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RESEARCH PAPER · Chemical Science · 2024

HgBr 2 : an easily growing wide-spectrum birefringent crystal

Ming‐Shu Zhang, Wen‐Dong Yao, Shao‐Min Pei, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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HgBr 2 : an easily growing wide-spectrum birefringent crystalOriginalReconstructing nearly isotropic microstructures to construct a one-dimensional framework causing record birefringence in thiophosphates13Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals66Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals8Novel antimony-based mixed halides exhibiting an excellent SHG response and a broad transmission range20Hg4InS2Cl5: Achieving Giant Optical Anisotropy by Introducing Well‐Aligned Linear [Hg2S2] Units14(C 6 H 5 N 2 )HgCl 3 : Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution38“All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy29A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals9Co-ligand tuning of MOF structural anisotropy for giant optical birefringence7Design of a high-performance infrared birefringent crystal Ba 4 HgP 2 Se 10 via a low-dimensional motif intercalation strategy2Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups12Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification6Hydrogen bonding regulation-oriented design of pyridine sulfonate as a promising UV birefringent crystal characterized by enhanced structural anisotropy11BaFS: Birefringence Enhanced by the Transformation from Optical Isotropy to Anisotropy via Interlayer Anion Substitution8From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal4From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal28Na2MP3O9 (M = K, Rb): Two Potential Zero-Order Waveplate Materials with DUV Cutoff Edges2Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence8Recent progress in structural design strategies of high-birefringence optical crystals54Planar [HgCl 3 ] and V‑Shaped [HgCl 2 ] Units Synergistically Creating a Prominent Halide Birefringent Crystal β ‐CsHg 2 Cl 5 with Wide‐Spectrum7Controlling d10 Metal in Phenylthiourea‐Based Hybrid Metal Halides to Actualize Dimensional Transformation and Significantly Improve the Birefringence11Low‐Dimensional Organic–Inorganic Hybrid Metal Halide with Large Optical Anisotropy9[HgX 2 ] Linear Group Enabled Ultraviolet Birefringent Crystal RbHg 5 Br 11 with Strong Optical Anisotropy and Wide Bandgap12Dual-tuning birefringence in hybrid crystals via Cd/Zn metal center and organic ligand isomerism0Polarization optical metrology for linear birefringence in transparent anisotropic medium0Pyrazinamide–IBr: an organic–inorganic hybrid crystal exhibiting giant optical anisotropy0[Hg3Se2]2- cluster drives giant optical anisotropy and broad infrared transparency16Investigation of anisotropic optical and acousto-optic properties of Hg2Br2 crystals1Cd[C(NH 2 ) 2 O] 2 Cl 2 : A Urea-Based Open-Framework Crystal with Concurrent Short UV Cutoff Edge and Large Birefringence1Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals11Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5Zr/Br-doped UIO-type core-shell MOF via organic functional grafting for elemental mercury removal0Unlocking Structural Anisotropy by Guest-Symmetry Modulation Strategy to Achieve Giant Birefringence in Molecular Crystals0Revisiting Bugarszky’s 1895 Chemical Equilibrium Study: Mercury Speciation Correction, Temperature-Corrected Thermodynamics, and Improved Accuracy with Sodium Bromide0From High Symmetry to High Symmetry: A Self‐Assembly Strategy for Synthesizing Large Birefringent Borates0Entropy‐Driven Precursor Symmetry Breaking for Phase‐Selective Synthesis of Noncentrosymmetric Rb 2 CdCl 2 I 20Cation-Modulated Activation of Linear Units in an Ordered Arrangement Achieves the Largest Optical Anisotropy in Wide-Bandgap Metal Chalcogenides0Domino‐Effect Amplification via Covalent‐Chain Engineering for Giant Birefringence in NaAsQ 2 (Q = S, Se) Crystals0

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38 direct citing papers saved.

  1. Reconstructing nearly isotropic microstructures to construct a one-dimensional framework causing record birefringence in thiophosphates

    Chemical Science · 2024-01-01

    Lin‐Tao Jiang, Xiao‐Ming Jiang, Yuhang Fan, Bin‐Wen Liu, Guo‐Cong Guo

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  2. Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals

    Angewandte Chemie International Edition · 2024-06-26

    Yang Li, Kang Min Ok

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  3. Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals

    Angewandte Chemie · 2024-06-26

    Yang Li, Kang Min Ok

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  4. Novel antimony-based mixed halides exhibiting an excellent SHG response and a broad transmission range

    Inorganic Chemistry Frontiers · 2024-12-05

    Luli Wang, Han Luo, Siyu Chen, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  5. Hg4InS2Cl5: Achieving Giant Optical Anisotropy by Introducing Well‐Aligned Linear [Hg2S2] Units

    Advanced Optical Materials · 2024-12-13

    Qixian Ren, Yu Chu, Wenqi Jin, Mengmeng Chen, Cui Chen, Yabo Wu, Shilie Pan

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  6. (C 6 H 5 N 2 )HgCl 3 : Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution

    Advanced Optical Materials · 2024-12-30

    Ru‐Ling Tang, Die‐Xue Yang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  7. “All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy

    Chemical Science · 2025-01-01

    Ru‐Ling Tang, Yi‐Lei Lv, Liang Ma, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo

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  8. A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals

    Inorganic Chemistry Frontiers · 2025-01-01

    Yi‐Lei Lv, Liang Ma, Guo-Ren Zhu, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  9. Co-ligand tuning of MOF structural anisotropy for giant optical birefringence

    Chemical Communications · 2025-01-01

    Svyatoslav A. Povarov, Ekaterina D Iukhnevich, Pavel V. Alekseevskiy, Dmitry I. Pavlov, Аndrei S. Potapov, Irina D. Yushina, Valentin A. Milichko, Alena N. Kulakova

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  10. Design of a high-performance infrared birefringent crystal Ba 4 HgP 2 Se 10 via a low-dimensional motif intercalation strategy

    Dalton Transactions · 2025-01-01

    Zhihui Xiong, Haotian Tian, Zhixi Li, Guowei Deng, Fang Ding, Qian Wu, Mingjun Xia

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  11. Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups

    Inorganic Chemistry Frontiers · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

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  12. Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification

    Dalton Transactions · 2025-01-01

    Pengfei Li, Xinlei Liu, Si-Qi Zhou, Mingchang Wang, Jingjing Wu, Yu‐Wu Zhong, Jiannian Yao

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  13. Hydrogen bonding regulation-oriented design of pyridine sulfonate as a promising UV birefringent crystal characterized by enhanced structural anisotropy

    Chemical Science · 2025-01-01

    Longyun Xu, Conggang Li, Shuaifeng Li, Huijian Zhao, Xianghao Kong, Zaixin Qu, Wen-Jie Feng, Ke Xu, Ning Ye, Zhanggui Hu

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  14. BaFS: Birefringence Enhanced by the Transformation from Optical Isotropy to Anisotropy via Interlayer Anion Substitution

    Small · 2025-01-14

    Chao‐Hong Xie, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  15. From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal

    Angewandte Chemie · 2025-02-22

    Xinyang Li, Xiyue Cheng, Chun‐Li Hu, Bingxuan Li, Zhengyang Zhou, Jian‐Han Zhang, Shuiquan Deng, Jiang‐Gao Mao, Fang Kong

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  16. From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal

    Angewandte Chemie International Edition · 2025-02-22

    Xin‐Yang Li, Xiyue Cheng, Chun‐Li Hu, Bingxuan Li, Zhengyang Zhou, Jian‐Han Zhang, Shuiquan Deng, Jiang‐Gao Mao, Fang Kong

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  17. Na2MP3O9 (M = K, Rb): Two Potential Zero-Order Waveplate Materials with DUV Cutoff Edges

    Inorganic Chemistry · 2025-03-04

    Huanhuan Zhao, Chenxu Li, Yi Huang, Qun Jing, Xuebin Yu, Zhaohui Chen

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  18. Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence

    Chemistry - A European Journal · 2025-04-07

    Yang Li, Jihyun Lee, Kang Min Ok

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  19. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  20. Planar [HgCl 3 ] and V‑Shaped [HgCl 2 ] Units Synergistically Creating a Prominent Halide Birefringent Crystal β ‐CsHg 2 Cl 5 with Wide‐Spectrum

    Advanced Optical Materials · 2025-06-03

    Yi‐Lei Lv, Ru‐Ling Tang, Cheng Chen, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  21. Controlling d10 Metal in Phenylthiourea‐Based Hybrid Metal Halides to Actualize Dimensional Transformation and Significantly Improve the Birefringence

    Advanced Optical Materials · 2025-07-20

    Yi‐Lei Lv, Ru‐Ling Tang, Liang Ma, Cheng Chen, Wenlong Liu, Sheng‐Ping Guo

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  22. Low‐Dimensional Organic–Inorganic Hybrid Metal Halide with Large Optical Anisotropy

    Advanced Optical Materials · 2025-08-05

    Siyu Li, Yakun Zhang, Dongxue Sun, Baoli Gao, Bingbing Zhang, Daqing Yang, Ying Wang

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  23. [HgX 2 ] Linear Group Enabled Ultraviolet Birefringent Crystal RbHg 5 Br 11 with Strong Optical Anisotropy and Wide Bandgap

    Advanced Science · 2025-09-09

    Yingtai Du, Wangfei Che, Yunfei Shi, Juanjuan Lu, Xiaodong Zhou, Ting Liu, Shilie Pan, Junjie Li

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  24. Dual-tuning birefringence in hybrid crystals via Cd/Zn metal center and organic ligand isomerism

    Dalton Transactions · 2026-01-01

    Yaoguo Shen, Xinyi Wang, Mengqing Wu, Yiman Yang, Lingxin Yan

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  25. Polarization optical metrology for linear birefringence in transparent anisotropic medium

    Light Advanced Manufacturing · 2026-01-01

    Shiwei Deng, Xunda Chang, Kerong Jiao, Kewu Li, Xin Xu, Yifan Wang, Jiayu Wang, Hua Shen, Yidong Tan

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  26. Pyrazinamide–IBr: an organic–inorganic hybrid crystal exhibiting giant optical anisotropy

    Dalton Transactions · 2026-01-01

    Meng-Fan Duan, Jiang‐Gao Mao, Bing‐Ping Yang

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  27. [Hg3Se2]2- cluster drives giant optical anisotropy and broad infrared transparency

    Nature Communications · 2026-01-06

    Qixian Ren, Chen Cui, Xinchen Chen, Yabo Wu, Ran An, Zhihua Yang, Shilie Pan

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  28. Investigation of anisotropic optical and acousto-optic properties of Hg2Br2 crystals

    Journal of Alloys and Compounds · 2026-03-01

    Zhongjie Yue, Zhaoqing Miao, Jian Song, Zhongjun Zhai, Xue Sun, Hongjie Liu, Xilong Wang, Chongjun He, Xutang Tao, Guodong Zhang

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  29. Cd[C(NH 2 ) 2 O] 2 Cl 2 : A Urea-Based Open-Framework Crystal with Concurrent Short UV Cutoff Edge and Large Birefringence

    Inorganic Chemistry · 2026-03-03

    Chenyuan Ma, Xin-Mei Zeng, Jia-Tong Li, Xing-Yu Bi, Zhi Gang Fang, Meihong Duan

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  30. Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals

    Journal of the American Chemical Society · 2026-03-05

    Chong‐An Chen, Yang Li, Congcong Jin, S. D. Lee, Zhihua Yang, Kang Min Ok

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  31. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  32. Zr/Br-doped UIO-type core-shell MOF via organic functional grafting for elemental mercury removal

    Journal of Physics and Chemistry of Solids · 2026-04-25

    Litao Zhang, Ping He, Jiang Wu, Naichao Chen, Xingyu Cao, Wenchu Yuan, Zhengyu Liu, Xiao Zhang, Runyao Ma

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  33. Unlocking Structural Anisotropy by Guest-Symmetry Modulation Strategy to Achieve Giant Birefringence in Molecular Crystals

    Journal of the American Chemical Society · 2026-06-16

    Chao‐Hong Xie, Yuan-Feng Li, Bin‐Wen Liu, Guo‐Cong Guo

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  34. Revisiting Bugarszky’s 1895 Chemical Equilibrium Study: Mercury Speciation Correction, Temperature-Corrected Thermodynamics, and Improved Accuracy with Sodium Bromide

    Inorganics · 2026-07-20

    Zoltán Köntös

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  35. From High Symmetry to High Symmetry: A Self‐Assembly Strategy for Synthesizing Large Birefringent Borates

    Small · 2026-08-03

    Chunjie Shen, Junwei Feng, Zhihua Yang, Shilie Pan, Feng Zhang

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  36. Entropy‐Driven Precursor Symmetry Breaking for Phase‐Selective Synthesis of Noncentrosymmetric Rb 2 CdCl 2 I 2

    Advanced Optical Materials · 2026-08-17

    Sheng Lv, Liangcheng Song, Yanling Xu, Jiahao Zhou, Chongqiang Zhu, Chunhui Yang

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  37. Cation-Modulated Activation of Linear Units in an Ordered Arrangement Achieves the Largest Optical Anisotropy in Wide-Bandgap Metal Chalcogenides

    Chemistry of Materials · 2026-09-09

    Wen‐Dong Yao, Xiao Huang, Qiu-Yang Du, Xu‐Bin Ni, Wenlong Liu, Sheng‐Ping Guo

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  38. Domino‐Effect Amplification via Covalent‐Chain Engineering for Giant Birefringence in NaAsQ 2 (Q = S, Se) Crystals

    Laser & Photonics Review · 2026-09-24

    Bo Zhang, Weiqi Huang, Yang Chi, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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