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RESEARCH PAPER · Chemical Communications · 2024

New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation

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New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisationOriginalExploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence10(C3N2H5)B3O3F2(OH)2: Realizing Large Birefringence via a Synergistic Effect between Anion F/OH‐Ratio Optimization and Cation Activation25LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] Motifs10The New Paradigm of Ligand Substitution-Driven Enhancement of Anisotropy from SO4 Units in Short-Wavelength Region14Li3[AlP2O7F(OH)](H2O)0.5 and A[Al2(PO4)2F(H2O)](A = K, Rb): Counter Cation Templates Derived Three Polar Alkaline Metal Fluoroaluminophosphates6新型非线性光学晶体和双折射晶体的研究进展(特邀)4Prediction of New Functional Fluorooxoborates with Expected Anionic Framework: A Case of CaB3O5F4NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence1Recent progress in structural design strategies of high-birefringence optical crystals54Reversal Enhancement of Birefringence by Stereochemically Active Lone Pairs in Sn(II)-Based Mixed Halides0Bromine for iodine: Unlocking short-wavelength UV phase matching in nonlinear optical metal halides6Modulation of Crystal Structure and Birefringence: Cation Size Effect in Alkali Metal Fluoroaluminoborates4Enhanced Birefringence in Hybrid Antimony Halides via π-Conjugated Organic Cation Design10Rational design of large birefringence infrared oxychalcogenides via heteroanionic octahedron engineering0Truss bridge-like anhydrous stacking in hybrid crystals triggers ultra-high stability and robust birefringence0Topological structural chemistry of fluorooxoborates: From fundamental building blocks to macroscopic optical performance regulation0First-principles study of Ba3B2O3F6 fluorooxoborate: From structural prediction to physical properties under high pressure0MAlB3O6F2 (M = Ca and Pb): Two New Fluoroaluminoborates Featuring π-Conjugated [BO3] and [AlO4F2] Units with Large Birefringence0Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation0

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  1. Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence

    Inorganic Chemistry Frontiers · 2024-01-01

    Chenhui Hu, Dongdong Chu, Xueling Hou, Feng Zhang, Jian Wei Han

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  2. (C3N2H5)B3O3F2(OH)2: Realizing Large Birefringence via a Synergistic Effect between Anion F/OH‐Ratio Optimization and Cation Activation

    Small Structures · 2024-07-28

    Chenhui Hu, Chunjie Shen, Huan Zhou, Jian Wei Han, Zhihua Yang, Kenneth Reinhard Poeppelmeier, Feng Zhang, Shilie Pan

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  3. LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] Motifs

    Inorganic Chemistry · 2024-08-21

    Ziting Yan, Jinbin Fan, Dongdong Chu, Zhihua Yang, Juanjuan Lu, Shilie Pan, Min Zhang

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  4. The New Paradigm of Ligand Substitution-Driven Enhancement of Anisotropy from SO4 Units in Short-Wavelength Region

    ACS Central Science · 2024-11-27

    Chenhui Hu, Huimin Li, Guangsheng Xu, Zhihua Yang, Jian Wei Han, Shilie Pan

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  5. Li3[AlP2O7F(OH)](H2O)0.5 and A[Al2(PO4)2F(H2O)](A = K, Rb): Counter Cation Templates Derived Three Polar Alkaline Metal Fluoroaluminophosphates

    Inorganic Chemistry · 2024-12-17

    Yucheng Hao, Changlin Chen, Cheng Hou, S. Liu, Peng Zheng, Yuan Ching Lin, Haijian Li, Xi Zhao, Kisan Koirala, Hongdian Lu, Chonghai Deng, Kunhong Hu

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  6. 新型非线性光学晶体和双折射晶体的研究进展(特邀)

    Chinese Journal of Lasers · 2025-01-01

    韩树娟 Han Shujuan, 杨志华 Yang Zhihua, 张方方 Zhang Fangfang, 李广卯 Li Guangmao, 李俊杰 Li Junjie, 吴雅博 Wu Yabo, 储冬冬 Chu Dongdong, 程孟 Cheng Meng, 张文彬 Zhang Wenbin, 丁文 Ding Wen, 潘世烈 Pan Shilie

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  7. Prediction of New Functional Fluorooxoborates with Expected Anionic Framework: A Case of CaB3O5F

    Chinese Physics Letters · 2025-02-24

    Ke-Wang Zhang, Wen-Qi 文琪 Jin 靳, Ke 珂 Li 李, Abudukadi Tudi, Linlin Liu, Congwei Xie, Yu Xie

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  8. NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence

    Inorganic Chemistry · 2025-05-01

    Chenhui Hu, Jiale Qu, Jinghui Hu, Junjie Liu, Wenchao Hu, Xiangzhan Jiang

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  9. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  10. Reversal Enhancement of Birefringence by Stereochemically Active Lone Pairs in Sn(II)-Based Mixed Halides

    Crystal Growth & Design · 2025-07-11

    Xu Liu, Abudukadi Tudi, Junben Huang, Juanjuan Lu, Zhaofeng Wu

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  11. Bromine for iodine: Unlocking short-wavelength UV phase matching in nonlinear optical metal halides

    Chinese Chemical Letters · 2025-07-27

    Mingchang Wang, Zhi Rong Lin, Jiajia Li, Jia-Min Lian, Yunxia Hu, Yan Chen, Ke‐Zhao Du, Jin Chen

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  12. Modulation of Crystal Structure and Birefringence: Cation Size Effect in Alkali Metal Fluoroaluminoborates

    Inorganic Chemistry · 2025-08-02

    Chao Wei, Danyang Dou, Bingbing Zhang, Ying Wang

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  13. Enhanced Birefringence in Hybrid Antimony Halides via π-Conjugated Organic Cation Design

    Crystal Growth & Design · 2025-09-02

    Luli Wang, Han Luo, Siyu Chen, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  14. Rational design of large birefringence infrared oxychalcogenides via heteroanionic octahedron engineering

    Chemical Communications · 2026-01-01

    Xinyao Qi, Haonan Liu, Yu-Jie Zhang, Shihui Ma, Hongping Wu, Zhanggui Hu, Hongwei Yu

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  15. Truss bridge-like anhydrous stacking in hybrid crystals triggers ultra-high stability and robust birefringence

    Inorganic Chemistry Frontiers · 2026-01-01

    Ping Wang, Qiya Huang, Xiaoli Meng, Lehui Liu, Qi Wu, Hongming Liu

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  16. Topological structural chemistry of fluorooxoborates: From fundamental building blocks to macroscopic optical performance regulation

    Coordination Chemistry Reviews · 2026-05-20

    Wenqing Sun, Congwei Xie, Xueling Hou, Zhihua Yang, Shilie Pan

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  17. First-principles study of Ba3B2O3F6 fluorooxoborate: From structural prediction to physical properties under high pressure

    Physica B Condensed Matter · 2026-06-13

    Nursultan E. Sagatov, Tatyana B. Bekker, А. В. Давыдов

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  18. MAlB3O6F2 (M = Ca and Pb): Two New Fluoroaluminoborates Featuring π-Conjugated [BO3] and [AlO4F2] Units with Large Birefringence

    Crystal Growth & Design · 2026-10-02

    Yaozu Li, Chao Wei, Wenjing Zhang, Huiyi Zhang, Bo Zhao, Bingbing Zhang, Ying Wang

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  19. Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation

    Coordination Chemistry Reviews · 2026-10-06

    Liyi Zhang, Pei Liu, Liling Cao, Ling Huang, Xuehua Dong, Guohong Zou

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