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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2024

New ultraviolet transparent rare-earth borates with enhanced birefringence induced by cation chemical substitution

Guanglian Sun, Xiaofang Qi, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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New ultraviolet transparent rare-earth borates with enhanced birefringence induced by cation chemical substitutionOriginalA Rare-Earth-Based Borate Optical Crystal with Enlarged Dihedral Angles of Distinct [BO3] Groups Exhibiting a Wide UV Transparent Range8BaPb2(CO3)2F2: Enhancing Birefringence by a Multiunit Synergy Effect9Deep ultraviolet transparent borophosphates LiAB 2 P 2 O 9 (A = NH 4 , K) and LiNaB 2 P 2 O 8 (OH) 2 ·H 2 O exhibiting a moderate second-harmonic generation response4Cationic substitution engineering induces a new quaternary chalcogenide in the A–M IIIA –M IVA –Q system for optical crystal applications1Selenoborates: a latent structure resource for infrared functional crystal materials1Synthesising a series of promising ultraviolet nonlinear optical materials with the aid of the flexibility of isolated [B 5 O 10 ] groups3Hydrogen‐Bonded Assembly of Functional Units for Constructing Linear and Nonlinear Optical Crystals10Cd3Sc(BO3)3: a novel orthoborate with pseudo-1D ∞[ScB6O18] chains0Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy8K 7 MgY 2 (B 5 O 10 ) 3 : a novel ultraviolet nonlinear optical crystal based on the [B 5 O 10 ] functional unit2Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency1[Ba2K][Br][SiS4]: An antiperovskite-type chalcohalide with simultaneously enhanced birefringence and band gap via cation-anion co-substitution0Synthesis, Crystal Structure, and Characterization of a New Borosilicate: Li 2 Ba 3 Y 3 B 5 SiO 180Potential Deep Ultraviolet Phosphate With Y‐Based: 1 [(PO 3 ) 4 ] ∞ Chains AYP 4 O 12 (A = K, NH 4 ) and the First [P 3 O 10 ] Anionic Framework KLiYP 3 O 100Influence of the Cation Size on Symmetry Breaking and Optical Performances in Ae2Mg3(BO3)2F4 (Ae = Sr, Ba)0

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  1. A Rare-Earth-Based Borate Optical Crystal with Enlarged Dihedral Angles of Distinct [BO3] Groups Exhibiting a Wide UV Transparent Range

    Inorganic Chemistry · 2024-07-26

    Jie Song, Xianghao Kong, Conggang Li, Jinmiao Jiao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

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  2. BaPb2(CO3)2F2: Enhancing Birefringence by a Multiunit Synergy Effect

    Inorganic Chemistry · 2024-12-02

    Yuan Hua Lin, Rongfang Zhang, Yucheng Hao, Ming-Yang Cao, Xuanlin Pan, Jiang‐Gao Mao

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  3. Deep ultraviolet transparent borophosphates LiAB 2 P 2 O 9 (A = NH 4 , K) and LiNaB 2 P 2 O 8 (OH) 2 ·H 2 O exhibiting a moderate second-harmonic generation response

    Journal of Materials Chemistry C · 2024-12-23

    Huanhuan Zhao, Chenxu Li, Juanjuan Lu, Zhihua Yang, Jian Wei Han, Shilie Pan

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  4. Cationic substitution engineering induces a new quaternary chalcogenide in the A–M IIIA –M IVA –Q system for optical crystal applications

    CrystEngComm · 2025-01-01

    Yue Wang, Xuezhong Li, Zihao Lou, Yong‐Fang Shi

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  5. Selenoborates: a latent structure resource for infrared functional crystal materials

    Inorganic Chemistry Frontiers · 2025-01-01

    Yihan Yun, Abudukadi Tudi, Zhihua Yang, Guangmao Li, Shilie Pan

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  6. Synthesising a series of promising ultraviolet nonlinear optical materials with the aid of the flexibility of isolated [B 5 O 10 ] groups

    Dalton Transactions · 2025-01-01

    Yixin Song, Hongwei Yu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  7. Hydrogen‐Bonded Assembly of Functional Units for Constructing Linear and Nonlinear Optical Crystals

    Advanced Optical Materials · 2025-04-29

    Ziqi Chen, Changyou Liu, Chenxu Li, Juanjuan Lu, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  8. Cd3Sc(BO3)3: a novel orthoborate with pseudo-1D ∞[ScB6O18] chains

    Polyhedron · 2025-06-24

    Runqing Liu, Yuntian Zhao, Jiming Huang, Shibo Guan, Senlin Leng

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  9. Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy

    Inorganic Chemistry · 2025-07-25

    Wen-Ye Gao, Siyu Ma, Bing-Wei Miao, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  10. K 7 MgY 2 (B 5 O 10 ) 3 : a novel ultraviolet nonlinear optical crystal based on the [B 5 O 10 ] functional unit

    New Journal of Chemistry · 2026-01-01

    Haozhen Liu, Shiyu Du, Paipai Zhang, Jiawei Zhao, Yanna Chen, Donghai An

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  11. Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency

    Inorganic Chemistry · 2026-02-05

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu, Yongmin Guo

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  12. [Ba2K][Br][SiS4]: An antiperovskite-type chalcohalide with simultaneously enhanced birefringence and band gap via cation-anion co-substitution

    Inorganic Chemistry Communications · 2026-03-10

    Yue Wang, Hua Wang, Rongfang Jiang, Yongfang Shi

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  13. Synthesis, Crystal Structure, and Characterization of a New Borosilicate: Li 2 Ba 3 Y 3 B 5 SiO 18

    Zeitschrift für anorganische und allgemeine Chemie · 2026-06-08

    Yidan Zhang, Xiaoqing Xu, HS Wu

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  14. Potential Deep Ultraviolet Phosphate With Y‐Based: 1 [(PO 3 ) 4 ] ∞ Chains AYP 4 O 12 (A = K, NH 4 ) and the First [P 3 O 10 ] Anionic Framework KLiYP 3 O 10

    European Journal of Inorganic Chemistry · 2026-09-15

    Jingru Xu, Jiawei Zhao, Paipai Zhang, Juhui Cui, Hong Lei Du, Minqiang Gai

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  15. Influence of the Cation Size on Symmetry Breaking and Optical Performances in Ae2Mg3(BO3)2F4 (Ae = Sr, Ba)

    Inorganic Chemistry · 2026-10-05

    Yu Qiu, Haonan Liu, Yujie Zhang, Hongping Wu, Hongwei Yu

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