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RESEARCH PAPER · Journal of the American Chemical Society · 2025

Ca 7 (TeO 3 ) 6 (MoO 4 ): A Promising Mid-Infrared Nonlinear Optical Crystal Activated via a Module-Oriented Dimensionality Reduction Strategy

Tinghui Zhang, Fei Liang, Conggang Li, Ning Ye, Zhanggui Hu

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Ca 7 (TeO 3 ) 6 (MoO 4 ): A Promising Mid-Infrared Nonlinear Optical Crystal Activated via a Module-Oriented Dimensionality Reduction StrategyOriginal(C 14 H 14 N 2 )MCl 4 (M = Zn, Cd): two hybrid metal halides exhibiting strong second harmonic generation responses, large birefringence, and broadband photoluminescence12Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification6Multifactorial Directed Regulation Of the [Io 3 ] − Units in Praseodymium-Contained Iodates0Nonlinear Optical Series A(VO2)3(SeO3)2 (A = NH4+, K+, and H3O+) with Large Birefringence Derived from High-Anisotropic VO6 Octahedra and SeO3 Pyramids8Modulation of Crystal Structure and Birefringence: Cation Size Effect in Alkali Metal Fluoroaluminoborates4Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals14Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals3A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response3Multifactorial directed regulation of anionic units in praseodymium-contained iodates1Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap3Deprotonation-Regulated Conformational Switching in Malonates Enables High-Performance Ultraviolet Polar Crystals3Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals5Stereochemically Active Lone‐Pair Electrons Driven High‐Performance and Self‐Powered X‐Ray Detection in Cs 2 TeMo 3 O 12 Crystal1A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination1A promising mid-infrared nonlinear optical crystal with well-balanced properties0Inorganic Ge-based ferroelectric perovskites towards quasi-phase-matching in the infrared region0Li 3 GaTe 4 O 11 : small ion-driven orientation of TeO n units in a tunnel-structured tellurite1Optical anisotropy in Mo–Te–O frameworks constructed from distorted MoO 6 and TeO 3 units0Synergism of [C 2 N 4 H 7 S] cations and anionic modulators: tailoring second-order nonlinear optics and birefringence in organic–inorganic crystals6Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )0InO6X (X = Cl, Br): distinct functional motif family for nonlinear optical materials5Engineering Eu3+-activated molybdenum tellurates via alkali metal co-doping for enhanced luminescence in advanced lighting and security ink applications6Microwave/Terahertz Dielectric Properties of a Novel NaSrGdMo 3 O 12 Scheelite Ceramic for Patch Antenna Applications3K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response1Rational design of a quasi-0D tungsten tellurite nonlinear optical crystal with exceptionally balanced properties1Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5Breaking Inversion Symmetry via Vanadium Coordination Engineering in Bismuth Vanadium Selenites0Metal tellurite oxides: Lone-pair-enabled coordination chemistry, polymerized architectures, and functional materials opportunities1Research advances in rare-earth nonlinear optical crystalline materials in 20250Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization0Entropy‐Driven Precursor Symmetry Breaking for Phase‐Selective Synthesis of Noncentrosymmetric Rb 2 CdCl 2 I 20Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal0A Telluromolybdate Mid-Infrared Nonlinear Optical Crystal with Wide Transparency and Strong Second-Harmonic Generation Response0Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)0

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34 direct citing papers saved.

  1. (C 14 H 14 N 2 )MCl 4 (M = Zn, Cd): two hybrid metal halides exhibiting strong second harmonic generation responses, large birefringence, and broadband photoluminescence

    Inorganic Chemistry Frontiers · 2025-01-01

    Xinhui Li, Pifu Gong, Mingxing Chen, Shujuan Zhuang, Man Qi, Wenqiang Wang, Xinfang Wang, Zhen Jia, Mingjun Xia

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  2. Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification

    Dalton Transactions · 2025-01-01

    Pengfei Li, Xinlei Liu, Si-Qi Zhou, Mingchang Wang, Jingjing Wu, Yu‐Wu Zhong, Jiannian Yao

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  3. Multifactorial Directed Regulation Of the [Io 3 ] − Units in Praseodymium-Contained Iodates

    SSRN Electronic Journal · 2025-01-01

    Ping Wang, Zhengli Liang, Zhenhua Li, Quanjie Yang, Lehui Liu, Xingxing Jiang, Zheshuai Lin, Hongming Liu

    Read original paper ↗ ·

  4. Nonlinear Optical Series A(VO2)3(SeO3)2 (A = NH4+, K+, and H3O+) with Large Birefringence Derived from High-Anisotropic VO6 Octahedra and SeO3 Pyramids

    Inorganic Chemistry · 2025-06-23

    Qian Wu, Tianyu Wang, Jingfang Zhou, Pifu Gong, Haochen Li, Haotian Tian, Mingjun Xia

    Read original paper ↗ ·

  5. Modulation of Crystal Structure and Birefringence: Cation Size Effect in Alkali Metal Fluoroaluminoborates

    Inorganic Chemistry · 2025-08-02

    Chao Wei, Danyang Dou, Bingbing Zhang, Ying Wang

    Read original paper ↗ ·

  6. Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals

    Angewandte Chemie International Edition · 2025-08-10

    Lingli Wu, Chensheng Lin, Huixin Fan, Shunda Yang, Tao Yan, Yunxia Song, Min Luo

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  7. Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals

    Angewandte Chemie · 2025-08-10

    Lingli Wu, Chensheng Lin, Huixin Fan, Shunda Yang, Tao Yan, Yunxia Song, Min Luo

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  8. A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response

    Inorganic Chemistry · 2025-08-11

    Hanjing Huang, Xianghao Kong, Huijian Zhao, Ning Ye, Zhanggui Hu, Conggang Li

    Read original paper ↗ ·

  9. Multifactorial directed regulation of anionic units in praseodymium-contained iodates

    Journal of Molecular Structure · 2025-09-01

    Ping Wang, Zhengli Liang, Zhenhua Li, Quanjie Yang, Lehui Liu, Lehui Liu, Xingxing Jiang, Hongming Liu, Hongming Liu

    Read original paper ↗ ·

  10. Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap

    Inorganic Chemistry · 2025-09-30

    Dandan Zhou, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  11. Deprotonation-Regulated Conformational Switching in Malonates Enables High-Performance Ultraviolet Polar Crystals

    Inorganic Chemistry · 2025-10-03

    Zhengyan Lin, Huili Liu, Liling Cao, Ling Huang, Xuehua Dong, Yuqiao Zhou, Daojiang Gao, Ning Ye

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  12. Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals

    Chemical Science · 2025-11-18

    Xiaoxu Wang, Tinghui Zhang, Huijian Zhao, Ning Jia, Hongjun Liu, Ning Ye, Zhanggui Hu, Conggang Li

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  13. Stereochemically Active Lone‐Pair Electrons Driven High‐Performance and Self‐Powered X‐Ray Detection in Cs 2 TeMo 3 O 12 Crystal

    Small Methods · 2025-11-19

    Feifei Guo, Jianhui Liu, Fuai Hu, Xi Feng, Yifan Hu, Zeliang Gao

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  14. A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination

    Dalton Transactions · 2026-01-01

    Chen Zhu, Xiao-Min Wu, Xiao-Xue Wang, Si-Qi Zhou, Jing-Jing Wu, Xin-Lei Liu, You-Qian Wu, Jiannian Yao, Peng-Fei Li, Yu-Wu Zhong

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  15. A promising mid-infrared nonlinear optical crystal with well-balanced properties

    Inorganic Chemistry Frontiers · 2026-01-01

    Yujun Wang, Yuning Qi, Yongkuan Xu, Ning Ye, Zhanggui Hu, Conggang Li

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  16. Inorganic Ge-based ferroelectric perovskites towards quasi-phase-matching in the infrared region

    Materials Chemistry Frontiers · 2026-01-01

    Guifu Zhang, Xiantan Lin, Xiaoqi Li, Xiaoyu Zhang, Yikun Fu, Qianxi Wang, Yicong Lv, Yan Fu, Wan Jiang Luo, Xitao Liu

    Read original paper ↗ ·

  17. Li 3 GaTe 4 O 11 : small ion-driven orientation of TeO n units in a tunnel-structured tellurite

    Dalton Transactions · 2026-01-01

    Jingfang Zhou, Pifu Gong, Chang Gao, Mingjun Xia, Jing Yu, Hongxia Zhang, Qian Wu

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  18. Optical anisotropy in Mo–Te–O frameworks constructed from distorted MoO 6 and TeO 3 units

    Dalton Transactions · 2026-01-01

    Cheng He, Kun Hu, Jing-Yang Zhou, Long Wu, Jian‐Han Zhang

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  19. Synergism of [C 2 N 4 H 7 S] cations and anionic modulators: tailoring second-order nonlinear optics and birefringence in organic–inorganic crystals

    Inorganic Chemistry Frontiers · 2026-01-01

    Wenxiao Zhang, Yumeng Cui, Siyu Li, Bingbing Zhang, Ying Wang

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  20. Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )

    Dalton Transactions · 2026-01-01

    Yi Yuan, Chun‐Li Hu, Dan-Dan Zhou, Jiang‐Gao Mao, Fang Kong

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  21. InO6X (X = Cl, Br): distinct functional motif family for nonlinear optical materials

    Science China Materials · 2026-01-04

    Dan-Dan Zhou, Chunli Hu, Bingxuan Li, Jianggao Mao, Fang Kong

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  22. Engineering Eu3+-activated molybdenum tellurates via alkali metal co-doping for enhanced luminescence in advanced lighting and security ink applications

    Progress in Solid State Chemistry · 2026-02-01

    Asif Ali Haider, WeiGang WANG, WeiGang WANG, Xianchen Huang, Jianguo Jia, Yuxin Liu, Bowen Wang, Bowen Wang, Jingkai Quan, Wei Qian, Dandan Gao, Jianqiang Wang, Jing Zhu

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  23. Microwave/Terahertz Dielectric Properties of a Novel NaSrGdMo 3 O 12 Scheelite Ceramic for Patch Antenna Applications

    Journal of the American Ceramic Society · 2026-02-27

    Xiangyu Xu, Kexin Xu, Haitao Wu, Zhanbai Feng

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  24. K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response

    Inorganic Chemistry · 2026-03-12

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu, Yongmin Guo

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  25. Rational design of a quasi-0D tungsten tellurite nonlinear optical crystal with exceptionally balanced properties

    Science China Chemistry · 2026-03-19

    Shijie Zhao, Lili Li, Tinghui Zhang, Huijian Zhao, Ning Ye, Zhanggui Hu, Conggang Li

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  26. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  27. Breaking Inversion Symmetry via Vanadium Coordination Engineering in Bismuth Vanadium Selenites

    Small · 2026-05-07

    Chanhee Ko, Congcong Jin, Taek Rim Kim, Seung Han Shin, Yunseung Kuk, Jiachen Lu, Chong‐An Chen, Wei Zeng, Joon Ik Jang, Kang Min Ok

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  28. Metal tellurite oxides: Lone-pair-enabled coordination chemistry, polymerized architectures, and functional materials opportunities

    Coordination Chemistry Reviews · 2026-05-07

    Yiyun Wang, Hongbo Cui, Jiayi Guo, Guijian Guan, Ming‐Yong Han

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  29. Research advances in rare-earth nonlinear optical crystalline materials in 2025

    Journal of Rare Earths · 2026-07-21

    Tiantian He, Dandan Zhou, Fang Kong, Jianggao Mao

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  30. Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization

    Coordination Chemistry Reviews · 2026-08-14

    Dan-Dan Zhou, Tian-Tian He, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  31. Entropy‐Driven Precursor Symmetry Breaking for Phase‐Selective Synthesis of Noncentrosymmetric Rb 2 CdCl 2 I 2

    Advanced Optical Materials · 2026-08-17

    Sheng Lv, Liangcheng Song, Yanling Xu, Jiahao Zhou, Chongqiang Zhu, Chunhui Yang

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  32. Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal

    Science China Chemistry · 2026-09-15

    Longyun Xu, Hanjing Huang, Conggang Li, Huijian Zhao, Conghe Liu, Kaidong Xu, Jina Wang, Ning Ye, Zhanggui Hu

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  33. A Telluromolybdate Mid-Infrared Nonlinear Optical Crystal with Wide Transparency and Strong Second-Harmonic Generation Response

    Inorganic Chemistry · 2026-09-16

    Hanyue Zhou, Wenli Zhao, Huijian Zhao, Zelong Liu, Shijie Zhao, Ning Ye, Zhanggui Hu, Conggang Li

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  34. Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)

    Inorganic Chemistry · 2026-09-28

    Xiangtian Liu, Bingchen Xiao, Lei Hou, Wencong Li, Wenlong Zhao, Kaixin Yin, Haonan Pei, Xiaonan Li, Zhuangzhuang Dong, Lili Liu

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