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RESEARCH PAPER · Journal of Materials Chemistry C · 2018

Oxyhalides: prospecting ore for optical functional materials with large laser damage thresholds

Zhihua Yang, Cong Hu, Miriding Mutailipu, Yanzhou Sun, Kui Wu, Min Zhang, Shilie Pan

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Oxyhalides: prospecting ore for optical functional materials with large laser damage thresholdsOriginalCrystal engineering, optical properties and electron density distribution of polar multicomponent materials containing sulfanilamide15Li 8 NaRb 3 (SO 4 ) 6 ·2H 2 O as a new sulfate deep-ultraviolet nonlinear optical material93Second-order nonlinear optical properties of CuGa In1-Se2 (x = 0.54): Experimental and theoretical investigations4Excellent Infrared Nonlinear Optical Crystals BaMO(IO3)5 (M = V, Ta) Predicted by First Principle Calculations9Size effect and identified superior functional units enhancing second harmonic generation responses on the II-IV-V2 type nonlinear optical crystals17Synthesis, Growth of Crack-Free Large-Size BaGa4Se7 Crystal, and Annealing Studies30Ag 7 TaSe 6 : a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response13Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity19Lone pair effects on ternary infrared nonlinear optical materials19Metal-cation substitutions induced the enhancement of second harmonic generation in A 8 BS 6 (A = Cu, and Ag; B = Si, Ge, and Sn)14Multifunctional property exploration: Bi 4 O 5 I 2 with high visible light photocatalytic performance and a large nonlinear optical effect32Structure, growth and characterization of a new naphthalene family crystal for fluorescence and third order nonlinear optical applications12Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites35A new class semi-organic nonlinear optical materials: Mono(4-sulfo benzene aminium) tri nickel(II) bis(dihydrogen phosphate) for photonic applications12First-principles investigation of structural, electronic, optical and thermodynamic properties of KAg2SbS412Quantum chemical calculations, structural, spectral and nonlinear optical investigations of a novel crystal N,N ′-diphenylguanidinium 3,5-dichlorobenzoate24DFT analysis on spectral and NLO properties of (2E)-3-[4-(dimethylamino) phenyl]-1-(naphthalen-2-yl) prop-2-en-1-one; a d-π-A chalcone derivative and its docking studies as a potent hepatoprotective agent23Hierarchy in nonlinear optical responses induced by metal cation tailoring effect in the In-containing chalcogenide compounds4The first barium lead oxychloride Ba27Pb8O8Cl54 with new isolated [Pb4O4] clusters3Influence of ammonium nitrate concentration on structural evolution and optical properties tuning of CdS nanoparticles synthesized by precipitation method22Ba 8 SrPb 24 O 24 Cl 18 : the first alkali-earth metal lead( ii ) oxyhalide with an intriguing multimember-ring layer9Designing excellent mid-infrared nonlinear optical materials with fluorooxo-functional group of d0 transition metal oxyfluorides63Interfacial Interaction between Suolunite Crystal and Silica Binding Peptide for Novel Bioinspired Cement12Atom-Resolved Analysis of Birefringence of Nonlinear Optical Crystals by Bader Charge Integration55Particularly developed transition from the 5 D 1 level of Eu 3+ and its significant contribution to the improved photocatalysis of (Bi 3 Li)O 4 Cl 2 via prolonging the decay time of the excited state9Band-Gap Modulation of Nonlinear-Optical Fluorooxoborates by Controlling the F/B Ratios4Structure-property survey and computer-assisted screening of mid-infrared nonlinear optical chalcohalides113Lattice Anharmonicity of Stereochemically Active Lone Pairs Controls Thermochromic Band Gap Reduction of PbVO3Cl28Hierarchical Contribution of Anions to Second Harmonic Generation in A2HgI4 (A = Na, Ag, Cu) Regulated Dramatically by Metal Cations4Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95A new rare-earth borate birefringent crystal with quasi-two-dimensional [BO 3 ] layers23Computationally assisted multistage design and prediction driving the discovery of deep-ultraviolet nonlinear optical materials41Sn 14 O 11 Br 6 : a promising birefringent material with a [Sn 14 O 11 Br 6 ] layer26Recent Developments on Molten Salt Synthesis of Inorganic Nanomaterials: A Review207Borosilicate Crystal LaBSiO5: A New Promising Ultraviolet Quasiphase Matching Material31Boosting photodegradation of dye solutions based on Eu3+ doping in Bismuth-layered oxyhalogenide semiconductor NaBi3O4Cl1.5Br0.517Polymorphic Pb14O8I12 and Pb7O4I6 oxyhalides featuring unprecedented [O8Pb14] clusters with broad IR transparency20Second-Harmonic-Generation-Active Oxyhalides: CuSb2O3X (X = Cl, Br)17CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ): design of two fluorooxoborates with benign layered structures via a salt-inclusion strategy28Metal oxyhalides: an emerging family of nonlinear optical materials124Screening Nitrides with High Debye Temperatures as Nonlinear Optical Materials19Experimental study on thermotropic side-chain liquid crystalline photo-sensitive polymers1Organic–Inorganic Hybrid Compound [H2-1,5-Diazabicyclo[3.3.0]octane]ZnBr4 with Reverse Symmetry Breaking Shows a Switchable Dielectric Anomaly and Robust Second Harmonic Generation Effect19Sb5O7I: Exploration of Ternary Antimony-Based Oxyhalide as a Nonlinear-Optical Material27Predicting Diamond-like Nitrides as Infrared Nonlinear Optical Materials with High Thermal Conductivity20Passively Q-switched single crystal fiber pulsed laser at 1.05 µm with T 3 C 2 T x as the saturable absorber4From CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency21Low temperature molten salt synthesis of noncentrosymmetric (NH 4 ) 3 SbF 3 (NO 3 ) 3 and centrosymmetric (NH 4 ) 3 SbF 4 (NO 3 ) 234Shooting mid-infrared nonlinear optical materials with targeted balance performances in ternary d0-transition metal oxides through first-principles13Mechanochemical Synthesis and Structure of the Alkali Metal Magnesium Chalcogenide Na6MgS46Pb(OH)I: A lead(II)-based oxyhalide with a large birefringence5Emission Mechanism of Bright and Eco‐Friendly ZnSeTe Quantum Dots28Alkali Metal Organic–Inorganic Hybrid Compounds with Different Crystal Dimensions Show Phase-Transition, Dielectric, and SHG Properties Based on a Quasi-Spherical Amine (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane12A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation41An organic–inorganic hybrid perovskite material [Me 3 NCMe 3 ]GaCl 4 exhibits a two-step off–on–off SHG response with a large temperature interval6Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence10Pb 2 (SeO 3 )(SiF 6 ): the first selenite fluorosilicate with a wide bandgap and large birefringence achieved through perfluorinated group modification45Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides8Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction26From HgGa2(SeO3)4 to Hg2Ga(SeO3)2F: The first HgI-based selenite birefringent crystal triggered by linear groups and fluoride ions29Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances173Pb 8 O 7 I 2 ·2CsI: the salt-inclusion strategy enriches the structural chemistry in lead oxyhalides1Cd 5 Te 4 O 12 X 2 (X = Cl, Br, I): a new oxyhalide family with [CdO 4 X] mixed anionic units and adjustable optical properties4Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups11Pb 4 O 3 I 2 : A Lead Oxyhalide IR Optical Crystal with an Unprecedented 1 ∞ [O 3 Pb 4 ] Chain Featuring a Wide Transmittance Range and Large Birefringence3Halogen-Driven Structural Engineering in Tellurium Oxyhalides: Enhanced SHG Response and Broad Optical Transparency6La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence13Halogen-Tuned BiOX (X = Cl, Br, I) Layered Crystals with Superior Broadband Nonlinear Saturable Absorption for Pulsed Laser Modulation2Research on the damage mechanism of near-infrared stray light irradiation of Al-based functional film2Tuning birefringence in alkaline-earth metal oxyhalides through diverse mixed-cation coordination architectures1Molecular Ferroelectric Exhibiting a 10-Fold Enhancement in Second Harmonic Generation over KDP6Orientational control of [IO 3 ] groups enables strong optical anisotropy and second-harmonic generation in noncentrosymmetric Pb(IO 3 ) 20The electronic structurs, refractive indices and Berry curvature induced by the spin-orbit coupling in BiOX compounds: A first-principles investigation0The electronic structures, refractive indices and Berry curvature induced by the spin-orbit coupling in BiOX compounds: A first-principles investigation0A Telluromolybdate Mid-Infrared Nonlinear Optical Crystal with Wide Transparency and Strong Second-Harmonic Generation Response0Space-Confined CVD Synthesis of 2D Single-Crystalline Tellurium Oxychloride0

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  1. Crystal engineering, optical properties and electron density distribution of polar multicomponent materials containing sulfanilamide

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  2. Li 8 NaRb 3 (SO 4 ) 6 ·2H 2 O as a new sulfate deep-ultraviolet nonlinear optical material

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  3. Second-order nonlinear optical properties of CuGa In1-Se2 (x = 0.54): Experimental and theoretical investigations

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  4. Excellent Infrared Nonlinear Optical Crystals BaMO(IO3)5 (M = V, Ta) Predicted by First Principle Calculations

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    Yingfeng Li, Mengqi Cui, Hejin Yan, Yang‐Xin Yu, Meicheng Li, Xiang Li, Lihua Chu, Bing Jiang, Mingde Qin

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  5. Size effect and identified superior functional units enhancing second harmonic generation responses on the II-IV-V2 type nonlinear optical crystals

    Chemical Physics · 2018-11-13

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  6. Synthesis, Growth of Crack-Free Large-Size BaGa4Se7 Crystal, and Annealing Studies

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  7. Ag 7 TaSe 6 : a new noncentrosymmetric selenide with fascinating “three in one” coordination modes and a strong second harmonic generation response

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  8. Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity

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  9. Lone pair effects on ternary infrared nonlinear optical materials

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  10. Metal-cation substitutions induced the enhancement of second harmonic generation in A 8 BS 6 (A = Cu, and Ag; B = Si, Ge, and Sn)

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  11. Multifunctional property exploration: Bi 4 O 5 I 2 with high visible light photocatalytic performance and a large nonlinear optical effect

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  12. Structure, growth and characterization of a new naphthalene family crystal for fluorescence and third order nonlinear optical applications

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  13. Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites

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  14. A new class semi-organic nonlinear optical materials: Mono(4-sulfo benzene aminium) tri nickel(II) bis(dihydrogen phosphate) for photonic applications

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  15. First-principles investigation of structural, electronic, optical and thermodynamic properties of KAg2SbS4

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  16. Quantum chemical calculations, structural, spectral and nonlinear optical investigations of a novel crystal N,N ′-diphenylguanidinium 3,5-dichlorobenzoate

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  17. DFT analysis on spectral and NLO properties of (2E)-3-[4-(dimethylamino) phenyl]-1-(naphthalen-2-yl) prop-2-en-1-one; a d-π-A chalcone derivative and its docking studies as a potent hepatoprotective agent

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  18. Hierarchy in nonlinear optical responses induced by metal cation tailoring effect in the In-containing chalcogenide compounds

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  19. The first barium lead oxychloride Ba27Pb8O8Cl54 with new isolated [Pb4O4] clusters

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  20. Influence of ammonium nitrate concentration on structural evolution and optical properties tuning of CdS nanoparticles synthesized by precipitation method

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  21. Ba 8 SrPb 24 O 24 Cl 18 : the first alkali-earth metal lead( ii ) oxyhalide with an intriguing multimember-ring layer

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  22. Designing excellent mid-infrared nonlinear optical materials with fluorooxo-functional group of d0 transition metal oxyfluorides

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  23. Interfacial Interaction between Suolunite Crystal and Silica Binding Peptide for Novel Bioinspired Cement

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  26. Band-Gap Modulation of Nonlinear-Optical Fluorooxoborates by Controlling the F/B Ratios

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  27. Structure-property survey and computer-assisted screening of mid-infrared nonlinear optical chalcohalides

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  28. Lattice Anharmonicity of Stereochemically Active Lone Pairs Controls Thermochromic Band Gap Reduction of PbVO3Cl

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  30. Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials

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  31. A new rare-earth borate birefringent crystal with quasi-two-dimensional [BO 3 ] layers

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  32. Computationally assisted multistage design and prediction driving the discovery of deep-ultraviolet nonlinear optical materials

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  33. Sn 14 O 11 Br 6 : a promising birefringent material with a [Sn 14 O 11 Br 6 ] layer

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  34. Recent Developments on Molten Salt Synthesis of Inorganic Nanomaterials: A Review

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  35. Borosilicate Crystal LaBSiO5: A New Promising Ultraviolet Quasiphase Matching Material

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  36. Boosting photodegradation of dye solutions based on Eu3+ doping in Bismuth-layered oxyhalogenide semiconductor NaBi3O4Cl1.5Br0.5

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  37. Polymorphic Pb14O8I12 and Pb7O4I6 oxyhalides featuring unprecedented [O8Pb14] clusters with broad IR transparency

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  38. Second-Harmonic-Generation-Active Oxyhalides: CuSb2O3X (X = Cl, Br)

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  39. CsAB 8 O 12 F 2 ·CsI (A = K + , NH 4 + ): design of two fluorooxoborates with benign layered structures via a salt-inclusion strategy

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  40. Metal oxyhalides: an emerging family of nonlinear optical materials

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  41. Screening Nitrides with High Debye Temperatures as Nonlinear Optical Materials

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  44. Sb5O7I: Exploration of Ternary Antimony-Based Oxyhalide as a Nonlinear-Optical Material

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  45. Predicting Diamond-like Nitrides as Infrared Nonlinear Optical Materials with High Thermal Conductivity

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  46. Passively Q-switched single crystal fiber pulsed laser at 1.05 µm with T 3 C 2 T x as the saturable absorber

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  47. From CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency

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  48. Low temperature molten salt synthesis of noncentrosymmetric (NH 4 ) 3 SbF 3 (NO 3 ) 3 and centrosymmetric (NH 4 ) 3 SbF 4 (NO 3 ) 2

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  49. Shooting mid-infrared nonlinear optical materials with targeted balance performances in ternary d0-transition metal oxides through first-principles

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  50. Mechanochemical Synthesis and Structure of the Alkali Metal Magnesium Chalcogenide Na6MgS4

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