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RESEARCH PAPER · Angewandte Chemie International Edition · 2025

La 3 ZrGa 5 O 14 : Band‐Inversion Strategy in Topology‐Protected Octahedron for Large Nonlinear Response and Wide Bandgap

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La 3 ZrGa 5 O 14 : Band‐Inversion Strategy in Topology‐Protected Octahedron for Large Nonlinear Response and Wide BandgapOriginalLa3Ga5HfO14: Rare-Earth Polyhedron Coupled with Structural Protected Octahedron for Designing Nonlinear Optical Material with Wide Bandgap and Well-Balanced Properties5Water Molecule-Driven Structural Evolution from Na2ZnCl4 to Na2ZnCl4·3H2O: A Route to Promising Deep-UV Nonlinear Optical Crystals0Ag(Te2O3)(PO4): The first Ag-containing phosphate-tellurite nonlinear optical crystal featuring novel zigzag layered structure0A Band‐Orientation Co‐Anchoring Strategy for the Design of a High‐Performance Mid‐Infrared Nonlinear Optical Crystal2A Band‐Orientation Co‐Anchoring Strategy for the Design of a High‐Performance Mid‐Infrared Nonlinear Optical Crystal12Hydrogen-bond-driven noncentrosymmetric structure formation in π-conjugated (C3H7N6)(IO3): achieving both strong SHG response and wide bandgap5Heterocationic strategy to design a nonlinear optical crystal with a polar anti-perovskite structure7KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy7Mid Infrared Nonlinear Optical Series A 4 MV 5 O 15 X (A = K, Rb; M = Zn, Cd; X = Cl, Br) with Strong Second Harmonic Generation Responses3A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination1A series of langasite-type compounds: size effect regulation for cation occupation and enhanced SHG response1Halogen-ion-driven polymorphs for high-performance nonlinear optical crystalline materials3Influence of point defects on the optical properties of La 3 Nb 0.5 Ga 5.5 O 14 crystals0Zn 0.7 Hg 0.3 Ga 2 Se 4 : a defect diamond-like selenide with a balanced band gap and nonlinear optical response0Quasi-degenerate cation occupation enables nearly defect-free functional crystals0Rb 2 ZnGe 3 Se 8 : A Large-Birefringence Layered Chalcogenide Enabled by Anisotropic Electrons in Tetrahedral Units0Research advances in rare-earth nonlinear optical crystalline materials in 20250AVP2S7 (A = K, Rb): Dual-Optimized Infrared Nonlinear Optical Thiophosphates via Heterovalent-Substitution-Driven Symmetry Breaking and Reinforced Interlayer Interactions0

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  1. La3Ga5HfO14: Rare-Earth Polyhedron Coupled with Structural Protected Octahedron for Designing Nonlinear Optical Material with Wide Bandgap and Well-Balanced Properties

    Inorganic Chemistry · 2025-06-03

    Jingxuan Hou, Dingxuan Zhao, Zifan Xu, Shihui Ma, Jiajia Wang, Hongwei Yu, Guang Peng, Ning Ye, Zhanggui Hu

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  2. Water Molecule-Driven Structural Evolution from Na2ZnCl4 to Na2ZnCl4·3H2O: A Route to Promising Deep-UV Nonlinear Optical Crystals

    Crystal Growth & Design · 2025-07-08

    Mengmeng Chen, Wangfei Che, Cui Chen, Qixian Ren, Juanjuan Lu, Yabo Wu

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  3. Ag(Te2O3)(PO4): The first Ag-containing phosphate-tellurite nonlinear optical crystal featuring novel zigzag layered structure

    Chinese Journal of Structural Chemistry · 2025-10-10

    Piao Tang, Xin Wen, Jindong Chen, Ning Ye, Guang Peng

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  4. A Band‐Orientation Co‐Anchoring Strategy for the Design of a High‐Performance Mid‐Infrared Nonlinear Optical Crystal

    Angewandte Chemie · 2025-10-17

    Haochen Li, Haotian Tian, Pifu Gong, Tianyu Wang, Hongyu Liu, Bing Li, Qian Wu, Mingjun Xia

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  5. A Band‐Orientation Co‐Anchoring Strategy for the Design of a High‐Performance Mid‐Infrared Nonlinear Optical Crystal

    Angewandte Chemie International Edition · 2025-10-17

    Haochen Li, Haotian Tian, Pifu Gong, Tianyu Wang, Hongyu Liu, Bing Li, Qian Wu, Mingjun Xia

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  6. Hydrogen-bond-driven noncentrosymmetric structure formation in π-conjugated (C3H7N6)(IO3): achieving both strong SHG response and wide bandgap

    Science China Chemistry · 2025-10-21

    Yu-Wei Kang, Chun‐Li Hu, Jiang‐Gao Mao

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  7. Heterocationic strategy to design a nonlinear optical crystal with a polar anti-perovskite structure

    Nature Communications · 2025-12-12

    Shuoxing Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  8. KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy

    Small · 2025-12-15

    Lei Hou, Siyu Li, Wencong Li, Bingchen Xiao, Yaoqing Chu, Bingbing Zhang, Ying Wang, Xinglong Chen, Lili Liu

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  9. Mid Infrared Nonlinear Optical Series A 4 MV 5 O 15 X (A = K, Rb; M = Zn, Cd; X = Cl, Br) with Strong Second Harmonic Generation Responses

    Inorganic Chemistry · 2025-12-23

    Haochen Li, Jinhua Wang, Haotian Tian, Xiaodong Zhang, T. Wang, Hongrui Liu, Bing Li, Pengyun Chen, Pifu Gong, Qian Wu, Shu Hai Guo, Mingjun Xia

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  10. A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination

    Dalton Transactions · 2026-01-01

    Chen Zhu, Xiao-Min Wu, Xiao-Xue Wang, Si-Qi Zhou, Jing-Jing Wu, Xin-Lei Liu, You-Qian Wu, Jiannian Yao, Peng-Fei Li, Yu-Wu Zhong

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  11. A series of langasite-type compounds: size effect regulation for cation occupation and enhanced SHG response

    Inorganic Chemistry Frontiers · 2026-01-01

    Zhi Deng, Nian‐Tzu Suen, Zhen‐Cheng Wu, Huizhi Gao, Sheng‐Ping Guo

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  12. Halogen-ion-driven polymorphs for high-performance nonlinear optical crystalline materials

    Chemical Science · 2026-01-01

    Yuwei Kang, Can Hui Yang, Yunjie Wang, Qi Wu

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  13. Influence of point defects on the optical properties of La 3 Nb 0.5 Ga 5.5 O 14 crystals

    CrystEngComm · 2026-01-01

    Jindong Chen, Hongxu Gu, Yang Shusen, Ning Ye, Kui Wu, Dazhi Lu

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  14. Zn 0.7 Hg 0.3 Ga 2 Se 4 : a defect diamond-like selenide with a balanced band gap and nonlinear optical response

    Dalton Transactions · 2026-01-01

    Qixian Ren, Junwei Feng, Longquan Shao, Meihuizi Zhou, Chen Cui, Yabo Wu

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  15. Quasi-degenerate cation occupation enables nearly defect-free functional crystals

    Research Square · 2026-05-11

    Haohai Yu, Jinfeng Han, Fei Liang, Kui Wu, Deliang Cui, Dazhi Lu, Hailong Zhang

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  16. Rb 2 ZnGe 3 Se 8 : A Large-Birefringence Layered Chalcogenide Enabled by Anisotropic Electrons in Tetrahedral Units

    Inorganic Chemistry · 2026-06-15

    Xinchen Chen, Yabo Wu, Wangfei Che, Shuyi Mi, Juanjuan Lu, Chen Cui

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  17. Research advances in rare-earth nonlinear optical crystalline materials in 2025

    Journal of Rare Earths · 2026-07-21

    Tiantian He, Dandan Zhou, Fang Kong, Jianggao Mao

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  18. AVP2S7 (A = K, Rb): Dual-Optimized Infrared Nonlinear Optical Thiophosphates via Heterovalent-Substitution-Driven Symmetry Breaking and Reinforced Interlayer Interactions

    Inorganic Chemistry · 2026-08-11

    Shao-Peng Gui, Zi-Nan Chen, Wei-Hua Yan, Yu‐Xuan Zhang, Mao‐Yin Ran, Sheng‐Ping Guo

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