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RESEARCH PAPER · Advanced Optical Materials · 2023

The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical Crystals

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The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical CrystalsOriginalUltrashort Phase‐Matching Wavelength and Strong Second‐Harmonic Generation in Deep‐UV‐Transparent Oxyfluorides by Covalency Reduction33Ultrashort Phase‐Matching Wavelength and Strong Second‐Harmonic Generation in Deep‐UV‐Transparent Oxyfluorides by Covalency Reduction3A Sharp Improvement of Sulfate's Birefringence Induced by the Synergistic Effect of Heteroleptic and Dimeric Strategies14Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer16NaB(OH) 3 CH 3 : a deep-ultraviolet optical crystal with unprecedented methyl-modified [B(OH) 3 CH 3 ] units6Giant Optical Anisotropy in a Covalent Molybdenum Tellurite via Oxyanion Polymerization43A Universal Design Strategy Achieving Large Birefringence and Short Phase‐Matching Capability of Optical Materials via Dissimilating Non‐π‐Conjugated Units6Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66A Giant Optically Anisotropic Phosphate Driven by Mixed Valence Mercury Units22K 15 La 7 (BO 3 ) 12 : A KBBF-Like Nonlinear-Optical Material with a Short Cutoff Edge and a Strong Second-Harmonic-Generation Response10Designing a Heteroleptic Tetrahedral Group with an Ultrahigh Polarizability Anisotropy by Optimizing the Bonding Electrons Activity and Their Distribution14La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups6Coordinated assembly of alkali and alkaline earth metals with the perfluorinated [AlF 6 ] group to design deep-ultraviolet zero-order waveplate materials2Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups11La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence13Recent progress in structural design strategies of high-birefringence optical crystals54A Preliminary Study on Artificial Intelligence-Based Camouflage Pattern Generation Method0[C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy13(C 4 H 8 N 5 )(PhPHO 2 )·H 2 O: a polar ionic cocrystal with strong second-harmonic generation and high birefringence0MAlB3O6F2 (M = Ca and Pb): Two New Fluoroaluminoborates Featuring π-Conjugated [BO3] and [AlO4F2] Units with Large Birefringence0

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  1. Ultrashort Phase‐Matching Wavelength and Strong Second‐Harmonic Generation in Deep‐UV‐Transparent Oxyfluorides by Covalency Reduction

    Angewandte Chemie International Edition · 2023-11-06

    Yilei Hu, Chao Wu, Xingxing Jiang, Kaining Duanmu, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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  2. Ultrashort Phase‐Matching Wavelength and Strong Second‐Harmonic Generation in Deep‐UV‐Transparent Oxyfluorides by Covalency Reduction

    Angewandte Chemie · 2023-11-06

    Yilei Hu, Chao Wu, Xingxing Jiang, Kaining Duanmu, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

    Read original paper ↗ ·
  3. A Sharp Improvement of Sulfate's Birefringence Induced by the Synergistic Effect of Heteroleptic and Dimeric Strategies

    Small · 2023-12-10

    Hongyuan Sha, Yanran Shang, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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  4. Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer

    Inorganic Chemistry Frontiers · 2024-01-01

    Qiao Xia, Xingxing Jiang, Qi Lu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Kazuyuki Tatsumi, Chi Zhang

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  5. NaB(OH) 3 CH 3 : a deep-ultraviolet optical crystal with unprecedented methyl-modified [B(OH) 3 CH 3 ] units

    Journal of Materials Chemistry C · 2024-01-01

    Chenhui Hu, Huimin Li, Jian Wei Han, Xueling Hou, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·
  6. Giant Optical Anisotropy in a Covalent Molybdenum Tellurite via Oxyanion Polymerization

    Advanced Science · 2024-01-30

    Tianhui Wu, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

    Read original paper ↗ ·
  7. A Universal Design Strategy Achieving Large Birefringence and Short Phase‐Matching Capability of Optical Materials via Dissimilating Non‐π‐Conjugated Units

    Advanced Optical Materials · 2024-04-18

    Huan Zhou, Shan Shu, Abudukadi Tudi, Wenqi Jin, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·
  8. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·
  9. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  10. A Giant Optically Anisotropic Phosphate Driven by Mixed Valence Mercury Units

    Laser & Photonics Review · 2024-10-24

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·
  11. K 15 La 7 (BO 3 ) 12 : A KBBF-Like Nonlinear-Optical Material with a Short Cutoff Edge and a Strong Second-Harmonic-Generation Response

    Inorganic Chemistry · 2024-12-07

    Fanlu Bu, Xiaorong Liu, Hongwei Yu, Runqing Liu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

    Read original paper ↗ ·
  12. Designing a Heteroleptic Tetrahedral Group with an Ultrahigh Polarizability Anisotropy by Optimizing the Bonding Electrons Activity and Their Distribution

    Laser & Photonics Review · 2024-12-12

    Hongyuan Sha, Dongling Yang, Qinghe Li, Lilin Yang, Zujian Wang, Rongbing Su, Chao He, Bin Su, Xiaoming Yang, Xifa Long

    Read original paper ↗ ·
  13. La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups

    ACS Materials Letters · 2024-12-19

    Ming‐Shu Zhang, Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  14. Coordinated assembly of alkali and alkaline earth metals with the perfluorinated [AlF 6 ] group to design deep-ultraviolet zero-order waveplate materials

    Dalton Transactions · 2025-01-01

    Shaohua Liu, Lili Zhang, Ke Li, Xiaotian Ma, Xifa Long, Yun Mo Yang

    Read original paper ↗ ·
  15. Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups

    Journal of Materials Chemistry C · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·
  16. La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence

    Inorganic Chemistry · 2025-05-01

    Pengfei Li, Xiaoxue Wang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  17. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  18. A Preliminary Study on Artificial Intelligence-Based Camouflage Pattern Generation Method

    Journal of big data and computing. · 2025-06-01

    Qi Jia, Y. G. Li

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  19. [C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy

    Chinese Journal of Chemistry · 2025-06-24

    Shaohua Liu, Xiaoqin Ma, Xifa Long, Yun Mo Yang

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  20. (C 4 H 8 N 5 )(PhPHO 2 )·H 2 O: a polar ionic cocrystal with strong second-harmonic generation and high birefringence

    Journal of Materials Chemistry C · 2026-01-01

    Peng Zhuang, Bing‐Ping Yang, Jiang‐Gao Mao

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  21. MAlB3O6F2 (M = Ca and Pb): Two New Fluoroaluminoborates Featuring π-Conjugated [BO3] and [AlO4F2] Units with Large Birefringence

    Crystal Growth & Design · 2026-10-02

    Yaozu Li, Chao Wei, Wenjing Zhang, Huiyi Zhang, Bo Zhao, Bingbing Zhang, Ying Wang

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