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RESEARCH PAPER · Chemical Communications · 2022

A 2 B 6 O 9 F 2 (A = NH 4 , K): new members of A 2 B 6 O 9 F 2 family with deep-UV cutoff edges and moderate birefringence

Zilong Chen, Zi‐Jian Li, Dongdong Chu, Fangfang Zhang, Xiaojing Li, Zhihua Yang, Xifa Long, Shilie Pan

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A 2 B 6 O 9 F 2 (A = NH 4 , K): new members of A 2 B 6 O 9 F 2 family with deep-UV cutoff edges and moderate birefringenceOriginalLow temperature molten salt synthesis of noncentrosymmetric (NH 4 ) 3 SbF 3 (NO 3 ) 3 and centrosymmetric (NH 4 ) 3 SbF 4 (NO 3 ) 234Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials24Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge14Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups8PbTeB 4 O 9 : a lead tellurium borate with unprecedented fundamental building block [B 4 O 10 ] and large birefringence12NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges6Two Short-Wave UV Beryllium Selenites Exhibiting Diverse Optical Properties Stemming from Functional Group Arrangements8NH4Y(SO4)2·H2O and NH4YSO4F2: Two New Ammonium‐Rare Earth Metal Sulfates with Enhanced Optical Anisotropy and Deep Ultraviolet Transmission3Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)12K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family4Expanding silver fluorooxoborate crystal chemistry: Ag 2 B 5 O 8 F with 3D double interpenetrating frameworks and Ag 3 B 5 O 8 F 2 with 2D layers5Size effect of cations in the A2B3O4F3 family: Based on the new member Cs2B3O4F34Three Cases of Borates with Different Dimensional Frameworks Induced by Metal Cations1Non-equivalent terminating roles of hydroxyl and fluorine in hydroxy/fluorooxo-borate optical functional materials2Topological structural chemistry of fluorooxoborates: From fundamental building blocks to macroscopic optical performance regulation0Linear [ICl 2 ] Units Induced Giant Optical Anisotropy in AICl 2 (A = NH 4 , Rb): A Pathway to Advanced Birefringent Materials4Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)0

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  1. Low temperature molten salt synthesis of noncentrosymmetric (NH 4 ) 3 SbF 3 (NO 3 ) 3 and centrosymmetric (NH 4 ) 3 SbF 4 (NO 3 ) 2

    Inorganic Chemistry Frontiers · 2023-01-01

    Qin Wang, Jinxuan Ren, Dan Wang, Liling Cao, Xuehua Dong, Ling Huang, Daojiang Gao, Guohong Zou

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  2. Fluorooxoborates: A precious treasure of deep-ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-02-03

    Hongkang Su, Ziting Yan, Xueling Hou, Min Zhang

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  3. Ba2B9O13F4·BF4: first fluorooxoborate with unprecedented infinite [B18O26F8] tubes and deep-ultraviolet cutoff edge

    Science China Chemistry · 2023-02-23

    Huan Pei, Xuefei Wang, Jie Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  4. Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups

    ACS Omega · 2023-06-02

    Yu Dang, Jingdong Yan, Xueling Hou, Hongsheng Shi

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  5. PbTeB 4 O 9 : a lead tellurium borate with unprecedented fundamental building block [B 4 O 10 ] and large birefringence

    Chemical Communications · 2023-11-28

    Ruonan Zhang, Abudukadi Tudi, Xia Yang, Xuping Wang, Zhihua Yang, Shujuan Han, Shilie Pan

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  6. NaRbB10O14(OH)4 and Na3CsB10O16(OH)2: Two Cases of Hydroxyborates with [B5Om(OH)n] Units and Deep Ultraviolet Cutoff Edges

    Inorganic Chemistry · 2024-04-24

    Huanhuan Zhao, Die Xu, Zhaohui Chen

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  7. Two Short-Wave UV Beryllium Selenites Exhibiting Diverse Optical Properties Stemming from Functional Group Arrangements

    Inorganic Chemistry · 2024-05-23

    Yurui Wang, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

    Read original paper ↗ ·

  8. NH4Y(SO4)2·H2O and NH4YSO4F2: Two New Ammonium‐Rare Earth Metal Sulfates with Enhanced Optical Anisotropy and Deep Ultraviolet Transmission

    Crystal Research and Technology · 2024-07-19

    Luyong Zhang, Shibin Wang, Zhencheng Wu, Xueling Hou, Zhihua Yang, Fangfang Zhang, Shilie Pan

    Read original paper ↗ ·

  9. Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)

    Chemistry of Materials · 2024-11-25

    Huan Pei, Luyong Zhang, Huanhuan Cheng, Shi‐Bin Wang, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  10. K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family

    Inorganic Chemistry · 2024-12-19

    Wencong Li, Zhaowei Hu, Yanyan Ding, Yueting Zhu, Qun Jing, Lili Liu

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  11. Expanding silver fluorooxoborate crystal chemistry: Ag 2 B 5 O 8 F with 3D double interpenetrating frameworks and Ag 3 B 5 O 8 F 2 with 2D layers

    Dalton Transactions · 2025-01-01

    Sergey N. Volkov, Xia Yang, Vadim E. Kireev, A. M. Banaru, Shujuan Han, Alevtina N. Gosteva, M. Yu. Arsent’ev, Dmitri O. Charkin, Alexey V. Povolotskiy, Yevgeny E. Savchenko, Maria Georgievna Krzhizhanovskaya, Stepan A. Vorobiev, Yulia A. Vaitieva, Sergey M. Aksenov, Fangfang Zhang

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  12. Size effect of cations in the A2B3O4F3 family: Based on the new member Cs2B3O4F3

    Materials Today Chemistry · 2025-03-06

    Bingliang Cheng, Wenjuan Ma, Abudukadi Tudi, Fangfang Zhang, Xifa Long, Shilie Pan, Yun Mo Yang

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  13. Three Cases of Borates with Different Dimensional Frameworks Induced by Metal Cations

    Inorganic Chemistry · 2025-03-06

    Zilong Chen, Bingliang Cheng, Abudukadi Tudi, Xiaojing Li, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  14. Non-equivalent terminating roles of hydroxyl and fluorine in hydroxy/fluorooxo-borate optical functional materials

    Science China Chemistry · 2025-06-03

    Huanhuan Cheng, Shilie Pan, Zhihua Yang

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  15. Topological structural chemistry of fluorooxoborates: From fundamental building blocks to macroscopic optical performance regulation

    Coordination Chemistry Reviews · 2026-05-20

    Wenqing Sun, Congwei Xie, Xueling Hou, Zhihua Yang, Shilie Pan

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  16. Linear [ICl 2 ] Units Induced Giant Optical Anisotropy in AICl 2 (A = NH 4 , Rb): A Pathway to Advanced Birefringent Materials

    Advanced Functional Materials · 2026-05-22

    Du Yinxia, C J Huang, Hongshan Wang, Linan Wang, Z Chen, Miriding Mutailipu, Shilie Pan, J F Li

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  17. Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)

    Inorganic Chemistry · 2026-09-28

    Xiangtian Liu, Bingchen Xiao, Lei Hou, Wencong Li, Wenlong Zhao, Kaixin Yin, Haonan Pei, Xiaonan Li, Zhuangzhuang Dong, Lili Liu

    Read original paper ↗ ·
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