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RESEARCH PAPER · Angewandte Chemie · 2024

Halogen Bond Unlocks Ultra‐High Birefringence

Jin Chen, Miao‐Bin Xu, Huai‐Yu Wu, Jun‐Yan Wu, Ke‐Zhao Du

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Halogen Bond Unlocks Ultra‐High BirefringenceOriginalSupramolecular Polymerization of Pseudo[2]rotaxanes Formation of per ‐Imidazole Pillar[5]arene‐based Host–Guest Complexations and Halogen Bonding Interactions1“All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy29A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals9Significant enhancement in the birefringence of metal phosphite halides via the introduction of π-conjugated cations17Unearthing Hydrogen Bonded Metal‐Free Crystal with Remarkable Optical Anisotropy9Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering4Giant Birefringence Induced by Intermolecular Aromatic Interactions in Hydrogen‐Bonded Organic Frameworks37Five-Membered [C 5 O 5 ] 2 – Rings as Birefringence-Active Genes for Ultrabirefringent Crystals27On-Surface Photodissociation Control within Magic-Sized Nanoclusters by Halogen Bonding3Overcoming the Bandgap‐Birefringence Trade‐Off: Proton‐Transfer Engineering of High‐Performance Ultraviolet‐Transparent Organic Crystal5Lock‐and‐Key Assembly Enables Record Birefringence in Monocyclic π‐Conjugated Crystals via Spatial Confinement of Linear Polyhalide0A Programmable Luminescent Sensing Platform via Site‐Selective Modular Installation in Metal–Organic Frameworks1Designing Novel Solar‐Blind Ultraviolet Nonlinear Optical Crystals Based on Local Proton Distribution Complementary Effect0A Dynamic Hydrogen‐Bonded Organic Framework With Giant OFF–ON Birefringence0

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  1. Supramolecular Polymerization of Pseudo[2]rotaxanes Formation of per ‐Imidazole Pillar[5]arene‐based Host–Guest Complexations and Halogen Bonding Interactions

    ChemistrySelect · 2024-11-01

    Zhengxiang Li, C.‐W. F. CHENG, Kaixuan Wang, Dezhi Zhao, Qing-Guo Meng, Chengyou Han

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  2. “All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy

    Chemical Science · 2025-01-01

    Ru‐Ling Tang, Yi‐Lei Lv, Liang Ma, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  3. A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals

    Inorganic Chemistry Frontiers · 2025-01-01

    Yi‐Lei Lv, Liang Ma, Guo-Ren Zhu, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  4. Significant enhancement in the birefringence of metal phosphite halides via the introduction of π-conjugated cations

    Chemical Science · 2025-01-01

    Ru‐Ling Tang, Yue Wang, Yi‐Lei Lv, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo

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  5. Unearthing Hydrogen Bonded Metal‐Free Crystal with Remarkable Optical Anisotropy

    Advanced Optical Materials · 2025-04-11

    Lin Qiu, Liang Ma, Wenlong Liu, Yuanyuan Sun, Ru‐Ling Tang

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  6. Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering

    Crystal Growth & Design · 2025-06-24

    Xiang Mao, Yu Yan, Yingzi Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  7. Giant Birefringence Induced by Intermolecular Aromatic Interactions in Hydrogen‐Bonded Organic Frameworks

    Advanced Materials · 2025-08-29

    Yayong Sun, Hongyuan Sha, Yanqiang Li, Yayu Yan, Weiqi Huang, Tao Ouyang, Liyang Qin, Siwen Zhang, Hao Huang, Qiaohong Li, Sangen Zhao, Chao He, Rongjian Sa, Jianguo Zhang, Tianhua Zhou

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  8. Five-Membered [C 5 O 5 ] 2 – Rings as Birefringence-Active Genes for Ultrabirefringent Crystals

    Journal of the American Chemical Society · 2025-09-16

    Jiachen Lu, Yang Li, Kang Min Ok

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  9. On-Surface Photodissociation Control within Magic-Sized Nanoclusters by Halogen Bonding

    ACS Nano · 2025-10-31

    Daniel P. Miller, Cord Bertram, Ishita Kemeny, Scott Simpson, Eva Zurek, U. Bovensiepen, Karina Morgenstern

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  10. Overcoming the Bandgap‐Birefringence Trade‐Off: Proton‐Transfer Engineering of High‐Performance Ultraviolet‐Transparent Organic Crystal

    Angewandte Chemie · 2026-03-05

    Lin Qiu, Xing‐Yu Li, Bing-Wei Miao, Hongjian Yu, Wenlong Liu, Yifan Sun, Ru‐Ling Tang

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  11. Lock‐and‐Key Assembly Enables Record Birefringence in Monocyclic π‐Conjugated Crystals via Spatial Confinement of Linear Polyhalide

    Angewandte Chemie · 2026-05-26

    Yun‐Xia Hu, Huai Yu Wu, Jia‐jia Li, Ming‐Chang Wang, Jia‐Min Lian, Jin Yu Luo, Yiru Fu, Zi‐Yan Chen, Yang‐Hang Guo, Jin Chen, Ke‐Zhao Du

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  12. A Programmable Luminescent Sensing Platform via Site‐Selective Modular Installation in Metal–Organic Frameworks

    Angewandte Chemie · 2026-07-15

    Zongsu Han, Kun‐Yu Wang, Zhaoyi Liu, Jiatong Huo, Joshua Rushlow, Yihao Yang, Rong‐Ran Liang, Hong-Cai “Joe” Zhou

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  13. Designing Novel Solar‐Blind Ultraviolet Nonlinear Optical Crystals Based on Local Proton Distribution Complementary Effect

    Angewandte Chemie · 2026-08-11

    Hongyuan Sha, Dongling Yang, Lilin Yang, Fan Xiao, Xiaoming Yang, Lingfei Lv, Chao He, Zhihua Yang, Fangfang Zhang, Zujian Wang, Xifa Long

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  14. A Dynamic Hydrogen‐Bonded Organic Framework With Giant OFF–ON Birefringence

    Angewandte Chemie · 2026-09-04

    Christopher A.G. Halliwell, M.R.J. Elsegood, Qiang Zhu, Shaun Fowler, Sandra Míguez‐Lago, Kenny Jolley, Deobrat Singh, Raquel Lizárraga, Antonio Fernández

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