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RESEARCH PAPER · Inorganic Chemistry · 2024

Two Short-Wave UV Antimony(III) Sulfates Exhibiting Large Birefringence

Yang Lan, Han Luo, Luli Wang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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Two Short-Wave UV Antimony(III) Sulfates Exhibiting Large BirefringenceOriginalRbSb(SO 4 )(H 2 PO 2 )F: a short-wave UV antimony( iii ) oxysalt with mixed-anions demonstrating enhanced birefringence11Structural Regulations of Layered Borates: From Centric Layers to Chiral Porous Layers3KSb2F7·2KNO3: Unveiling the peak birefringence in inorganic antimony oxysalts10Optimization of Functional Building Blocks Generates a Substantial Improvement in Birefringence from Sn2OSO4 to Sn3O2(OH)(HSO4)6The New Paradigm of Ligand Substitution-Driven Enhancement of Anisotropy from SO4 Units in Short-Wavelength Region14Harnessing the dual role of DMSO in the synthesis of SbOCl·DMSO: an excellent nonlinear optical crystal with unique 1D spiral chain10Structural chemistry of antimony( iii ) oxalates with lone pairs: polyhedral distortion [SbO 4 F 2 ], π-conjugation [C 2 O 4 ], and birefringence tuning1Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency10One-Dimensional Perovskite RbGeI3 with Large Optical Anisotropy3Double Sb‐N Coordination Enables Record‐High Birefringence in UV‐Transparent Crystals71Double Sb‐N Coordination Enables Record‐High Birefringence in UV‐Transparent Crystals8Recent progress in structural design strategies of high-birefringence optical crystals54Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering4Enhanced Birefringence in Hybrid Antimony Halides via π-Conjugated Organic Cation Design10A 2 Sb 2 SO 4 F 6 (A = NH 4 + , Na + ): two sulfate fluoride crystals exhibiting enhanced birefringence driven by stereochemically active antimony( iii )1Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals11Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence1Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation0

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  1. RbSb(SO 4 )(H 2 PO 2 )F: a short-wave UV antimony( iii ) oxysalt with mixed-anions demonstrating enhanced birefringence

    Journal of Materials Chemistry C · 2024-01-01

    Jinwen Tan, Han Luo, Shiyi Wang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  2. Structural Regulations of Layered Borates: From Centric Layers to Chiral Porous Layers

    Precision Chemistry · 2024-05-19

    Chong‐An Chen, Guo‐Yu Yang

    Read original paper ↗ ·

  3. KSb2F7·2KNO3: Unveiling the peak birefringence in inorganic antimony oxysalts

    Chinese Chemical Letters · 2024-06-26

    Qin Lin Wang, Han Luo, Luli Wang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  4. Optimization of Functional Building Blocks Generates a Substantial Improvement in Birefringence from Sn2OSO4 to Sn3O2(OH)(HSO4)

    Inorganic Chemistry · 2024-07-31

    Yuqi Chen, Han Luo, Zeqiao Yin, Xuehua Dong, Daojiang Gao, Yuqiao Zhou, Ling Huang, Liling Cao, Guohong Zou

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  5. The New Paradigm of Ligand Substitution-Driven Enhancement of Anisotropy from SO4 Units in Short-Wavelength Region

    ACS Central Science · 2024-11-27

    Chenhui Hu, Huimin Li, Guangsheng Xu, Zhihua Yang, Jian Wei Han, Shilie Pan

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  6. Harnessing the dual role of DMSO in the synthesis of SbOCl·DMSO: an excellent nonlinear optical crystal with unique 1D spiral chain

    Inorganic Chemistry Frontiers · 2025-01-01

    Xiande Peng, Xiangyuan Li, Yingzi Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  7. Structural chemistry of antimony( iii ) oxalates with lone pairs: polyhedral distortion [SbO 4 F 2 ], π-conjugation [C 2 O 4 ], and birefringence tuning

    Dalton Transactions · 2025-01-01

    Yunxiao Zhang, Guangsheng Xu, Ke Li, Wei Jia, Xiaoyu Dong

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  8. Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency

    Inorganic Chemistry · 2025-01-24

    Jiale Xue, Shuyao Wang, Xiande Peng, Zhengyan Lin, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

    Read original paper ↗ ·

  9. One-Dimensional Perovskite RbGeI3 with Large Optical Anisotropy

    Inorganic Chemistry · 2025-02-12

    Huige Chen, Deshuai Xiao, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Lei Kang

    Read original paper ↗ ·

  10. Double Sb‐N Coordination Enables Record‐High Birefringence in UV‐Transparent Crystals

    Angewandte Chemie International Edition · 2025-03-11

    Pu Zhang, Xuehua Dong, Ling Huang, Zhien Lin, Yuqiao Zhou, Guohong Zou

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  11. Double Sb‐N Coordination Enables Record‐High Birefringence in UV‐Transparent Crystals

    Angewandte Chemie · 2025-03-11

    Pu Zhang, Xuehua Dong, Ling Huang, Zhien Lin, Yuqiao Zhou, Guohong Zou

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  12. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  13. Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering

    Crystal Growth & Design · 2025-06-24

    Xiang Mao, Yu Yan, Yingzi Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  14. Enhanced Birefringence in Hybrid Antimony Halides via π-Conjugated Organic Cation Design

    Crystal Growth & Design · 2025-09-02

    Luli Wang, Han Luo, Siyu Chen, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  15. A 2 Sb 2 SO 4 F 6 (A = NH 4 + , Na + ): two sulfate fluoride crystals exhibiting enhanced birefringence driven by stereochemically active antimony( iii )

    New Journal of Chemistry · 2026-01-01

    Jia Wang, Wenbin Zhang, Zhihua Yang, Shujuan Han, Shilie Pan

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  16. Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals

    Journal of the American Chemical Society · 2026-03-05

    Chong‐An Chen, Yang Li, Congcong Jin, S. D. Lee, Zhihua Yang, Kang Min Ok

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  17. Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence

    Crystal Growth & Design · 2026-06-29

    Ying Long, Xuehua Dong, Lin Qi, Lindong Luan, Zichen Ren, Zhien Lin, Guohong Zou

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  18. Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation

    Coordination Chemistry Reviews · 2026-10-06

    Liyi Zhang, Pei Liu, Liling Cao, Ling Huang, Xuehua Dong, Guohong Zou

    Read original paper ↗ ·
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