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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2023

An overview of Mg-based IR nonlinear optical materials

Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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An overview of Mg-based IR nonlinear optical materialsOriginalDouble alkaline earth metals sulfide SrMgGeS4 with high laser-induced damage threshold and strong second-harmonic generation29Regulating the key performance parameters for Hg-based IR NLO chalcogenides via bandgap engineering strategy26Ga-based IR nonlinear optical materials: Synthesis, structures, and properties65Enhanced near-infrared optical transmission in zinc germanium phosphide crystals via precise magnesium doping3Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Polar-Layer-Driven Reconstruction of a Noncentrosymmetric Vandate Mid-Infrared Nonlinear-Optical Crystal10Accelerating the discovery of high-performance nonlinear optical materials using active learning and high-throughput screening11Structural diversity and photocurrent responses of multi-component chalcogenidometalates8Impact of Microstructural Units Configuration and Arrangement on Phase-Matching in Nonlinear Optical KGa5Se8 Crystals9From Centrosymmetric Eu 2 Ga 2 S 5 to Noncentrosymmetric EuMg 6 Ga 6 S 16 via Introduction of Distorted MgS 6 Octahedron: Featuring Wide Bandgap and Nonlinear Optical Activity3Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29A high-performance IR nonlinear optical material Sr 3 MnGe 2 S 8 achieved via partial cation substitution-induced structural transformation2Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties6Selenium-Based Molecular Cage Crystal β-P 4 Se 3 Br 2 : A Promising Candidate for Infrared Nonlinear Optical Applications1Chiral three-dimensional cadmium(II)-based coordination polymer constructed from a lactic acid derivative: synthesis, structure and properties0Origin of Large Second-Harmonic Generation in Nonpolar Molybdenum Tellurite Compounds0From Centrosymmetric Mg 2 GeS 4 to Noncentrosymmetric CdMg 3 Ge 2 S 8 : Cation-Mixing-Driven Symmetry Reduction4High‐Performance Infrared Nonlinear Optical Crystals Discovery Guided by High‐Throughput Computation, Machine Learning, and Experimental Verification6High‐Performance Infrared Nonlinear Optical Crystals Discovery Guided by High‐Throughput Computation, Machine Learning, and Experimental Verification2EuMn6Ga6S16: A Wide Bandgap Europium-Based Nonlinear Optical Sulfide0Beyond the bandgap bottleneck: structure–property design principles for infrared nonlinear optical phosphides0

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  1. Double alkaline earth metals sulfide SrMgGeS4 with high laser-induced damage threshold and strong second-harmonic generation

    Materials Today Physics · 2023-09-29

    Hongshan Wang, Yu Chu, Xueting Pan, Zhihua Yang, Shilie Pan, Junjie Li

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  2. Regulating the key performance parameters for Hg-based IR NLO chalcogenides via bandgap engineering strategy

    Chinese Chemical Letters · 2023-12-12

    A-Yang Wang, Shenghua Zhou, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  3. Ga-based IR nonlinear optical materials: Synthesis, structures, and properties

    Coordination Chemistry Reviews · 2023-12-21

    Jiaxiang Zhang, Ping Feng, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  4. Enhanced near-infrared optical transmission in zinc germanium phosphide crystals via precise magnesium doping

    Physical Chemistry Chemical Physics · 2024-01-01

    Shichao Cheng, Xueyan Zhang, Xiangran Kong, Tao Liu, Jingdong Yan, T. A. Prikhna, Yunfei Shang, Zuotao Lei, Chunhui Yang

    Read original paper ↗ ·

  5. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

    Chemical Science · 2024-01-01

    Ping Feng, Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  6. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  7. Polar-Layer-Driven Reconstruction of a Noncentrosymmetric Vandate Mid-Infrared Nonlinear-Optical Crystal

    Inorganic Chemistry · 2024-10-28

    Haochen Li, Haotian Tian, Pifu Gong, Tianyu Wang, Qian Wu, Mingjun Xia

    Read original paper ↗ ·

  8. Accelerating the discovery of high-performance nonlinear optical materials using active learning and high-throughput screening

    Journal of Materials Chemistry C · 2025-01-01

    Victor Trinquet, Matthew L. Evans, Gian‐Marco Rignanese

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  9. Structural diversity and photocurrent responses of multi-component chalcogenidometalates

    Inorganic Chemistry Frontiers · 2025-01-01

    Chang Liu, Wen-Jing Tian, Mao‐Yin Ran, Pan Gao, Panpan Jing, Yi Liu, Hua Lin

    Read original paper ↗ ·

  10. Impact of Microstructural Units Configuration and Arrangement on Phase-Matching in Nonlinear Optical KGa5Se8 Crystals

    ACS Applied Materials & Interfaces · 2025-02-24

    Mingxin Li, Yan Jie Guo, Meng-Na Jing, Meng-Ke Gao, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

    Read original paper ↗ ·

  11. From Centrosymmetric Eu 2 Ga 2 S 5 to Noncentrosymmetric EuMg 6 Ga 6 S 16 via Introduction of Distorted MgS 6 Octahedron: Featuring Wide Bandgap and Nonlinear Optical Activity

    Inorganic Chemistry · 2025-08-21

    Qiu-Yang Du, Wen‐Dong Yao, Xu-Bin Ni, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  12. Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs

    Coordination Chemistry Reviews · 2025-09-03

    Hong Chen, Xin‐Tao Wu, Hua Lin

    Read original paper ↗ ·

  13. A high-performance IR nonlinear optical material Sr 3 MnGe 2 S 8 achieved via partial cation substitution-induced structural transformation

    Inorganic Chemistry Frontiers · 2025-11-14

    A-Lan Xu, Mao‐Yin Ran, Zuju Ma, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

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  14. Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties

    Coordination Chemistry Reviews · 2025-11-19

    Wei Huang, Chi Wang, Guohong Tang, Kexin Huang, Baojun Chen, Z. Y. He, Z. Y. He

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  15. Selenium-Based Molecular Cage Crystal β-P 4 Se 3 Br 2 : A Promising Candidate for Infrared Nonlinear Optical Applications

    Inorganic Chemistry · 2026-01-14

    Xingwang Zhu, Chao Wang, Chensheng Lin, Cheng Hu, Shunda Yang, Tao Yan, Min Luo

    Read original paper ↗ ·

  16. Chiral three-dimensional cadmium(II)-based coordination polymer constructed from a lactic acid derivative: synthesis, structure and properties

    Acta Crystallographica Section C Structural Chemistry · 2026-02-20

    Xiu-Ju Yin, Yan Lin, Jia-Hui Luo, Xiao-Ling Wang, Yuan Lu, Zhong‐Xuan Xu

    Read original paper ↗ ·

  17. Origin of Large Second-Harmonic Generation in Nonpolar Molybdenum Tellurite Compounds

    Molecules · 2026-02-26

    Z. F. Li, Xiyue Cheng, Qian Xu, Xiu Wang, Guoliang Liu, Shuiquan Deng

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  18. From Centrosymmetric Mg 2 GeS 4 to Noncentrosymmetric CdMg 3 Ge 2 S 8 : Cation-Mixing-Driven Symmetry Reduction

    Chemistry of Materials · 2026-04-07

    Chonglei Xu, Eric A. Gabilondo, Michael J. Waters, Yunseung Kuk, James M. Rondinelli, P. Shiv Halasyamani

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  19. High‐Performance Infrared Nonlinear Optical Crystals Discovery Guided by High‐Throughput Computation, Machine Learning, and Experimental Verification

    Angewandte Chemie International Edition · 2026-04-24

    Yan Xiao, Zhaoxi Yu, Yumiao Niu, Yidan Chen, Lin Shen, Daqing Yang, Ying Wang, Bingbing Zhang

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  20. High‐Performance Infrared Nonlinear Optical Crystals Discovery Guided by High‐Throughput Computation, Machine Learning, and Experimental Verification

    Angewandte Chemie · 2026-04-24

    Yan Xiao, Zhaoxi Yu, Yumiao Niu, Yidan Chen, Lin Shen, Daqing Yang, Ying Wang, Bingbing Zhang

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  21. EuMn6Ga6S16: A Wide Bandgap Europium-Based Nonlinear Optical Sulfide

    Inorganic Chemistry · 2026-08-16

    Yu‐Xuan Zhang, Jiang-Hui Fan, Zhen‐Cheng Wu, Shao-Peng Gui, Mao‐Yin Ran, Sheng‐Ping Guo

    Read original paper ↗ ·

  22. Beyond the bandgap bottleneck: structure–property design principles for infrared nonlinear optical phosphides

    Coordination Chemistry Reviews · 2026-09-22

    Zichang Wang, Dajiang Mei, Ximeng Lv, Shuchang Wu, Yang Liu, Jingdong Yan, Xiangran Kong, Hongwei Leng, Zuotao Lei, Chunhui Yang

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