‐Hsien Lee

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  19. Modulation of perovskite-related frameworks induced by alkaline earth metals in phosphate fluorides A 2 MPO 4 F (A = K, Rb; M = Ba, Ca)

    New Journal of Chemistry · 2019-01-01

    Kun Chai, Shichao Cheng, Hongyi Li, Bin Dai

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  20. Syntheses, structures, anomalous phase transition and optical properties of two new polymorphic α- and β-LiMoPO 6

    Dalton Transactions · 2019-01-01

    Haonan Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Yicheng Wu

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  21. Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses

    Chemistry of Materials · 2019-03-29

    Yahui Li, Guopeng Han, Hongwei Yu, Hao Li, Zhihua Yang, Shilie Pan

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  22. Further Example of Diphosphates: Synthesis and Characterization of K2Li2P2O7

    Zeitschrift für anorganische und allgemeine Chemie · 2019-07-10

    Lingyun Dong, Xusheng Ge, Pengfei Zhang, Qian Li, Sufang Sun, Shigang Shen

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  23. Syntheses, crystal structures, and characterizations of three new pyrophosphates CsNaZnP2O7, RbNaZnP2O7, and RbLiMgP2O7

    Solid State Sciences · 2019-07-22

    Huimin Song, Shengzi Zhang, Yunfei Li, Wang Liu, Zheshuai Lin, Jiyong Yao, Guochun Zhang

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  24. [NH4]12[(MoO2)2O(HPO4)2]4[PO4]Cl·0.5H2O: A mixed phosphomolybdate with nonlinear optical properties

    Inorganica Chimica Acta · 2019-10-08

    Zhongqi Jiang, Wenqiang Chen, Qun Jing, Ming‐Hsien Lee, Zhaohui Chen

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  25. Effets du molybdène dans les verres de phosphates : relations structure-propriétés

    Unknown journal · 2019-11-22

    Kadiali Bodiang

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  26. K 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups

    Dalton Transactions · 2020-01-01

    Wenyao Zhang, Wenqi Jin, Zhihua Yang, Shilie Pan

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  27. Alignment of Polar Moieties Leading to Strong Second Harmonic Response in KCsMoP2O9

    Chemistry of Materials · 2020-03-13

    Tuohetijiang Baiheti, Shujuan Han, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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  28. Effect of Mo/P Ratios on Dimensions: Syntheses, Structures, and Properties of Three New Molybdophosphates

    Inorganic Chemistry · 2020-04-03

    Haonan Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  29. Chiral Template‐Driven Macroscopic Chirality Control: Structure‐Second‐Harmonic Generation Properties Relationship

    European Journal of Inorganic Chemistry · 2020-12-22

    Hongil Jo, Xinglong Chen, Hee‐Seung Lee, Kang Min Ok

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  30. K 2 ZnMoP 2 O 10 : a novel nonlinear optical molybdophosphate with a strong second harmonic generation response and moderate birefringence

    Journal of Materials Chemistry C · 2021-01-01

    Haonan Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  31. RbMo 2 P 3 O 14 with large birefringence mainly induced by highly distorted [MoO 6 ] in uncommon [Mo 2 P 3 O 14 ] ∞ layers

    Dalton Transactions · 2021-01-01

    Rui Zhang, Xin Su, Jie Zhang, Mingyao Xiong, Yineng Huang

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  32. A 6 Mo 2 P 4 O 19 (A = Rb, Cs) and Rb 2 MoP 2 O 9 : new molybdophosphates with distinct polyanionic configurations

    Dalton Transactions · 2021-12-13

    Maierhaba Abudoureheman, Juanjuan Zheng, Peng Wang, Bo Wei, Zhiyong Guo, Zhaohui Chen, Yanna Chen

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  33. K 2 MgMoP 2 O 10 and K 3 Mg 2 MoP 3 O 14 : two new molybdophosphates exhibiting different optical anisotropies induced by variable dimensionality of the anion framework

    Dalton Transactions · 2024-01-01

    Zhixia Gao, Qiuyuan Feng, Juanjuan Lu, Hong Lei Du

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  34. A new ultraviolet-transparent molybdate featuring a layered structure and moderate birefringence

    New Journal of Chemistry · 2025-01-01

    Shiyu Du, Paipai Zhang, Haozhen Liu, Donghai An, Yanna Chen

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  35. Four noncentrosymmetric molybdophosphates discovered by a chemical substitution strategy

    Dalton Transactions · 2025-01-01

    Zhixia Gao, Ke Li, Hong Du, Tuohetijiang Baiheti

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  36. pH‐Regulated Ring‐Opening/Closing Transformation in Polyoxometalates Enables High‐Performance Nonlinear Optical Crystals

    Angewandte Chemie · 2025-11-06

    Wei Zeng, Jing Zhang, Yao Tian, Hongmei Zeng, Zhien Lin, Liujiang Zhou, Kang Min Ok, Guohong Zou

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  37. pH‐Regulated Ring‐Opening/Closing Transformation in Polyoxometalates Enables High‐Performance Nonlinear Optical Crystals

    Angewandte Chemie International Edition · 2025-11-06

    Wei Zeng, Jing Zhang, Yao Tian, Hongmei Zeng, Zhien Lin, Liujiang Zhou, Kang Min Ok, Guohong Zou

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  38. Ba 3 (MoO 2 F 3 )PO 4 F 2 : Rational Design and Synthesis of an Alkaline-Earth Phosphate Fluoride as a Birefringent Crystal

    Crystal Growth & Design · 2025-11-26

    Feng Xu, Mengya Qin, Bin Su, Chao He, Shaohua Yu, Yu Li, Rong Guo, Chan Zheng

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  39. K 2 ZnMoP 2 O 10 : crystal growth, optical characterization, and structure–property insights into phase matching

    CrystEngComm · 2026-01-01

    Youbin Wang, Haonan Liu, Yujie Zhang, Hongping Wu, Hongping Wu, Zhanggui Hu

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