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RESEARCH PAPER · Inorganic Chemistry · 2017

Photoconversion Mechanisms and the Origin of Second-Harmonic Generation in Metal Iodates with Wide Transparency, NaLn(IO3)4 (Ln = La, Ce, Sm, and Eu) and NaLa(IO3)4:Ln3+ (Ln = Sm and Eu)

Seung‐Jin Oh, Hyung-Gu Kim, Hongil Jo, Tae Gil Lim, Jae Soo Yoo, Kang Min Ok

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Photoconversion Mechanisms and the Origin of Second-Harmonic Generation in Metal Iodates with Wide Transparency, NaLn(IO3)4 (Ln = La, Ce, Sm, and Eu) and NaLa(IO3)4:Ln3+ (Ln = Sm and Eu)OriginalNoncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond21M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates16Near-ultraviolet and blue light excited Sm3+ doped Lu2MoO6 phosphor for potential solid state lighting and temperature sensing133Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response66KBi(IO 3 ) 3 (OH) and NaBi(IO 3 ) 4 : from the centrosymmetric chain to a noncentrosymmetric double layer18REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62Structure–Optical Behavior Correlation, Optimized Photoluminescence, and DFT Calculation of La7O6(BO3)(PO4)2:Sm3+ Micropowder for Solid State Lighting33Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties6Design and realization on orange-red emitting of samarium activated sodium lanthanum metaphosphate with low CCT and high CP34Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance17Dimensionality–Band Gap–Third-Harmonic Generation Property Relationship in Novel Main-Group Metal Iodates37Homochiral three-dimensional noncentrosymmetric lanthanide coordination polymers directed by chiral linkers: syntheses, crystal structures, and optical properties8Scintillation materials based on metal iodates by rare earth doping modifications for use in radioluminescence and X-ray imaging21Structural Origin of Very Large Second-Harmonic Generation of a Layered Perovskite, Na0.5Bi2.5Nb2O921A Highly Sensitive Turn-Off Fluorescent Probe Based on 2d Eu(Iii)-Mofs Nanosheets for Glutathione in Vitro and Living Cells5Hydrothermal Synthesis of New Mixed-Oxoanion Materials: Rare Earth Iodate Sulfates Sm(Io3)(So4) and Ln2(Io3)3(So4)Oh•3h2o (Ln = Sm, EU, Dy)5General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates15RE(OH) 2 NO 3 (RE = Tb, Dy, Ho, and Er): Synthesis and Nonlinear Optical Properties of Water-Resistant Lanthanide Hydroxide Nitrates15LiRE(SO 4 ) 2 (RE = Y, Gd, Eu): noncentrosymmetric chiral rare-earth sulfates with very large band gaps21A new polar alkaline earth–rare earth iodate: Ba 2 Ce(IO 3 ) 8 (H 2 O)10A review on the advancements in the characterization of the high-pressure properties of iodates44LiGa(IO3)4: An Excellent NLO Material with Unprecedented 2D [Ga(IO3)4]∞− Layer Synthesized by Aliovalent Substitution20NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure3NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure0Microwave-hydrothermal synthesis, near ultraviolet/infrared-excited green fluorescence and ratiometric thermometry of Er3+-activated iodate phosphors17Unveiling the Intrinsic Superior SHG Performance of Ce 4+ Fluoride Masked by Subtle Ce 3+ Impurity and Its Effective Removal13Unveiling the Intrinsic Superior SHG Performance of Ce4+ Fluoride Masked by Subtle Ce3+ Impurity and Its Effective Removal2Narrow Optical Linewidths in Stoichiometric Layered Rare-Earth Crystals4Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials3A Polar Cerium Iodate Ce 2 (IO 3 ) 6 (H 2 O) with a Strong Second-Harmonic Generation Response in Trivalent Ce-Based Materials1LiMn(IO 3 ) 3 : A Noncentrosymmetric Iodate Synthesized by Polyhedral Volume Ratio Modulation0

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  1. Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond

    Dalton Transactions · 2017-01-01

    Hongil Jo, Seung‐Jin Oh, Kang Min Ok

    Read original paper ↗ ·

  2. M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates

    Crystal Growth & Design · 2017-08-16

    Tong-Ying Chang, Bing‐Ping Yang, Chun‐Li Hu, Dong Yan, Jiang‐Gao Mao

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  3. Near-ultraviolet and blue light excited Sm3+ doped Lu2MoO6 phosphor for potential solid state lighting and temperature sensing

    Journal of Alloys and Compounds · 2017-12-18

    Li Li, Shaoke Fu, Yifei Zheng, Chen Li, Peng Chen, Guotao Xiang, Sha Jiang, Xianju Zhou

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  4. Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response

    Chemistry - A European Journal · 2018-11-08

    Tushagu Abudouwufu, Min Zhang, Shichao Cheng, Zhihua Yang, Shilie Pan

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  5. KBi(IO 3 ) 3 (OH) and NaBi(IO 3 ) 4 : from the centrosymmetric chain to a noncentrosymmetric double layer

    Dalton Transactions · 2019-01-01

    Ying‐Jie Jia, Yi-Gang Chen, Ting Wang, Yao Guo, Xiao‐Fang Guan, Xian‐Ming Zhang

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  6. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie International Edition · 2019-06-18

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiao‐Han Zhang, Jiang‐Gao Mao

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  7. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie · 2019-06-18

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiaohan Zhang, Jiang‐Gao Mao

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  8. Structure–Optical Behavior Correlation, Optimized Photoluminescence, and DFT Calculation of La7O6(BO3)(PO4)2:Sm3+ Micropowder for Solid State Lighting

    ACS Applied Electronic Materials · 2019-07-23

    Jing Zhu, Meihua Yang, Yi Che, Zhuohui Zhang, Xinchen Ge, Jiyun Xiang, Yang Zhou, Kai Xiong, Hongwei Yu

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  9. Five New Silver Rare‐Earth Iodates, AgLn(IO3)4 (Ln=Pr, Sm, Dy, Er and Tm): Synthesis, Structures and Properties

    ChemistrySelect · 2019-08-06

    Qi Wu, Xian Liu, Siran Xu, Hongbing Pi, Yanjun Li

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  10. Design and realization on orange-red emitting of samarium activated sodium lanthanum metaphosphate with low CCT and high CP

    Journal of Alloys and Compounds · 2019-08-27

    Yang Zhou, Xinchen Ge, Zhuohui Zhang, Wenjie Luo, Hang Xu, Wufu Li, Jing Zhu

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  11. Incorporating rare-earth cations with moderate electropositivity into iodates for the optimized second-order nonlinear optical performance

    Inorganic Chemistry Frontiers · 2020-01-01

    Lin Lin, Longhua Li, Chao Wu, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  12. Dimensionality–Band Gap–Third-Harmonic Generation Property Relationship in Novel Main-Group Metal Iodates

    Chemistry of Materials · 2020-04-07

    Geonju Park, Hye Ryung Byun, Joon Ik Jang, Kang Min Ok

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  13. Homochiral three-dimensional noncentrosymmetric lanthanide coordination polymers directed by chiral linkers: syntheses, crystal structures, and optical properties

    CrystEngComm · 2021-01-01

    Yunseung Kuk, Kang Min Ok

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  14. Scintillation materials based on metal iodates by rare earth doping modifications for use in radioluminescence and X-ray imaging

    CrystEngComm · 2021-01-01

    Weiwei Xu, Hui Xu, Shuai‐Hua Wang, Zhilin Wang, Xieming Xu, Xianhui Zhang, Shaofan Wu

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  15. Structural Origin of Very Large Second-Harmonic Generation of a Layered Perovskite, Na0.5Bi2.5Nb2O9

    Chemistry of Materials · 2021-08-04

    Ki-Sung Kim, Min Hyung Lee, Kang Min Ok

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  16. A Highly Sensitive Turn-Off Fluorescent Probe Based on 2d Eu(Iii)-Mofs Nanosheets for Glutathione in Vitro and Living Cells

    Journal of the American Ceramic Society · 2022-01-01

    Mengmeng Zhu, Yunpeng Liu, Chao Xia, Hairong Zeng, Song Hu, Danyu Jiang, Guohong Zhou, Huili Li

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  17. Hydrothermal Synthesis of New Mixed-Oxoanion Materials: Rare Earth Iodate Sulfates Sm(Io3)(So4) and Ln2(Io3)3(So4)Oh•3h2o (Ln = Sm, EU, Dy)

    Solid State Sciences · 2022-01-01

    Ceren Kütahyalı Aslani, Vladislav V. Klepov, Hans‐Conrad zur Loye

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  18. General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates

    Physical Review Materials · 2022-04-28

    Akun Liang, Robin Turnbull, Plácida Rodríguez-Hernández, Alfonso Muñoz, M. Jasmin, Lan-Ting Shi, Daniel Errandonea

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  19. RE(OH) 2 NO 3 (RE = Tb, Dy, Ho, and Er): Synthesis and Nonlinear Optical Properties of Water-Resistant Lanthanide Hydroxide Nitrates

    Inorganic Chemistry · 2022-11-01

    Min Chen, Zhengli Liang, Xiaoxiao Wang, Jiehua Li, Xingguo Chen, Xingxing Jiang, Zheshuai Lin, Zhen Ma, Hongming Liu

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  20. LiRE(SO 4 ) 2 (RE = Y, Gd, Eu): noncentrosymmetric chiral rare-earth sulfates with very large band gaps

    Materials Chemistry Frontiers · 2022-11-30

    Sunghwan Cho, Kang Min Ok

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  21. A new polar alkaline earth–rare earth iodate: Ba 2 Ce(IO 3 ) 8 (H 2 O)

    Dalton Transactions · 2023-01-01

    Xueying Zhang, Xiaohan Zhang, Bing‐Ping Yang, Jiang‐Gao Mao

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  22. A review on the advancements in the characterization of the high-pressure properties of iodates

    Progress in Materials Science · 2023-03-01

    Akun Liang, Robin Turnbull, Daniel Errandonea

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  23. LiGa(IO3)4: An Excellent NLO Material with Unprecedented 2D [Ga(IO3)4]∞− Layer Synthesized by Aliovalent Substitution

    Small · 2023-09-07

    Shuoxing Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  24. NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure

    Russian Journal of Inorganic Chemistry · 2023-11-01

    Oksana P. Grigorieva, Sergey Yu. Stefanovich, Dmitri O. Charkin, В. А. Долгих, Konstantin A. Lysenko

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  25. NaLn(IO3)4 Iodates (Ln = Pr, Tb): New Representatives of Nonlinear Optical Crystals with the NaY(IO3)4 Structure

    Журнал неорганической химии · 2023-11-01

    Oksana P. Grigorieva, Sergey Yu. Stefanovich, Dmitri O. Charkin, В. А. Долгих, Konstantin A. Lysenko

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  26. Microwave-hydrothermal synthesis, near ultraviolet/infrared-excited green fluorescence and ratiometric thermometry of Er3+-activated iodate phosphors

    Ceramics International · 2024-11-06

    Junpeng Li, Qian Hu, Yin Hsien Su, Quan Li, Zhouyan Li, Jintao Xie, Bo Wang, Hongming Jiang, Hongzhi Zhang, Jing Zhu

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  27. Unveiling the Intrinsic Superior SHG Performance of Ce 4+ Fluoride Masked by Subtle Ce 3+ Impurity and Its Effective Removal

    Angewandte Chemie International Edition · 2025-02-18

    Mengyue Li, Xin Liu, Rui Wang, Li‐Ming Wu, Li‐Ming Wu, Ling Chen, Qi Wu, Qi Wu

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  28. Unveiling the Intrinsic Superior SHG Performance of Ce4+ Fluoride Masked by Subtle Ce3+ Impurity and Its Effective Removal

    Angewandte Chemie · 2025-02-18

    Mengyue Li, Xin Liu, Rui Wang, Li‐Ming Wu, Ling Chen, Qi Wu

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  29. Narrow Optical Linewidths in Stoichiometric Layered Rare-Earth Crystals

    Physical Review Letters · 2025-05-27

    Donny R. Pearson, Ashwith Varadaraj Prabhu, Selvin Tobar, Jack A. D’Amelio, Amy Tram, Zachary W. Riedel, Daniel P. Shoemaker, Elizabeth A. Goldschmidt

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  30. Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials

    Chinese Chemical Letters · 2025-11-01

    Xuan Li, Tianhui Wu, Meiqi Liu, Yang Zhao, Jiahang Liu, Miao Zhang, Weiwei Cao, Jianmin Gu, Desong Wang

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  31. A Polar Cerium Iodate Ce 2 (IO 3 ) 6 (H 2 O) with a Strong Second-Harmonic Generation Response in Trivalent Ce-Based Materials

    Inorganic Chemistry · 2026-03-17

    Jiahang Liu, Miao Zhang, Shizheng Li, Ziyang Wang, Yang Zhao, NianRui Qu, Weiwei Cao, Jianmin Gu, Tianhui Wu

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  32. LiMn(IO 3 ) 3 : A Noncentrosymmetric Iodate Synthesized by Polyhedral Volume Ratio Modulation

    Inorganic Chemistry · 2026-05-26

    Ruilan Kong, Weitong Wang, Shuoxing Yang, S W, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yizhi Wu, HS Wu

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