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RESEARCH PAPER · Advanced Materials · 2016

Emerging Multifunctional Metal–Organic Framework Materials

Bin Li, Hui‐Min Wen, Yuanjing Cui, Wei Zhou, Guodong Qian, Banglin Chen

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Emerging Multifunctional Metal–Organic Framework MaterialsOriginalPorous Metal-Organic Frameworks: Promising Materials for Methane Storage408Polystyrene Sulfonate Threaded through a Metal–Organic Framework Membrane for Fast and Selective Lithium‐Ion Separation421Catalytic degradation of chemical warfare agents and their simulants by metal-organic frameworks372Core–Shell Gold Nanorod@Metal–Organic Framework Nanoprobes for Multimodality Diagnosis of Glioma222An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors1210Metal-Organic Frameworks for Energy Applications1200Strong Electromagnetic Wave Response Derived from the Construction of Dielectric/Magnetic Media Heterostructure and Multiple Interfaces289Single-Site Cobalt Catalysts at New Zr 12 (μ 3 -O) 8 (μ 3 -OH) 8 (μ 2 -OH) 6 Metal–Organic Framework Nodes for Highly Active Hydrogenation of Nitroarenes, Nitriles, and Isocyanides256Template-Directed Growth of Well-Aligned MOF Arrays and Derived Self-Supporting Electrodes for Water Splitting502Optimized Separation of Acetylene from Carbon Dioxide and Ethylene in a Microporous Material559Microstructural Engineering and Architectural Design of Metal–Organic Framework Membranes202Metal-organic framework one-dimensional fibers as efficient catalysts for activating peroxymonosulfate196Introduction of Red‐Green‐Blue Fluorescent Dyes into a Metal–Organic Framework for Tunable White Light Emission270Metal-Organic-Framework-Based Materials as Platforms for Renewable Energy and Environmental Applications843Exploration of porous metal–organic frameworks for gas separation and purification726Straightforward Loading of Imidazole Molecules into Metal–Organic Framework for High Proton Conduction358Gas adsorption properties of hybrid graphene-MOF materials208Metal–Organic Frameworks as Platforms for Catalytic Applications1717A DNA‐Threaded ZIF‐8 Membrane with High Proton Conductivity and Low Methanol Permeability191Integration of Plasmonic Effects and Schottky Junctions into Metal–Organic Framework Composites: Steering Charge Flow for Enhanced Visible‐Light Photocatalysis569Biological metal–organic frameworks: Structures, host–guest chemistry and bio-applications419High-yield bottom-up synthesis of 2D metal–organic frameworks and their derived ultrathin carbon nanosheets for energy storage229A g-C 3 N 4 /MIL-101(Fe) heterostructure composite for highly efficient BPA degradation with persulfate under visible light irradiation198Bifunctional electrocatalysts of MOF-derived Co–N/C on bamboo-like MnO nanowires for high-performance liquid- and solid-state Zn–air batteries193Conductive two-dimensional metal–organic frameworks as multifunctional materials530Direct evidence of charge separation in a metal–organic framework: efficient and selective photocatalytic oxidative coupling of amines via charge and energy transfer320Metal–organic framework-derived one-dimensional porous or hollow carbon-based nanofibers for energy storage and conversion533Photochemistry and photophysics of MOFs: steps towards MOF-based sensing enhancements656Spatial confinement of a cationic MOF: a SC–SC approach for high capacity Cr( vi )-oxyanion capture in aqueous solution176Supramolecular delivery systems based on pillararenes188Dynamic traction of lattice-confined platinum atoms into mesoporous carbon matrix for hydrogen evolution reaction584High Rate Magnesium–Sulfur Battery with Improved Cyclability Based on Metal–Organic Framework Derivative Carbon Host187Single Pt Atoms Confined into a Metal–Organic Framework for Efficient Photocatalysis837Functionalization of Metal–Organic Frameworks for Photoactive Materials188Copper Metal–Organic Framework Nanoparticles Stabilized with Folic Acid Improve Wound Healing in Diabetes396Encapsulating highly catalytically active metal nanoclusters inside porous organic cages444Photocatalytic Hydrogen Production Coupled with Selective Benzylamine Oxidation over MOF Composites542Incorporation of Imidazolium-Based Poly(ionic liquid)s into a Metal–Organic Framework for CO 2 Capture and Conversion505Recent advances in luminescent lanthanide based Single-Molecule Magnets301Metal–Organic Frameworks for Separation1305Quasi-MOF: Exposing Inorganic Nodes to Guest Metal Nanoparticles for Drastically Enhanced Catalytic Activity256Boosting Photocatalytic Hydrogen Production of Porphyrinic MOFs: The Metal Location in Metalloporphyrin Matters266Zr(IV)-Based Metal-Organic Framework with T-Shaped Ligand: Unique Structure, High Stability, Selective Detection, and Rapid Adsorption of Cr2O72– in Water269From Metal–Organic Frameworks to Single‐Atom Fe Implanted N‐doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media860From UV to Near‐Infrared Light‐Responsive Metal–Organic Framework Composites: Plasmon and Upconversion Enhanced Photocatalysis308Lower Activation Energy for Catalytic Reactions through Host–Guest Cooperation within Metal–Organic Frameworks211Cerium Metal–Organic Framework for Photocatalysis525Biomimetic O2-Evolving metal-organic framework nanoplatform for highly efficient photodynamic therapy against hypoxic tumor213Metal–Organic‐Framework‐Based Catalysts for Photoreduction of CO 2584Interface-Assisted Synthesis of 2D Materials: Trend and Challenges710Mesoporous Metal–Organic Frameworks: Synthetic Strategies and Emerging Applications205Pore surface engineering of metal–organic frameworks for heterogeneous catalysis214Ultrathin two-dimensional metal-organic framework nanosheets for functional electronic devices222Ultrasmall Metal Nanoparticles Confined within Crystalline Nanoporous Materials: A Fascinating Class of Nanocatalysts411Unveiling Charge-Separation Dynamics in CdS/Metal–Organic Framework Composites for Enhanced Photocatalysis400ZnO@MOF@PANI core-shell nanoarrays on carbon cloth for high-performance supercapacitor electrodes176Metal–organic frameworks: Structures and functional applications1404Lanthanide‐Based Thermometers: At the Cutting‐Edge of Luminescence Thermometry1173Semisacrificial Template Growth of Self‐Supporting MOF Nanocomposite Electrode for Efficient Electrocatalytic Water Oxidation313Metal–Organic Frameworks for Photocatalysis and Photothermal Catalysis1277A 2D metal–organic framework/Ni(OH) 2 heterostructure for an enhanced oxygen evolution reaction176A metal–organic framework with suitable pore size and dual functionalities for highly efficient post-combustion CO 2 capture193Carbon capture and conversion using metal–organic frameworks and MOF-based materials2616Improving MOF stability: approaches and applications1666Multifunctional porous hydrogen-bonded organic framework materials1346Single-atom catalysts templated by metal–organic frameworks for electrochemical nitrogen reduction228Monometallic Catalytic Models Hosted in Stable Metal–Organic Frameworks for Tunable CO2 Photoreduction384Metal-Organic-Framework-Based Single-Atom Catalysts for Energy Applications779Incorporation of biomolecules in Metal-Organic Frameworks for advanced applications336Guest-Induced Ultrasensitive Detection of Multiple Toxic Organics and Fe 3+ Ions in a Strategically Designed and Regenerative Smart Fluorescent Metal–Organic Framework220MOF‐Based Hierarchical Structures for Solar‐Thermal Clean Water Production330Functional metal–organic frameworks for catalytic applications345Metal–Organic Frameworks and Their Derived Materials: Emerging Catalysts for a Sulfate Radicals‐Based Advanced Oxidation Process in Water Purification294Highly efficient sunlight-driven reduction of Cr(VI) by TiO2@NH2-MIL-88B(Fe) heterostructures under neutral conditions313Metal–Organic Framework (MOF) Hybrid as a Tandem Catalyst for Enhanced Therapy against Hypoxic Tumor Cells192Ambient Fast Synthesis and Active Sites Deciphering of Hierarchical Foam‐Like Trimetal–Organic Framework Nanostructures as a Platform for Highly Efficient Oxygen Evolution Electrocatalysis517High-performance single atom bifunctional oxygen catalysts derived from ZIF-67 superstructures272Encapsulating Perovskite Quantum Dots in Iron‐Based Metal–Organic Frameworks (MOFs) for Efficient Photocatalytic CO2 Reduction776Postsynthetic Metalation of a Robust Hydrogen-Bonded Organic Framework for Heterogeneous Catalysis280Hydrophobic Metal–Organic Frameworks301Recent advances in detecting and regulating ethylene concentrations for shelf-life extension and maturity control of fruit: A review203Metal-organic frameworks for catalysis: State of the art, challenges, and opportunities562Porous metal-organic frameworks for gas storage and separation: Status and challenges891Switching on the Photocatalysis of Metal–Organic Frameworks by Engineering Structural Defects542MOF × Biopolymer: Collaborative Combination of Metal–Organic Framework and Biopolymer for Advanced Anticancer Therapy181Linker functionalized metal-organic frameworks341Application of QD-MOF composites for photocatalysis: Energy production and environmental remediation347Turning on Visible-Light Photocatalytic C−H Oxidation over Metal–Organic Frameworks by Introducing Metal-to-Cluster Charge Transfer508High capacity Hg(II) and Pb(II) removal using MOF-based nanocomposite: Cooperative effects of pore functionalization and surface-charge modulation180Controlling the morphology of metal–organic frameworks and porous carbon materials: metal oxides as primary architecture-directing agents333From isolated Ti-oxo clusters to infinite Ti-oxo chains and sheets: recent advances in photoactive Ti-based MOFs260From metal–organic frameworks to single/dual-atom and cluster metal catalysts for energy applications536MOF-derived Fe,Co@N–C bifunctional oxygen electrocatalysts for Zn–air batteries201Optimization strategies of composite phase change materials for thermal energy storage, transfer, conversion and utilization348Organic solid-state lasers: a materials view and future development444Rare-earth metal–organic frameworks: from structure to applications461Metal–Organic Frameworks Significantly Enhance Photocatalytic Hydrogen Evolution and CO2 Reduction with Earth-Abundant Copper Photosensitizers310Metal–Organic Frameworks for Biomedical Applications998Advances in transition-metal (Zn, Mn, Cu)-based MOFs and their derivatives for anode of lithium-ion batteries213Metal–Organic Framework Magnets634Conductive MOFs373Photocatalytic CO2 reduction over metal-organic framework-based materials776Optimization of the Pore Structures of MOFs for Record High Hydrogen Volumetric Working Capacity237Copper-Based Metal–Organic Framework as a Controllable Nitric Oxide-Releasing Vehicle for Enhanced Diabetic Wound Healing189Metal-organic frameworks for QCM-based gas sensors: A review205Highly efficient capture of phosphate from water via cerium-doped metal-organic frameworks221Nano-sized metal-organic frameworks: Synthesis and applications301Nanocasting SiO2 into metal–organic frameworks imparts dual protection to high-loading Fe single-atom electrocatalysts480Boosting Catalysis of Pd Nanoparticles in MOFs by Pore Wall Engineering: The Roles of Electron Transfer and Adsorption Energy238Super hygroscopic nanofibrous membrane-based moisture pump for solar-driven indoor dehumidification249Conductive Metal–Organic Frameworks: Design, Synthesis, and Applications183Design and applications of water-stable metal-organic frameworks: status and challenges261Precise fabrication of single-atom alloy co-catalyst with optimal charge state for enhanced photocatalysis183Metal organic framework (MOF)-based micro/nanoscaled materials for heavy metal ions removal: The cutting-edge study on designs, synthesis, and applications377Incorporating Transition‐Metal Phosphides Into Metal‐Organic Frameworks for Enhanced Photocatalysis240Nanomaterials to relieve tumor hypoxia for enhanced photodynamic therapy180Rare earth metal–organic frameworks (RE-MOFs): Synthesis, properties, and biomedical applications257Nitrogen-doped carbon wrapped Co-Mo2C dual Mott–Schottky nanosheets with large porosity for efficient water electrolysis209Multifunctional metal–organic framework heterostructures for enhanced cancer therapy282Integration of Pd nanoparticles with engineered pore walls in MOFs for enhanced catalysis259Beyond the Visible: Bioinspired Infrared Adaptive Materials415Microenvironment Modulation in Metal–Organic Framework-Based Catalysis368Metal-organic frameworks for improving wound healing185Metal‐Organic Frameworks Nanocomposites with Different Dimensionalities for Energy Conversion and Storage222Isoreticular chemistry within metal–organic frameworks for gas storage and separation584Recent Advances in Metal–Organic Frameworks Derived Nanocomposites for Photocatalytic Applications in Energy and Environment264Luminescent lanthanide nanocomposites in thermometry: Chemistry of dopant ions and host matrices192Integration of metal-organic frameworks and covalent organic frameworks: Design, synthesis, and applications391Metal organic frameworks as hybrid porous materials for energy storage and conversion devices: A review273Metal–Organic Framework-Based Hierarchically Porous Materials: Synthesis and Applications1631Modulating Coordination Environment of Single-Atom Catalysts and Their Proximity to Photosensitive Units for Boosting MOF Photocatalysis445Self-adaptive dual-metal-site pairs in metal-organic frameworks for selective CO2 photoreduction to CH4843Conquering the Hypoxia Limitation for Photodynamic Therapy701Electrostatic Attraction-Driven Assembly of a Metal–Organic Framework with a Photosensitizer Boosts Photocatalytic CO 2 Reduction to CO271Piezo‐Photocatalysis over Metal–Organic Frameworks: Promoting Photocatalytic Activity by Piezoelectric Effect418A General Strategy to Immobilize Single‐Atom Catalysts in Metal–Organic Frameworks for Enhanced Photocatalysis208Light‐Assisted CO2 Hydrogenation over Pd3Cu@UiO‐66 Promoted by Active Sites in Close Proximity181Adsorptive removal of organic dyes via porous materials for wastewater treatment in recent decades: A review on species, mechanisms and perspectives390Benchmark uranium extraction from seawater using an ionic macroporous metal–organic framework208Biomedical Applications of Metal−Organic Frameworks for Disease Diagnosis and Drug Delivery: A Review218Seignette salt induced defects in Zr-MOFs for boosted Pb(Ⅱ) adsorption: universal strategy and mechanism insight181Charge Separation by Creating Band Bending in Metal–Organic Frameworks for Improved Photocatalytic Hydrogen Evolution208Porphyrin-based framework materials for energy conversion263Design Rules of Hydrogen-Bonded Organic Frameworks with High Chemical and Thermal Stabilities604Progress and potential of metal-organic frameworks (MOFs) for gas storage and separation: A review356Zirconium-based metal-organic frameworks for fluorescent sensing227Long Persistent Luminescence from Metal–Organic Compounds: State of the Art203MOF‐Based Photocatalytic Membrane for Water Purification: A Review188Metal organic frameworks for wastewater treatment, renewable energy and circular economy contributions185MOF-Based Electrocatalysts: An Overview from the Perspective of Structural Design307

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