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RESEARCH PAPER · Angewandte Chemie International Edition · 2017

ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide Bandgap

Hongming Liu, Qi Wu, Xingxing Jiang, Zheshuai Lin, Xiang‐Gao Meng, Xingguo Chen, Jingui Qin

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ABi2(IO3)2F5 (A=K, Rb, and Cs): A Combination of Halide and Oxide Anionic Units To Create a Large Second‐Harmonic Generation Response with a Wide BandgapOriginalCrystal Growth and Optical Properties of Beryllium-Free Nonlinear Optical Crystal K3Ba3Li2Al4B6O20F35A cation size effect on the framework structures in ABi 2 SeO 3 F 5 (A = K and Rb): first examples of alkali metal bismuth selenite fluorides14Effects of dopants on the adhesion and electronic structure of a SnO 2 /Cu interface: a first-principles study15Influence of A-site cations on germanium iodates as mid-IR nonlinear optical materials: A 2 Ge(IO 3 ) 6 (A = Li, K, Rb and Cs) and BaGe(IO 3 ) 6 ·H 2 O43Pb 3 (SeO 3 )Br 4 : a new nonlinear optical material with enhanced SHG response designed via an ion-substitution strategy36Non-Centrosymmetric RbNaMgP 2 O 7 with Unprecedented Thermo-Induced Enhancement of Second Harmonic Generation239Co‐Crystals of 2‐Amino‐5‐Nitropyridine Barbital with Extreme Birefringence and Large Second Harmonic Generation Effect32Combination of d 10 -cations and fluorine anion as active participants to design novel borate/carbonate nonlinear optical materials24Nonbonding Electrons Driven Strong SHG Effect in Hg2GeSe4: Experimental and Theoretical Investigations60Assisting the Effective Design of Polar Iodates with Early Transition-Metal Oxide Fluoride Anions206Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24Second-order nonlinear optical crystals with mixed anions250Rational Design of a LiNbO3-like Nonlinear Optical Crystal, Li2ZrTeO6, with High Laser-Damage Threshold and Wide Mid-IR Transparency Window152Excellent Infrared Nonlinear Optical Crystals BaMO(IO3)5 (M = V, Ta) Predicted by First Principle Calculations9Recent advances and future perspectives on infrared nonlinear optical metal halides223Ce(IO3)2F2⋅H2O: The First Rare‐Earth‐Metal Iodate Fluoride with Large Second Harmonic Generation Response66A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions137A Facile Route to Nonlinear Optical Materials: Three‐Site Aliovalent Substitution Involving One Cation and Two Anions23(H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer19Centrosymmetric K 2 SO 4 ·(SbF 3 ) 2 and noncentrosymmetric Rb 2 SO 4 ·(SbF 3 ) 2 resulting from cooperative effects of lone pair and cation size63Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity19Investigation into the optimized growth, anisotropic properties and theoretical calculations of the polar material Cs 2 TeW 3 O 128Pb 7 F 12 Cl 2 : a promising infrared nonlinear optical material with high laser damage threshold19RbSbSO 4 Cl 2 : an excellent sulfate nonlinear optical material generated due to the synergistic effect of three asymmetric chromophores79Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence34Synthesis and structure of a new mixed metal iodate Ba 3 Ga 2 (IO 3 ) 1217Synthesis, structure and characterization of M(IO 3 ) 2 (HIO 3 ) (M = Ca, Sr) as new anhydrous alkaline earth metal bis-iodate hydrogeniodate compounds16BaV2O6·H2O: A nonlinear optical crystal with a large bandgap7Crystallographic Investigations into the Polar Polymorphism of BaTeW2O9: Phase Transformation, Controlled Crystallization, and Linear and Nonlinear Optical Properties26Two Non-π-Conjugated Deep-UV Nonlinear Optical Sulfates268New cadmium-selenium-oxyhalides: Noncentrosymmetric Cd5(SeO3)4Cl2(H2O) and centrosymmetric Cd2(SeO3)F2, Cd2(SeO3)(OH)Br17Refractive Index Modulates Second-Harmonic Responses in RE 8 O(CO 3 ) 3 (OH) 15 X (RE = Y, Lu; X = Cl, Br): Rare-Earth Halide Carbonates as Ultraviolet Nonlinear Optical Materials37Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses67Cs3Na(H2C3N3O3)4·3H2O: A Mixed Alkali‐Metal Hydroisocyanurate Nonlinear Optical Material Containing π‐Conjugated Six‐Membered‐Ring Units68KBiCl2SO4: The First Bismuth Chloride Sulfate Being Second-Order Nonlinear Optical Active44REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion125REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion62Synthesis and Crystal Structure of a New Iodate (Pb0.6Ba0.4)(Pb0.4Ba0.6)[IO3]4 Analogous to Sr[IO3]22LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO398LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO337First-Principles Design and Simulations Promote the Development of Nonlinear Optical Crystals299K5(W3O9F4)(IO3): An Efficient Mid-Infrared Nonlinear Optical Compound with High Laser Damage Threshold114(NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior92(NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior11Abnormal bandgap enlargement resulted in a promising mid-infrared nonlinear optical material Rb 2 CdBrI 3 with an ultrahigh laser damage threshold10Bi 4 O(I 3 O 10 )(IO 3 ) 3 (SeO 4 ): trimeric condensation of IO 4 3− monomers into the I 3 O 10 5− polymeric anion observed in a three-component mixed-anion NLO material20From BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation14From centrosymmetric to noncentrosymmetric: intriguing structure evolution in d 10 -transition metal iodate fluorides36Helix-constructed polar rare-earth iodate fluoride as a laser nonlinear optical multifunctional material25Polar polymorphism: α- and β-KCsWP 2 O 9 nonlinear optical materials with a strong second harmonic generation response25A Promising Fluorooxoborate Framework with Flexibile Capability for Diverse Cations to Enhance the Second Harmonic Generation14Rational Design of the Nonlinear Optical Response in a Tin Iodate Fluoride Sn(IO3)2F290Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials164Lead Mixed Oxyhalides Satisfying All Fundamental Requirements for High‐Performance Mid‐Infrared Nonlinear Optical Materials55ZnIO3F: Zinc Iodate Fluoride with Large Birefringence and Wide Band Gap57K2Na(IO3)2(I3O8) with Strong Second Harmonic Generation Response Activated by Two Types of Isolated Iodate Anions46Ba(IO3)F: An Alkaline-Earth-Metal Iodate Fluoride Crystal with Large Band Gap and Birefringence24New Alkaline-Earth Metal Fluoroiodates Exhibiting Large Birefringence and Short Ultraviolet Cutoff Edge with Highly Polarizable (IO 3 F) 2– Units63High Coordinate Metal Iodate Chlorides with Diverse Structural Motifs and Tunable Birefringence10Ba2[MoO3(OH)(IO3)2]IO3: A Promising SHG Material Featuring a Λ-Shaped Functional Motif Achieved by Universal Mono-Site Substitution50A 2 Bi 2 (SeO 3 ) 3 F 2 (A = K and Rb): Excellent Mid-Infrared Nonlinear Optical Materials with Both Strong SHG Responses and Large Band Gaps64Pb 18 O 8 Cl 15 I 5 : A Polar Lead Mixed Oxyhalide with Unprecedented Architecture and Excellent Infrared Nonlinear Optical Properties165Pb18O8Cl15I5: A Polar Lead Mixed Oxyhalide with Unprecedented Architecture and Excellent Infrared Nonlinear Optical Properties29Recent Advances in Oxide‐based Nonlinear Optical Materials with Wide Infrared Transparency Beyond 6 μm38From Ag2Zr(IO3)6 to LaZr(IO3)5F2: A Case of Constructing Wide‐band‐gap Birefringent Materials through Chemical Cosubstitution11Stuffed Tridymite Structures: Synthesis, Structure, Second Harmonic Generation, Optical, and Multiferroic Properties14Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95[GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution42AgBi(SO 4 )(IO 3 ) 2 : aliovalent substitution induces structure dimensional upgrade and second harmonic generation enhancement37Ba 2 [FeF 4 (IO 3 ) 2 ]IO 3 : a promising nonlinear optical material achieved by chemical-tailoring-induced structure evolution8Barium fluoroiodate crystals with a large band gap and birefringence22NaGaI 3 O 9 F: a new alkali metal gallium iodate combined with IO 3 − and IO 3 F 2− units16Pb 2 TiFO(SeO 3 ) 2 Br: a new polar compound with the strongest second harmonic generation in the selenite bromide family29Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap26SrTi(IO 3 ) 6 ·2H 2 O and SrSn(IO 3 ) 6 : distinct arrangements of lone pair electrons leading to large birefringences11Unexpected aliovalent cation substitution between two NLO materials LiBa 3 Bi 6 (SeO 3 ) 7 F 11 and Ba 3 Bi 6.5 (SeO 3 ) 7 F 10.5 O 0.518Na3Bi(IO3)6: An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition11A Polar Material with Facility of Crystal Growth and a Large Second-Harmonic Generation Response3A Deep‐UV Nonlinear Optical Borosulfate with Incommensurate Modulations71A Deep‐UV Nonlinear Optical Borosulfate with Incommensurate Modulations13Cd3(IO3)(IO4)F2·0.1CdO: A Nonlinear-Optical Crystal with the Introduction of Fluoride into Iodate Containing Both [IO3]− and [IO4]3– Groups18A New Anhydrous Polar Rare-Earth Iodate Fluoride, Ce(IO3)2F2, Exhibiting a Large Second-Harmonic-Generation Effect and Improved Overall Performance35CsZrF4(IO3): The First Polar Zirconium Iodate with cis-[ZrO2F6] Polyhedra Inducing Optimized Balance of Large Band Gap and Second Harmonic Generation47Be2(BO3)(IO3): The First Anion‐mixed Van der Waals Member in the KBe2BO3F2 Family with a Very Strong Second Harmonic Generation Response130Be2(BO3)(IO3): The First Anion‐mixed Van der Waals Member in the KBe2BO3F2 Family with a Very Strong Second Harmonic Generation Response8A2MoO2F3(IO2F2) (A = Rb, Cs): Strong Nonlinear Optical Responses and Enlarged Band Gaps through Fluorine Incorporation50Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]10Chemical substitution – oriented design of a new polar PbFIO3 achieving a balance between large second-harmonic generation response and wide band gap16AMoO3(IO3) (A = Na and K): Two promising optical materials via properly assembling the Λ-shaped basic building units19A new I 3 O 9 3− group constructed from IO 3 − and IO 5 5− anion units in Cs 3 [Ga 2 O(I 3 O 9 )(IO 3 ) 4 (HIO 3 )]4M4O(IO3)3(I3O7F3)BF4 (M = Pb, Sr): Promising Nonlinear Optical Materials Featuring the Unprecedented Windmill-Shaped [I3O7F3]2– Polyfluoroiodate Anion12K 3 V 2 O 3 F 4 (IO 3 ) 3 : a high-performance SHG crystal containing both five and six-coordinated V 5+ cations33Investigations on the Synthesis, Crystal Structure, Linear- and Nonlinear-Optical Properties of the Zinc Germanate Rb2ZnGe2O627Ba 4 Ag 5 (IO 3 ) 6 (I 3 O 8 ) 3 (I 4 O 11 ) 2 : a nonlinear optical crystal containing two types of polyiodate anions16BaI 3 O 9 H: a new alkaline-earth metal hydroxy iodate with two groups2CaCe(IO 3 ) 3 (IO 3 F)F: a promising nonlinear optical material containing both IO 3 − and IO 3 F 2− anions22Cs 2 VOF 4 (IO 2 F 2 ): Rationally designing a noncentrosymmetric early-transition-metal fluoroiodate24Metal oxyhalides: an emerging family of nonlinear optical materials124Unprecedented boat-shaped [Mo 2 O 5 (IO 3 ) 4 ] 2− polyanions induced a strong second harmonic generation response31HgSO4: An excellent mid-infrared sulfate nonlinear optical crystal with wide band gap and strong second harmonic generation response19Polar lanthanide copper iodates LnCu(IO3)5 (Ln = La, Ce, Pr, and Nd): Synthesis, crystal structure and characterization6Cs2Bi2OSi2O7: A Promising Bismuth Silicate Nonlinear Optical Crystal with Face-Sharing BiO5 Polyhedra Exhibiting Strengthened Second Harmonic Generation Response and Birefringence43Synthesis, crystal structure and optical properties of the first bromine-containing iodate: Pb2IO3Br30RbBiP2S6: A Promising IR Nonlinear Optical Material with a Giant Second-Harmonic Generation Response Designed by Aliovalent Substitution80NH4IO2F2 and (NH4)3(IO2F2)3·H2O: A Series of Ammonium-Containing Fluoroiodates with Wide Band Gaps12MIO 3 F (M = Co and Ni): Magnetic Iodate Fluorides with Zigzag Chains16Synthesis and Crystal Structure of Fluoride K2(Ta0.9I0.1)F7 with the Micro-Isomorphic Substitution in the Ta Cationic Position0Ce 3 F 4 (SO 4 ) 4 : cationic framework assembly for designing polar nonlinear optical material through fluorination degree modulation23Recent advances in F-containing iodate nonlinear optical materials6Polar Bismuth Selenite Iodate Oxide BiSeIO6 with Three Types of Lone Pair Cations in One Structure6CsHfF4(IO3): A Hafnium Iodate Exhibiting a Strong Second-Harmonic-Generation Effect and a Wide Band Gap Achieved by Mixed-Ligand Acentric Coordination8A review on the advancements in the characterization of the high-pressure properties of iodates44Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials53Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials5ε-La(IO3)3: A Polar Iodate with High Thermal Stability and a Large Second-Harmonic-Generation Response Obtained by a Supercritical Hydrothermal Method8Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit38Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit1A survey of stereoactive oxysalts for linear and nonlinear optical applications40Two Noncentrosymmetric Bismuth Phosphates: Rational Design Synthesis and Optical Properties4LiGa(IO3)4: An Excellent NLO Material with Unprecedented 2D [Ga(IO3)4]∞− Layer Synthesized by Aliovalent Substitution20Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence6Chromium iodate: the structure and origin of optical second harmonic generation1From NaGa(IO3)3F to NaGa(IO3)2F2 and NaGa(IO3)4: The Effects of Chemical Substitution between F– Anions and IO3– Groups on the Structures and Properties of Gallium Iodates13Hydrothermally synthesized first acentric apatite (Bi 5 Na 5 )[PO 4 ] 6 Cl 2 with wide Bi–Na isomorphism and doubled c -axis3From ZnF2 to ZnF2(H2O)4: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge19A2Pb3[H2N(CH2COO)2]3Cl5 (A = K, Rb): Porous Crystals Constructed on [Pb3Cl5O6] Clusters with Comprehensive Nonlinear Optical Performance3Anhydrous Aluminum Iodate: Strong Second Harmonic Generation Effect Contributed by Unbonded and Antibonding Orbitals3From Pb6(HPO3)(H2PO3)Cl9 to Pb6(HPO3)2Br8(H2O)·H2O: Halogen Regulation to Achieve Inorganic Metal Phosphite Halide Nonlinear Optical Material with Unprecedented Pb-Centered Polyhedral Units13(C10N2H10)(HI2O6)(HIO3)(IO3): A Birefringent Material Featuring Large π-Conjugated Organic Cation and Two Types of Iodate Anions2SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap8Rare-Earth/d10 Dual-Metal Oxychalcogenides as Infrared Nonlinear-Optical Materials10Cd 5 Te 4 O 12 X 2 (X = Cl, Br, I): a new oxyhalide family with [CdO 4 X] mixed anionic units and adjustable optical properties4Deep-ultraviolet sulfamate halides with halogen-centered secondary building units for enhanced optical anisotropy4Different p-block elements induce C 3 [111] octahedral distortion in titanium to generate an intense nonlinear effect14A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response3Metal Chloride‐Iodate Nonlinear Optical Materials via Direct Chlorination of Centrosymmetric Metal Iodate Crystals0Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials10KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy7Breaking Layered Limitations via Electrostatic-to-Covalent Conversion toward Three-Dimensional T2-Cluster-Based Chalcogenides7IO3–-Mediated Short-Range Magnetic Order in 2D Honeycomb LiFe(IO3)2F20

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  32. Refractive Index Modulates Second-Harmonic Responses in RE 8 O(CO 3 ) 3 (OH) 15 X (RE = Y, Lu; X = Cl, Br): Rare-Earth Halide Carbonates as Ultraviolet Nonlinear Optical Materials

    Chemistry of Materials · 2019-03-12

    Liling Cao, Yunxia Song, Guang Peng, Min Luo, Yi Jin Yang, Chensheng Lin, Dan Zhao, Feng Xu, Zheshuai Lin, Ning Ye

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  33. Two Polar Molybdenum(VI) Iodates(V) with Large Second-Harmonic Generation Responses

    Chemistry of Materials · 2019-03-29

    Yahui Li, Guopeng Han, Hongwei Yu, Hao Li, Zhihua Yang, Shilie Pan

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  34. Cs3Na(H2C3N3O3)4·3H2O: A Mixed Alkali‐Metal Hydroisocyanurate Nonlinear Optical Material Containing π‐Conjugated Six‐Membered‐Ring Units

    European Journal of Inorganic Chemistry · 2019-04-08

    Xianghe Meng, Fei Liang, Jian Tang, Kaijin Kang, Qian Huang, Wenlong Yin, Zheshuai Lin, Mingjun Xia

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  35. KBiCl2SO4: The First Bismuth Chloride Sulfate Being Second-Order Nonlinear Optical Active

    Crystal Growth & Design · 2019-06-06

    Zeng-Hao Yue, Zhen‐Tao Lu, Huaiguo Xue, Sheng‐Ping Guo

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  36. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie International Edition · 2019-06-18

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiao‐Han Zhang, Jiang‐Gao Mao

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  37. REI5O14 (RE=Y and Gd): Promising SHG Materials Featuring the Semicircle‐Shaped I5O143− Polyiodate Anion

    Angewandte Chemie · 2019-06-18

    Jin Chen, Chun‐Li Hu, Fei‐Fei Mao, Bing‐Ping Yang, Xiaohan Zhang, Jiang‐Gao Mao

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  38. Synthesis and Crystal Structure of a New Iodate (Pb0.6Ba0.4)(Pb0.4Ba0.6)[IO3]4 Analogous to Sr[IO3]2

    Crystallography Reports · 2019-07-01

    Elena L. Belokoneva, Olga Reutova, Olga V. Dimitrova, Anatoly S. Volkov

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  39. LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO3

    Angewandte Chemie International Edition · 2019-09-20

    Ying‐Jie Jia, Yi-Gang Chen, Yao Guo, Xiao‐Fang Guan, Chengbo Li, Bingxuan Li, Minmin Liu, Xian‐Ming Zhang

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  40. LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO3

    Angewandte Chemie · 2019-09-20

    Ying‐Jie Jia, Yi-Gang Chen, Yao Guo, Xiao‐Fang Guan, Chengbo Li, Bingxuan Li, Min‐Min Liu, Xian‐Ming Zhang

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  41. First-Principles Design and Simulations Promote the Development of Nonlinear Optical Crystals

    Accounts of Chemical Research · 2019-10-29

    Lei Kang, Fei Liang, Xingxing Jiang, Zheshuai Lin, Chuangtian Chen

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  42. K5(W3O9F4)(IO3): An Efficient Mid-Infrared Nonlinear Optical Compound with High Laser Damage Threshold

    Chemistry of Materials · 2019-12-04

    Chao Wu, Lin Lin, Xingxing Jiang, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, P. Shiv Halasyamani, Chi Zhang

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  43. (NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior

    Angewandte Chemie International Edition · 2019-12-09

    Huixin Fan, Chensheng Lin, Kaichuang Chen, Guang Peng, Bingxuan Li, Ge Zhang, Xifa Long, Ning Ye

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  44. (NH4)Bi2(IO3)2F5: An Unusual Ammonium‐Containing Metal Iodate Fluoride Showing Strong Second Harmonic Generation Response and Thermochromic Behavior

    Angewandte Chemie · 2019-12-09

    Huixin Fan, Chensheng Lin, Kaichuang Chen, Guang Peng, Bingxuan Li, Ge Zhang, Xifa Long, Ning Ye

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  45. Abnormal bandgap enlargement resulted in a promising mid-infrared nonlinear optical material Rb 2 CdBrI 3 with an ultrahigh laser damage threshold

    Journal of Materials Chemistry C · 2020-01-01

    Qi Wu, Xian Liu, Yeshuang Du, Chunlin Teng, Fei Liang

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  46. Bi 4 O(I 3 O 10 )(IO 3 ) 3 (SeO 4 ): trimeric condensation of IO 4 3− monomers into the I 3 O 10 5− polymeric anion observed in a three-component mixed-anion NLO material

    Dalton Transactions · 2020-01-01

    Fei‐Fei Mao, Jinyu Hu, Bingxuan Li, Hua Wu

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  47. From BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation

    CrystEngComm · 2020-01-01

    Xian Liu, Can Yang, Qi Wu, Juan Sun, Fei Liang

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  48. From centrosymmetric to noncentrosymmetric: intriguing structure evolution in d 10 -transition metal iodate fluorides

    Chemical Communications · 2020-01-01

    Liling Cao, Min Luo, Chensheng Lin, Yuqiao Zhou, Dan Zhao, Tao Yan, Ning Ye

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  49. Helix-constructed polar rare-earth iodate fluoride as a laser nonlinear optical multifunctional material

    Chemical Science · 2020-01-01

    Guang Peng, Yi Jin Yang, Tao Yan, Dan Zhao, Bingxuan Li, Ge Zhang, Zheshuai Lin, Ning Ye

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  50. Polar polymorphism: α- and β-KCsWP 2 O 9 nonlinear optical materials with a strong second harmonic generation response

    Journal of Materials Chemistry C · 2020-01-01

    Tuohetijiang Baiheti, Shujuan Han, Abudukadi Tudi, Zhihua Yang, Shilie Pan

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