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RESEARCH PAPER · Inorganic Chemistry · 2023

Noncentrosymmetric γ-Cs2I4O11 Obtained from IO4 Polyhedral Rearrangements in the Centrosymmetric β-Phase

Mingli Liang, Matthew R. Lacroix, Ce Tao, Michael J. Waters, James M. Rondinelli, P. Shiv Halasyamani

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Noncentrosymmetric γ-Cs2I4O11 Obtained from IO4 Polyhedral Rearrangements in the Centrosymmetric β-PhaseOriginal[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology20(NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence22A survey of stereoactive oxysalts for linear and nonlinear optical applications40NaMoO 3 (IO 3 )(H 2 O): water molecule introduction induces strong second harmonic generation response, widened band gap and large anisotropy8First-principles screening of metal–organic frameworks for entangled photon pair generation5Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates13Chiral Bimetallic Cuprous-Lead Hybrid Iodide Single Crystals toward Occurrence of Second Harmonic Generation3Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups11Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification6Multifactorial Directed Regulation Of the [Io 3 ] − Units in Praseodymium-Contained Iodates0Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching19Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching0Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions5Multifactorial directed regulation of anionic units in praseodymium-contained iodates1Second‐Harmonic‐Generation Circular‐Dichroism in Chiral Perovskite Single Crystals Enhanced by Self‐Trapped Excitonic State12Halogenated Metal–Organic Frameworks for Entangled Photon Pair Generation0

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  1. [M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology

    Inorganic Chemistry Frontiers · 2023-01-01

    Qianqian Chen, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

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  2. (NH 4 ) 2 (I 5 O 12 )(IO 3 ) and K 1.03 (NH 4 ) 0.97 (I 5 O 12 )(IO 3 ): Mixed‐Valent Polyiodates with Unprecedented I 5 O 12 − Unit Exhibiting Strong Second‐Harmonic Generation Responses and Giant Birefringence

    Small · 2023-07-25

    Nan Ma, Jin Chen, Bingxuan Li, Chun‐Li Hu, Jiang‐Gao Mao

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  3. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  4. NaMoO 3 (IO 3 )(H 2 O): water molecule introduction induces strong second harmonic generation response, widened band gap and large anisotropy

    Dalton Transactions · 2023-12-06

    Yi Shui, Zhengli Liang, Zhenhua Li, Jiahao Wan, Lehui Liu, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  5. First-principles screening of metal–organic frameworks for entangled photon pair generation

    Materials for Quantum Technology · 2024-02-23

    S. Shanmuga Sundara Raj, Simón Paiva, Rubén A. Fritz, Felipe Herrera, Yamil J. Colón

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  6. Lanthanide Contraction Eliminates Disorder while Holding Robust Second Harmonic Generation in a Series of Polyiodates

    Chemistry of Materials · 2024-10-04

    Zhenhua Li, Yi Shui, Zhengli Liang, Lehui Liu, Jiahao Wan, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  7. Chiral Bimetallic Cuprous-Lead Hybrid Iodide Single Crystals toward Occurrence of Second Harmonic Generation

    Inorganic Chemistry · 2024-12-02

    Danping Chen, Peihan Wang, Yanqing Liu, Guokui Liu, Jing Wei, Yongshen Zheng, Yangyang Dang

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  8. Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups

    Journal of Materials Chemistry C · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  9. Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification

    Dalton Transactions · 2025-01-01

    Pengfei Li, Xinlei Liu, Si-Qi Zhou, Mingchang Wang, Jingjing Wu, Yu‐Wu Zhong, Jiannian Yao

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  10. Multifactorial Directed Regulation Of the [Io 3 ] − Units in Praseodymium-Contained Iodates

    SSRN Electronic Journal · 2025-01-01

    Ping Wang, Zhengli Liang, Zhenhua Li, Quanjie Yang, Lehui Liu, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  11. Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching

    Angewandte Chemie International Edition · 2025-03-31

    Min-Quan Lin, Chun‐Li Hu, M. Duan, Bingxuan Li, Jiang‐Gao Mao, Bing‐Ping Yang

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  12. Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching

    Angewandte Chemie · 2025-03-31

    Min-Quan Lin, Chun‐Li Hu, M. Duan, Bingxuan Li, Jiang‐Gao Mao, Bing‐Ping Yang

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  13. Cs2CdV2O6Br2: A Mid-Infrared Nonlinear Optical Vanadate Containing Both d0/d10 Transition Metal Cations and Bromine Anions

    Inorganic Chemistry · 2025-06-30

    Lei Geng, Baozhu Zhu, You‐Zhao Lan, Chang‐Yu Meng, Qi Wu

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  14. Multifactorial directed regulation of anionic units in praseodymium-contained iodates

    Journal of Molecular Structure · 2025-09-01

    Ping Wang, Zhengli Liang, Zhenhua Li, Quanjie Yang, Lehui Liu, Lehui Liu, Xingxing Jiang, Hongming Liu, Hongming Liu

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  15. Second‐Harmonic‐Generation Circular‐Dichroism in Chiral Perovskite Single Crystals Enhanced by Self‐Trapped Excitonic State

    Advanced Functional Materials · 2025-09-07

    Jinhui Yu, Min Li, Yicong Lv, Bowen Liao, Guangrong Tan, Jinyu Zou, Xitao Liu, Yibo Han, Liang Li

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  16. Halogenated Metal–Organic Frameworks for Entangled Photon Pair Generation

    Chemistry of Materials · 2025-12-14

    Wilson R. Raney, Yamil J. Colón

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