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RESEARCH PAPER · Chemical Communications · 2006

Uranyl ion complexation by citric and tricarballylic acids: hydrothermal synthesis and structure of two- and three-dimensional uranium–organic frameworks

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Uranyl ion complexation by citric and tricarballylic acids: hydrothermal synthesis and structure of two- and three-dimensional uranium–organic frameworksOriginal[N(CH3)4][(UO2)2F5]: A new organically templated open-framework uranium oxide fluoride (MUF-2)38Easy access to stable pentavalent uranyl complexes98Synthesis, structure and fluorescent studies of novel uranium coordination polymers in the pyridinedicarboxylic acid system172Selective Oxo Functionalization of the Uranyl Ion with 3d Metal Cations136Solvothermal Synthesis and Crystal Structure of Uranyl Complexes with 1,1‐Cyclobutanedicarboxylic and (1R,3S)‐(+)‐Camphoric Acids – Novel Chiral Uranyl‐Organic Frameworks39Reaction of uranyl nitrate with carboxylic diacids under hydrothermal conditions. Crystal structure of complexes with l(+)-tartaric and oxalic acids75Neodymium( iii ) d (–)-citramalate: a chiral three-dimensional framework with water-filled channels15Uranyl citrate dimers as guests in a copper–bipyridine framework: a novel heterometallic inorganic–organic hybrid compound35Uranyl ion complexation by the tripodal ligand nitrilotriacetate18Dioxouranium(VI)‐Carboxylate Complexes. Speciation of UO22+‐1,2,3‐Propanetricarboxylate System in NaClaq at Different Ionic Strengths and at T = 25 °C7Uranyl Ion Complexation by Citric and Citramalic Acids in the Presence of Diamines61In situ ligand synthesis with the cation under hydrothermal conditions38Syntheses, structures and magnetic properties of a series of 2D and 3D lanthanide complexes constructed by citric ligand28Structural Diversity and Potential Applications of Metal–Organic Coordination Polymers0Novel two-dimensional uranyl–organic assemblages in the citrate and d (–)-citramalate families46Hydrothermal chemistry of Th(IV) with aromatic dicarboxylates: New framework compounds and in situ ligand syntheses78Highlights in Uranium Coordination Chemistry59Hydrothermal synthesis of uranyl–organic frameworks with pyrazine-2,3-dicarboxylate linkers52Pyrazinetetracarboxylic Acid as an Assembler Ligand in Uranyl−Organic Frameworks74Preparation, Structures, and Photocatalytic Properties of Three New Uranyl−Organic Assembly Compounds218Structural Variation within Homometallic Uranium(VI) Carboxyphosphonates: In Situ Ligand Synthesis, Directed Assembly, Metal−Ligand Coordination and Hydrogen Bonding82Uranyl−Organic Frameworks with 1,2,3,4-Butanetetracarboxylate and 1,2,3,4-Cyclobutanetetracarboxylate Ligands70Uranyl Ion Complexes with Cucurbit[n]urils (n = 6, 7, and 8): A New Family of Uranyl-Organic Frameworks127Uranyl Ion Complexes with Cucurbit[5]uril: from Molecular Capsules to Uranyl-Organic Frameworks103A macrocyclic approach to transition metal and uranyl Pacman complexes103Synthesis and crystal structure of pentavalent uranyl complexes. The remarkable stability of UO2X (X = I, SO3CF3) in non-aqueous solutions95Uranyl–organic bilayer assemblies with flexible aromatic di-, tri- and tetracarboxylic acids55Poly[(μ2-2-hydroxy-2-methylpropionato-κ3O1,O2:O1′)(μ2-2-hydroxy-2-methylpropionato-κ2O1:κO1′)dioxidouranium(VI)]1Two uranyl–organic frameworks with pyridinecarboxylate ligands. A novel heterometallic uranyl–copper(II) complex with a cation–cation interaction57Homometallic Uranium(VI) Phosphonoacetates Containing Interlayer Dipyridines69Oxo ligand functionalization in the uranyl ion (UO22+)335A Nanosized Uranyl Camphorate Cage and its Use as a Building Unit in a Metal−Organic Framework47Uranyl Ion Complexation by Cucurbiturils in the Presence of Perrhenic, Phosphoric, or Polycarboxylic Acids. Novel Mixed-Ligand Uranyl−Organic Frameworks79Synthesis, vibrational spectroscopy and crystal structure of zinc and sodium tricarboxylate coordination polymers with the flexible ligand tricarballylate anion (TCA3−)12Construction of Three‐Dimensional Uranyl–Organic Frameworks with Benzenetricarboxylate Ligands77Americium(III) coordination chemistry: An unexplored diversity of structure and bonding40Synthesis, Crystal Structures, and Characterization of Two 3d‐3d Heterometallic Coordination Frameworks: [ZnCo(Hcit)Cl] and [ZnCo(Hcit)Br]2Uranyl−Organic Assemblies with Acetate-Bearing Phenyl- and Cyclohexyl-Based Ligands45An uranyl citrate coordination polymer with a 3D open-framework involving uranyl cation-cation interactions57Uranyl–Alkali Metal Ion Heterometallic Complexes with Cucurbit[6]uril and a Sulfonated Catechol67Advances in the investigation of dioxouranium(VI) complexes of interest for natural fluids94Potentiometric and spectrophotometric characterization of the UO2 2+-citrate complexes in aqueous solution, at different concentrations, ionic strengths and supporting electrolytes22Uranyl–organic one- and two-dimensional assemblies with 2,2′-bipyridine-3,3′-dicarboxylic, biphenyl-3,3′,4,4′-tetracarboxylic and bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acids50Uranyl–Pyromellitate Coordination Polymers: Toward Three-Dimensional Open Frameworks with Large Channel Systems833-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials76Uranyl Hybrid Material Derived from In Situ Ligand Synthesis: Formation, Structure, and an Unusual Phase Transformation36Uranyl Hybrid Material Derived from In Situ Ligand Synthesis: Formation, Structure, and an Unusual Phase Transformation7Nanomaterials and nanotechnologies in nuclear energy chemistry46Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures418Interaction of tetravalent actinides and Np(V) with some hydroxy carboxylic acids0Bisactinyl halogenated complexes: relativistic density functional theory calculation and experimental synthesis9Chiral uranyl-organic compounds assembled with achiral furandicarboxylic acid by spontaneous resolution45One- to three-dimensional uranyl–organic assemblies with 3-sulfophthalic and 5-sulfoisophthalic acids29Uranyl–3d block metal ion heterometallic carboxylate complexes including additional chelating nitrogen donors37A Uranyl Hybrid Compound Designed from Urea‐Bearing Dipropionic Acid162,2′‐Bipyridine and 1,10‐Phenanthroline as Coligands or Structure‐Directing Agents in Uranyl–Organic Assemblies with Polycarboxylic Acids56Structure and Dynamics of Uranyl(VI) and Plutonyl(VI) Cations in Ionic Liquid/Water Mixtures via Molecular Dynamics Simulations43The crystal chemistry of uranium carboxylates394Molecular and Polymeric Uranyl and Thorium Complexes with Sulfonate‐Containing Ligands33MOFs of Uranium and the Actinides95Physicochemical Properties of Inorganic Citrates1Chemical controls on uranyl citrate speciation and the self-assembly of nanoscale macrocycles and sandwich complexes in aqueous solutions20Design, synthesis and structure of uranyl coordination polymers from 2-D layer to 3-D network structure2Binding constant determination of uranyl–citrate complex by ACE using a multi‐injection method4UO22+-polycarboxylate heterometallic complexes: structure, spectra, and photocatalytic properties12Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species93Variations on the Honeycomb Topology: From Triangular- and Square-Grooved Networks to Tubular Assemblies in Uranyl Tricarballylate Complexes34Experimental and Theoretical Approaches to Three Uranyl Coordination Polymers Constructed by Phthalic Acid and N,N′-Donor Bridging Ligands: Crystal Structures, Luminescence, and Photocatalytic Degradation of Tetracycline Hydrochloride56Influence of Pyrazine/Piperazine Based Guest Molecules in the Crystal Structures of Uranyl Thiophene Dicarboxylate Coordination Polymers: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye47Uranyl Ion Complexes with Chiral Malic and Citramalic, and Prochiral Citric and Tricarballylic Acids: Influence of Coligands and Additional Metal Cations19Crown Ethers and Their Alkali Metal Ion Complexes as Assembler Groups in Uranyl–Organic Coordination Polymers with cis-1,3-, cis-1,2-, and trans-1,2-Cyclohexanedicarboxylates34Diverse stacked and entangled topologies in cadmium tricarballylate coordination polymers with nitrobenzene detection capability8Uranyl Tricarballylate Triperiodic and Nanotubular Species. Counterion Control of Nanotube Diameter13Controlling Cation‐Cation Interactions in Uranyl Coordination Dimers by Varying the Length of the Dicarboxylate Linker4Uptake and Toxicity of Respirable Carbon-Rich Uranium-Bearing Particles: Insights into the Role of Particulates in Uranium Toxicity24Nanotubule inclusion in the channels formed by a six-fold interpenetrated, triperiodic framework7(R,R)-Tartrate as a polytopic ligand for UO22+: Mono- and diperiodic coordination polymers including di- and tetranuclear subunits31,1ʹ-Dimethyl-4,4ʹ-bipyridinium as a multivalent structure-directing counterion to anionic uranyl ion polycarboxylate complexes9Uranium Dynamics in Pit Lakes0Synthesis and Characterization of Three-Dimensional Uranyl Coordination Polymers Containing Selenophene and Tellurophene Linkers0

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  1. [N(CH3)4][(UO2)2F5]: A new organically templated open-framework uranium oxide fluoride (MUF-2)

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  2. Easy access to stable pentavalent uranyl complexes

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  3. Synthesis, structure and fluorescent studies of novel uranium coordination polymers in the pyridinedicarboxylic acid system

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  4. Selective Oxo Functionalization of the Uranyl Ion with 3d Metal Cations

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    Polly Louise Arnold, Dipti Patel, Alexander J. Blake, Claire Wilson, Jason B. Love

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  5. Solvothermal Synthesis and Crystal Structure of Uranyl Complexes with 1,1‐Cyclobutanedicarboxylic and (1R,3S)‐(+)‐Camphoric Acids – Novel Chiral Uranyl‐Organic Frameworks

    European Journal of Inorganic Chemistry · 2006-07-28

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  6. Reaction of uranyl nitrate with carboxylic diacids under hydrothermal conditions. Crystal structure of complexes with l(+)-tartaric and oxalic acids

    Polyhedron · 2006-08-07

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  7. Neodymium( iii ) d (–)-citramalate: a chiral three-dimensional framework with water-filled channels

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  8. Uranyl citrate dimers as guests in a copper–bipyridine framework: a novel heterometallic inorganic–organic hybrid compound

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  9. Uranyl ion complexation by the tripodal ligand nitrilotriacetate

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  10. Dioxouranium(VI)‐Carboxylate Complexes. Speciation of UO22+‐1,2,3‐Propanetricarboxylate System in NaClaq at Different Ionic Strengths and at T = 25 °C

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  11. Uranyl Ion Complexation by Citric and Citramalic Acids in the Presence of Diamines

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  12. In situ ligand synthesis with the cation under hydrothermal conditions

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  13. Syntheses, structures and magnetic properties of a series of 2D and 3D lanthanide complexes constructed by citric ligand

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  14. Structural Diversity and Potential Applications of Metal–Organic Coordination Polymers

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  15. Novel two-dimensional uranyl–organic assemblages in the citrate and d (–)-citramalate families

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  16. Hydrothermal chemistry of Th(IV) with aromatic dicarboxylates: New framework compounds and in situ ligand syntheses

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  17. Highlights in Uranium Coordination Chemistry

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  18. Hydrothermal synthesis of uranyl–organic frameworks with pyrazine-2,3-dicarboxylate linkers

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  19. Pyrazinetetracarboxylic Acid as an Assembler Ligand in Uranyl−Organic Frameworks

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  20. Preparation, Structures, and Photocatalytic Properties of Three New Uranyl−Organic Assembly Compounds

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  21. Structural Variation within Homometallic Uranium(VI) Carboxyphosphonates: In Situ Ligand Synthesis, Directed Assembly, Metal−Ligand Coordination and Hydrogen Bonding

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  22. Uranyl−Organic Frameworks with 1,2,3,4-Butanetetracarboxylate and 1,2,3,4-Cyclobutanetetracarboxylate Ligands

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  23. Uranyl Ion Complexes with Cucurbit[n]urils (n = 6, 7, and 8): A New Family of Uranyl-Organic Frameworks

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  24. Uranyl Ion Complexes with Cucurbit[5]uril: from Molecular Capsules to Uranyl-Organic Frameworks

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  25. A macrocyclic approach to transition metal and uranyl Pacman complexes

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  26. Synthesis and crystal structure of pentavalent uranyl complexes. The remarkable stability of UO2X (X = I, SO3CF3) in non-aqueous solutions

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  27. Uranyl–organic bilayer assemblies with flexible aromatic di-, tri- and tetracarboxylic acids

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  28. Poly[(μ2-2-hydroxy-2-methylpropionato-κ3O1,O2:O1′)(μ2-2-hydroxy-2-methylpropionato-κ2O1:κO1′)dioxidouranium(VI)]

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  29. Two uranyl–organic frameworks with pyridinecarboxylate ligands. A novel heterometallic uranyl–copper(II) complex with a cation–cation interaction

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  30. Homometallic Uranium(VI) Phosphonoacetates Containing Interlayer Dipyridines

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  31. Oxo ligand functionalization in the uranyl ion (UO22+)

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  32. A Nanosized Uranyl Camphorate Cage and its Use as a Building Unit in a Metal−Organic Framework

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  33. Uranyl Ion Complexation by Cucurbiturils in the Presence of Perrhenic, Phosphoric, or Polycarboxylic Acids. Novel Mixed-Ligand Uranyl−Organic Frameworks

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  34. Synthesis, vibrational spectroscopy and crystal structure of zinc and sodium tricarboxylate coordination polymers with the flexible ligand tricarballylate anion (TCA3−)

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  35. Construction of Three‐Dimensional Uranyl–Organic Frameworks with Benzenetricarboxylate Ligands

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  36. Americium(III) coordination chemistry: An unexplored diversity of structure and bonding

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  37. Synthesis, Crystal Structures, and Characterization of Two 3d‐3d Heterometallic Coordination Frameworks: [ZnCo(Hcit)Cl] and [ZnCo(Hcit)Br]

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  38. Uranyl−Organic Assemblies with Acetate-Bearing Phenyl- and Cyclohexyl-Based Ligands

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  39. An uranyl citrate coordination polymer with a 3D open-framework involving uranyl cation-cation interactions

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  40. Uranyl–Alkali Metal Ion Heterometallic Complexes with Cucurbit[6]uril and a Sulfonated Catechol

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  41. Advances in the investigation of dioxouranium(VI) complexes of interest for natural fluids

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  42. Potentiometric and spectrophotometric characterization of the UO2 2+-citrate complexes in aqueous solution, at different concentrations, ionic strengths and supporting electrolytes

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  43. Uranyl–organic one- and two-dimensional assemblies with 2,2′-bipyridine-3,3′-dicarboxylic, biphenyl-3,3′,4,4′-tetracarboxylic and bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acids

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  44. Uranyl–Pyromellitate Coordination Polymers: Toward Three-Dimensional Open Frameworks with Large Channel Systems

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  45. 3-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials

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  46. Uranyl Hybrid Material Derived from In Situ Ligand Synthesis: Formation, Structure, and an Unusual Phase Transformation

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  47. Uranyl Hybrid Material Derived from In Situ Ligand Synthesis: Formation, Structure, and an Unusual Phase Transformation

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  48. Nanomaterials and nanotechnologies in nuclear energy chemistry

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  49. Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures

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  50. Interaction of tetravalent actinides and Np(V) with some hydroxy carboxylic acids

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