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RESEARCH PAPER · Laser & Photonics Review · 2024

A Giant Optically Anisotropic Phosphate Driven by Mixed Valence Mercury Units

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A Giant Optically Anisotropic Phosphate Driven by Mixed Valence Mercury UnitsOriginalNoncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap16Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups12Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups11Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification6Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence8Unveiling the potential of rare-earth XCuSeO (X = Dy, Sm) oxychalcogenides for high-performance UV shielding and photovoltaics2From AgHgI(SO4) to AgHg3I3.2Cl1.8(SO4): Symmetry Breaking of the Belousovite‐Type Topology by Mixed Halides to Achieve Strong Nonlinear Optical Effect14La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence13Recent progress in structural design strategies of high-birefringence optical crystals55(NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance1[TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence18[TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence4CsICl 2 : A Record-Birefringent Inorganic Crystal with Ultrawide Infrared Transparency Enabled by Linear Interhalogen ICl 2 – Units38Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy8[Cd 4 P 2 ][I 3 ] and [Cd 2 P][CdCl 3 ]: two Millon's phase phosphides exhibiting wide band gaps and large birefringence0A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination1Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )0[Hg3Se2]2- cluster drives giant optical anisotropy and broad infrared transparency16Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5Record‐High Birefringence with Ultralow Dichroic Loss Realized by Cation‐Templated Engineering Ordered Assembly of Linear Birefringent‐Active Unit6AVP2S7 (A = K, Rb): Dual-Optimized Infrared Nonlinear Optical Thiophosphates via Heterovalent-Substitution-Driven Symmetry Breaking and Reinforced Interlayer Interactions0EuMn6Ga6S16: A Wide Bandgap Europium-Based Nonlinear Optical Sulfide0

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  1. Noncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap

    Chemical Science · 2024-01-01

    Dandan Zhou, Chun‐Li Hu, Xinwei Zhang, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·
  2. Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups

    Inorganic Chemistry Frontiers · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·
  3. Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups

    Journal of Materials Chemistry C · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  4. Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification

    Dalton Transactions · 2025-01-01

    Pengfei Li, Xinlei Liu, Si-Qi Zhou, Mingchang Wang, Jingjing Wu, Yu‐Wu Zhong, Jiannian Yao

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  5. Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence

    Chemistry - A European Journal · 2025-04-07

    Yang Li, Jihyun Lee, Kang Min Ok

    Read original paper ↗ ·
  6. Unveiling the potential of rare-earth XCuSeO (X = Dy, Sm) oxychalcogenides for high-performance UV shielding and photovoltaics

    Journal of Solid State Chemistry · 2025-04-24

    Banat Gul, Mohannad Mahmoud Ali Al-Hmoud, Muhammad Salman Khan, Siti Maisarah Aziz

    Read original paper ↗ ·
  7. From AgHgI(SO4) to AgHg3I3.2Cl1.8(SO4): Symmetry Breaking of the Belousovite‐Type Topology by Mixed Halides to Achieve Strong Nonlinear Optical Effect

    Laser & Photonics Review · 2025-04-30

    Qian‐Qian Chen, Ming‐Zhi Zhang, Jin Chen, Bingxuan Li, Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·
  8. La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence

    Inorganic Chemistry · 2025-05-01

    Pengfei Li, Xiaoxue Wang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·
  9. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  10. (NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance

    Journal of Molecular Structure · 2025-06-07

    Chen-Yuan Ma, Qiang Tu, Yu-Ming Pan, Pei De Han, Meihong Duan, Zhi Gang Fang

    Read original paper ↗ ·
  11. [TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence

    Angewandte Chemie International Edition · 2025-06-17

    Bo Zhang, Wei‐Qi Huang, Jiaxiang Zhang, Xintao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·
  12. [TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence

    Angewandte Chemie · 2025-06-17

    Bo Zhang, Wei‐Qi Huang, Jiaxiang Zhang, Xintao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·
  13. CsICl 2 : A Record-Birefringent Inorganic Crystal with Ultrawide Infrared Transparency Enabled by Linear Interhalogen ICl 2 – Units

    Journal of the American Chemical Society · 2025-07-21

    Chong‐An Chen, Yang Li, Congcong Jin, Kang Min Ok

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  14. Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy

    Inorganic Chemistry · 2025-07-25

    Wen-Ye Gao, Siyu Ma, Bing-Wei Miao, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

    Read original paper ↗ ·
  15. [Cd 4 P 2 ][I 3 ] and [Cd 2 P][CdCl 3 ]: two Millon's phase phosphides exhibiting wide band gaps and large birefringence

    Dalton Transactions · 2026-01-01

    Fupeng Wang, Guang Peng, Ning Ye, Jindong Chen

    Read original paper ↗ ·
  16. A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination

    Dalton Transactions · 2026-01-01

    Chen Zhu, Xiao-Min Wu, Xiao-Xue Wang, Si-Qi Zhou, Jing-Jing Wu, Xin-Lei Liu, You-Qian Wu, Jiannian Yao, Peng-Fei Li, Yu-Wu Zhong

    Read original paper ↗ ·
  17. Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )

    Dalton Transactions · 2026-01-01

    Yi Yuan, Chun‐Li Hu, Dan-Dan Zhou, Jiang‐Gao Mao, Fang Kong

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  18. [Hg3Se2]2- cluster drives giant optical anisotropy and broad infrared transparency

    Nature Communications · 2026-01-06

    Qixian Ren, Chen Cui, Xinchen Chen, Yabo Wu, Ran An, Zhihua Yang, Shilie Pan

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  19. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  20. Record‐High Birefringence with Ultralow Dichroic Loss Realized by Cation‐Templated Engineering Ordered Assembly of Linear Birefringent‐Active Unit

    Advanced Functional Materials · 2026-05-22

    Jing‐Jing Zhao, Q Zhang, Shu‐Fang Li, Honggang Gu, Shiyuan Liu, Hongbo Huang, Bingbing Zhang, Dong Yan

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  21. AVP2S7 (A = K, Rb): Dual-Optimized Infrared Nonlinear Optical Thiophosphates via Heterovalent-Substitution-Driven Symmetry Breaking and Reinforced Interlayer Interactions

    Inorganic Chemistry · 2026-08-11

    Shao-Peng Gui, Zi-Nan Chen, Wei-Hua Yan, Yu‐Xuan Zhang, Mao‐Yin Ran, Sheng‐Ping Guo

    Read original paper ↗ ·
  22. EuMn6Ga6S16: A Wide Bandgap Europium-Based Nonlinear Optical Sulfide

    Inorganic Chemistry · 2026-08-16

    Yu‐Xuan Zhang, Jiang-Hui Fan, Zhen‐Cheng Wu, Shao-Peng Gui, Mao‐Yin Ran, Sheng‐Ping Guo

    Read original paper ↗ ·