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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2017

Li 2 CdGeSe 4 and Li 2 CdSnSe 4 : biaxial nonlinear optical materials with strong infrared second-order responses and laser-induced damage thresholds influenced by photoluminescence

Jian‐Han Zhang, Daniel J. Clark, Ashley Weiland, Stanislav S. Stoyko, Yong Soo Kim, Joon Ik Jang, Jennifer A. Aitken

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Li 2 CdGeSe 4 and Li 2 CdSnSe 4 : biaxial nonlinear optical materials with strong infrared second-order responses and laser-induced damage thresholds influenced by photoluminescenceOriginalCorrection: Infrared nonlinear optical properties of lithium-containing diamond-like semiconductors Li 2 ZnGeSe 4 and Li 2 ZnSnSe 411Li2MnSnSe4: A New Quaternary Diamond‐Like Semiconductor with Nonlinear Optical Response and Antiferromagnetic Property16Thallium indium germanium sulphide (TlInGe2S6) as efficient material for nonlinear optical application20Na 6 Zn 3 MIII2Q 9 (M III = Ga, In; Q = S, Se): four new supertetrahedron-layered chalcogenides with unprecedented vertex-sharing T 3 -clusters and desirable photoluminescence performances31Ternary Mixed-Metal Cd4GeS6: Remarkable Nonlinear-Optical Properties Based on a Tetrahedral-Stacking Framework41Cation substitution inducing gap changes and covalent interaction flexibility enhancing second harmonic generation responses in d10 metal chalcogenides11Facile molten salt synthesis, structural, morphological and optical studies of ASiO3: Eu2+, Er3+ (A = Ca, Ba, Sr) perovskites14Adjustable optical nonlinearity in d 10 cations containing chalcogenides via dp hybridization interaction13From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals26Rational design of infrared nonlinear optical chalcogenides by chemical substitution287A review of the AI2B II C IV DVI4 family as infrared nonlinear optical materials: the effect of each site on the structure and optical properties59Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials164Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials55Synthesis and structure of the new semiconductor compounds Tl2BIIDIVX4 (BII–Cd, Hg; DIV– Si, Ge; X–Se, Te) and isothermal sections of the Tl2Se–CdSe-Ge(Sn)Se2 systems at 570 K14Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials130α‑Li2ZnGeS4: A Wide-Bandgap Diamond-like Semiconductor with Excellent Balance between Laser-Induced Damage Threshold and Second Harmonic Generation Response157Phase Matching, Strong Frequency Doubling, and Outstanding Laser-Induced Damage Threshold in the Biaxial, Quaternary Diamond-like Semiconductor Li 4 CdSn 2 S 779Crystal growth, electronic and optical properties of Tl2CdSnSe4, a recently discovered prospective semiconductor for application in thin film solar cells and optoelectronics26Synergism of multiple functional chromophores significantly enhancing the birefringence in layered non-centrosymmetric chalcohalides20Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials47Cu 4 MnGe 2 S 7 and Cu 2 MnGeS 4 : two polar thiogermanates exhibiting second harmonic generation in the infrared and structures derived from hexagonal diamond22Design and synthesis of Ba 3 SiSe 5 with suitable birefringence modulated via M IV atoms in the Ba–M IV –Q (M IV = Si, Ge; Q = S, Se) system3Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials184Syntheses, Structures and Properties of Alkali and Alkaline Earth Metal Diamond-Like Compounds Li2MgMSe4 (M = Ge, Sn)12Structure Tuning, Strong Second Harmonic Generation Response, and High Optical Stability of the Polar Semiconductors Na1–xKxAsQ234Partial congener substitution induced centrosymmetric to noncentrosymmetric structural transformation and nonlinear optical properties of PbSnSiS413Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties24Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties145Structural, elastic, electronic and optical properties of the newly synthesized selenides Tl2CdXSe4 (X = Ge, Sn)11The Combination of Structure Prediction and Experiment for the Exploration of Alkali‐Earth Metal‐Contained Chalcopyrite‐Like IR Nonlinear Optical Material104Rb 2 CdSi 4 S 10 : novel [Si 4 S 10 ] T2-supertetrahedra-contained infrared nonlinear optical material with large band gap79d6versus d10, Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K2TGe3Ch8 (T = Fe, Cd; Ch = S, Se)18MB 3 P 2 S 10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B 6 P 4 S 20 ] T3-supertetrahedra2Phase Competition and Strong SHG Responses of the Li2MIIMIVSe4 Family: Atom Response Theory Predictions versus Experimental Results24Recent progress of newly developed functional building units and corresponding nonlinear optical materials14BaCu2SiS4: A New Member of the AIIBI2MIVQ4 Chalcogenide Family with a Chiral Crystal Structure6A new nonlinear optical crystal Li0.81Ag0.19InSe2 with balanced properties for efficient nonlinear conversion in the mid-IR region10Crystal structure, electronic structure, and optical properties of Cu4ZnGe2S7 and Cu4CdGe2S7: Polar diamond-like semiconductors exhibiting second harmonic generation10Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates153Mechanochemical synthesis and structural characterization of the I2-II-IV-VI4 quaternary chalcogenide Ag2CdGeSe42Structural, optoelectronic, and magnetic behaviors of Li2BeTM (TM = V, Cr, Mn, Fe) Se4 compounds using DFT investigations0K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties6Isothermal Sections Tl2se–Cdse–Si(Ge)Se2, Quasi-Binary Systems Tl2si(Ge)Se3–Cdse, Tl2cdgese4–Gese2 and the Crystal Structure, Electronic and Optical Properties of Novel Quaternary Selenides Tl2cdsi(Ge)3se81新型非线性光学晶体和双折射晶体的研究进展（特邀）4Cd5As2Br4: A Ternary Arsenide with Nonlinear Optical Property3Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties3Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties26Structural Evolution and Optical Tunability of Diamond-Like Semiconductors Li 2 Zn 1– x Cd x SnS 4 , Li 2 CdSn(S 1– y Se y ) 4 , and Li 2 ZnSn(S 1– y Se y ) 44KGdSiSe 4 and KGdGeSe 4 : two rare earth-based selenides with wide bandgaps and large nonlinear optical responses0KGdSiSe4 and KGdGeSe4: Two Rare Earth Metal-Based Selenides with Wide Bandgaps and Large Nonlinear Optical Responses0Polyhedral replacement-guided design of Ce3MnGaSe7 featuring strong second-harmonic genera-tion and high laser-induced damage threshold0Zn 0.7 Hg 0.3 Ga 2 Se 4 : a defect diamond-like selenide with a balanced band gap and nonlinear optical response0Harnessing tetrahedral diversity: The path to superior diamond-like IR NLO crystals13Variation of Tetrahedrons and Cations Regulates LIDTs in 3D‐DL Structure MIR‐NLO Crystals0

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  1. Correction: Infrared nonlinear optical properties of lithium-containing diamond-like semiconductors Li 2 ZnGeSe 4 and Li 2 ZnSnSe 4

    Dalton Transactions · 2017-01-01

    Ashley Weiland, Jian‐Han Zhang, Daniel J. Clark, Jacilynn A. Brant, Charles W. Sinagra, Yong Soo Kim, Joon Ik Jang, Jennifer A. Aitken

    Read original paper ↗ ·

  2. Li2MnSnSe4: A New Quaternary Diamond‐Like Semiconductor with Nonlinear Optical Response and Antiferromagnetic Property

    Chemistry - An Asian Journal · 2017-10-07

    Xiaoshuang Li, Chao Li, Molin Zhou, Yicheng Wu, Jiyong Yao

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  3. Thallium indium germanium sulphide (TlInGe2S6) as efficient material for nonlinear optical application

    Journal of Alloys and Compounds · 2017-11-24

    Oleg Yu Khyzhun, Volodymyr Babizhetskyy, Ivan V. Kityk, G.L. Myronchuk, Jarosław Jedryka, Gandham Lakshminarayana, Volodymyr Levytskyy, Oksana Tsisar, Л.В. Піскач, O.V. Parasyuk, A.M. El Naggar, A.A. Albassam, Michał Piasecki

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  4. Na 6 Zn 3 MIII2Q 9 (M III = Ga, In; Q = S, Se): four new supertetrahedron-layered chalcogenides with unprecedented vertex-sharing T 3 -clusters and desirable photoluminescence performances

    Inorganic Chemistry Frontiers · 2018-01-01

    Ailijiang Abudurusuli, Kui Wu, Yilimiranmu Rouzhahong, Zhihua Yang, Shilie Pan

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  5. Ternary Mixed-Metal Cd4GeS6: Remarkable Nonlinear-Optical Properties Based on a Tetrahedral-Stacking Framework

    Inorganic Chemistry · 2018-07-13

    Mengyue Li, Bingxuan Li, Hua Lin, Yong‐Fang Shi, Zuju Ma, Li‐Ming Wu, Xintao Wu, Qi‐Long Zhu

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  6. Cation substitution inducing gap changes and covalent interaction flexibility enhancing second harmonic generation responses in d10 metal chalcogenides

    Journal of Alloys and Compounds · 2018-07-30

    Jianian Cheng, Ming‐Hsien Lee, Jun Zhang

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  7. Facile molten salt synthesis, structural, morphological and optical studies of ASiO3: Eu2+, Er3+ (A = Ca, Ba, Sr) perovskites

    Journal of Materials Science Materials in Electronics · 2018-07-30

    Shambhavi Katyayan, Sadhana Agrawal

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  8. Adjustable optical nonlinearity in d 10 cations containing chalcogenides via dp hybridization interaction

    Dalton Transactions · 2019-01-01

    Jianian Cheng, Bing‐Hua Lei, Chen Zhou, Shilie Pan, Zhihua Yang

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  9. From centrosymmetric to noncentrosymmetric: cation-directed structural evolution in X 3 ZnB 5 O 10 (X = Na, K, Rb) and Cs 12 Zn 4 (B 5 O 10 ) 4 crystals

    Inorganic Chemistry Frontiers · 2019-01-01

    Tuohetijiang Baiheti, Shujuan Han, Abudukadi Tudi, Zhihua Yang, Hualiang Yu, Shilie Pan

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  10. Rational design of infrared nonlinear optical chalcogenides by chemical substitution

    Coordination Chemistry Reviews · 2019-12-21

    Hua Lin, Wenbo Wei, Hong Chen, Xintao Wu, Qi‐Long Zhu

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  11. A review of the AI2B II C IV DVI4 family as infrared nonlinear optical materials: the effect of each site on the structure and optical properties

    Chemical Communications · 2020-01-01

    Guangmao Li, Zhihua Yang, Junjie Li, Shilie Pan

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  12. Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2020-03-11

    Xinglong Chen, Hongil Jo, Kang Min Ok

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  13. Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials

    Angewandte Chemie · 2020-03-11

    Xinglong Chen, Hongil Jo, Kang Min Ok

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  14. Synthesis and structure of the new semiconductor compounds Tl2BIIDIVX4 (BII–Cd, Hg; DIV– Si, Ge; X–Se, Te) and isothermal sections of the Tl2Se–CdSe-Ge(Sn)Se2 systems at 570 K

    Journal of Solid State Chemistry · 2020-05-06

    Andrii Selezen, Ivan D. Olekseyuk, G.L. Myronchuk, O.V. Smitiukh, Л.В. Піскач

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  15. Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2020-06-29

    Weikang Wang, Dajiang Mei, Fei Liang, Jun Zhao, Yuandong Wu, Zheshuai Lin

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  16. α‑Li2ZnGeS4: A Wide-Bandgap Diamond-like Semiconductor with Excellent Balance between Laser-Induced Damage Threshold and Second Harmonic Generation Response

    Chemistry of Materials · 2020-09-01

    Jian‐Han Zhang, Daniel J. Clark, Jacilynn A. Brant, Kimberly A. Rosmus, P. Grima, Jonathan W. Lekse, Joon Ik Jang, Jennifer A. Aitken

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  17. Phase Matching, Strong Frequency Doubling, and Outstanding Laser-Induced Damage Threshold in the Biaxial, Quaternary Diamond-like Semiconductor Li 4 CdSn 2 S 7

    Chemistry of Materials · 2020-11-25

    Jian‐Han Zhang, Stanislav S. Stoyko, Andrew J. Craig, P. Grima, Joshua W. Kotchey, Joon Ik Jang, Jennifer A. Aitken

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  18. Crystal growth, electronic and optical properties of Tl2CdSnSe4, a recently discovered prospective semiconductor for application in thin film solar cells and optoelectronics

    Optical Materials · 2020-12-01

    Tuan V. Vu, Anatoliy A. Lavrentyev, B.V. Gabrelian, Andrii Selezen, Л.В. Піскач, G.L. Myronchuk, M. Denysyuk, V.A. Tkach, Khang D. Pham, Oleg Yu Khyzhun

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  19. Synergism of multiple functional chromophores significantly enhancing the birefringence in layered non-centrosymmetric chalcohalides

    Inorganic Chemistry Frontiers · 2020-12-23

    Junben Huang, Jianian Cheng, Bing‐Hua Lei, Zhonglei Wei, Shilie Pan, Zhihua Yang

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  20. Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials

    Journal of Materials Chemistry C · 2021-01-01

    Chang Liu, Shenghua Zhou, Yu Xiao, Chao Zhang, Hua Lin, Yi Liu

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  21. Cu 4 MnGe 2 S 7 and Cu 2 MnGeS 4 : two polar thiogermanates exhibiting second harmonic generation in the infrared and structures derived from hexagonal diamond

    Dalton Transactions · 2021-01-01

    Jennifer R. Glenn, Jeong Bin Cho, Yiqun Wang, Andrew J. Craig, Jian‐Han Zhang, Marvene Cribbs, Stanislav S. Stoyko, Kate E. Rosello, Christopher Barton, Allyson Bonnoni, P. Grima, Joseph H. MacNeil, James M. Rondinelli, Joon Ik Jang, Jennifer A. Aitken

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  22. Design and synthesis of Ba 3 SiSe 5 with suitable birefringence modulated via M IV atoms in the Ba–M IV –Q (M IV = Si, Ge; Q = S, Se) system

    Dalton Transactions · 2021-01-01

    Huanhuan Cheng, Abudukadi Tudi, Peng Wang, Kewang Zhang, Zhihua Yang, Shilie Pan

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  23. Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2021-08-26

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  24. Syntheses, Structures and Properties of Alkali and Alkaline Earth Metal Diamond-Like Compounds Li2MgMSe4 (M = Ge, Sn)

    Materials · 2021-10-18

    Hongbo Gao, Kewang Zhang, Ailijiang Abudurusuli, Chen Bai, Zhihua Yang, Kangrong Lai, Junjie Li, Shilie Pan

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  25. Structure Tuning, Strong Second Harmonic Generation Response, and High Optical Stability of the Polar Semiconductors Na1–xKxAsQ2

    Journal of the American Chemical Society · 2021-10-19

    Abishek K. Iyer, Jeong Bin Cho, Hye Ryung Byun, Michael J. Waters, Shiqiang Hao, Benjamin M. Oxley, Venkat Gopalan, Christopher Wolverton, James M. Rondinelli, Joon Ik Jang, Mercouri G. Kanatzidis

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  26. Partial congener substitution induced centrosymmetric to noncentrosymmetric structural transformation and nonlinear optical properties of PbSnSiS4

    Journal of Alloys and Compounds · 2021-12-23

    Jiazheng Zhou, Ling Luo, Yu Chu, Peng Wang, Zhiyong Guo, Xin Su, Junjie Li

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  27. Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties

    Angewandte Chemie · 2021-12-24

    Xiaohui Li, Zhi‐Hui Shi, Mei Yang, Wenlong Liu, Sheng‐Ping Guo

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  28. Sn7Br10S2: The First Ternary Halogen‐Rich Chalcohalide Exhibiting a Chiral Structure and Pronounced Nonlinear Optical Properties

    Angewandte Chemie International Edition · 2021-12-24

    Xiaohui Li, Zhi‐Hui Shi, Mei Yang, Wenlong Liu, Sheng‐Ping Guo

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  29. Structural, elastic, electronic and optical properties of the newly synthesized selenides Tl2CdXSe4 (X = Ge, Sn)

    The European Physical Journal B · 2022-03-01

    S. Karkour, Abdelmadjid Bouhemadou, Djamel Allali, Khelifa Haddadi, Saad Bin-Omran, R. Khenata, Yarub Al-Douri, Abdelhak Ferhat Hamida, Ahmadi Mohammad Hadi, Alaa Farag Abd El-Rehim

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  30. The Combination of Structure Prediction and Experiment for the Exploration of Alkali‐Earth Metal‐Contained Chalcopyrite‐Like IR Nonlinear Optical Material

    Advanced Science · 2022-04-11

    Peng Wang, Yu Chu, Abudukadi Tudi, Congwei Xie, Zhihua Yang, Shilie Pan, Junjie Li

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  31. Rb 2 CdSi 4 S 10 : novel [Si 4 S 10 ] T2-supertetrahedra-contained infrared nonlinear optical material with large band gap

    Materials Horizons · 2022-11-25

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  32. d6versus d10, Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K2TGe3Ch8 (T = Fe, Cd; Ch = S, Se)

    Inorganic Chemistry · 2022-12-27

    Bingheng Ji, Fei Wang, Kui Wu, Bingbing Zhang, Jian Wang

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  33. MB 3 P 2 S 10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B 6 P 4 S 20 ] T3-supertetrahedra

    Dalton Transactions · 2023-01-01

    Jiazheng Zhou, Xin Su, Ling Luo, Junjie Li, Feng Yu

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  34. Phase Competition and Strong SHG Responses of the Li2MIIMIVSe4 Family: Atom Response Theory Predictions versus Experimental Results

    Chemistry of Materials · 2023-01-24

    Wen‐Dong Yao, Xiyue Cheng, Sheng‐Ping Guo, Myung‐Hwan Whangbo, Bohan Ding, Shuiquan Deng

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  35. Recent progress of newly developed functional building units and corresponding nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-05-11

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  36. BaCu2SiS4: A New Member of the AIIBI2MIVQ4 Chalcogenide Family with a Chiral Crystal Structure

    Zeitschrift für anorganische und allgemeine Chemie · 2023-09-08

    Arka Sarkar, Gayatri Viswanathan, Kui Wu, Gordon J. Miller, Kirill A. Kovnir

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  37. A new nonlinear optical crystal Li0.81Ag0.19InSe2 with balanced properties for efficient nonlinear conversion in the mid-IR region

    Journal of Alloys and Compounds · 2023-10-02

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  38. Crystal structure, electronic structure, and optical properties of Cu4ZnGe2S7 and Cu4CdGe2S7: Polar diamond-like semiconductors exhibiting second harmonic generation

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  39. Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates

    Chemical Society Reviews · 2024-01-01

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  40. Mechanochemical synthesis and structural characterization of the I2-II-IV-VI4 quaternary chalcogenide Ag2CdGeSe4

    Zeitschrift für Naturforschung B · 2024-04-29

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  41. Structural, optoelectronic, and magnetic behaviors of Li2BeTM (TM = V, Cr, Mn, Fe) Se4 compounds using DFT investigations

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  42. K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties

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  43. Isothermal Sections Tl2se–Cdse–Si(Ge)Se2, Quasi-Binary Systems Tl2si(Ge)Se3–Cdse, Tl2cdgese4–Gese2 and the Crystal Structure, Electronic and Optical Properties of Novel Quaternary Selenides Tl2cdsi(Ge)3se8

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  44. 新型非线性光学晶体和双折射晶体的研究进展（特邀）

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  45. Cd5As2Br4: A Ternary Arsenide with Nonlinear Optical Property

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  46. Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties

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  47. Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties

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  48. Structural Evolution and Optical Tunability of Diamond-Like Semiconductors Li 2 Zn 1– x Cd x SnS 4 , Li 2 CdSn(S 1– y Se y ) 4 , and Li 2 ZnSn(S 1– y Se y ) 4

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  49. KGdSiSe 4 and KGdGeSe 4 : two rare earth-based selenides with wide bandgaps and large nonlinear optical responses

    Dalton Transactions · 2026-01-01

    Zhenglong Li, Guansong Zheng, Chen Bai, Leyan Nian, Shilie Pan, Junjie Li

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  50. KGdSiSe4 and KGdGeSe4: Two Rare Earth Metal-Based Selenides with Wide Bandgaps and Large Nonlinear Optical Responses

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