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RESEARCH PAPER · Angewandte Chemie International Edition · 2023

Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates

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Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in GermanatesOriginalK 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence18The transformation of a zero-dimensional cluster into a one-dimensional chain structure achieving a dramatically enhanced birefringence in tin( ii )-based oxalates33Cd2Nb2Te4O15: A Novel Pseudo‐Aurivillius‐Type Tellurite with Unprecedented Nonlinear Optical Properties and Excellent Stability40Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence9Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence41In Situ Chiral Template Approach to Synthesize Homochiral Lead Iodides for Second‐Harmonic Generation11In Situ Chiral Template Approach to Synthesize Homochiral Lead Iodides for Second‐Harmonic Generation68Ag 2 [TeO 2 (OH) 4 ]: a nonlinear optical tellurate with balanced comprehensive performance2New ultraviolet transparent rare-earth borates with enhanced birefringence induced by cation chemical substitution15β -CsHg 2 I 5 , a compound with rare [Hg 2 I 5 ] dimers and large optical anisotropy2AX·(H2SeO3)n (A = K, Cs; X = Cl, Br; n = 1, 2): A Series of Ionic Cocrystals as Promising UV Birefringent Materials with Large Birefringence and Wide Band Gap20Giant Optical Anisotropy in a Covalent Molybdenum Tellurite via Oxyanion Polymerization43Na12(NbO)3(PO4)7: A Congruent Melting Nonlinear Optical Crystal with Large NbO6 Distortion and High Laser-Induced Damage Threshold4Li13YGe4O16: A Mid-infrared Rare-Earth Germanate Nonlinear Optical Crystal Featuring a Broad Transmission Range and an Enlarged Band Gap10Near Ultraviolet‐Excitable Cyan‐Emissive Hybrid Copper(I) Halides Nonlinear Optical Crystals with Near‐Unity Photoluminescence Quantum Yield and High‐Efficiency X‐ray Scintillation82Near Ultraviolet‐Excitable Cyan‐Emissive Hybrid Copper(I) Halides Nonlinear Optical Crystals with Near‐Unity Photoluminescence Quantum Yield and High‐Efficiency X‐ray Scintillation13La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra4K4Cd3Ge4O13: A Congruent-Melting Germanate Nonlinear Optical Crystal with a Moderate Second-Harmonic Generation Intensity and Broad Transparent Window2A Giant Optically Anisotropic Phosphate Driven by Mixed Valence Mercury Units22“Three functions in one”: multifunctional rare-earth cyamelurates with magnetism, luminescence, and giant optical nonlinearity6Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)4Different p-block elements induce C 3 [111] octahedral distortion in titanium to generate an intense nonlinear effect14A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy22A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy5La 3 ZrGa 5 O 14 : Band‐Inversion Strategy in Topology‐Protected Octahedron for Large Nonlinear Response and Wide Bandgap18La3ZrGa5O14: Band‐Inversion Strategy in Topology‐Protected Octahedron for Large Nonlinear Response and Wide Bandgap1Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence8Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy16Ca 7 (TeO 3 ) 6 (MoO 4 ): A Promising Mid-Infrared Nonlinear Optical Crystal Activated via a Module-Oriented Dimensionality Reduction Strategy34La3Ga5HfO14: Rare-Earth Polyhedron Coupled with Structural Protected Octahedron for Designing Nonlinear Optical Material with Wide Bandgap and Well-Balanced Properties5Exceptional Second Harmonic Generation in Ultraviolet Nonlinear Optical Oxyfluoroniobate Crystals via Structural Fingerprint Optimization of Polar Chains22Exceptional Second Harmonic Generation in Ultraviolet Nonlinear Optical Oxyfluoroniobate Crystals via Structural Fingerprint Optimization of Polar Chains8A Series of Pentanary Rare-Earth Oxysulfides Obtained by Heterovalent Cation and Anion Cosubstitution Exhibiting Nonlinear Optical Activity and Ultrawide Band Gaps1Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap3A Band‐Orientation Co‐Anchoring Strategy for the Design of a High‐Performance Mid‐Infrared Nonlinear Optical Crystal12Enhancement of Birefringence in Alkali Metal Sulfates Induced by Rare Earth Metal-Centered Polyhedra and Structure Regulation via Cations2Spatial Distribution of the Second Harmonic Emission of a Bent Organic Crystal2Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals5KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy7Mid Infrared Nonlinear Optical Series A 4 MV 5 O 15 X (A = K, Rb; M = Zn, Cd; X = Cl, Br) with Strong Second Harmonic Generation Responses3A promising mid-infrared nonlinear optical crystal with well-balanced properties0A series of langasite-type compounds: size effect regulation for cation occupation and enhanced SHG response1Realizing Phase‐Matching of Nonlinear Optical [ABa 3 Br 2 ][Ga 5 Se 10 ] (A = Cs, Rb, K, Na) Through Large Anisotropic Lattice Distortion111D Cobalt‐Cytidine Monophosphate Coordination Polymer Exhibiting Efficient Ultraviolet Second‐Harmonic Generation7V-Shaped Pseudo-Chains Coupled with Lone-Pair-Distorted [GeX 3 ] − Units Enable Large Birefringence in Ge(II) Hybrid Halides2K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response1Rational design of a quasi-0D tungsten tellurite nonlinear optical crystal with exceptionally balanced properties1Synergistic One-Dimensional Conductive Pathways and Local Polarization Fields for Intrinsic Bulk Charge Separation in Nonpolar Oxide Photocatalysts0Cd/V Ratio-Driven Centrosymmetric Transition of Crystal Structures in Cesium Cadmium Vanadate Oxychlorides Cs 3 CdV 4 O 12 Cl and CsCdV 2 O 6 Cl0Hierarchical Ordering Decouples the SHG–Birefringence–LIDT Trade‐Off in a Single‐Phase Mid‐Infrared Nonlinear Optical Crystal0A Telluromolybdate Mid-Infrared Nonlinear Optical Crystal with Wide Transparency and Strong Second-Harmonic Generation Response0

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  1. K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence

    Dalton Transactions · 2023-01-01

    Luyong Zhang, Shi‐Bin Wang, Fangfang Zhang, Zhihua Yang, Xueling Hou

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  2. The transformation of a zero-dimensional cluster into a one-dimensional chain structure achieving a dramatically enhanced birefringence in tin( ii )-based oxalates

    Inorganic Chemistry Frontiers · 2023-01-01

    Liying Ren, Linhong Cheng, Xiaoyan Zhou, Jinxuan Ren, Liling Cao, Ling Huang, Xuehua Dong, Yuqiao Zhou, Daojiang Gao, Guohong Zou

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  3. Cd2Nb2Te4O15: A Novel Pseudo‐Aurivillius‐Type Tellurite with Unprecedented Nonlinear Optical Properties and Excellent Stability

    Small · 2023-05-28

    Qiang Wang, Xuehua Dong, Ling Huang, Kang Min Ok, Zhien Lin, Guohong Zou

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  4. Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence

    Angewandte Chemie · 2023-12-20

    Tianhui Wu, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  5. Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence

    Angewandte Chemie International Edition · 2023-12-20

    Tianhui Wu, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  6. In Situ Chiral Template Approach to Synthesize Homochiral Lead Iodides for Second‐Harmonic Generation

    Angewandte Chemie · 2023-12-21

    Juan Cheng, Gangji Yi, Zhizhuan Zhang, Ying Long, Hongmei Zeng, Ling Huang, Guohong Zou, Zhien Lin

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  7. In Situ Chiral Template Approach to Synthesize Homochiral Lead Iodides for Second‐Harmonic Generation

    Angewandte Chemie International Edition · 2023-12-21

    Juan Cheng, Gangji Yi, Zhizhuan Zhang, Ying Long, Hongmei Zeng, Ling Huang, Guohong Zou, Zhien Lin

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  8. Ag 2 [TeO 2 (OH) 4 ]: a nonlinear optical tellurate with balanced comprehensive performance

    Journal of Materials Chemistry C · 2024-01-01

    Wenjing Tan, Xuefan Wang, Ruqing Wei, Hongbo Huang, Daqing Yang, Ying Wang, Bingbing Zhang

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  9. New ultraviolet transparent rare-earth borates with enhanced birefringence induced by cation chemical substitution

    Inorganic Chemistry Frontiers · 2024-01-01

    Guanglian Sun, Xiaofang Qi, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  10. β -CsHg 2 I 5 , a compound with rare [Hg 2 I 5 ] dimers and large optical anisotropy

    Dalton Transactions · 2024-01-01

    Yingying Kong, Hongshan Wang, Wang Zhao, Qi Sun, Junjie Li, Shilie Pan

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  11. AX·(H2SeO3)n (A = K, Cs; X = Cl, Br; n = 1, 2): A Series of Ionic Cocrystals as Promising UV Birefringent Materials with Large Birefringence and Wide Band Gap

    Inorganic Chemistry · 2024-01-18

    Mengmeng Zhu, Junbo Wang, Lei Hou, Yiwen Yuan, Lili Liu, Yaoqing Chu, Chunmei Huang

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  12. Giant Optical Anisotropy in a Covalent Molybdenum Tellurite via Oxyanion Polymerization

    Advanced Science · 2024-01-30

    Tianhui Wu, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  13. Na12(NbO)3(PO4)7: A Congruent Melting Nonlinear Optical Crystal with Large NbO6 Distortion and High Laser-Induced Damage Threshold

    Inorganic Chemistry · 2024-02-08

    Ziyan Lv, Rukang K. Li

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  14. Li13YGe4O16: A Mid-infrared Rare-Earth Germanate Nonlinear Optical Crystal Featuring a Broad Transmission Range and an Enlarged Band Gap

    Inorganic Chemistry · 2024-02-15

    Jinmiao Jiao, Conggang Li, Yuheng She, Haiyan Shi, Wenhao Di, Ning Ye, Zhanggui Hu, Yicheng Wu

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  15. Near Ultraviolet‐Excitable Cyan‐Emissive Hybrid Copper(I) Halides Nonlinear Optical Crystals with Near‐Unity Photoluminescence Quantum Yield and High‐Efficiency X‐ray Scintillation

    Angewandte Chemie International Edition · 2024-07-09

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  16. Near Ultraviolet‐Excitable Cyan‐Emissive Hybrid Copper(I) Halides Nonlinear Optical Crystals with Near‐Unity Photoluminescence Quantum Yield and High‐Efficiency X‐ray Scintillation

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    Jing‐Li Qi, Yue Guo, Jiajing Wu, Qiao‐Feng Huang, Junjie Xu, Shufang Yan, Wenlong Liu, Sheng‐Ping Guo

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  17. La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra

    Inorganic Chemistry · 2024-07-25

    Jingxuan Hou, Jiajia Wang, Fei Liang, Shihui Ma, Hongwei Yu, Hongping Wu, Ning Ye, Zhanggui Hu, Yicheng Wu

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  18. K4Cd3Ge4O13: A Congruent-Melting Germanate Nonlinear Optical Crystal with a Moderate Second-Harmonic Generation Intensity and Broad Transparent Window

    Inorganic Chemistry · 2024-09-30

    Yujun Wang, Jing Chai, Jinmiao Jiao, Xianghao Kong, Tinghui Zhang, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  19. A Giant Optically Anisotropic Phosphate Driven by Mixed Valence Mercury Units

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  20. “Three functions in one”: multifunctional rare-earth cyamelurates with magnetism, luminescence, and giant optical nonlinearity

    Chemical Science · 2025-01-01

    Jing Zhang, Yuxiao Liu, Fangyan Wang, Pifu Gong, Zhaoyi Li, Xinyuan Zhang, Fei Liang, Shu Hai Guo, Zhanggui Hu, Yicheng Wu

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  21. Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)

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  22. Different p-block elements induce C 3 [111] octahedral distortion in titanium to generate an intense nonlinear effect

    Chemical Science · 2025-01-01

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  23. A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy

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  24. A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy

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  25. La 3 ZrGa 5 O 14 : Band‐Inversion Strategy in Topology‐Protected Octahedron for Large Nonlinear Response and Wide Bandgap

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  26. La3ZrGa5O14: Band‐Inversion Strategy in Topology‐Protected Octahedron for Large Nonlinear Response and Wide Bandgap

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  27. Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence

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  28. Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy

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  29. Ca 7 (TeO 3 ) 6 (MoO 4 ): A Promising Mid-Infrared Nonlinear Optical Crystal Activated via a Module-Oriented Dimensionality Reduction Strategy

    Journal of the American Chemical Society · 2025-05-15

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  30. La3Ga5HfO14: Rare-Earth Polyhedron Coupled with Structural Protected Octahedron for Designing Nonlinear Optical Material with Wide Bandgap and Well-Balanced Properties

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  31. Exceptional Second Harmonic Generation in Ultraviolet Nonlinear Optical Oxyfluoroniobate Crystals via Structural Fingerprint Optimization of Polar Chains

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  32. Exceptional Second Harmonic Generation in Ultraviolet Nonlinear Optical Oxyfluoroniobate Crystals via Structural Fingerprint Optimization of Polar Chains

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  33. A Series of Pentanary Rare-Earth Oxysulfides Obtained by Heterovalent Cation and Anion Cosubstitution Exhibiting Nonlinear Optical Activity and Ultrawide Band Gaps

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  34. Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap

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  35. A Band‐Orientation Co‐Anchoring Strategy for the Design of a High‐Performance Mid‐Infrared Nonlinear Optical Crystal

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  36. Enhancement of Birefringence in Alkali Metal Sulfates Induced by Rare Earth Metal-Centered Polyhedra and Structure Regulation via Cations

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  37. Spatial Distribution of the Second Harmonic Emission of a Bent Organic Crystal

    Advanced Optical Materials · 2025-10-26

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  38. Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals

    Chemical Science · 2025-11-18

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  39. KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy

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  40. Mid Infrared Nonlinear Optical Series A 4 MV 5 O 15 X (A = K, Rb; M = Zn, Cd; X = Cl, Br) with Strong Second Harmonic Generation Responses

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  41. A promising mid-infrared nonlinear optical crystal with well-balanced properties

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  42. A series of langasite-type compounds: size effect regulation for cation occupation and enhanced SHG response

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  43. Realizing Phase‐Matching of Nonlinear Optical [ABa 3 Br 2 ][Ga 5 Se 10 ] (A = Cs, Rb, K, Na) Through Large Anisotropic Lattice Distortion

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  44. 1D Cobalt‐Cytidine Monophosphate Coordination Polymer Exhibiting Efficient Ultraviolet Second‐Harmonic Generation

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  45. V-Shaped Pseudo-Chains Coupled with Lone-Pair-Distorted [GeX 3 ] − Units Enable Large Birefringence in Ge(II) Hybrid Halides

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  46. K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response

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  47. Rational design of a quasi-0D tungsten tellurite nonlinear optical crystal with exceptionally balanced properties

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  48. Synergistic One-Dimensional Conductive Pathways and Local Polarization Fields for Intrinsic Bulk Charge Separation in Nonpolar Oxide Photocatalysts

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  49. Cd/V Ratio-Driven Centrosymmetric Transition of Crystal Structures in Cesium Cadmium Vanadate Oxychlorides Cs 3 CdV 4 O 12 Cl and CsCdV 2 O 6 Cl

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  50. Hierarchical Ordering Decouples the SHG–Birefringence–LIDT Trade‐Off in a Single‐Phase Mid‐Infrared Nonlinear Optical Crystal

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