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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2023

Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)

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Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)OriginalA defect pyrochlore-like acentric cubic lead titanium-tellurate crystal exhibiting strong second harmonic generation activity and an extended transparent window4Rb 8 Nb 10 Ge 6 O 41 : a new niobium-germanate crystal featuring unique one-dimensional [Nb 7 O 30 ] ∞ chains and wide mid-IR transparency2Three in one: a cadmium bismuth vanadate NLO crystal exhibiting a large second-harmonic generation response and enhanced birefringence12Li13YGe4O16: A Mid-infrared Rare-Earth Germanate Nonlinear Optical Crystal Featuring a Broad Transmission Range and an Enlarged Band Gap10From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials9From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials50La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra4K4Cd3Ge4O13: A Congruent-Melting Germanate Nonlinear Optical Crystal with a Moderate Second-Harmonic Generation Intensity and Broad Transparent Window2A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy22A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy5La3Ga5HfO14: Rare-Earth Polyhedron Coupled with Structural Protected Octahedron for Designing Nonlinear Optical Material with Wide Bandgap and Well-Balanced Properties5Sr2CdGe3O9: A Potential Zero-Order Waveplate Crystal Featuring an Enlarged Bandgap and Extended Mid-Infrared Transparency1Unveiling the hidden potential of gallic acid: A multifaceted study of its physical and optical properties3Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals5A promising mid-infrared nonlinear optical crystal with well-balanced properties0K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response1

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  1. A defect pyrochlore-like acentric cubic lead titanium-tellurate crystal exhibiting strong second harmonic generation activity and an extended transparent window

    Inorganic Chemistry Frontiers · 2024-01-01

    Tinghui Zhang, Lili Li, Jing Chai, Haitao Zhou, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  2. Rb 8 Nb 10 Ge 6 O 41 : a new niobium-germanate crystal featuring unique one-dimensional [Nb 7 O 30 ] ∞ chains and wide mid-IR transparency

    Dalton Transactions · 2024-01-01

    Jing Chai, Yuheng She, Jinmiao Jiao, Lili Li, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  3. Three in one: a cadmium bismuth vanadate NLO crystal exhibiting a large second-harmonic generation response and enhanced birefringence

    Inorganic Chemistry Frontiers · 2024-01-01

    Shuya Liu, Conggang Li, Jinmiao Jiao, Yuheng She, Tinghui Zhang, Dianxing Ju, Ning Ye, Zhanggui Hu, Yicheng Wu

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  4. Li13YGe4O16: A Mid-infrared Rare-Earth Germanate Nonlinear Optical Crystal Featuring a Broad Transmission Range and an Enlarged Band Gap

    Inorganic Chemistry · 2024-02-15

    Jinmiao Jiao, Conggang Li, Yuheng She, Haiyan Shi, Wenhao Di, Ning Ye, Zhanggui Hu, Yicheng Wu

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  5. From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials

    Angewandte Chemie · 2024-03-13

    Yuwei Kang, Can Yang, Jie Gou, Yaolong Zhu, Qingwen Zhu, Weilin Xu, Qi Wu

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  6. From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2024-03-13

    Yuwei Kang, Can Yang, Jie Gou, Yaolong Zhu, Qingwen Zhu, Weilin Xu, Qi Wu

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  7. La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra

    Inorganic Chemistry · 2024-07-25

    Jingxuan Hou, Jiajia Wang, Fei Liang, Shihui Ma, Hongwei Yu, Hongping Wu, Ning Ye, Zhanggui Hu, Yicheng Wu

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  8. K4Cd3Ge4O13: A Congruent-Melting Germanate Nonlinear Optical Crystal with a Moderate Second-Harmonic Generation Intensity and Broad Transparent Window

    Inorganic Chemistry · 2024-09-30

    Yujun Wang, Jing Chai, Jinmiao Jiao, Xianghao Kong, Tinghui Zhang, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  9. A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy

    Angewandte Chemie International Edition · 2025-02-11

    Qi‐Chang Song, Chun‐Li Hu, Fang Kong, Fang Kong, Jiang‐Gao Mao

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  10. A Wide Band Gap Germanate with the Largest Second Harmonic Generation Response Created by Hypoxic Strategy

    Angewandte Chemie · 2025-02-11

    Qi‐Chang Song, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  11. La3Ga5HfO14: Rare-Earth Polyhedron Coupled with Structural Protected Octahedron for Designing Nonlinear Optical Material with Wide Bandgap and Well-Balanced Properties

    Inorganic Chemistry · 2025-06-03

    Jingxuan Hou, Dingxuan Zhao, Zifan Xu, Shihui Ma, Jiajia Wang, Hongwei Yu, Guang Peng, Ning Ye, Zhanggui Hu

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  12. Sr2CdGe3O9: A Potential Zero-Order Waveplate Crystal Featuring an Enlarged Bandgap and Extended Mid-Infrared Transparency

    Inorganic Chemistry · 2025-09-26

    Yujun Wang, Peng Zhao, Xianghao Kong, Tinghui Zhang, Ning Ye, Zhanggui Hu, Conggang Li

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  13. Unveiling the hidden potential of gallic acid: A multifaceted study of its physical and optical properties

    International Journal of Modern Physics B · 2025-11-17

    M. Keerthana, R.S. Priyadharshini, M Saravanan

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  14. Tailoring ordered structures with distorted [TeO 3 ] and aligned [ScO 6 ] motifs for balanced nonlinear optical properties in rare-earth tellurate crystals

    Chemical Science · 2025-11-18

    Xiaoxu Wang, Tinghui Zhang, Huijian Zhao, Ning Jia, Hongjun Liu, Ning Ye, Zhanggui Hu, Conggang Li

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  15. A promising mid-infrared nonlinear optical crystal with well-balanced properties

    Inorganic Chemistry Frontiers · 2026-01-01

    Yujun Wang, Yuning Qi, Yongkuan Xu, Ning Ye, Zhanggui Hu, Conggang Li

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  16. K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response

    Inorganic Chemistry · 2026-03-12

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu, Yongmin Guo

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