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RESEARCH PAPER · Inorganic Chemistry · 2024

AX·(H2SeO3)n (A = K, Cs; X = Cl, Br; n = 1, 2): A Series of Ionic Cocrystals as Promising UV Birefringent Materials with Large Birefringence and Wide Band Gap

Mengmeng Zhu, Junbo Wang, Lei Hou, Yiwen Yuan, Lili Liu, Yaoqing Chu, Chunmei Huang

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AX·(H2SeO3)n (A = K, Cs; X = Cl, Br; n = 1, 2): A Series of Ionic Cocrystals as Promising UV Birefringent Materials with Large Birefringence and Wide Band GapOriginalDesigning excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups23NaVSeO 5 : synergistic combinations to synthesize excellent birefringent materials8Pb 2 (SeO 3 )(SiF 6 ): the first selenite fluorosilicate with a wide bandgap and large birefringence achieved through perfluorinated group modification46A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals9Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups11Hydrogen bonding regulation-oriented design of pyridine sulfonate as a promising UV birefringent crystal characterized by enhanced structural anisotropy11Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence8Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy16La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence13NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence1A Neutron Diffraction Study of the Crystal Structure of Hydrogen-Containing Compounds at the MOND Station, NRC KI1[C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy13Effect of Multiple Hydrogen Bonding on the π-Conjugated Groups and Optical Properties in Molecular Crystals5A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination1Polymerization-enhanced optical anisotropy in selenites: a trimeric [H 2 Se 3 O 7 ] motif delivering large UV birefringence0Synergistic Enhancement of Optical Anisotropy in Nitrate Sulfamate for UV Applications: Role of Functional Group Alignment and Hydrogen Bond Network1Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5The novel Zn-based ultraviolet birefringent crystals combined both large birefringence and wide bandgap2Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides0Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides0

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  1. Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Xiaoyan Zhou, Xiang Mao, Pu Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  2. NaVSeO 5 : synergistic combinations to synthesize excellent birefringent materials

    Inorganic Chemistry Frontiers · 2024-01-01

    Qiuyuan Feng, Jialong Wang, Changyou Liu, Qun Jing, Xiaoyu Dong

    Read original paper ↗ ·

  3. Pb 2 (SeO 3 )(SiF 6 ): the first selenite fluorosilicate with a wide bandgap and large birefringence achieved through perfluorinated group modification

    Chemical Science · 2024-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  4. A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals

    Inorganic Chemistry Frontiers · 2025-01-01

    Yi‐Lei Lv, Liang Ma, Guo-Ren Zhu, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  5. Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups

    Journal of Materials Chemistry C · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  6. Hydrogen bonding regulation-oriented design of pyridine sulfonate as a promising UV birefringent crystal characterized by enhanced structural anisotropy

    Chemical Science · 2025-01-01

    Longyun Xu, Conggang Li, Shuaifeng Li, Huijian Zhao, Xianghao Kong, Zaixin Qu, Wen-Jie Feng, Kaidong Xu, Ning Ye, Zhanggui Hu

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  7. Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence

    Chemistry - A European Journal · 2025-04-07

    Yang Li, Jihyun Lee, Kang Min Ok

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  8. Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy

    Laser & Photonics Review · 2025-04-10

    Piao Tang, Xin Wen, Yuchen Yan, Cao Xue, Jindong Chen, Chensheng Lin, Min Luo, Ning Ye, Guang Peng

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  9. La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence

    Inorganic Chemistry · 2025-05-01

    Pengfei Li, Xiaoxue Wang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  10. NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence

    Inorganic Chemistry · 2025-05-01

    Chenhui Hu, Jiale Qu, Jinghui Hu, Junjie Liu, Wenchao Hu, Xiangzhan Jiang

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  11. A Neutron Diffraction Study of the Crystal Structure of Hydrogen-Containing Compounds at the MOND Station, NRC KI

    Crystallography Reports · 2025-06-01

    Irina P. Makarova, N. N. Isakova, A. I. Kalyukanov, Sergey M. Aksenov, Dmitri O. Charkin, Oleg I. Siidra, Alla L. Tolstikhina, Radmir V. Gainutdinov, В. А. Коморников

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  12. [C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy

    Chinese Journal of Chemistry · 2025-06-24

    Shaohua Liu, Xiaoqin Ma, Xifa Long, Yun Mo Yang

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  13. Effect of Multiple Hydrogen Bonding on the π-Conjugated Groups and Optical Properties in Molecular Crystals

    Inorganic Chemistry · 2025-11-03

    Hangwei Jia, Xiangrong Song, Muhammad Arif, Yaqi Jin, Feng Yu, Xueling Hou

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  14. A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination

    Dalton Transactions · 2026-01-01

    Chen Zhu, Xiao-Min Wu, Xiao-Xue Wang, Si-Qi Zhou, Jing-Jing Wu, Xin-Lei Liu, You-Qian Wu, Jiannian Yao, Peng-Fei Li, Yu-Wu Zhong

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  15. Polymerization-enhanced optical anisotropy in selenites: a trimeric [H 2 Se 3 O 7 ] motif delivering large UV birefringence

    Inorganic Chemistry Frontiers · 2026-01-01

    Xize Zhan, Gangji Yi, Xuan Zou, Gen Li, Lu Liu, Jiarong Lv, Hongmei Zeng, Zhien Lin, Guohong Zou

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  16. Synergistic Enhancement of Optical Anisotropy in Nitrate Sulfamate for UV Applications: Role of Functional Group Alignment and Hydrogen Bond Network

    Small · 2026-04-09

    Xiaotian Ma, Hongyuan Sha, Qianzhen Zhang, Ruyi Niu, Xiya Wen, Xifa Long, Shilie Pan, Yun Mo Yang

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  17. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  18. The novel Zn-based ultraviolet birefringent crystals combined both large birefringence and wide bandgap

    Applied Physics Letters · 2026-06-15

    Xinyue Shi, Xueqing Liu, Yipeng Pang, Yuan Fang, Degao Zhong, Bing Teng, Y Huang, Zhoubin Lin, Shijia Sun

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  19. Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides

    Angewandte Chemie International Edition · 2026-09-03

    S. D. Lee, Wei Zeng, Congcong Jin, Chong‐An Chen, Kang Min Ok

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  20. Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides

    Angewandte Chemie · 2026-09-03

    S. D. Lee, Wei Zeng, Congcong Jin, Chong‐An Chen, Kang Min Ok

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